共查询到20条相似文献,搜索用时 15 毫秒
1.
A high-energy X-ray diffraction study has been carried out on a series of 0.5Li2S + 0.5[(1 − x)GeS2 + xGeO2] glasses with x = 0.0, 0.1, 0.2, 0.4, 0.6 and 0.8. Structure factors were measured to wave vectors as high as 30 Å−1 resulting in atomic pair distribution functions with high real space resolution. The three dimensional atomic-scale structure of the glasses was modeled by reverse Monte Carlo simulations based on the diffraction data. Results from the simulations show that at the atomic-scale 0.5Li2S + 0.5[(1 − x)GeS2 + xGeO2] glasses may be viewed as an assembly of independent chains of (Li+-S)2GeS2/2 and (Li+-O)2GeO2/2 tetrahedra as repeat units, where the Li ions occupy the open space between the chains. The new structure data may help understand the reasons for the sharp maximum in the Li+ ion conductivity at x ∼ 0.2. 相似文献
2.
Wenlong Yao 《Journal of Non》2008,354(18):2045-2053
The structure and properties of glasses in the MI + M2S + (0.1Ga2S3 + 0.9GeS2), M = Li, Na, K and Cs, system were studied using Raman, IR spectroscopy, DSC and density measurements to help better understand the ionic transport in these glasses. The glass forming ranges of these ternary glasses were compared to those of the binary alkali sulfide and germanium sulfide systems. The more extensive glass forming range in the Na2S system was used to examine the more extensive changes of structure and properties of these glasses as a function of Na2S content. As expected, non-bridging sulfurs (NBS) form with the addition of alkali sulfide. Unlike their oxide counterparts, however, the alkali sulfide doped glasses appear to support longer-range super-structural units. For example, evidence that the adamantine-like structure exists in the K2S and Cs2S modified glasses is found in the Raman spectra of the glasses. The structural role of the alkali iodide addition was also explored since the addition of alkali iodide helps to improve the conductivity. For most of these glasses, as observed in many other oxide glasses, the added MI dissolves interstitially into the glass structure network without changing the alkali sulfide network structure. In 0.6Na2S + 0.4(0.1Ga2S3 + 0.9GeS2) glasses, however, the added NaI may affect the glass structure as it causes systematic changes in the frequency of the Ge-S network mode as seen in the Raman spectra. 相似文献
3.
Glasses of the system: (70−x) TeO2 + 15B2O3 + 15P2O5 + xLi2O, where x = 5, 10, 15, 20, 25 and 30 mol% were prepared by melt quench technique. Dependencies of their glass transition temperatures (Tg) and infrared (IR) absorption spectra on composition were investigated. It is found that the gradual replacement of oxides, TeO2 by Li2O, decreases the glass transition temperature and increases the fragility of the glasses. Also, IR spectra revealed broad weak and strong absorption bands in the investigated range of wave numbers from 4000 to 400 cm−1. These bands were assigned to their corresponding bond modes of vibration with relation to the glass structure. 相似文献
4.
Studies of some mechanical and optical properties of: (70 − x)TeO2 + 15B2O3 + 15P2O5 + xLi2O glasses
Specimens of the glassy system: (70 − x)TeO2 + 15B2O3 + 15P2O5 + xLi2O, where x = 5, 10, 15, 20, 25 and 30 mol% were prepared by the melt-quenching. An ultrasonic pulse-echo technique was employed, at 5 MHz, for measuring: the ultrasonic attenuation, longitudinal and shear wave velocities, elastic moduli, Poisson ratio, Debye temperature and hardness of the present glasses. It is found that the gradual replacement of TeO2 by Li2O in the glass matrix up to 30 mol% leads to decrease the average crosslink density and rigidity of prepared samples which affects the properties, i.e., the hardness, ultrasonic wave velocities and elastic moduli are decreased, while the Poisson ratio and the ultrasonic attenuation are increased. Also, optical absorption spectra were recorded in the range, 200-800 nm for these glasses. The obtained results showed that a gradual shift in the fundamental absorption edge toward longer wavelengths occurred. Values of both of the optical energy gap, Eopt, and width tails, ΔE, are determined. It is observed that Eopt is decreased and ΔE increased with the increase of Li2O in the glass matrix up to 30 mol%. The compositional dependences of the above properties are discussed and correlated to the structure of tested glasses. 相似文献
5.
