准光激励毫米波圆波导旋转TE6 2模式产生器

 介绍了采用准光方法激励圆波导产生旋转TE_{6 2}模式的设计原理、测试方法和实验结果。该模式产生器由毫米波光学系统和开放同轴波导谐振腔系统组成:毫米波光学系统由角锥喇叭天线、双曲面反射镜、抛物面反射镜、修正抛物面反射镜等部件组成;开放同轴波导谐振腔系统由开放同轴波导谐振腔、圆波导、测试辐射喇叭天线组成。通过网络分析仪和毫米波近场自动测试系统测试表明:该模式产生器在频率为96.4 GHz附近产生的圆波导旋转TE_{6 2}模式的纯度达到97%。     

基于偏振旋转光反馈下的外光注入VCSEL产生高性能毫米波

本文提出一种基于偏振旋转光反馈下的外光注入垂直腔 表面发射激光器(VCSEL)产生高性能毫米波的方案, 并利用描述外部扰动下VCSEL动态特性的自旋反转模型(SFM), 对所产生的毫米波的特性进行了数值研究. 研究结果表明: 一个受到主VCSEL(M-VCSEL)光注入的副VCSEL(S-VCSEL)在一定条件下可以产生单周期(P1)振荡, 即在光波上调制了一个微波信号. 通过调节外光注入强度ξ_i以及S-VCSEL与M-VCSEL之间频率失谐Δν, 可以获得频率在30---60 GHz范围内连续可调的毫米波信号. 在外光注入VCSEL中引入偏振旋转光反馈, 通过选取合适的反馈强度ξ_f以及反馈延迟时间τ, 产生的毫米波信号的线宽可以得到明显窄化. 对于光注入S-VCSEL所产生的线宽为5.509 MHz的毫米波, 在引入偏振旋转光反馈后, 毫米波线宽可以降低到230.2 kHz. 本文的研究对高速光载无线(RoF)系统中优质毫米波信号的获取具有一定的参考意义.     

高功率毫米波圆波导TM01—TE11模式变换分析

 在数值研究高功率毫米波TM₀₁—TE₁₁光滑弯曲圆波导模式变换的基础上，对弯曲波导的几何结构进行了优化分析。在模式耦合理论的基础上，优化出了比较好的几何结构，并发现了圆波导半径、弯曲圆波导曲率和频率以及频带宽度之间的变化规律。以此数据设计的模式变换器的转换效率可达99%，带宽超过29.8%。     

利用扫描隧道显微镜在溶液中直接观测过渡族金属硫属化合物

本文利用自制的溶液扫描隧道显微镜在溶液环境下直接观测到TiSe₂、MoTe₂和TaS₂样品的原子分辨率图像. 通过将单晶样品在溶液中直接解理,可以保护解理过的新鲜样品表面在几个小时内不会被严重污染. 利用自行搭建的溶液扫描隧道显微镜,首先观察到了TiSe₂活泼样品的原子分辨率图像,并观察到了TiSe₂表面所特有的点缺陷和三角形缺陷结构. 此外,还观察到了MoTe₂的原子分辨率超结构和TaS₂表面的电荷密度波结构. 结果表明：在室温、溶液环境下能更高效的研究过渡族金属硫属化合物等活泼样品的表面电子态结构,同样适用于溶液环境下的电催化和电化学研究.     

基于同轴TM812模谐振腔的毫米波多注速调管

 研究了群聚电子注穿越同轴TM₈₁₂模谐振腔的换能效率和同轴TM₈₁₂模谐振腔中微波能量的提取方法,论证了其作为毫米波多注速调管的输出腔的可行性。研究结果表明:理想群聚电子注穿越同轴TM₈₁₂模谐振腔的换能效率可达3.29%,一般群聚电子注穿越同轴TM₈₁₂模谐振腔的换能效率可达1.86%;采用同轴TM₈₁₂模谐振腔与沿轴向的同轴线耦合可以实现微波能量的提取;在输出腔工作频率为100.945 GHz,外观品质因数为2 243情形下,根据估算,最大输出功率可达15 kW。     

各向异性非线性介质平板波导中的TM波

本文讨论了在三层平板介质波导中TM₀模的传播问题.三层介质的芯区是一层各向异性的Kerr型介质,上下两层则是线性介质.本文将利用E_x² >> E_x²这一性质,求解非线性方程组,给出零级近似和1级近似的解析解.     

