掺Cu~+氟磷玻璃的分时荧光及能量转移

本文分别在室温和低温下测定了氟磷酸盐玻璃中用不同波长激发Cu~+的分时荧光光谱以及不同发光波长的荧光寿命.随延迟时间增加,发光峰值移向长波.当采用长波长激发时,在发光主峰两边出现多个子峰结构,展现了激活离子之间的能量转移.     

Mechanisms of fluorescence enhancement in rare earth sol-gel glass containing Al

Analysis of glasses containing Eu and Tb dopants yields new insights about the role of Al³⁺ co-doping in improving fluorescence yield of glasses containing rare earth (RE) dopants. Our work suggests that Al co-doping enhances fluorescence by two important mechanisms. (1) At low Al:RE ratio the site symmetry is lowered, allowing more admixture of opposite parity wavefunctions and increased transition probability. (2) At high Al:RE ratio, the highest frequency phonons are of lower energy; so nonradiative decay rates are reduced. In addition, a new technique - post-annealing immersion - is introduced, which allows the study of RE location in the sol-gel matrix. Al co-doping is observed to increase the tendency for RE ions to reside on pore surfaces.     

LiF及AlF3对掺Tm3+氟磷玻璃光学、光谱性质、析晶性能及结构的影响

为了平衡掺铥氟磷玻璃对辐射寿命、发射截面和析晶稳定性的综合要求,研究了LiF及AlF₃对掺铥氟磷玻璃光学光谱性质和析晶性能的影响. 研究表明,高达30 mol%的LiF仍可保证氟磷玻璃具有较好的析晶稳定性能且其在提高Tm³⁺离子的辐射寿命上具有非常重要的作用;高AlF₃玻璃具有很好的析晶稳定性能,但Tm³⁺离子在其中的辐射寿命下降较快; 鉴于LiF和AlF₃含量的相对变化对发射截面的影响不大,因此 关键词： 氟磷玻璃 辐射寿命 发射截面 析晶稳定性     

Laser-induced quadrupole-quadrupole collisional energy transfer in Xe-Kr

By considering the relative velocity distribution function and multipole expansion interaction Hamiltonian, a three-state model for calculating the cross section of laser-induced quadrupole-quadrupole collisional energy transfer is presented. Calculated results in Xe-Kr system show that in the present system, the laser-induced collision process occurs for ～4 ps, which is much shorter than the dipole-dipole laser-induced collisional energy transfer (LICET) process. The spectrum of laser-induced quadrupole-quadrupole collisional energy transfer in Xe-Kr system has wider tunable range in an order of magnitude than the dipole-dipole LICET spectra. The peak cross section decreases and moves to the quasi-static wing with increasing temperature and the full width at half peak of the profile becomes larger as the system temperature increases.     

Enhancement of Tb emission by non-radiative energy transfer from Dy in silicate glass

A study of energy transfer was performed in dysprosium-terbium-doped silicate glasses at room temperature. Enhancement of the Tb³⁺ emission and a decrease in the Dy³⁺ emission are observed as a result of energy transfer from Dy³⁺ ions to Tb³⁺ ions. The energy transfer efficiencies, transfer probabilities, as well as average donor-acceptor distances were also calculated. It is concluded that the energy transfer mechanism between Dy³⁺ and Tb³⁺ ion is mainly electric dipole-dipole in nature.     

Calculation of laser induced collisional energy transfer in the Sr-Ca system

Based on the four-state model of laser-induced collisional energy transfer,the cross section of the collisional energy transfer in the Sr-Ca system is obtained.Various factors,including field intensity,relative speed,and temperature,which influence the collisional cross section,are discussed for illustrating the features of the Sr-Ca laser-induced collisional energy transfer(LICET) process.The calculated results show that the LICET spectral profiles obviously become narrower when the laser field intensity i...     

