Influence of the Si–O–C interplayer on the flexural behaviors of C/Si–C–N composites

Carbon fiber reinforced Si–C–N matrix composite(C/Si–C–N) with a Si–O–C interlayer (C/Si–O–C/Si–C–N) was fabricated via CVI and PIP process. The flexural behaviors of C/Si–O–C/Si–C–N were investigated using the three-point-bending method and the SEM technique. The results indicated that the flexural strengh of the C/Si–O–C/Si–C–N increases with increasing temperature and the modulus of the composite is essentially unchanged. The strength of C/Si–O–C/Si–C–N is comparable to that of C/PyC/Si–C–N, and the role of Si–O–C interlayer in C/Si–C–N can rival that of the PyC interlayer. The weaker interfacial bonding and the larger thickness of Si–O–C interlayer make a contribution to this at RT while the thinner interlayer and unstable structure of Si–O–C interphase do it above 1300 °C.     

Balance the oxidation resistance and mechanical properties of C/Si–C–N composite by a Si–O–C interphase

Carbon fiber reinforced Si–C–N matrix composite with a Si–O–C interphase (C/Si–O–C/Si–C–N) was fabricated via chemical vapor infiltration and polymer impregnation and pyrolysis process. The mechanical properties and oxidation behaviors of C/Si–O–C/Si–C–N were investigated using three-point-bending test and thermogravimetry. The results indicated that the oxidation resistance of C/Si–O–C/Si–C–N was improved as compared to C/Si–C–N with pyrolytic carbon (PyC) interphase (C/PyC/Si–C–N). The higher oxidation resistance of C/Si–O–C/Si–C–N attributed to the high inoxidizability of Si–O–C interlayer and low thermal stress in matrix. The flexural strength of C/Si–O–C/Si–C–N rivaled that of C/PyC/Si–C–N and the modulus was higher than that of C/PyC/Si–C–N. The suitable interphase and the optimized interface bonding can get the high oxidation resistance of the composites with the mechanical properties maintained.     

Phase diagram of Bi up to 140 kbars

The phase diagram of Bi has been studied by resistometric techniques in the temperature range of 30 to 300°K up to pressures of 140 kbars. Using the original Bridgman phase notation, the phase transitions I–II, II–III, I–III, III–IV and V–VI were observed. Two new phases, designated VIII and IX were observed in this region. The triple points occurring between I–II–III near 29.5 kbars and 160°K, between IV–V–VIII near 55 kbars and 240°K, between V–VI–VIII near 72 kbars and 255°K and between VI–VIII–IX near 135 kbars and 250°K. Earlier measurements were adjusted to the 1970 Drickamer pressure scale and compared to the present results. A phase diagram is proposed for pressures to 140 kbars. Calculations of the volume changes and latent heats of transformation are made near the triple points I–II–III, IV–V–VIII and V–VI–VIII using the measured volume changes of Bridgman for the I–II, IV–V and V–VI transitions. The latent heat associated with the III–IV transition was calculated using the volume data of Bridgman to be less than ? 2 cal/mol.     

Phase Transitions in Bismuth-Containing Elastostressed AlGaInSbBi–InSb Heterosystems

Physics of the Solid State - The specific features of phase transitions in elastostressed Al–Ga–In–Sb–Bi heterosystems and In–Sb–Bi and Al–In–Bi...     

Temperature dependence of twinning stress – Analogy between Cu–Ni–Al and Ni–Mn–Ga shape memory single crystals

Abstract

To obtain a direct non-magnetic analogy to Ni–Mn–Ga 10M martensite with highly mobile twin boundaries, we present the recalculation of twinning systems in Cu–Ni–Al martensite. In this approach, the twinning planes denoted as Type I, Type II and compound have similar orientations for both alloys (Ni–Mn–Ga and Cu–Ni–Al). In Cu–Ni–Al, compound twinning exhibits the twinning stress of 1 to 2 MPa comparable to twining stress of Ni–Mn–Ga. In contrast Type II twinning stress of Cu–Ni–Al is approximately 20 MPa, i.e. much higher than twinning stress for Type II in Ni–Mn–Ga (0.1 to 0.3 MPa). Similarly to Ni–Mn–Ga, the twinning stress of Type II in Cu–Ni–Al is temperature independent. Moreover, no temperature dependence was found also for compound twinning in Cu–Ni–Al.     