用超短光脉冲简并四波混频测量介质弛豫率的研究

本文讨论用ps光脉冲简并四波混频测量非线性介质弛豫率和在适度或强的相位调制情况下测量激光脉冲宽度的方法,通过用计算机模拟及与实验结果比较,得出结论:对t_p>>τ_r和t_p<<τ_r两种极限情况,该方法是足够精确的.对τ_r/t_p的中间情况,该方法只能给出一个估计.     

具有密度跃层分层流体中回转体激发内波特性实验

在具有连续密度跃层的分层流体中,对长径比为7:1的回转体在迎水和背水运动下激发体积效应与尾迹效应内波特性开展了系列实验.结果表明,体积效应激发内波属于一种相对于回转体定常的多模态Lee波结构,而尾迹效应激发主控内波为相对于回转体非定常的拟Lee波结构,这是一类由湍流尾迹中大尺度相干结构作为移动源激发的内波结构,在Lee波与拟Lee波之间存在一个与长径比近似为线性关系的临界转捩Froude数Fr_c,当FrFr_c 时拟Lee波为主控内波,而且拟Lee波相关速度Froude数近似为一个常数0.8,其无因次峰-峰幅值随Fr的增大近似线性增大,其中Fr为回转体特征直径Froude数.结果还表明,回转体头部与尾部几何形式并不影响其激发内波临界转捩Froude数Fr_c、 拟Lee波相关速度Froude数及其峰-峰幅值变化特性.     

高功率毫米波圆波导半径微扰模式变换器的优化设计

 从半径渐变波导的耦合波方程出发,利用龙格-库塔法进行优化数值迭代,得到在3 mm波段,TE₀₃-TE₀₂, TE₀₂-TE₀₁高效率模式变换器的设计参数。通过优化程序,设计出了6周期TE₀₃-TE₀₂和3周期TE₀₂-TE₀₁模式变换器优化尺寸。利用CST微波工作室电磁仿真软件对结构尺寸进行优化仿真,仿真结果与优化程序计算结果基本一致。以此数据设计中心频率94 GHz的TE₀₃-TE₀₂,TE₀₂-TE₀₁模式变换器功率转换效率可以达到98.5%以上,90%功率转换的绝对带宽分别达到3.5和7.0 GHz以上,优于设计要求。     

TM01-TE11双弯形圆波导模式转换器轴线长度与拍波波长关系研究

 对于TM₀₁-TE₁₁双弯形圆波导模式转换器，在保持出射端口与入射端口轴线平行且两曲率半径相等时，通过对其轴线长度与TE₁₁和TM₀₁模式间拍波波长的分析，证明了在两模式间实现有效转换时，两者成正比例关系，且比例常数为2/2，并给出了相应的物理解释。通过对具体参数及模拟结果的分析，得出了模拟功率转换效率超过98%时所适用的频率下限，其值为TM₀₁模式截止频率的1.07倍。     

PEG-Na2SO4-PAR体系中Pd(Ⅱ)、U(Ⅵ)、Mo(Ⅵ)的萃取分离

本文研究了在聚乙二醇－２０００（ＰＥＧ）－硫酸钠（Ｎａ２ＳＯ４）－４－（２－吡啶偶氮）－间苯二酚（ＰＡＲ）体系中,Ｐｄ（Ⅱ）、Ｕ（Ⅵ）、Ｌａ（Ⅲ）、Ｍｏ（Ⅵ）的萃取行为。实验结果表明,在ｐＨ４．５￣７．５溶液中,Ｐｄ（Ⅱ）、Ｕ（Ⅵ）、可被ＰＥＧ相几乎完全萃取,Ｌａ（Ⅲ）部分被萃取,而Ｍｏ（Ⅵ）则不被蔺取,从而实现了Ｍｏ（Ⅵ）与Ｐｄ（Ⅱ）、Ｕ（Ⅵ）混合离子间的定量分离,并初步探讨了ＰＥＧ相的萃取机理     

