Reservoir transport equations by compositional approach

The objective of this paper is to present an overview of the fundamental equations governing transport phenomena in compressible reservoirs. A general mathematical model is presented for important thermo-mechanical processes operative in a reservoir. Such a formulation includes equations governing multiphase fluid (gas-water-hydrocarbon) flow, energy transport, and reservoir skeleton deformation. The model allows phase changes due to gas solubility. Furthermore, Terzaghi's concept of effective stress and stress-strain relations are incorporated into the general model. The functional relations among various model parameters which cause the nonlinearity of the system of equations are explained within the context of reservoir engineering principles. Simplified equations and appropriate boundary conditions have also been presented for various cases. It has been demonstrated that various well-known equations such as Jacob, Terzaghi, Buckley-Leverett, Richards, solute transport, black-oil, and Biot equations are simplifications of the compositional model.Notation List B reservoir thickness - B formation volume factor of phase - Cⁱ mass of component i dissolved per total volume of solution - C ⁱ mass fraction of component i in phase - C heat capacity of phase at constant volume - C_p heat capacity of phase at constant pressure - D ⁱ hydrodynamic dispersion coefficient of component i in phase - D_MTf thermal liquid diffusivity for fluid f - F = F(x, y, z, t) defines the boundary surface - f_p fractional flow of phase - g gravitational acceleration - H_p enthalpy per unit mass of phase - J_p volumetric flux of phase - k_rf relative permeability to fluid f - k₀ absolute permeability of the medium - M_p ⁱ mass of component i in phase - n porosity - N rate of accretion - P_f pressure in fluid f - p_ca capillary pressure between phases and =p-p - Rⁱ rate of mass transfer of component i from phase to phase - Rⁱ _source source rate of component i within phase - S saturation of phase - s gas solubility - T temperature - t time - U displacement vector - u velocity in the x-direction - v velocity in the y-direction - V volume of phase - V_s velocity of soil solids - W_i body force in coordinate direction i - x horizontal coordinate - z vertical coordinate Greek Letters _p volumetric coefficient of compressibility - _T volumetric coefficient of thermal expansion - _ij Kronecker delta - volumetric strain - _m thermal conductivity of the whole matrix - internal energy per unit mass of phase - gf suction head - density of phase - _ij tensor of total stresses - _ij tensor of effective stresses - volumetric content of phase - f viscosity of fluid f     

Mixed convection flow in narrow vertical ducts

The mixed convection flow in a vertical duct is analysed under the assumption that , the ratio of the duct width to the length over which the wall is heated, is small. It is assumed that a fully developed Poiseuille flow has already been set up in the duct before heat from the wall causes this to be changed by the action of the buoyancy forces, as measured by a buoyancy parameter . An analytical solution is derived for the case when the Reynolds numberRe, based on the duct width, is of 0 (1). This is extended to the case whenRe is 0 (^–1) by numerical integrations of the governing equations for a range of values of representing both aiding and opposing flows. The limiting cases, || 1 andR=Re of 0 (1), andR and both large, with of 0 (R ^1/3) are considered further. Finally, the free convection limit, large with R of 0 (1), is discussed.

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Mischkonvektion in engen senkrechten Rohren

Zusammenfassung Mischkonvektion in einem senkrechten Rohr wird unter der Voraussetzung untersucht, daß das Verhältnis der Rohrbreite zur Länge, über welche die Wand beheizt wird, klein ist. Es wird angenommen, daß sich bereits eine voll entwickelte Poiseuille-Strömung in dem Rohr eingestellt hat, bevor Antriebskräfte, gemessen mit dem Auftriebsparameter , aufgrund der Wandbeheizung die Strömung verändern. Es wird eine analytische Lösung für den Fall erhalten, daß die mit der Rohrbreite als charakteristische Länge gebildete Reynolds-ZahlRe konstant ist. Dies wird mittels einer numerischen Integration der wichtigsten Gleichungen auf den FallRe =f (^–1) sowohl für Gleich- als auch für Gegenstrom ausgedehnt. Weiterhin werden die beiden Grenzfälle betrachtet, wenn || 1 undR=Re konstant ist, sowieR und beide groß mit proportionalR ^1/3. Schließlich wird der Grenzfall der freien Konvektion, großes mit konstantem R, diskutiert.

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Nomenclature g acceleration due to gravity - Gr Grashof number - G modified Grashof number - h duct width - l length of the heated section of the duct wall - p pressure - Pr Prandtl number - Q flow rate through the duct - Q ₀ heat transfer on the wally=0 - Q ₁ heat transfer on the wally=1 - Re Reynolds number - R modified Reynolds number - T temperature of the fluid - T ₀ ambient temperature - T applied temperature difference - u, velocity component in thex-direction - v, velocity component in they-direction - x, co-ordinate measuring distance along the duct - y, co-ordinate measuring distance across the duct - buoyancy parameter - ₀ modified buoyancy parameter, ₀=R ^–1/3 - coefficient of thermal expansion - ratio of duct width to heated length, =h/l - (non-dimensional) temperature - _w applied temperature on the wally=0 - kinematic viscosity - density of the fluid - ₀ shear stress on the wally=0 - ₁ shear stress on the wally=1 - stream function     

Effect of the Nature of the Interaction between a Gas and a Surface on the Relations for the Knudsen Layer in the Case of Strong Evaporation

The effect of the temperature accommodation coefficient _T on the relations at the Knudsen layer edge is investigated for strong evaporation using the moment method. An explicit expression for the dimensionless density as a function of the temperature and the Mach number M is obtained for 0 < _T < 1. For _T = 0 the entire solution is obtained in explicit form. It is shown that for = 0 and a condensation coefficient << 1 the temperature outside the Knudsen layer changes sharply as M varies from 0 to a certain value much less than unity after which the temperature ceases to depend on . For the model of specular reflection of the molecules from the surface the density and the temperature outside the Knudsen layer are found in explicit form as functions of the Mach number.     