Relaxation method for constructing the interaction potentials of metal–nonmetal atomic pairs

An algorithm that employs the method of successive relaxation for determining the parameters of the pairwise interaction potential of iron and nonmetallic atoms that implicitly considers the redistribution of electron density between atoms is developed. The parameters of the interatomic interaction potential are calculated for ten pairs of elements: Fe–P, Fe–S, Fe–B, Fe–V, Fe–Mo, Fe–Cr, Fe–Mn, Fe–Si, Fe–Ni, and Fe–Al. The structural and thermodynamic properties of solid solutions based on iron and pure materials, and some pairwise interaction potentials constructed earlier in the Lennard–Jones form for identical metal atoms and homogeneous pairs of different metal–metal atoms, are used in these calculations.     

Thermal and structural characterization of Cu–Al–Mn–X (Ti,Ni) shape memory alloys

In this study, the Cu–Al–Mn–X (X = Ni, Ti) shape memory alloys at the range of 10–12 at.% of aluminum and 4–5 at.% manganese were produced by arc melting. We have investigated the effects of the alloying elements on the transformation temperatures, and the structural and the magnetic properties of the quaternary Cu–Al–Mn–X (X = Ni, Ti) shape memory alloys. The evolution of the transformation temperatures was studied by differential scanning calorimetry with different heating and cooling rates. The characteristic transformation temperatures and the thermodynamic parameters were highly sensitive to variations in the aluminum and manganese content, and it was observed that the nickel addition into the Cu–Al–Mn system decreased the transformation temperature although Ti addition caused an increase in the transformation temperatures. The effect of the nickel and the titanium on the thermodynamic parameters such as enthalpy and entropy values was investigated. The structural changes of the samples were studied by X-ray diffraction measurements and by optical microscope observations at room temperature. It is evaluated that the element Ni has been completely soluble in the matrix, and the main phase of the Cu–Al–Mn–Ni sample is martensite, and due to the low solubility of the Ti, the Cu–Al–Mn–Ti sample has precipitates, and a martensite phase at room temperature. The magnetic properties of the Cu–Al–Mn, Cu–Al–Mn–Ni and Cu–Al–Mn–Ti samples were investigated, and the effect of the nickel and the titanium on the magnetic properties was studied.     

Local structure and local conduction paths in amorphous (In,Ga,Hf)–ZnO semiconductor thin films

The local structure and local conduction paths of Ga–In–Zn–O (GIZO) and Hf–In–Zn–O (HIZO) amorphous thin films were investigated by the extended X-ray absorption fine structure (EXAFS). We found that the local hindrance paths of In–Ga and In–Hf exist in the conduction paths of amorphous GIZO and HIZO semiconductor thin films, respectively.     

Numerical approximation of the Vlasov–Maxwell–Fokker–Planck system in two dimensions

A numerical method is developed for solving the Vlasov–Maxwell–Fokker–Planck system in two spatial dimensions. This system of equations is a model for a collisional plasma in the presence of a self consistent electromagnetic field. The numerical procedure is a type of deterministic particle method and is an extension to include the full electromagnetic field of the approximation method of Wollman and Ozizmir [S. Wollman, E. Ozizmir, Numerical approximation of the Vlasov–Poisson–Fokker–Planck system in two dimensions, J. Comput. Phys. 228 (2009) 6629–6669]. In addition, the long time asymptotic behavior of solutions is studied. It is determined that the solution to the Vlasov–Maxwell–Fokker–Planck system converges to the same steady state solution as that for the Vlasov–Poisson–Fokker–Planck system.     

The current–voltage characteristic in an ultrasmall junction

The current–voltage characteristics of ultrasmall superconductor–insulator–normal metal (S–I–N), and a superconductor–insulator–superconductor (S–I–S) junctions are computed in the presence of a dissipative transmission line. The amplitude of the discontinuous jump at the energy gap of a single-particle current is greatly influenced by the size of the capacitance and the impedance of the external transmission line in the small junction. The results agree with Ambegaokar–Baratoff in the limit of vanishing impedance of a transmission line or large junction capacitance.     

On quasi-periodic solutions of the 2+1 dimensional Caudrey–Dodd–Gibbon–Kotera–Sawada equation

The 2+1 dimensional Caudrey–Dodd–Gibbon–Kotera–Sawada equation is decomposed into systems of integrable ordinary differential equations resorting to the nonlinearization of Lax pairs. The Abel–Jacobi coordinates are introduced to straighten the flows, from which quasi-periodic solutions of the 2+1 dimensional Caudrey–Dodd–Gibbon–Kotera–Sawada equation are obtained in terms of Riemann theta functions.     