Investigation on luminescence and energy transfer in Tb-doped lead telluroborate glasses

This work reports on the visible luminescence properties and energy transfer processes responsible for non-exponential nature of the decay curves and also quenching of luminescence intensity of the ⁵D₃→⁷F_J transitions of Tb³⁺ ions in lead telluroborate (PTB) glasses containing different Tb³⁺ concentrations. The XRD and FT-IR spectra were measured to study the glassy nature and composition of the prepared glasses. The radiative properties are determined using the Judd-Ofelt theory to judge the suitability of studied glasses as practical photonic material. These parameters suggest that the PTBTb20 glass has the potential to produce intense green emission (544 nm) through the ⁵D₄→⁷F₅ transition.     

Ba-Sr系统激光感生碰撞能量转移的数值计算

以现有的激光感生碰撞能量转移的四能级理论模型为基础,通过直接积分态振幅的运动方程,对弱场、强场两种情况下Ba-Sr系统的激光感生碰撞能量转移过程进行了数值计算,得到了两种情况下的激光感生碰撞跃迁概率和碰撞截面的谱线线型.在弱场情况下的数值计算结果与近似解析解的计算结果符合很好.对强场情况下的数值积分计算结果表明：激光感生碰撞作用随转换激光强度的增大而增强;强场时激光感生碰撞截面谱线的峰值位置明显偏离了共振频率并向紫端移动,且碰撞截面谱线的半宽度(即调谐范围)较之弱场明显变小. 关键词： 激光感生碰撞能量转移 碰撞截面 Ba-Sr系统 强场     

Differential, elastic integral and moment transfer cross sections for electron scattering from N2 at intermediate- and high-energies

A complex optical model potential modified by incorporating the concept of bonded atom, with the overlapping effect of electron clouds between two atoms in a molecule taken into consideration, is firstly employed to calculate the differential cross sections, elastic integral cross sections, and moment transfer cross sections for electron scattering from molecular nitrogen over the energy range 300—1000eV by using additivity rule model at Hartree—Fock level. The bonded-atom concept is used in the study of the complex optical model potential composed of static, exchange, correlation polarization and absorption contributions. The calculated quantitative molecular differential cross sections, elastic integral cross sections, and moment transfer cross sections are compared with the experimental and theoretical ones wherever available, and they are found to be in good agreement with each other. It is shown that the additivity rule model together with the complex optical model potential modified by incorporating the concept of bonded atom is completely suitable for the calculations of differential cross section, elastic integral cross section and moment transfer cross section over the intermediate- and high-energy ranges.     

稀土离子间反斯托克斯能量传递计算的改进2.数值模拟计算和分析

对稀土离子能级的动力学过程进行了数值计算,并对各个能级的布居概率改变进行了分析。发现如果不考虑斯托克斯过程和反斯托克斯过程之间的区别而采用原有声子辅助能量传递理论中相同的计算公式对待两种过程的话,得到的理论计算结果就与我们实验得到的校准的结果不一致,为了能够准确描述反斯托克斯能量传递过程,众所周知的量子喇曼理论相对于经典拉曼理论在斯托克斯与反斯托克斯过程的强度比上所增加的比值系数exp{ΔE/kT}被首次成功地引入来描述反斯托克斯能量传递。在能量传递计算理论中引入该比值系数之后,理论计算结果与实验结果符合的非常好,并且发现该比值系数在对纳米尺度材料的光子学研究探索中会发挥至关重要的作用。     

中、高能电子被SO2分子散射的微分截面、动量转移截面及弹性积分截面

在考虑分子内成键原子间的电子云重叠效应的基础上,提出了一种能够准确计算“中、高能电子-分子”散射的微分截面、动量转移截面及弹性积分截面的修正势方法.利用可加性规则、使用Hartree-Fock波函数并采用被这一方法修正过的复光学势,在100—1000eV内对电子被SO2分子散射的微分截面、动量转移截面及弹性积分截面进行了计算,并将计算结果与实验及其他理论结果进行比较.结果表明,利用这一修正过的复光学势及可加性规则获得的微分截面比利用未修正的复光学势及可加性规则得到的结果准确得多,计算得到的动量转移截面及弹性积分截面在入射电子能量不低于200eV时也都比较接近实验值.     