New concepts in relative permeabilities at high capillary numbers for surfactant flooding

Flooding oil reservoirs with surfactant solutions can increase the amount of oil that can be recovered. Macroscopic modelling of the process requires relative permeabilities to be functions of saturation and capillary number. With only limited experimental data, relative permeabilities have usually been assumed to be linear functions of saturation at high capillary numbers. The experimental data is reviewed, some of which suggest that this assumption is not necessarily correct. The basis for the assumption is therefore reviewed and it is concluded that the linear model corresponds to microscopically segregated flow in the porous medium. Based on new but equally plausible complementary assumptions about the flow pattern, a mixed flow model is derived. These models are then shown to be limiting cases of a droplet model which represents the mixing scale within the porous medium and gives a physical basis for interpolating between the models. The models are based on physical concepts of flow in a porous medium and so the approach described here represents a significant improvement in the understanding of high capillary number flow. This is shown by the fact that fewer parameters are needed to describe experimental data.Notation A total cross-sectional area assigned to capillary bundle - A ⁽ⁱ⁾ physical cross-sectional area of tube i - c ⁽ⁱ⁾ ordered configurational label for droplets in tube i - c configuration label for tube i (order not considered) - D defined by Equation (26) - E(...) expectation value with respect to the trinomial distribution - S _r ⁽⁾ fractional flow of phase - k absolute permeability - k _r relative permeability of phase - k _r ⁰ endpoint relative permeability of phase - L capillary tube length in bundle model - m ⁽ⁱ⁾ number of droplets of phase a occupying tube i - n exponent for phase a in Equation (2) - N number of droplets in bundle model - N _c capillary number - p pressure - p(c') probability of configuration c - Q ⁽ⁱ⁾ total volume flow rate in tube i - S saturation of phase - S flowing saturation of phase - S _r residual saturation of phase - S _r ⁽⁾ saturations when fractional flow of phase is 1 in the case of varying residual saturations for three-phase flow ( ) - t _c residence time for droplet configuration c - v ⁽ⁱ⁾ total fluid velocity in bundle tube i - , phase label - p pressure differential across capillary bundle - ⁽ⁱ⁾ tube conductivity defined by Equation (7) - viscosity of phase - interfacial tension - gradient operator - ... average over tube droplet configurations     

Parameter determination for thermodynamical models of the pseudoelastic behaviour of shape memory alloy by resistivity measurements and infrared thermography

Two thermodynamical models of pseudoelastic behaviour of shape memory alloys have been formulated. The first corresponds to the ideal reversible case. The second takes into account the hysteresis loop characteristic of this shape memory alloys.Two totally independent techniques are used during a loading-unloading tensile test to determine the whole set of model parameters, namely resistivity and infrared thermography measurements. In the ideal case, there is no difficulty in identifying parameters.Infrared thermography measurements are well adapted for observing the phase transformation thermal effects.Notations 1 austenite 2 martensite - ₍₎ Macroscopic infinitesimal strain tensor of phase - ₍₂₎ ^f Traceless strain tensor associated with the formation of martensite phase - Macroscopic infiniesimal strain tensor - Macroscopic infinitesimal strain tensor deviator - _f Trace - Equivalent strain - ^pe Macroscopic pseudoelastic strain tensor - x Distortion due to parent (austenite =1)product (martensite =2) phase transformation (traceless symmetric second order tensor) - M Total mass of a system - M() Total mass of phase - V Total volume of a system - V() Total volume of phase - z=M(2)/M Weight fraction of martensite - 1-z=M(1)/M Weight fraction of austenite - u ₀ ^* () Specific internal energy of phase (=1,2) - s ₀ ^* () Specific internal entropy of phase - Specific configurational energy - Specific configurational entropy - ₀ ^f (T) Driving force for temperature-induced martensitic transformation at stress free state ( ₀ ^f T) = T ^*–Ts ^*) - Kirchhoff stress tensor - Kirchhoff stress tensor deviator - Equivalent stress - Cauchy stress tensor - Mass density - K Bulk moduli (K ₀=K) - L Elastic moduli tensor (order 4) - E Young modulus - Energetic shear (₀ = ) - Poisson coefficient - M _s ^o (M _F ^o ) Martensite start (finish) temperature at stress free state - A _s ^o (A _F ^o ) Austenite start (finish) temperature at stress free state - C _v Specific heat at constant volume - k Conductivity - Pseudoelastic strain obtained in tensile test after complete phase transformation (AM) (unidimensional test) - ₀ Thermal expansion tensor - r Resistivity - 1MPa 10⁶ N/m ² - ⁽⁾ Specific free energy of phase - _n Specific free energy at non equilibrium (R model) - _n ^eq Specific free energy at equilibrium (R model) - _n ^v Volumic part of ^eq - Specific free energy at non equilibrium (R _L model) - _conf Specific coherency energy (R _L model) - _c Specific free energy at constrained equilibria (R _L model) - _it (T) Coherency term (R _L model)     

Determination of permeability tensors for two-phase flow in homogeneous porous media: Theory