Nuclear Physical Properties of Austenitic Nickel and Manganese Steels under Neutron Irradiation in Nuclear Fission (Fast) and Fusion Reactors

Physics of Atomic Nuclei - The nuclear physical properties of austenitic chromium-nickel steel EK-164 (Fe–16Cr–19Ni–2Mo–2Mn–Nb–Ti–B) and its...     

EPR Studies of DOPA–Melanin Complexes with Netilmicin and Cu(II) at Temperatures in the Range of 105–300?K

The application of electron paramagnetic resonance (EPR) spectroscopy in pharmacy of melanin complexes with netilmicin and Cu(II) was presented. The continuous microwave saturation of EPR spectra of DOPA–melanin and the complexes was performed. EPR spectra were measured on an X-band (9.3?GHz) spectrometer at temperatures in the range of 105–300?K. Paramagnetic copper ions decrease the intensity of the EPR lines of melanin’s free radicals. It was found that fast spin–lattice relaxation characterizes DOPA–melanin–Cu(II) complexes. Slow spin–lattice relaxation processes exist in melanin’s paramagnetic centers of DOPA–melanin and DOPA–melanin–netilmicin, [DOPA–melanin–netilmicin]–Cu(II), [DOPA–melanin–Cu(II)]–netilmicin complexes. Spin–lattice relaxation processes are faster at higher temperatures. The homogeneous broadening of EPR lines for melanin complexes was observed. The practical consequences of differences between paramagnetic properties of melanin complexes with netilmicin and the complexes with Cu(II) were discussed.     

A simple model to predict long-range atomic ordering temperatures in Cu-based shape memory alloys

The order–disorder and order–order phase transition temperatures in the austenitic phase of Cu-based shape memory alloys were used to obtain a set of first- and second-neighbour pair interchange energies. To this end, a mean field model was postulated. Then, the applicability to different alloys of this simple model was analysed. It was found that a good agreement with the experimental phase diagram is obtained for Cu–Zn–Al, Cu–Al–Ni and Cu–Al–Be alloys using composition-independent parameters. It was also found that for Cu–Al–Mn alloys, composition-dependent pair interchange energies need to be employed.     

Structure and mechanical property variations in Mg–Gd–Y–Zn–Zr alloy depending on its composition and processing conditions

An effect of alloying element content on mechanical properties and precipitate formation in Mg–RE alloys was studied for Mg–8Gd–4Y–1Zn–0.4Zr (wt%) and Mg–10Gd–5Y–1.8Zn–0.4Zr (wt%). It is shown that small variations in the alloying element concentration can be used to manipulate the alloy microstructure and precipitate formation towards eliminating the asymmetry (tension/compression) and anisotropy of yield stress.     

Amount of valence charge of Al- and Zn-based quasicrystals and related approximant crystals evaluated by chemical shift observations and Bader analysis

The amounts of decreased charge at Al sites of Al-based (Al–Pd–Cr–Fe, Al–Si–Mn, and Al–Re–Si) and at Zn sites of Zn-based (Zn–Mg–Zr) quasicrystals and approximant crystals were estimated. The evaluation was done by comparisons between chemical shifts experimentally observed by soft-X-ray emission spectroscopy and the amount of valence charge obtained by Bader analysis for first principle calculations of reference materials (Al, α-Al₂O₃, Zn, and ZnO). Decreased charges at Al sites of Al-based quasicrystals and at Zn sites of Zn-based quasicrystals were evaluated to be 1.0–2.5 e^–/atom and 1.1–1.2 e^–/atom, respectively. A covalent bonding nature alloy of Al–Re–Si also showed a decrease in valence charge at Al sites.     

Calculation of Nuclear Stopping in the Semiclassical Approximation

Technical Physics - The results of calculating nuclear stopping in the semiclassical approximation for the H–Be, H–C, H–W, O–C, O–Be, and O–Al systems are...     

Magnetic properties of 3D nanocomposites consisting of an opal matrix with embedded spinel ferrite particles

The magnetic properties of 3D nanocomposites representing Mn–Zn, Ni–Zn, Co–Zn, La–Co–Zn, and Nd–Co–Zn spinel ferrite particles embedded in the interspherical spaces of opal matrices are studied. Experimental data are obtained in the temperature interval 2–300 K by measuring the magnetization at a static magnetic field strength of up to 50 kOe and the ac magnetic susceptibility at an alternating magnetic field amplitude of 4 kOe and a frequency of 80 Hz.