Planar imaging of a laboratory flame and of internal combustion in an automobile engine using UV rayleigh and fluorescence light

Rayleigh scattering of tunable excimer laser light (193 nm and 248 nm) is used to obtain 2-D images of the distribution of total densities in a laboratory flame and in a cylinder of an automobile engine. Because the UV light is very strongly scattered, there is ample signal and there is excellent contrast of Rayleigh light against surface scattered light, even in the small volume of the engine cylinder. The laboratory flame data are converted to an image of the temperature field. The Rayleigh images are compared with those from planar laser induced predissociative fluorescence, which yield state-specific densities of selected molecules. The experimental arrangement is the same except for the selection of laser wavelength and the filtering of the radiated light.     

Stimulated raman pumping to H2 (v″=1, J″=1) and resonance-enhanced multiphoton ionization from it using a single laser

Light pulses from one ArF laser are used both a) to produce H₂ in v=1, J=1 of the X-state by means of stimulated Raman pumping (SRP) and b) to analyze for that state via (2+1) resonance-enhanced multiphoton ionization (REMPI). Both SRP and REMPI have been previously measured in H₂, but with a different laser for each process. Some of our laser light is Raman shifted in H₂. The resulting mixture of fundamental (193 nm) and first Stokes (210 nm) light is focused into low-pressure H₂ where the SRP and REMPI both occur. The SRP is efficient and it produces only v=1, J=1. As the laser is tuned, a REMPI spectrum occurs from excitation by two photons of 193 nm, by two photons of 210 nm, or by one photon each of 210 and 193 nm. The features of this approach are a) that the necessary temporal and spatial overlaps are automatically achieved, b) that the frequency difference generated in the Raman shifter is precisely that needed for SRP, c) that large pulse energies are available for the REMPI, and d) that only one laser is needed.     

Laser FM spectroscopy with photochemical modulation

We have combined the techniques of frequency-modulation spectroscopy (FMS) and photochemical-modulation spectroscopy to carry out high-resolution, high-sensitivity absorption measurements on the formyl and amino radicals. Using the (0,9⁰, 0)-(0,0¹, 0) band of theÃ,² A- ,² A transition of HCO at 614 nm, we obtained a sensitivity limit for absorption of 1.5×10^–6. Reconstructed spectra of several HCO lines are presented.     

Temperature measurement using degenerate four-wave mixing with non-saturating laser powers

We report the use of Degenerate Four-Wave Mixing (DFWM) in the OHA ^{2 +} X ² ( = 0 = 0) band for temperature determination in a propane/air flame using laser powers below the saturation level. We show that at these low power levels the dependence of the signal on the dipole moment for the transition has to be established before meaningful temperature data can be obtained. This presents a paradox in that the temperature has to be known before the form of the dependence on the dipole moment can be determined. Solutions to this paradox are presented. We also show that absorption of the laser beams in this OH band system cannot be neglected and that failure to correctly account for the absorption leads to a large over estimate of the flame temperature. Furthermore, we show that the accuracy of the absorption-corrected temperature is critically dependent on the accuracy with which the measurement position within the flame is known. Finally, the temperature calculated from DFWM spectra using the correct dipole moment power and absorption is compared to the temperatures obtained using Laser-Induced Fluorescence (LIF) and Coherent Anti-Stokes Raman Spectroscopy (CARS).     

Asymptotic completeness for a new class of Stark effect Hamiltonians

Existence and completeness of the wave operators is shown for the Stark effect Hamiltonian in one dimension with a potentialV =W, whereW is a bounded function with four bounded derivatives. This class of potentials include some almost periodic functions and periodic functions with average zero over a period (Stark-Wannier Hamiltonians). In the last section we discuss classical particle scattering for the same class of potentials.Partially supported by NSF-grant DMS-8401748     

Degenerate four-wave-mixing spectroscopy in NaH

We performed DFWM spectroscopy on X ^–1+–A ¹⁺ transitions in NaH produced in an indirect photochemical reaction between Na(3p) and H₂ and detected v=1, 2 and 3 ground state vibrational levels of NaH molecules, whereas with resonance enhanced CARS, we observed v=0 levels only. This different sensitivity can be explained by considering the Franck-Condon-factors and the relevant damping coefficients for the corresponding transitions in the NaH molecule. Time resolved DFWM spectroscopy showed that NaH(v=1) molecules effectively live much longer than Na(3p) atoms which merely follow the laser excitation pulse.     