In this paper we continue previous studies of the closure problem for two-phase flow in homogeneous porous media, and we show how the closure problem can be transformed to a pair of Stokes-like boundary-value problems in terms of pressures that have units of length and velocities that have units of length squared. These are essentially geometrical boundary value problems that are used to calculate the four permeability tensors that appear in the volume averaged Stokes' equations. To determine the geometry associated with the closure problem, one needs to solve the physical problem; however, the closure problem can be solved using the same algorithm used to solve the physical problem, thus the entire procedure can be accomplished with a single numerical code.Nomenclature a a vector that maps V onto , m^-1. - A a tensor that maps V onto . - A area of the - interface contained within the macroscopic region, m². - A area of the -phase entrances and exits contained within the macroscopic region, m². - A area of the - interface contained within the averaging volume, m². - A area of the -phase entrances and exits contained within the averaging volume, m². - Bo Bond number (= (=(–)g²/). - Ca capillary number (= v/). - g gravitational acceleration, m/s². - H mean curvature, m^-1. - I unit tensor. - permeability tensor for the -phase, m². - viscous drag tensor that maps V onto V. - ^* dominant permeability tensor that maps onto v , m². - ^* coupling permeability tensor that maps onto v , m². - characteristic length scale for the -phase, m. - l characteristic length scale representing both and , m. - L characteristic length scale for volume averaged quantities, m. - n unit normal vector directed from the -phase toward the -phase. - n unit normal vector representing both n and n . - n unit normal vector representing both n and n . - P pressure in the -phase, N/m². - p superficial average pressure in the -phase, N/m². - p intrinsic average pressure in the -phase, N/m². - p –p , spatial deviation pressure for the -phase, N/m². - r ₀ radius of the averaging volume, m. - r position vector, m. - t time, s. - v fluid velocity in the -phase, m/s. - v superficial average velocity in the -phase, m/s. - v intrinsic average velocity in the -phase, m/s. - v –v , spatial deviation velocity in the -phase, m/s. - V volume of the -phase contained within the averaging volmue, m³. - averaging volume, m³. Greek Symbols V /, volume fraction of the -phase. - viscosity of the -phase, Ns/m². - density of the -phase, kg/m³. - surface tension, N/m. - (v +v ^T ), viscous stress tensor for the -phase, N/m².     

On laminar flow through a uniformly porous pipe

Numerous investigations ([1] and [4–9]) have been made of laminar flow in a uniformly porous circular pipe with constant suction or injection applied at the wall. The object of this paper is to give a complete analysis of the numerical and theoretical solutions of this problem. It is shown that two solutions exist for all values of injection as well as the dual solutions for suction which had been noted by previous investigators. Analytical solutions are derived for large suction and injection; for large suction a viscous layer occurs at the wall while for large injection one solution has a viscous layer at the centre of the channel and the other has no viscous layer anywhere. Approximate analytic solutions are also given for small values of suction and injection.

Nomenclature

General r distance measured radially - z distance measured along axis of pipe - u velocity component in direction of z increasing - v velocity component in direction of r increasing - p pressure - density - coefficient of kinematic viscosity - a radius of pipe - V velocity of suction at the wall - r ²/a ² - R wall or suction Reynolds number, Va/ - f() similarity function defined in (6) - u ₀() eigensolution - U(0) a velocity at z=0 - K an arbitrary constant - B _K Bernoulli numbers Particular Section 5 perturbation parameter, –2/R - ² a constant, –K - x / - g(x) f()/ Section 6 perturbation parameter, –R/2 - ² a constant, –K - g() f() - g _c ()=g() near centre of pipe - * point where g()=0 Section 7 2/R - ² K - t (1–)/ - w(t, ) [1–f(t)]/ - ₀, ₁ constants - g() f()– ₀ - ₀/ - ₀ a constant - * point where f()=0     

Stability characteristics of condensate films

The linear stability theory is used to study stability characteristics of laminar condensate film flow down an arbitrarily inclined wall. A critical Reynolds number exists above which disturbances will be amplified. The magnitude of the critical Reynolds number is in all practical situations so small that a laminar gravity-induced condensate film can be expected to be unstable. Several stabilizing effects are acting on the film flow; at an inclined wall these effects are due to surface tension, gravity and condensation mass transfer.

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Zusammenfassung Mit Hilfe der linearen Stabilitätstheorie werden die Stabilitätseigenschaften laminarer Kondensatfilme an einer geneigten Wand untersucht. Es zeigt sich, daß Kondensatfilme in jedem praktischen Fall ein unstabiles Verhalten aufweisen. Der stabilisierende Einfluß von Oberflächenspannung, Schwerkraft und Stoffübertragung durch Kondensation bewkkt jedoch, daß Störungen in bestimmten Wellenlängenbereichen gedämpft werden.

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Nomenclature c=c^*/u₀ complex wave velocity, celerity, dimensionless - c^*=c _r ^* + i c _i ^* complex wave velocity, celerity, dimensional - c_p specific heat at constant pressure - g gravitational acceleration - h_fg latent heat - k thermal conductivity of liquid - p^* pressure - p=p^*/u₀ ² dimensionless pressure - Pe=Pr Re^* Peclet number - Pr Prandtl number - Re^*=u₀ / Reynolds number (defined with surface velocity) - S temperature perturbation amplitude - t^* time - t=t^* u₀/ dimensionless time - T temperature - T_s saturation temperature - T_w wall temperature - T=T_s-T_w temperature drop across liquid film - u^*, v^* velocity components - u=u^*/u₀ dimensionless velocity components - v=v^*/u₀ dimensionless velocity components - u₀ surface velocity of undisturbed film flow - v _g ^* vapor velocity - x^*, y^* coordinates - x=x^*/ dimensionless coordinates - y=y^*/ dimensionless coordinates Greek Symbols =^* wave number, dimensionless - ^*=2 /^* wave number dimensional - ^* wave length, dimensional - =^*/ wave length, dimensionless - local thickness of undisturbed condensate film - kinematic viscosity, liquid - density, liquid - _g density vapor - surface tension - = (1 +) film thickness of disturbed film, Fig. 1 - stream function perturbation amplitude - angle of inclination Base flow quantities are denoted by^–, disturbance quantities are denoted by.     