Exploring the additivity of binaural and monaural masking release

Experiment 1 examined comodulation masking release (CMR) for a 700-Hz tonal signal under conditions of N(o)S(o) (noise and signal interaurally in phase) and N(o)S(π) (noise in phase, signal out of phase) stimulation. The baseline stimulus for CMR was either a single 24-Hz wide narrowband noise centered on the signal frequency [on-signal band (OSB)] or the OSB plus, a set of flanking noise bands having random envelopes. Masking noise was either gated or continuous. The CMR, defined with respect to either the OSB or the random noise baseline, was smaller for N(o)S(π) than N(o)S(o) stimulation, particularly when the masker was continuous. Experiment 2 examined whether the same pattern of results would be obtained for a 2000-Hz signal frequency; the number of flanking bands was also manipulated (two versus eight). Results again showed smaller CMR for N(o)S(π) than N(o)S(o) stimulation for both continuous and gated masking noise. The CMR was larger with eight than with two flanking bands, and this difference was greater for N(o)S(o) than N(o)S(π). The results of this study are compatible with serial mechanisms of binaural and monaural masking release, but they indicate that the combined masking release (binaural masking-level difference and CMR) falls short of being additive.     

流动注射氢化物发生-原子荧光光谱法测定土壤中有效态As(Ⅲ)和As(Ⅴ)

提出了一种流动注射氢化物发生 原子荧光光谱法测定土壤中有效态As(Ⅲ )和As(Ⅴ )的方法。在0 1mol·L-1柠檬酸介质 (pH =3 1)中选择性测定As(Ⅲ ) ,然后用L 半胱氨酸流动注射在线还原As(Ⅴ )后测定总砷 ,由二者之差求得As(Ⅴ )。设计了在线还原及氢化物发生流路和操作程序 ,选择了各项化学条件和流路参数。As(Ⅲ )和As(Ⅴ )的检出限 (3σ)分别为 0 11和 0 0 7ng·mL-1。对于 10ng·mL-1As(Ⅲ )溶液 ,连续7次测定得精密度 (RSD)为 1 43% ,应用于实际土壤样品的测定 ,加标回收率在 82 %～ 10 4%之间     

Synthesis, characterization and relaxivity of DTPA double alkyl esters heterocyclic gadolinium(III) complexes

The DTPA ligand modified by heterocyclic compound and linked through double alkyl ester covalent bond was synthesized by acylation reaction between diethylenetriamine pentaacetic (DTPA) bisanhydride and a novel heterocyclic compound. The corresponding paramagnetic Gd(III) complex was gained by the reaction of the DTPA ligand with GdCl3.6H2O. The structure of the ligand and its Gd(III) complex was characterized by elemental analysis, FTIR and 1H NMR, and the longitudinal relaxivity (R1) was measured. Besides, the magnetic resonance imaging of the new Gd(III) complex in vitro was studied. The result suggested that the stability of the complex was well, and when the Gd(III) quantity was identical, the R1 of the Gd(III) complex (5.12 mmol x L(-1) x s(-1)) was higher than the clinical magnetic resonance imaging contrast agent Gd-DTPA (3.64 mmol x L(-1).     

Co-transition absorption property of K2ZnCl4:Co2+ crystal

Single-crystal K(2)ZnCl(4) doped with Co2+ has been grown successfully by use of the Czochralski technique. The absorption spectrum of the crystal was measured. The most intense line, centered at 650 nm, was associated with the transition (4)A(2)-->(4)T(1P), and a novel and important result that corporate transition (co-transition) between (4)A(2)-->(4)T(1F) and (4)A(2)-->(4)T(2) of Co2+ in the region of 1300-2400 nm was found and discussed. The mechanism that caused the phenomenon was explained by energy-level splitting theory. In the tetrahedral approximation, using the quantum and Tanaba-Sugano theories, Racah parameter B and crystal field parameter 10Dq were calculated. The optical energy gap, deduced to be 4.82 eV, was lower than that of pure K2ZnCl4.     

