外噪声场对二元混合物相分离的驱动作用

采用蒙特卡罗法研究了外高斯噪声场对二元混合物体系相分离的驱动作用.研究发现，高斯噪声场的引入可以加快体系畴的生长，驱动体系形成沿着［1,1］取向的条状畴结构.在噪声强度一定、噪声作用的概率小于0.015时，高斯噪声场消除了深度淬火引起的体系畴的冻结，畴的生长因子随噪声作用概率线性增加.对足够强的高斯噪声场，存在一个最佳的作用概率区域，其间体系能形成取向性好的条状畴结构. 关键词： 高斯噪声 二元混合物 相分离     

六方密堆二元合金的有序结构

采用晶格气体模型,用密度波理论确定了六方密堆二元合金的10种有序结构类型、14种完全有序结构,并对一些典型实验结果给予解释. 关键词： 六方密堆晶格 二元合金 有序结构 密度波     

HFC混合物二元交互作用系数研究

目前国际上已商业化使用或提出的潜在的环保工质,大多数为氢氟烃(HFC)混合物,利用状态方程描述混合工质热力性质时,交互作用系数是重要参数之一。本文应用Peng-Robinson状态方程对多种HFC二元混合物的气液相平衡(vapor—liquid equilibrium,VLE)实验数据进行了回归,得到了相应混合物的交互作用系数。提出了交互作用系数新关联式,结果表明所得到的交互作用系数能很好的应用于描述HFC混合物气液相平衡性质,计算精度可以满足工程应用的需要。     

微槽内二元混合液体的流动沸腾

1引言微型结构由于其巨大的应用潜力，作为热控制和冷却的有效手段已被引入电子集成电路、生物医学、航天、高效紧凑式与微型换热器、材料加工等现代高新技术领域。由于相交换热能传递更多的热量，微结构中的流动沸腾受到了日益重视。但微通道中流体流动和换热的特性当然与所用工质有关。微通道内液体混合物的流动沸腾至今极少见到公开报道［‘］。彭和王等人l‘－‘］报道了对微通道和微槽结构内单组元液体流动沸腾的研究，发现起始沸腾点所需壁面过热度比常规尺度槽道内的低得多，没有明显的部分核沸腾现象，同时发现微槽尺寸对流动沸腾的…     

一般流体及含超临界组元混合物表面张力密度梯度理论模型

表面张力是非常重要的物性参数之一,特别对于沸腾和凝结换热的计算是必不可少的.但目前的研究成果主要集中于纯物质,对有重要工程应用前景的混合工质研究还很少.本文应用密度梯度理论,结合比容平移后的Peng-Robinson方程建立了混合物的表面张力模型,该模型不含有任何需要表面张力实验数据回归确定的经验可调系数.计算结果表明,本文建立的模型具有很好的通用性和计算精度,能在广泛的温度范围内较好地再现一般流体混合物和含超临界组元混合物的表面张力数据.     

用染料激光增益降低二元混合物中少量化合物的受激拉曼散射可探测浓度

在二元混合物构成的圆形谐振腔中,用染料的激光增益增强了少量化合物(乙醇溶液中的甲醇、水溶液中的乙醇)的受激拉曼散射（SRS）光谱,将少量化合物在悬垂液滴中的瞬态SRS探测极限提高了近一个数量级. 用受激拉曼散射理论,解释了增强少量化合物SRS的机理. 关键词： 受激拉曼散射 染料激光增益 二元混合物 最小可探测浓度     

含醇二元体系表面张力预测模型

表面张力是重要的物性参数之一,与人们的生产生活密切相关.醇类及其混合物具有重要的工业应用价值.含醇混合物作为特殊的缔合体系,由于氢键的存在,性质复杂.本文应用密度梯度理论结合比容平移后的Peng-Robinson状态方程,回归了醇、水纯净物的作用因子关联式系数,建立了混合物的表面张力预测模型,计算了含醇二元缔合体系的表面张力,该模型不含有任何需要混合物表面张力实验数据回归确定的经验可调参数,对绝大多数含醇混合物具有很好的通用性和计算精度.     