Solutions for the anisotropic elastic wedge at critical wedge angles

The classical solution for an isotropic elastic wedge loaded by uniform tractions on the sides of the wedge becomes infinite everywhere in the wedge when the wedge angle 2 equals , 2 or 2_* where tan 2_* = 2_*. When the wedge is loaded by a concentrated couple at the wedge apex the solution also becomes infinite at 2 = 2_*. A similar situation occurs when the wedge is anisotropic except that 2_* is governed by a different equation and depends on material properties. Solutions which do not become infinite everywhere in the wedge are available for isotropic elastic wedges. In this paper we present solutions for the anisotropic elastic wedge at critical wedge angles. The main feature of the solutions obtained here is that they are in a real form even though Stroh's complex formalism is employed.     

Laminar stability analysis of condensate film flow

The linear stability theory is used to study stability characteristics of laminar gravity-induced condensate film flow down an arbitrarily inclined wall. The coupled equations describing the velocity and temperature disturbances are solved numerically. The results show that laminar condensate films are unstable in all practical situations. Several stabilizing effects are acting on the film flow; these are: the angle of inclination, the surface tension at large wave numbers, the condensation rate at small Reynolds numbers, and to a certain extent the Prandtl number. For a vertical plate, the expected wavelengths of the disturbances are presented as functions of the Reynolds numbers of the condensate flow.

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Zusammenfassung Mit Hilfe der linearen StabilitÄtstheorie werden die StabilitÄtseigenschaften laminarer Kondensatfilme an ebenen WÄnden untersucht. Die Gleichungssysteme, die Temperatur- und Geschwindigkeitsstörungen beschreiben, werden numerisch gelöst. Es zeigt sich, da\ Kondensatfilme in jedem praktischen Fall ein unstabiles Verhalten aufweisen. Der stabilisierende Einflu\ von OberflÄchenspannung, Schwerkraft und Stoffübertragung durch Kondensation werden diskutiert. Für eine senkrechte Wand werden die zu erwartenden WellenlÄngen der Störungen als Funktion der Reynoldszahlen des Kondensatfilms angegeben.

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Abrreviations

Nomenclature C^*=C _r ^* + iC _i ^* dimensional complex wave velocity - C=C^*/u₀ dimensionless wave velocity - c_p specific heat at constant pressure - g gravitational acceleration - h_n defined by Eq. (16) - h_fg latent heat - k thermal conductivity - Pe=PrRe Peclet number - Pr Prandtl number - P_y defined by Eq. (15) - q iaPe - Re=u₀ Reynolds number - S temperature disturbance amplitude - t^* dimensional time - t=t^* u₀/ dimensionless time - T dimensional temperature - T_s saturation temperature - T_w wall temperature - T =T_s–T_w temperature drop across liquid film - u^*, v^* dimensional velocity component - v=v^*/u₀ dimensionless velocity components - u₀ dimensional surface velocity of undisturbed film flow - x^*, y^* dimensional coordinates - x=x^*/ dimensionless coordmates - Y_n functional vector defined by Eq. (20) Greek Symbols dimensionless wave number - roots of Eq. (20) - n defined by Eq. (21) - local thickness of undisturbed condensate film - ^* wavelength, dimensional - wavelength, dimensionless - temperature variable - kinematic viscosity of liquid - liquid density - _g vapor density - surface tension - stream function disturbance amplitude - stream function - angle of inclination     

Heat transfer between gas-liquid spray stream flowing perpendicularly to the row of the cylinders

Experimental investigation and analysis of heat transfer process between a gas-liquid spray flow and the row of smooth cylinders placed in the surface perpendicular to the flow has been performed. Among others, there was taken into account in the analysis the phenomenon of droplets bouncing and omitting the cylinder as well as the phenomenon of the evaporation process from the liquid film surface.In the experiments test cylinders were used, which were placed between two other cylinders standing in the row.From the experiments and the analysis the conclusion can be drawn that the heat transfer coefficients values for a row of the cylinders are higher than for a single cylinder placed in the gasliquid spray flow.

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Wärmeübergang an eine senkrecht anf eine Zylinderreihe auftreffende Gas-Flüssigkeits-Sprüh-Strömung

Zusammenfassung Es wurden Messungen und theoretische Analysen des Wärmeübergangs zwischen einer Gas-FlüssigkeitsSprüh-Strömung und den glatten Oberflächen einer Zylinderreihe durchgeführt, die senkrecht zum Sprühstrahl angeordnet waren. Dabei wurde in der Analyse unter anderem das Phänomen betrachtet, daß die Tropfen die Zylinderwand treffen und verfehlen können und daß sich ein Verdampfungsprozeß aus dem flüssigen Film an der Zylinderoberfläche einstellt.Gemessen wurde an einem zwischen zwei Randzylindern befindlichen Zylinder.Die Experimente und die Analyse gestatten die Schlußfolgerung, daß der Wärmeübergangskoeffizient für eine Zylinderreihe höher ist als für einen einzelnen Zylinder in der Sprühströmung.