Identification and imaging of hot O2 (v″=2, 3, or 4) in hydrogen flames using 193 nm- and 210 nm-range light

Some simple molecules can be excited by light within the tuning ranges of ArF (193–194 nm) and KrF (247.8–248.8 nm) excimer lasers and their fluorescence has been previously used for imaging. Additional wavelength ranges should become available by Raman shifting. As a demonstration, we present excitation and fluorescence spectra from hot O₂ obtained (a) with tunable 193 nm-range light and (b) with that light shifted into the 210 nm range. All measurements are via predissociative upper states. In the 193 nm range, results are compared with those of Andresen's group. In the 210 nm range, the light is tuned to various excitation wavelengths in the (5 3), (8 4), and (7 4) bands of the B–X transition. The (7 4) excitations are well separated and the (7 v) fluoresence spectrum is in accord with Franck-Condon calculations. The wavelengths tend to overlap for the (5 3) and (8 4) excitations and the fluorescence is weaker. State-specific two-dimensional fluorescence images of an H₂-O₂ flame are obtained in both wavelength ranges to illustrate the use of the method.We acknowledge the National Science Foundation and the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research     

Effect of hydrogen doping on the magnetic properties of Gd2CuO4

We report the results of ac-susceptibility and dc-magnetization measurements for H_yGd₂CuO₄ (0y0.54). It is shown thatH doping lowers the weak ferromagnetic component in the material. The distinct hysteresis loops observed atT=77 K for both non- and hydrogenated samples change its shape withy. The magnetic ordering temperatures T _N ^Cu and T _N ^Gd , as determined from the temperature dependencies of ac-susceptibility, remain unchanged with sample's hydrogenation. This result seems to indicate that extra electrons are not doped onto the Cu-O planes of Gd₂CuO₄. The frequency dependencies ofx(, T) andx(, T) for bothy=0 andy=0.15 samples are analysed., The maximums ofx andx found at about 200K are considered in terms of susceptibility dependence on the spin-lattice relaxation time (). The anomalies in ac-susceptibility found recently in Gd₂CuO₄ atT _a=8 K andT _b=9.5 K decrease significantly withy. Results are discussed in the context of available data on 214T-type compounds.     

Quantitative one-dimensional single-pulse multi-species concentration and temperature measurement in the lift-off region of a turbulent H2/air diffusion flame

In this article, we report on one-dimensional single-pulse measurements of temperature and major-species concentration (O₂, N₂, H₂O and H₂) in a turbulent H₂/air jet diffusion flame using Raman and Rayleigh scattering of KrF* excimer-laser radiation. Spatial resolution of 0.5 mm along a 6mm long line has been obtained, with reasonable error limits for mole fraction ( = 5 % for N₂ detection) and temperature (T = 8 %) determination at flame temperatures. We present various profiles showing the composition and temperature along a line at different heights in the flame with particular emphasis on the lift-off region (i.e. lowx/D). In this zone, temperature and mixture fraction can be determined simultaneously — from a single laser pulse — in a spatial region extending from unburnt gas in the center of the jet across the flame front into the cool air of the surrounding atmosphere. This allows for the first time the systematic study of the shape and width of the high-temperature region and the corresponding concentration and temperature gradients. The comparison of averaged data and scatter plots with previous pointwise measurements shows good agreement.     

Rotational distribution of nascent OH radicals after H2O2 photolysis at 193 nm

The rotational distribution of OH(X ²,v=0) radicals was investigated by resonant laser-induced fluorescence (LIF) after photolysis of H₂O₂ at 193 nm. A microcomputer equipped LIF arrangement allowed special shot-by-shot normalization of the fluorescence signal for noise reduction. Using a least-squares procedure we were able to account for all measured line intensities including overlapping lines (blends) and obtain a complete rotational state distribution of the OH(X ²,v=0) state. The rotational excitation shows a Gaussian-like distribution with a maximum atK=12 and with 16% of the total available energy (17,400 cm^–1) appearing in rotation. Only 1% of the available energy is converted into vibration, leaving over 83% for translational excitation. The measured rotational distribution appears to fit a semiclassical theory.     

Observed difference between the probabilities of recoilless resonance absorptionf′ and reemissionf″ of gamma-quanta in single crystals of Na2[Fe(CN)5NO]·2 H2O

The recoilless absorption probability factor,f, and recoilless reemission,f, both measured on Na₂[Fe(CN)₅NO]·2 H₂O single crystals using the black filter technique, were found to be different. Unexpectedly, the results found weref>f. In the calculation off, selfabsorption in the scatterer, non-ideality of the black filter and the influence of non-resonant scattering processes have all been taken into account. By varying the scattering geometry for the incoming and outgoing -beam relative to the crystallographic axes only a change in the reemitted valuesf _a, f_b, f_c could be detected because of the long lifetime of the excited nucleus (10^–7 s) relative to the lattice vibration frequencies (10¹² Hz).     

A generalized representation for dielectric dispersion

The generalized formulation for dielectric dispersion is extended for dielectrics exhibiting strongly overlapping arcs in the- complex plane. Subsequently, a novel network representation is developed whereby Negative Impedance Converters (NICs) are employed along with passive R-C elements. Satisfactory agreement is obtained in comparing the experimental results with those calculated using the new formulation.     

A generalized formula to determine the relaxation time distribution in dielectrics

The distribution of relaxation times is derived for dielectrics with constants featuring general functions in the - plane. A simple algorithm to determine the distribution parameters is also suggested. The algebraic method adopted enables translation of the algorithm into software to facilitate an efficient processing of data. The new distribution developed here could have an effective use in studies of dispersion in dielectrics and interfaces.     