高斯白噪声对神经元二维映射模型动力学的影响

从神经元二维映射模型出发，用高斯白噪声模拟了神经元的噪声环境，进而研究了高斯白噪声对参数空间相图的影响.研究发现，噪声可以提高系统的可兴奋性.通过数值模拟研究了噪声引起的相干共振现象.结果表明，只有当系统参数选取在静息区域且接近连续点火和静息状态分界线时才可以得到相干共振现象. 关键词： 高斯白噪声 神经元二维映射模型 相图 相干共振     

HCs/HCs和HCs/CO2二元体系表面张力的预测

表面张力是非常重要的物性之一,本文将比容平移后的PR状态方程和密度梯度理论结合,建立了不依赖于混合物表面张力和气液相平衡实验数据的二元混合物表面张力的纯预测模型。对碳氢/碳氢和碳氢/二氧化碳二元体系的表面张力进行了预测,结果表明,本文模型对两组元碳原子数相差不大或者两组元分子结构满足链状和环状或环状和环状组合的碳氢/碳氢二元体系有较高的预测精度,同时模型对碳氢/二氧化碳二元体系表面张力也有较好的预测能力。     

Nonradiative Relaxation of Thiacarbocyanine Dyes in Binary Mixtures

It was found that preferential solvation of cyanine dyes in binary mixtures can strongly affect both their isomerization and aggregation; the comparison of absorption and fluorescence excitation spectra might be a useful tool for studying these nonradiative processes.     

On the Statistical Mechanics and Surface Tensions of Binary Mixtures

Within a lattice model describing a binary mixture with fixed concentrations of the species we discuss the relationship between the surface tension of the mixture and the concentrations.     

Demixing in Isotropic Binary Mixtures of Rodlike Macromolecules

A binary mixture of long rigid rods of diameters D _i and lengths L _i (i=1, 2) may demix into two isotropic phases, and we give necessary conditions on the molecular size parameters for this transition to exist. These conditions imply that the two diameters must be sufficiently unequal, D ₂/D ₁>( + )², or D ₂/D ₁<( + )², while the length ratio is limited to an interval f _–(D ₂/D ₁)<L ₂/L ₁<f ₊(D ₂/D ₁). The functions f _± are given explicitly.     

Ground-State Properties and Phase Separation of Binary Mixtures in Mesoscopic Ring Lattices

We investigated the spatial phase separation of the two components forming a bosonic mixture distributed in a four-well lattice with a ring geometry. We studied the ground state of this system, described by means of a binary Bose–Hubbard Hamiltonian, by implementing a well-known coherent-state picture which allowed us to find the semi-classical equations determining the distribution of boson components in the ring lattice. Their fully analytic solutions, in the limit of large boson numbers, provide the boson populations at each well as a function of the interspecies interaction and of other significant model parameters, while allowing to reconstruct the non-trivial architecture of the ground-state four-well phase diagram. The comparison with the L-well (L=2,3) phase diagrams highlights how increasing the number of wells considerably modifies the phase diagram structure and the transition mechanism from the full-mixing to the full-demixing phase controlled by the interspecies interaction. Despite the fact that the phase diagrams for L=2,3,4 share various general properties, we show that, unlike attractive binary mixtures, repulsive mixtures do not feature a transition mechanism which can be extended to an arbitrary lattice of size L.     

两元混合物反重力流蒸发传热传质数值研究

近年来微槽内的液体流动和传热受到了广泛关注,成为新的研究热点。本文在对热润湿作用下水平螺旋管表面反重力流形成及其流动特性进行探索的基础上,建立了适用于水平螺旋槽管壁面二元混合物反重力流蒸发传热传质耦合的物理模型。模拟结果表明,由于液膜内部存在着传质,径向有明显的浓度梯度,从而降低了蒸发传热的温度推动力。酒精溶液的浓度越...     