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Nomenclature a distance between axes of cylinders, m - c _l specific heat capacity of liquid, J/kg K - c _g specific heat capacity of gas, J/kg K - D cylinder diameter, m - g _l mass velocity of liquid, kg/m²s - ¯k average volume ratio of liquid entering film to amount of liquid directed at the cylinder in gas-liquid spray flow, dimensionless - k() local volume ratio of liquid entering film to amount of liquid directed at the cylinder in gas-liquid spray flow, dimensionless - L specific latent heat of vaporisation, J/kg - m mass fraction of water in gas-liquid spray flow, dimensionless - M constant in Eq. (9) - p pressure, Pa - p _g statical pressure of gas, Pa - p _w pressure of gas on the cylinder surface, Pa - p external pressure on the liquid film surface, Pa - r cylindrical coordinate, m - R radius of cylinder, m - T temperature, K, °C - T _l, t_l liquid temperature in the gas-liquid spray, K, °C - T _w,t_w temperature of cylinder surface, K, °C - T temperature of gas-liquid film interface, K - U liquid film velocity, m/s - w gas velocity on cylinder surface, m/s - w _g gas velocity in free stream, m/s - W _l liquid vapour mass ratio in free stream, dimensionless - W liquid vapour mass ratio at the edge of a liquid film, dimensionless - x coordinate, m - y coordinate, m - z complex variable, dimensionless - average heat transfer coefficient, W/m²K - local heat transfer coefficient, W/m² K - average heat transfer coefficient between cylinder surface and gas, W/m² K - _g, local heat transfer coefficient between cylinder surface and gas, W/m² K - mass transfer coefficient, kg/m²s - liquid film thickness, m - _lg dynamic diffusion coefficient of liquid vapour in gas, kg/m s - pressure distribution function on a cylinder surface - function defined by Eq. (3) - _l liquid dynamic viscosity, kg/m s - _g gas dynamic viscosity, kg/m s - cylindrical coordinate, rad, deg - _l thermal conductivity of liquid, W/m K - _g thermal conductivity of gas, W/m K - mass transfer driving force, dimensionless - _l density of liquid, kg/m³ - _g density of gas, kg/m³ - _w shear stress on the cylinder surface, N/m² - _w shear stress exerted by gas at the liquid film surface, N/m² - air relative humidity, dimensionless - T -T _w - _w =T _wT_l Dimensionless parameters I= enhancement factor of heat transfer - m ^*=M _l/M_g molar mass of liquid to the molar mass of gas ratio - Nu _g= D/ _g gas Nusselt number - Pr _g=c _{g g}/_g gas Prandtl number - Pr _l=c_lll liquid Prandtl number - ¯r=(r–R)/ dimensionless coordinate - Re _g=w_gD _g/_g gas Reynolds number - Re _g,max=w_g,max D _g/_g gas Reynolds number calculated for the maximal gas velocity between the cylinders - Sc=m ^* _g/_l–g Schmidt number =/R dimensionless film thickness     

Stability of stationary traveling waves on the surface of a vertical film of viscous fluid

The stability of stationary traveling waves of the first and second families with respect to infinitesimal perturbations of arbitrary wavelength is subjected to a detailed numerical investigation. The existence of a unique region of stability of the first family is established for wave numbers (₁, ₁) corresponding to the optimal wave regime. There are several regions of stability of the second family ( _k , _k),k=2,3,..., lying close to the local flow rate maxima. In the regions of instability the growth rates of perturbations of the first family are several times greater than for the second family. This difference increases with increase in the Reynolds number. The calculations make it possible to explain a number of experimental observations.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 33–41, May–June, 1989.The authors are grateful to V. Ya. Shkadov for his constant interest, and to A. G. Kulikovskii, A. A. Barmin and their seminar participants for useful discussions and suggestions.     

Mixed convection from a horizontal plate to fluids of any Prandtl number

Laminar mixed convection over a horizontal plate with uniform wall temperature or uniform wall heat flux is analyzed by introducing proper buoyancy parameters and transformation variables for fluids of any Prandtl number between 0.001 and 10,000. Both cases of buoyancy assisting and opposing flow conditions are investigated. For the buoyancy-assisting case, the obtained numerical results are very accurate over the entire range of mixed convection intensity from pure forced convection limit to pure free convection limit. For the buoyancy-opposing case, solutions are obtained from the forced convection limit to the point of breakdown.

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Mischkonvektion an einer horizontalen Platte für Fluide mit beliebiger Prandtl-Zahl

Zusammenfassung Es wurde laminare Mischkonvektion an einer horizontalen Platte mit einheitlicher Wandtemperatur oder einheitlicher Wandwärmestromdichte bei Einführung zweckmäßiger Auftriebsparameter und Transformationsvariablen für Fluide mit beliebiger Prandtl-Zahl zwischen 0,001 und 10 000 untersucht. Es wurden die Fälle der Strömung entgegen und in Richtung der Auftriebskraft untersucht. Für den Fall der Strömung in Richtung der Auftriebskraft wurden sehr genaue numerische Ergebnisse für den gesamten Bereich der gemischten Konvektion von rein erzwungener Konvektion bis zu rein freier Konvektion erhalten. Für den Fall der Strömung entgegen der Auftriebsrichtung wurden Lösungen für erzwungene Konvektion bis zum Umkehrpunkt erhalten.