Spectroscopic studies of Eu doped calibo glass: Effect of the addition of barium carbonate, energy transfer in the presence of Sm

Optical properties of Eu³⁺ doped calibo glass has been studied in presence and absence of BaO and their dependence on BaO concentration explored. It is found that the fluorescence intensity increases and approaches maximum for 10% of BaO content but get quenched for higher concentrations. The energy transfer between two asimilar rare earth ions (Sm³⁺:Eu³⁺) doped in calibo glass has been verified on the basis of changes in fluorescence yield.     

中、高能电子被SO2分子散射的微分截面、动量转移截面及弹性积分截面

在考虑分子内成键原子间的电子云重叠效应的基础上, 提出了一种能够准确计算“中、高能电子-分子”散射的微分截面、动量转移截面及弹性积分截面的修正势方法. 利用可加性规则、使用Hartree-Fock波函数并采用被这一方法修正过的复光学势, 在100—1000eV内对电子被SO₂分子散射的微分截面、动量转移截面及弹性积分截面进行了计算, 并将计算结果与实验及其他理论结果进行比较. 结果表明, 利用这一修正过的复光学势及可加性规则获得的微分截面比利用未修正的复光学势及可加性规则得到的结果准 关键词： 可加性规则 微分截面 动量转移截面 电子散射     

The cross sections and their temperature dependence of collisional energy transfer from high vibrationally excited ethylene molecules to electronic ground state Rubidium atoms

The cross sections and their temperature dependence of collisional energy transfer from the high vibrationally excited C_2H_4 to the electronic ground sate of Rb (V-E) have been studied by the method of IR laser pump combined with fluorescence probe. The fluorescence of rudidium atoms due to V-E energy transfer was detected. The measured rate constants of this V-E energy transfer is about 10~(-10)cm~2molec~(-1)s~(-1) and the corresponding cross section varies from 60 (?)~2 to 90 (?)~2. The cross sections decrease with increasing temperature over the temperature range of 393-683 K.     

Nonradiative charge transfer in collisions of protons with rubidium atoms

The nonradiative charge-transfer cross sections for protons colliding with Rb(5s) atoms are calculated by using the quantum-mechanical molecularorbital close-coupling method in an energy range of 10 3 keV-10 keV.The total and state-selective charge-transfer cross sections are in good agreement with the experimental data in the relatively low energy region.The importance of rotational coupling for chargetransfer process is stressed.Compared with the radiative charge-transfer process,nonradiative charge transfer is a dominant mechanism at energies above 15 eV.The resonance structures of state-selective charge-transfer cross sections arising from the competition among channels are analysed in detail.The radiative and nonradiative charge-transfer rate coefficients from low to high temperature are presented.     

中低速C3+与He，Ne，Ar原子相互作用过程中单电子转移绝对截面的测量

实验测量了1.7v₀—4.2v₀(v₀为玻尔速度,v₀=2.19×10⁸cm/s)的C³⁺与He,Ne,Ar原子碰撞过程中单电子转移绝对截面.将实验结果与多体经典轨道蒙特卡罗模拟计算结果做了比较,发现测量结果与多体经典轨道蒙特卡罗模拟计算结果在趋势上相符.当入射离子速度在1.7v₀—2 关键词： 离子-原子碰撞 单电子转移 绝对截面     

Near infrared fluorescence and energy transfer in Ce/Nd Co-doped CaxSr1−xS

Novel near infrared (NIR) phosphors Ca_xSr_1−xS:Ce³⁺,Nd³⁺ were synthesized by a solid state reaction. The NIR emission was realized through an efficient absorption by the allowed 4f-5d transition of Ce³⁺ and efficient energy transfer to Nd³⁺ via well-matched energy levels. Ce³⁺ and Nd³⁺ content in CaS/SrS was optimized. It was found that CaS:Ce³⁺,Nd³⁺ gave much stronger NIR emission than that of SrS:Ce³⁺,Nd³⁺. Further studies on Ca_xSr_1−xS:Ce³⁺,Nd³⁺ indicated that both visible emission of Ce³⁺ and NIR emission of Nd³⁺ were observably affected by Ca/Sr ratio. The energy transfer efficiency, which can be estimated from fluorescence lifetime of Ce³⁺, increased from 52% to 74% for the Ca_xSr_1−xS:Ce³⁺,Nd³⁺ (x=0 to 1) series, accompanied with a shift of maximal emission wavelength of Ce³⁺ from 482 to 505 nm. The results showed that overlap between emission spectrum of Ce³⁺ and excitation spectrum of Nd³⁺ plays an important role in the energy transfer efficiency, and Ce³⁺ emitting in green or blue-greenish region sensitized the Nd³⁺ NIR fluorescence emission more efficiently than that in blue region.     

