共查询到20条相似文献,搜索用时 93 毫秒
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Kalman滤波-流动注射化学发光法同时测定痕量铌和钽的研究 总被引:3,自引:0,他引:3
流动注射化学发光(Flow injection-chemiluminescence,简称FI-CL)是基于流动注射(FI)进样技术与化学发光(CL)定量分析结合的痕量分析技术,具有仪器简单、操作方便及易于自动化等特点,从而在分析痕量元素方面取得了较大进展,尤其在痕量金属元素快速分析方面更具有优势. 相似文献
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本文研究了应用Ga(没食子酸)-H2O2-OH^-化学发光体系,流动注射技术测定乙醛的条件,如反应介质及其pH值,Ga及H2O2溶液的浓度,温度,试液混合次序与化学发光强度的关系等,选择了流动注射系统的若干参数,所拟定的方法测定乙醛的浓度范围为每mL1.7×10^-3~4.4×10^-7g,相对标准偏差为1.8%(2×10^-5g/mL,乙醛溶液进行11次平行测定)检出限为每mL3.1×10^-8 相似文献
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流动注射化学发光测定水中的苯酚 总被引:4,自引:0,他引:4
基于苯酚对鲁米诺-铁氰化钾化学发光体系有增敏作用,建立起测定苯酚的新方法。苯酚浓度在0.01-10mg/L范围内与化学发光强度呈良好的线性关系,标准曲线为△I=307.44C(mg/L)-36.929(n=9,r^2=0.9983),检出限(3σ)为0.004mg/L,对1mg/L的苯酚进行11次平行测定,相对标准偏差(RSD)为1.06%。本法已用于废水中苯酚的测定。 相似文献
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偶合反应流动注射化学发光测定锆的研究 总被引:1,自引:0,他引:1
基于Zr置换Co-NTA配合物中的Co(Ⅱ)和Co(Ⅱ)催化过氧化氢氧化鲁米诺产生化学发光的反应,建立了偶合反应流动注射化学发光测定锆的新方法。方法的线性范围为1×10^-10-1×10^-7g.ml^-1,检出限为3×10^-11g.ml^-1,方法用于地矿术中锆的测定,结果满意。 相似文献
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基于钒(Ⅳ)对铬(Ⅵ)氧化I-产生I2的诱导作用,和I2氧化鲁米诺产生化学发光的反应,建立了无机偶合反应流动注射化学发光测定痕量钒的新方法。本方法线性范围1×10-6~1×10-2g/L,RSD=2.8%(n=11次,c=8×10-6g/L),检出限为7×10-7g/L。本法用于水样、人发中钒的测定,结果令人满意。 相似文献
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流动注射化学发光传感器测定抗坏血酸 总被引:9,自引:0,他引:9
基于抗坏血酸抑制KMnO4-鲁米诺体系化光反应这一效应,设计出一种简便,快速,灵敏度高的消耗型化学发光抗坏血酸传感器。该传感器线性响应范围为1.0*10^-5-4.0*10^-3g/L;相对标准偏差为2.3%(1.0*10^-4g/L,n=11); 相似文献
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流动注射化学发光同时测定废水中的三价铬和六价铬 总被引:10,自引:4,他引:10
首次将镀铜锌粒作成优良的还原柱,在线还原Cr(Ⅵ)成Cr(Ⅲ),以鲁米诺-H2O2(KBr)体系流动注射化学发光同时测定废水中两种价态的铬。分析速率为60试样/h;线性范围为1.0×10^-5-1.0×10^-9mol/L;测Cr(Ⅲ)及Cr(Ⅵ)的相对标准偏差(n=6)分别为0.37%-4.0%及1.2%-4.4%;测定Cr(Ⅲ)的检出限2.3×10^-11mol/L。测定结果与标准方法无显差 相似文献
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全固定化试剂流动注射化学发光测定铜 总被引:5,自引:3,他引:5
采用离子交换固定法把Luminol(Lu),CN^-固定在阴离子交换树脂上,串入流动注射系统中,当一定量洗脱剂被注入阴离子交换柱时,洗脱下来的Lu和CN^-与分析物Cu^2+发生化学反应,产生化学发光,实现对Cu^2+的在线检测。本法检出限为1.3×10^-9g/mL,线性范围为4.0×10^-9-6.0×10^-6g/mL,RSD为3.4%,单次测定在1min内能完成。已用于井水中铜的测定,结果 相似文献
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流动注射化学发光法测定DL-酪氨酸 总被引:6,自引:1,他引:6
在甲醛存在下 ,高锰酸钾与DL 酪氨酸能够发生化学发光反应 ,产生很强的化学发光。据此采用流动注射技术 ,建立了一种测定DL 酪氨酸的化学发光分析法。方法的检出限为 2 .9× 1 0 - 8g/mL ,相对标准偏差为 1 .5 % ( 1 .0× 1 0 - 6g/mLDL 酪氨酸 ,n =1 1 ) ,线性范围为 1 .0× 1 0 - 7g/mL~ 5 .0× 1 0 - 6g/mL。 相似文献
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Jianxiu Du 《Analytica chimica acta》2003,481(2):239-244
A sensitive and selective flow injection chemiluminescence (CL) method combined with controlled potential electrolysis technique was described for the determination of molybdenum. The method is based on the chemiluminescence reaction of luminol with unstable molybdenum(III) in alkaline solution. The molybdenum(III) was on-line reduced from molybdenum(VI) via controlled potential electrolysis technique using a homemade flow-through carbon electrolytic cell at the potential of −0.6 V (versus Ag/AgCl). The method allows the determination of molybdenum in the 5.0×10−10 to 5.0×10−7 g ml−1 range with a limit of detection (3σ) of 5×10−11 g ml−1 molybdenum. The relative standard deviation is 2.6% for the 1.0×10−9 g ml−1 molybdenum solution in 11 repeated measurements. This method was successfully applied to the determination of molybdenum in water samples. 相似文献