Recapitulating Quantum Phase Space Representation by Virtue of Normally Ordered Gaussian Form of Wigner Operator

Using the normally ordered Gaussian form of the Wigner operator we recapitulate the quantum phase space representation, we derive a new formula for searching for the classical correspondence of quantum mechanical operators; we also show that if there exists the eigenvector ｜q〉λ,v of linear combination of the coordinate and momentum operator, （λQ ＋ vP）, where λ,v are real numbers, and ｜q〉λv is complete, then the projector ｜q〉λ,vλ,v〈q｜ must be the Radon transform of Wigner operator. This approach seems concise and physical appealing.     

Fluctuations-Inclusive Approach to Phase Transitions in Binary Mixtures

The hierarchical reference theory of fluids (HRT) is applied to the study of the phase diagram of binary mixtures of simple fluids. This approach implements the renormalization group machinery into a liquid-state theory in order to systematically deal with the effect of long-range correlations which play a crucial role in the onset of criticality and phase separation. The effect of fluctuations is embodied in a partial differential equation (PDE) for the free energy of the mixture. Recently, a robust numerical algorithm has been developed which enabled us to integrate this PDE on a substantial density mesh even at low temperature, when the coexistence region spreads over most of the density– concentration plane.We have considered a model mixture of spherical particles interacting via a hard-core plus attractive tail potential, and adjusted the particle diameters ₁, ₂ and the strengths of the attractive interactions ₁₁, ₂₂, ₁₂ so as to mimic mixtures of simple fluids such as argon–krypton or neon–krypton. In the latter case the theory reproduces the occurrence of a minimum in the critical temperature (the so-called critical double point) and of immiscibility at high pressure. We have also studied the phase diagram of a symmetric mixture such that ₁= ₂ and ₁₁= ₂₂ as the ratio = ₁₂/ ₁₁ is varied. In particular, we find that, in agreement with the mean-field picture, by decreasing , a critical endpoint occurring at equal species concentration is turned into a tricritical point. An interesting feature of the HRT is that, whenever phase coexistence occurs, the conditions of phase equilibria are implemented by the theory itself, without any need of enforcing them a posteriori. This allows one to straightforwardly map the phase diagram and the critical lines of the mixture.     

H-Point Standard Addition Method (HPSAM) in Simultaneous Spectrophotometric Determination of Binary Mixtures: An Overview

Abstract

The H-point standard addition method (HPSAM) is a modification of the standard addition method that transforms the incorrigible error resulting from the presence of a direct interferent in the determination of an analyte into a constant systematic error. This error can then be evaluated and eliminated. The method was established for resolving strongly overlapping spectra of two analytes and permits both proportional and constant errors produced by the matrix of the sample to be corrected directly. The technique is based on the principle of dual-wavelength spectrophotometry and the standard addition method. The application of the method requires only two wavelengths, and the analytical signal caused by one of the species should be constant and that of the other should differ as much as possible. This overview discusses both the theoretical and practical aspects of HPSAM applications.     

Stationary properties of a single-mode laser system with non-Gaussian and Gaussian noise

A single-mode laser system with non-Gaussian and Gaussian noise is investigated. The stationary mean value and the normalized variance of the laser intensity are numerically calculated under the condition that the stationary probability distribution function (SPDF) is derived. The SPDF as a function of the laser intensity exhibits a maximum. The maximum becomes smaller with the increase of the correlation intensity or the non-Gaussian parameter, where the later is a measure of the deviation from the Gaussian characteristic. The maximum becomes larger as the correlation time increases. The laser intensity stationary mean value decreases with the increase of the correlation intensity or the non-Gaussian parameter while increases with the correlation time increasing. The laser intensity normalized variance increases with the increase of the correlation intensity or the non-Gaussian parameter while decreases as the correlation time increases.     

Ordered Structures of a Few Ions in the Paul Trap

We have carried out a molecular dynamics stimulation for a few Paul-trapped ions exerted by a trapping force, inter-ion Coulomb forces and a damping force from a cooling source. The geometric structure in the ordered phase is studied in detail. It is found that the structure varies regularly with the ion number and forms concentric shells when the ion number grows. Furthermore, the similarity between the ions' structure and the potential of the trap is also presented. Finally, the case in the second stability region is investigated, which gives a comparison with that in the first stability region.