Survey and research on up-conversion emission character and energy transition of Yb/Er/Tm co-doped phosphate glass and glass ceramic

By conventional high-temperature melting method, Yb³⁺/Er³⁺/Tm³⁺ co-doped phosphate glass was synthesized. After annealing the precursor glass, the phosphate glass ceramic (GC) was obtained. By measuring the X-ray diffraction (XRD) spectrum, it is proved that the LiYbP₄O₁₂ and Li₆P₆O₁₈ nano-crystals have existed in the phosphate GC. The up-conversion (UC) emission intensity of the GC is obvious stronger compared to that of the glass. The reason is that the shorter distance between rare earth ions in the glass ceramic increases the energy transitions from the sensitized ions (Yb³⁺) to the luminous ions (Er³⁺ and Tm³⁺). By studying the dependence of UC emissions on the pump power, the 523 and 546 nm green emissions of Er³⁺ ions in the glass are two-photon processes. But in the glass ceramic, they are two/three-photon processes. The phenomenon implies that a three-photon process has participated in the population of the two green emissions. Using Dexter theory, we discuss the energy transitions of Er³⁺ and Tm³⁺. The results indicate the energy transition of Tm³⁺ to Er³⁺ is very strong in the GC, which changes the population mechanism of UC emissions of Er³⁺.     

A comparative study of the energy migration and energy transfer in highly doped Nd:YAG single crystal

The donor-donor (D-D) energy migration interaction parameter C_DD in high-concentration Nd³⁺-doped YAG laser crystal is estimated, for the first time, by using the Yokota-Tanimoto (Y-T) model and the spectral overlap model (SOM) of Kushida. Firstly, the experimental luminescence decay curves of ⁴F_3/2 state of Nd³⁺ ions in YAG laser crystal at room temperature for 2.0 and 3.0 at% Nd³⁺ concentrations reported by Mao are fitted successfully by using the Y-T model and the parameter C_DD is obtained to be 1.50×10⁻³⁹ cm⁶/s. Secondly, the parameter C_DD is also directly calculated by using the SOM of Kushida: C_DD is calculated to be 2.73×10⁻³⁹ cm⁶/s. By comparing the energy migration interaction parameter C_DD and the donor-acceptor (D-A) energy transfer interaction parameter C_DA (1.794×10⁻⁴⁰ cm⁶/s), it is concluded that energy migration rate between Nd³⁺ ions in YAG laser crystal was about 11 times larger than energy transfer rate, and that energy migration would play a very important role in high-concentration Nd³⁺ -doped YAG laser crystal.     

两原子相干共振能量传递的单次与N次能量提取

两原子间隔一定距离且两原子跃迁频率接近时,两原子之间可发生能量传递.理论研究了供能原子和受能原子两共振原子的能量传递.求解薛定谔方程得出两原子共振能量传递效率.结果表明,供能原子在真空场中的激发态寿命在能量传递效率中起到十分重要的作用.能量传递效率与两原子间距离的负三次幂的正弦值的平方成正比,在一阶近似条件下,与两原子间距离的6次方成反比.以供能原子处于激发态时为初始时刻,能量从初始时刻随时间由供能原子向受能原子传递,对受能原子的单次能量提取的最大值大约在供能原子寿命的2/3时刻;对受能原子的连续N次能量提取的最大值,每次提取时间大约在供能原子寿命的1/2时刻.