DTPA双酰胺杂环钆(Ⅲ)配合物的合成、表征与弛豫效能

通过二乙三胺五乙酸(DTPA)酸酐与一种新型杂环化合物的酰化反应,得到了双酰胺共价键链接、杂环化合物修饰的DTPA配体。再与GdCl₃·6H₂O反应得到相应的顺磁性钆(Ⅲ)配合物。通过元素分析、FTIR、1H NMR等手段表征了配体和金属配合物的结构,进而测定了配合物的纵向弛豫率(R₁)。结果表明,配合物分子稳定性很好,且在同等含钆量条件下,这种新型钆(Ⅲ)金属配合物的R₁(5.12 mmol·L-1·s-1)高于临床应用的磁共振成像对比剂Gd-DTPA(3.64 mmol·L-1·s-1)。     

金电极上2,3-二巯基丁二酸镍配合物修饰膜的化学特性研究

采用非现场表面增强拉曼光谱(ex-situ SERS)与电还原等方法,对2,3-二巯基丁二酸(DMSA)及与Ni(Ⅱ)所形成的配位化合物DMSA-Ni(Ⅱ),在活性Au电极表面的修饰膜进行了研究。先由紫外吸收光谱测算了DMSA与Ni2+形成的配合物参数,其配位比为1∶2,稳定常数为4.716×107,可知形成的配合物较稳定。研究表明,DMSA与活性Au发生了吸附作用,DMSA-Ni(Ⅱ)形成的是S—Ni—O配位键,DMSA-Ni(Ⅱ)在Au电极上电还原时出现了两个还原峰,认为：负扫出现的第1个还原峰是由DMSA-Ni(Ⅱ)配合物动态平衡中的DMSA与Au吸附键合的RS—Au基团产生,而第2个还原峰与配合物中的Ni2+有关。通过Au表面DMSA-Ni(Ⅱ)修饰膜覆盖度的测定、分子面积的比对表明,DMSA-Ni(Ⅱ)在活性Au表面的分子排布状态可能是分散的或局部连接的单分子层,而非聚集在一起的致密层或分子间重叠的多层形式。     

19F Magnetic resonance imaging of perfluorooctanoic acid encapsulated in liposome for biodistribution measurement

The tissue distribution of perfluorooctanoic acid (PFOA), which is known to show unique biological responses, has been visualized in female mice by (19)F magnetic resonance imaging (MRI) incorporated with the recent advances in microimaging technique. The chemical shift selected fast spin-echo method was applied to acquire in vivo (19)F MR images of PFOA. The in vivo T(1) and T(2) relaxation times of PFOA were proven to be extremely short, which were 140 (+/- 20) ms and 6.3 (+/- 2.2) ms, respectively. To acquire the in vivo (19)F MR images of PFOA, it was necessary to optimize the parameters of signal selection and echo train length. The chemical shift selection was effectively performed by using the (19)F NMR signal of CF(3) group of PFOA without the signal overlapping because the chemical shift difference between the CF(3) and neighbor signals reaches to 14 kHz. The most optimal echo train length to obtain (19)F images efficiently was determined so that the maximum echo time (TE) value in the fast spin-echo sequence was comparable to the in vivo T(2) value. By optimizing these parameters, the in vivo (19)F MR image of PFOA was enabled to obtain efficiently in 12 minutes. As a result, the time course of the accumulation of PFOA into the mouse liver was clearly pursued in the (19)F MR images. Thus, it was concluded that the (19)F MRI becomes the effective method toward the future pharmacological and toxicological studies of perfluorocarboxilic acids.     

Highly efficient infrared-to-visible energy upconversion in Er(3+):Y(2)O(3)

Very intense green and red emission was observed at room temperature from the (4)S(3/2) and (4)F(9/2) levels of Er(3+):Y(2)O(3). A cw diode laser at 975 nm was used as a pump for resonant sequential excitation of the (4)I(11/2) and (4)F(7/2) levels. The fluorescence was easily visible to the naked eye, even with 27 mW of excitation power. It was found that at 850 mW of cw excitation power the total luminance was 39,000 cd/m(2). This corresponds to ~100 muW of green emission and 270 muW of red emission.     

四碘荧光素与牛血清白蛋白相互作用的荧光光谱研究

用荧光光谱法研究了四碘荧光素与牛血清白蛋白的结合反应。测得该反应的结合常数为2.65×105 L·mol-1,结合数n=0.86,探讨了它们的相互作用机理。四碘荧光素主要以疏水作用力与牛血清白蛋白相互作用,同时,牛血清白蛋白的存在会增强四碘荧光素的发光,且强度的变化在一定范围内与牛血清白蛋白的浓度成正比。以此为基础在pH 8.64的条件下建立了测定牛血清白蛋白的方法。该法的线性范围为8×10-7～9×10-6 mol·L-1,精密度为3.4%,检出限9.88×10-8 mol·L-1。