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Nomenclature C _f local friction coefficient - f reduced stream function - g gravitational acceleration - Gr local Grashof number for UWT,g (T _w –T )x ³/ ² - Gr* local Grashof number for UHF,g q _w x ⁴/k ² - m =10 for UWT; and =6 for UHF - n =5 for UWT; and =3 for UHF - Nu local Nusselt number - p pressure - Pr Prandtl number,/ - q _w wall heat flux - Ra local Rayleigh number for UWT,Gr Pr - Ra* local Rayleigh number for UHF,Gr*Pr - Re local Reynolds number,u x/ - T fluid temperature - T _w wall temperature - T free-stream temperature - u velocity component inx-direction - u free-stream velocity - v velocity component iny-direction - x coordinate parallel to the plate - y coordinate normal to the plate Greek symbols thermal diffusivity - thermal expansion coefficient - =0 for UWT; and =1 for UHF - buoyancy parameter, =( Ra)^1/5/( Re)^1/2 for UWT; and =( Ra*)^1/6/( Re)^1/2 for UHF - pseudo-similarity variable, (y/x) - dimensionless temperature, =(T–T )/(T _w –T ) for UWT; and =(T–T )/(q _w x/k) for UHF - =[( Re)^1/2+( Ra)^1/5] for UWT; and =[( Re)^1/2+( Ra*)^1/6] for UHF - dynamic viscosity - kinematic viscosity - /(1+) - dimensionless pressure - density - Pr/(1+Pr) - _w wall shear stress,(u/y) _y=0 - stream function - Pr/(1+Pr)^1/3     

Convective heat transfer within fibrous insulation slabs

A numerical study of convective heat flow within a fibrous insulating slab is presented. The material is treated as an anisotropic porous medium and the variation of properties with temperature is taken into account. Good agreement is obtained with available experimental data for the same geometry.

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Zusammenfassung Für den konvektiven Wärmestrom in einem faserförmigen Isolierstoff wird eine numerische Berechnung angegeben. Der Stoff wird als anisotropes poröses Medium mit temperaturabhängigen Stoffwerten angesehen. Die Übereinstimmung mit verfügbaren Versuchswerten ist gut.

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Nomenclature C_p specific heat of the gas at the mean temperature - Da Darcy number=k_y/H² - Gr^* modified Grashof number=gTHk_y/²= (Grashof number) × (Darcy number) - H thickness of the specimen - P gas pressure - Pr^* modified Prandtl number= C_p/_x - Ra^* modified Rayleigh number=Gr^* Pr^* - R_p ratio of permeabilities=k_y/k_x - R_k ratio of conductivities= _y/_x - T absolute temperature of the gas - t₁ absolute temperature of the hot face - T₂ absolute temperature of the cold face - T_m mean temperature of the gas=(T₁+T₂)/2 - k_x specific permeability of the porous medium along the x-direction - k_y specific permeability of the porous medium along the y-direction - p T/T_m - q exponent - r exponent - u gas velocity along the x-direction - v gas velocity along the y-direction - X_* distance along the x-direction - y_* distance along the y-direction - T temperature difference=t₁–T₂ - thermal coefficient of expansion of the gas - _m thermal coefficient of expansion of the gas at the mean temperature - _* T–T_m - dimensionless temperature= ^*/T - _a apparent thermal conductivity of the porous medium along the x-direction - _al local apparent thermal conductivity of the porous medium along the x-direction - _x thermal conductivity of the porous medium along the x-direction in the absence of convection - _y thermal conductivity of the porous medium along the y-direction in the absence of convection - dynamic viscosity of the gas - _m dynamic viscosity of the gas at the mean temperature - kinematic viscosity of the gas - _m kinematic viscosity of the gas at the mean temperature - density of the gas - _m density of the gas at the mean temperature - ^* stream function at any point - dimensionless stream function= ^*/( _m/_m)     

Heteroclinic orbits in singular systems: A unifying approach

We consider singularly perturbed systems , such that=f(, _o, 0). _o ^m , has a heteroclinic orbitu(t). We construct a bifurcation functionG(, ) such that the singular system has a heteroclinic orbit if and only ifG(, )=0 has a solution=(). We also apply this result to recover some theorems that have been proved using different approaches.     

Analytical solution for transient laminar fully developed free convection in vertical channels

Using Green's function method, analytical solutions for transient fully developed natural convection in open-ended vertical circular and two-parallel-plate channels are presented. Different fundamental boundary conditions for these two configurations have been investigated and the corresponding fundamental solutions are obtained. These fundamental solutions may be used to obtain solutions satisfying more general thermal boundary conditions. In terms of the obtained unsteady temperature and velocity profiles, the transient volumetric flow rate, mixing cup emperature and local nusselt number are estimated.Zusammenfassung Für oben und unten offene vertikale Kanäle mit Kreisquerschnitt bzw. als Parallelplattenanordnung werden unter Verwendung der Methode der Greenschen Funktionen analytische Lösungen für die nichtstationäre, vollausgebildete, natürliche Konvektion gefunden und zwar unter Zugrundelegung verschiedener Fundamental-Randbedingungen bezüglich beider Konfigurationen. Die so ermittelten Fundamentallösungen können zur Gewinnung von Lösungen für allgemeine Randbedingungen dienen. Der zeitlich veränderliche Volumenstrom, die Mischtemperatur und die Nusselt-Zahl werden mit Bezug auf die erhaltenen nichtstationären Profile für Temperatur und Geschwindigkeit näher analysiert.