Infrared-infrared double-resonance spectra involving fermi perturbed levels and CO stretch band transitions of CD3OH

Infrared-infrared double-resonance spectroscopy has been carried out for CD₃OH. Seven of the observed double resonance signals occur in the congested Q-branch region of the C-O stretch band while one is a transition to an excited torsional state. The signals appear as single signals as opposed to the more regular appearance as pairs. Three of the observed transitions involve excited-state levels which are shifted by Fermi resonance between excited C-O stretch-state levels and levels of high-lying torsional modes of the vibrational ground state. These resonances result in a considerable change in the Stark shift for the excited-state levels compared with unperturbed levels. The a-component _a of the permanent electric-dipole moment value has been determined for several ground-state levels. The average value in the ground state is calculated to be _a =0.918D. The results have allowed the assignment of several previously reported far-infrared laser lines and also confirmed assignments proposed by other workers.     

Two-dimensional commensurate soliton structures

A phase diagram of pinned soliton structures in two dimensions has been found for a repulsive interactionU(x) between solitons withU(x)>0. The critical fugacity of the commensurate soliton structure is shown to be proportional toU(l), wherel is the period of this structure.     

Four-wave mixing in CO via the C 1Σ+ (υ′=0) state

Coherent vacuum ultraviolet (VUV) radiation was generated by four-wave difference frequency mixing (_VUV=2₁–₂) of pulsed dye laser radiation in carbon monoxide (CO). The frequency ₁ was tuned to the C ¹⁺(=0)X ¹⁺(=0) two-photon transition, while the dye laser frequency ₂ was scaned around 17650 cm^–1 which corresponds to the A ¹(=7)«C ¹⁺(=0) transition energy. The VUV intensity was found to be strongly wavelength dependent. The analysis of the spectrum revealed (i) that the VUV intensity was enhanced by the rotational levels of the A ¹(=7) state and (ii) that the off-resonance excitation in the C ¹⁺(=0)X ¹⁺(=0) two-photon transition greatly contributed to the present four-wave mixing process. The effects of pumping laser detuning, saturation and foreign gases are briefly discussed.     

Nonequilibrium phase transitions in stochastic lattice systems: Influence of the hopping rates

Two-dimensional lattice-gas models with attractive interactions and particle-conserving hopping dynamics under the influence of a very large external electric field E along a principal axis are studied in the case of different ratios between the jump rates in the field direction and perpendicular to it using different transition probabilities. We investigate the dependence of the non-equilibrium steady-state properties on the transition mechanism. We find self-similarity with respect to (T, ) and a coexistence curve critical exponent which, for small, seems independent of. There is some evidence that this exponent might be halfway between the equilibrium mean field and Onsager's values. A crossover toward mean-field behavior for large seems also identified.Partially supported by the US-Spanish Cooperative Research Program, Grant CCB-8402025.     

Study of the Anglular Structure of Emission from the Radio Galaxy 3C295 in the Decameter Wavelength Range

We present the results of observations of the angular structure of the radio source 3C295 at decameter waves using the URAN-1 and URAN-2 interferometers. It is shown that the radio image of 3C295 at these frequencies differs drastically from the structure of this object observed at higher frequencies. The simplest model of the structure of this radio galaxy, comprising one component with a Gaussian brightness distribution of angular size (7.4 ± 0.4)× (8.7± 0.4) at 25 MHz and (9.1± 0.5)× (10.6 ± 0.5) at 20 MHz, is determined. A decrease in the spectral density of the emission with decreasing frequency, observed below 50 MHz, is explained.     

The dependence of susceptibility on the high-frequency field at ferromagnetic resonance

The dependence of the uniform precession amplitude and susceptibility at ferromagnetic resonance on the high-frequency fieldh is discussed on the basis of an equation for the energy balance and classical equations for the spin wave amplitudes. The dependence (h) is first determined in the lowest non-linear approximation. According to these calculations, the initial decline of the susceptibility differs from Schlömann's quadratic law. The influence of other nonlinear interactions between spin wavesk0 is then discussed on a certain special assumption of the type of two-magnon scattering. It is shown that such interactions can lead to the appearance of a maximum in the h.f. field dependence of the uniform precession amplitude.     

Gas‐Kinetic Temperature of Planar High‐Frequency Capacitive Discharge Plasma in N2/CO2/He Gas Mixtures

Using methods of emission spectroscopy, we have determined the gaskinetic temperature fields of planar highfrequency capacitive discharge plasma in N₂/CO₂/He gas mixtures depending on the excitation frequency, discharge current, pressure, and chemical composition of the mixture. It is shown that the dominant contribution to the neutral component heating in the center of the discharge chamber is made by the processes of V–T relaxation of vibrationally excited molecules N₂(X ¹, V) and CO₂(X ¹, V), whereas in the zones near the electrodes an important role in the heating is played, along with the V–T relaxation of the N₂(X ¹, V) and CO₂(X ¹, V) molecules, by the processes of deactivation of the metastable states A ³ of the N₂ molecule.