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在NaOH-NaHCO3介质中,铁氰化钾氧化西咪替丁产生快速化学发光反应,0.5 s后发光达到最大,2 s后迅速衰减至零。本文结合流动注射技术,建立了一种化学发光测定西咪替丁的新方法。针对这一快速发光反应,设计了与之相应的管路系统和最短的反应管道来捕捉最大化学发光信号,发光强度与西咪替丁质量浓度在5×10-7~1×10-4g/mL范围内呈线性关系,检出限为1.1×10-7g/mL。对5×10-6g/mL西咪替丁进行11次平行测定,相对标准偏差为1.8%。本法已用于西咪替丁片剂的测定。 相似文献
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流动注射化学发光法测定痕量NO_2~-的研究与应用 总被引:1,自引:0,他引:1
Based on the principle of the reaction of NO2-with I-and formation of I2 in HCl solution,and the chemiluminescence(CL) reaction between luminol and I2 in an alkaline medium.A fairly sensitive,simple and rapid flow-injection analysis-chemiluminescence method for the determina-tion of trace nitrite with the luminal-I——NO2-coupling luminescence system has been developed.Experiment conditions of flow-injection analysis are optimized.When satisfying the condition that Luminol as 4.0×10-4 mol/L,0.7 % KI,0.04 mol/... 相似文献
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Anastasios Economou Demetrius G ThemelisGeorgios Theodoridis Paraskevas D Tzanavaras 《Analytica chimica acta》2002,463(2):249-255
This work reports a novel flow injection (FI) method for the determination of captopril, 1-[(2S)-3-mercapto-2-methylpropionyl]-l-proline (CPL), based on the enhancement CPL affords on the chemiluminescence (CL) reaction between luminol and hydrogen peroxide. For this purpose alkaline luminol and hydrogen peroxide solutions were mixed online, the sample containing CPL was injected into an aqueous carrier stream, mixed with the luminol-hydrogen peroxide stream and pumped into a glass flow cell positioned in front of a photomultiplier tube (PMT). The increase in the CL intensity was recorded in the form of FI peaks, the height of which was related to the CPL mass concentration in the sample. Different chemical and instrumental parameters affecting the CL response were investigated. Under the selected conditions, the log-log calibration curve was linear in the range 5-5000 μg l−1 of CPL, the limit of detection was 2 μg l−1 (at the 3σ level), the R.S.D., sr was 3.1% at the 100 μg l−1 level (n=8) and the sampling rate was 180 injections h−1. The method was applied to the determination of CPL in pharmaceutical formulations with recoveries in the range 100±3%. 相似文献
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Jason W Costin 《Analytica chimica acta》2003,480(1):67-77
The determination of the amino acids proline, histidine, tyrosine, arginine, phenylalanine and tryptophan using flow injection analysis (FIA) with chemiluminescence detection is described. Proline was the only amino acid to exhibit chemiluminescence with the tris(2,2-bipyridyl)ruthenium(III) reaction at pH 10. While, histidine was found to selectively enhance the reaction of luminol with Mn(II) salts in a basic medium. Acidic potassium permanganate chemiluminescence was able to selectively determine tyrosine at pH 6.75. Low pressure separations using a C18 guard column allowed the simultaneous determination of tyrosine and tryptophan or phenylalanine and tryptophan with acidic potassium permanganate and copper(II)-amino acid-hydrogen peroxide chemiluminescence, respectively. Precision for each method was less than 3.9% (R.S.D.) for five replicates of a standard (1×10−5 M) and the detection limits ranged between 4×10−9 and 7×10−6 M. Preliminary investigations revealed that the methodology developed was able to selectively determine the individual amino acids in an equimolar mixture of the 20 naturally occurring amino acids. 相似文献
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