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Analytische Lösung für die nichtstationäre vollausgebildete laminare freie Konvektion invertikalen Kanälen

Nomenclature a local heat transfer coefficient based on the area of the heat transfer surface,q/(T _w –T ₀)=±(T/y)_w/(T_w–T₀), minus and plus signs apply respectively for heating and cooling in case of parallel-plate channel and vice versa in case of a tube - average heat transfer coefficient over the channel - c _p specific heat of fluid at constant pressure - f volumetric flow rate, for circular channels and or two-parallel-plate channels - F dimensionless volumetric flow rate,f/(2lvGr^*) for circular channels forfw/(lvGr ^*) for two-parallel-plate channels - g gravitational body force per unit mass (acceleration) - G Green's function - Gr Grashof number,±g(T _w–T₀)w³/v² in case of an isothermal boundary of±gqw ⁴/2kv² in case of a uniform heat flux (UHF) on the heat transfer boundary, the plus and minus signs apply to upward (heating) and downward (cooling) flows, respectively. ThusGr is a positive number in both cases. - Gr ^* modified Grashof number,wGr/l - h heat gained or lost by fluid from the entrance up to a particular elevation in the channel, ₀ fc _p(T _m–T ₀) for all cases - J ₀ Bessel function of zero order - k thermal conductivity of fluid - l height of channel - L dimensionless height of channel,1/Gr ^* - Nu local Nusselt number,|a| w/k - average Nusselt number, - p pressure of fluid inside the channel at any cross-section - p pressure defect at any point,p–p _s - p ₀ pressure of fluid at the channel entrance - p _s hydrostatic pressure, ₀ gz where the minus and plus signs are for upward (heating) and downward (cooling) flows, respectively - p dimensionless pressure defect at any point(pw ⁴)/(₀ l ²² Gr ²) - Pr Prandtl number,c _p/k - q heat flux at the heat transfer surface,q=±k(T/y)_w where the minus and plus signs are, respectively, for cooling and heating in case of circular pipe and vice versa in case of a parallel-plate channel - Ra Rayleigh number,GrPr - Ra ^* modified Rayleigh number,Gr ^*Pr - t time - T fluid temperature at any point - T _m mixing-cup (mixed-mean) temperature over any cross section, for circular channels, and for two-parallelplate channels - T ₀ initial and channel-inlet fluid temperature - T _w temperature of the heat-transfer wall - u axial velocity component at any point - U dimensionless axial velocity,uw ²/(lvGr^*) - w radius of circular tube or width (between plates) of parallel-plate channel - y radial or transverse coordinate - y dimensionless radial or transverse coordinate,y/w - z axial coordinate - Z dimensional axial coordinate,z/(lGr ^*) Greek symbols constant appears in Eq. (8) - parameter appears in Eq. (9) which equals the integration of with respect to or volumetric coefficient of thermal expansion - _n eigenvalues - parameter appears in Eq. (7) - _n eigenvalues - parameter appears in Eq. (12) - _n eigenvalues - parameter appears in Eq. (9) - dimensionless temperature,(T–T ₀)/(T_w–T₀) in case of an isothermal heat transfer boundary and(T–T ₀)/(qw/2k) for UHF boundary - _m dimensionless mixing cup temperature,(T _m–T₀)/(T_w–T₀) in case of an isothermal heat transfer boundary and(T _m–T₀)/(qw/2k) for UHF boundary - _w dimensionless temperature of the heat-transfer wall, equals unity in case of an isothermal heat transfer boundary and(T _w–T₀)/(qw/2k) for a UHF boundary - _n eigenvalues - dynamic viscosity of fluid - kinematic viscosity of fluid, /₀ - fluid density at temperatureT,₀[1–(T–T ₀)] - ₀ fluid density atT ₀ - demensionless time,tk/(cw²)     

The rheology of polymeric liquid crystals

The molecular theory of Doi has been used as a framework to characterize the rheological behavior of polymeric liquid crystals at the low deformation rates for which it was derived, and an appropriate extension for high deformation rates is presented. The essential physics behind the Doi formulation has, however, been retained in its entirety. The resulting four-parameter equation enables prediction of the shearing behavior at low and high deformation rates, of the stress in extensional flows, of the isotropic-anisotropic phase transition and of the molecular orientation. Extensional data over nearly three decades of elongation rate (10^–2–10¹) and shearing data over six decades of shear rate (10^–2–10⁴) have been correlated using this analysis. Experimental data are presented for both homogeneous and inhomogeneous shearing stress fields. For the latter, a 20-fold range of capillary tube diameters has been employed and no effects of system geometry or the inhomogeneity of the flow-field are observed. Such an independence of the rheological properties from these effects does not occur for low molecular weight liquid crystals and this is, perhaps, the first time this has been reported for polymeric lyotropic liquid crystals; the physical basis for this major difference is discussed briefly. A Semi-empirical constant in eq. (18), N/m² - c rod concentration, rods/m³ - c ^* critical rod concentration at which the isotropic phase becomes unstable, rods/m³ - C interaction potential in the Doi theory defined in eq. (3) - d rod diameter, m - D semi-empirical constant in eq. (19), s^–1 - D _r lumped rotational diffusivity defined in eq. (4), s^–1 - rotational diffusivity of rods in a concentrated (liquid crystalline) system, s^–1 - D _ro rotational diffusivity of a dilute solution of rods, s^–1 - f distribution function defining rod orientation - F tensorial term in the Doi theory defined in eq. (7) (or eq. (19)), s^–1 - G tensorial term in the Doi theory defined in eq. (8) - K _B Boltzmann constant, 1.38 × 10^–23 J/K-molecule - L rod length, m - S scalar order parameter - S tensor order parameter defined in eq. (5) - t time, s - T absolute temperature, K - u unit vector describing the orientation of an individual rod - rate of change ofu due to macroscopic flow, s^–1 - v fluid velocity vector, m/s - v velocity gradient tensor defined in eq. (9), s^–1 - V mean field (aligning) potential defined in eq. (2) - x coordinate direction, m - Kronecker delta (= 0 if = 1 if = ) - _r ratio of viscosity of suspension to that of the solvent at the same shear stress - _s solvent viscosity, Pa · s - ^* viscosity at the critical concentrationc ^*, Pa · s - v ₁, v₂ numerical factors in eqs. (3) and (4), respectively - deviatoric stress tensor, N/m² - volume fraction of rods - ⁰ constant in eq. (16) - ^* volume fraction of rods at the critical concentrationc ^* - average over the distribution functionf(u, t) (= d ²u f(u, t)) - gradient operator - d ²u integral over the surface of the sphere (|u| = 1)     

Concentration-dependent behaviour of the shear viscosity of coal-fuel oil suspensions

A function correlating the relative viscosity of a suspension of solid particles in liquids to their concentration is derived here theoretically using only general thermodynamic ideas, with out any consideration of microscopic hydrodynamic models. This function ( _r = exp (1/2B ^* C ²)) has a great advantage over the many different functions proposed in literature, for it depends on a single parameter,B ^*, and is therefore concise. To test the validity of this function, a least-squares regression analysis was undertaken of available data on the viscosity and concentration of suspensions of coal particles in fuel oil, which promise to be a useful alternative to fuel oil in the near future. The proposed function was found to accurately describe the concentration-dependent behaviour of the relative viscosity of these suspensions. Furthermore, an attempt was made to obtain information about the factors affecting the value ofB ^*, however the results were only qualitative because of, among other things, the inaccuracy of the viscosity measurements in such highly viscous fluids. shear viscosity of the suspension - ₀ shear viscosity of the Newtonian suspending medium - _r = /₀ relative viscosity - solid volume concentration - c solid weight concentration - _m maximum attainable volume concentration of solids - solid volume concentration at which the relative viscosity of the suspension becomes infinite - c _m maximum attainable solid weight concentration - _s density of the solid phase - _l density of the liquid phase - _m density of the suspension - k _n coefficients of theø-power series expansion of _r - { _j } sets of parameters specifying the thermodynamic state of the solid phase of a suspension - T absolute temperature (K) - f (c, T, _j) formal expression for the relative variation of the viscosity with concentration = [1 / (/c)] _T,j - d median size of the granulometric distribution - _B plastic or Bingham viscosity - K consistency factor - n flow index - g ([c _m –c],T, _j ) function including an asymptotic divergence asc tends toc _m , formally describing the concentration dependent behaviour of the shear viscosity of a suspension - A (T, _j) regression analysis parameters - B (T, _j) regression analysis parameters - B ^* (T, _j ) regression analysis parameters     

Stability of the T ∞FT < T ∞α relation between Vogel temperatures of flow and glass transition against determination variants

Dynamic shear measurements in the frequency range from 10^–4 to 500 rad/s at the flow and main transition of a polydisperse poly(vinyl acetate) and a monodisperse polystyrene sample are presented. For both samples the Vogel temperature of the flow transition T _FT is smaller than the Vogel temperature of the main transition T , independent of the criteria used for data evaluation. The difference between the two Vogel temperatures corresponds to results for samples with other molecular weight and polydispersity from the literature. The T _FT <T relation is discussed in terms of short () and long (FT) dynamic glass transitions in entangled polymers. The relation is explained by preaveraging of the energy landscape for the long flow transition by the short glass transition.     

Structure and rheology of styrene methyl methacrylate copolymers

Summary In a series of homopolymers and copolymers of styrene (S) and methyl methacrylate (MMA) (100/0, 85/15, 50/50, 15/85, 0/100),T _g ,G and | ^*| increased significantly when MMA was increased beyond 50%. Although the magnitude ofJ _e ⁰ asymptote was the same, it occurred at decreasing frequencies with increasing MMA. TheJ increases linearly withT —T _g, but more so with polystyrene (PS) than with polymethyl methacrylate (PMMA). The | ^*| showed non-Newtonian behavior at decreasing frequency with increasing MMA, the asymptotic form being consistent withGraessley models. The viscoelastic behavior can be correlated with chain flexibility and SMS triad concentration in copolymers.

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Zusammenfassung Man findet, daß bei einer Reihe von Homopolymerisaten und Copolymerisaten von Styrol (S) und Methylmethacrylat (MMA) (100/0, 85/15, 50/50, 15/85, 0/100)T _g, G und | ^*| erheblich anwachsen, wenn der MMA-Gehalt 50% übersteigt. Obgleich die Größe des asymptotischen Wertes vonJ _e ⁰ konstant bleibt, wird dieser mit wachsendem MMA-Gehalt schon bei kleineren Frequenzen annähernd erreicht.J wächst linear mitT —T _g, jedoch bei Polystyrol (PS) stärker als bei Polymethylmethacrylat (PMMA). Der Betrag der komplexen Viskosität | ^*| zeigt mit wachsendem MMA-Gehalt von einer kleiner werdenden Frequenz ab ein nicht-newtonsches Verhalten an, wobei der asymptotische Verlauf einer Modellvoraussage nachGraessley folgt. Das viskoelastische Verhalten kann mit der Kettenflexibilität und der Konzentration der SMS-Triaden in den Kopolymerisaten korreliert werden.

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With 6 figures and 4 tables