Qiang Mei 《Journal of Non》2003,324(3):264-276
The glass forming range of the Ag2S + B2S3 + GeS2 ternary system was investigated for the first time and a wide range of ternary glasses were obtained. The Archimedes’ method was used to determine the densities of the Ag-B-Ge glasses. The thermal properties of these thioborogermanate glasses were studied by DSC and TMA. The Raman, IR and NMR spectroscopy were used to explore the short-range order structure of the binary (Ag-B) and (Ag-Ge) and ternary (Ag-B-Ge) glasses. The results show the presence of bridging sulfur tetrahedral units, GeS4/2 and AgBS4/2, and trigonal units, BS3/2, in the ternary glasses. Non-bridging sulfur units, AgSGeS3/2 and Ag3B3S3S3/2 six membered rings, are also observed in these glasses at higher Ag2S modification levels because the further addition of Ag2S results in the degradation of the bridging structures to form non-bridging structures. The NMR studies show that Ag2S goes into the GeS2 subnetwork to form Ag3S3GeS1/2 groups before going to the B2S3 subnetwork. In doing so, it is suggested that B10S20 supertetrahedra exist in Ag2S + B2S3 and Ag2S + B2S3 + GeS2 glasses. Significantly B-S-Ge bonds form in the B2S3 + GeS2 glasses, whereas they appear to be absent in the ternary glasses. From these observations, a structural model for these glasses has been developed and proposed. 相似文献
6.
Glasses in the La2O3−CaO−B2O3 ternary system were studied. The glass forming range as determined by the appearance of the annealed cast was found to match previously published findings. Clear glasses were formed in the composition range of 5.7−19.1 mol% La2O3 with constant B2O3 content of 71.4 mol%, and in glasses of constant La2O3:CaO ratio of 1:4 with B2O3 content in the range of 71.4-55.0 mol%. The non-linear optical crystalline phase La2Ca2B10O19 was crystallized from the clear glasses after heat treatments, as determined by powder XRD. Two types of the LaBO3 crystalline phases were detected in the partially and the fully crystallized glass compositions outside the glass forming range. Data are reported for the glass transition temperature (Tg), dilatometric softening point (Td), linear coefficient of expansion (α), onset crystallization temperature (Tx), exothermal peak temperature (TP), density (ρ) and index of refraction (nD) in the clear glasses. 相似文献
7.
Yusuke Himei Tomohiro Nagakane Naoyuki Kitamura Akihiko Sakamoto 《Journal of Non》2008,354(27):3113-3119
Reduction in the temperature coefficient of the optical path length, dS/dT of Li2O-Al2O3-SiO2 glass-ceramics with near-zero thermal expansion coefficient was attempted using control of the temperature coefficient of electronic polarizability, ?, and the thermal expansion coefficient, α. The dS/dT value of 2.6 mol% B2O3-doped glass-ceramic was 12.5 × 10−6/°C, which was 0.9 × 10−6/°C smaller than that of B2O3-free glass-ceramic. On the other hand, reduction in dS/dT through B2O3 doping was not confirmed in precursor glasses. Results showed that reduction in dS/dT of the glass-ceramic through B2O3 doping is caused by the reduction in ?. The reduction in ? from B2O3 doping was probably attributable to numerical reduction in non-bridging oxide ions with larger ? value by the concentration of boron ions in the residual glass phase. In addition, application of hydrostatic pressure during crystallization was effective to inhibit precipitation of β-spodumene solid solution, which thereby decreases dS/dT. The dS/dT value of B2O3-doped glass-ceramic crystallized under 196 MPa was 11.7 × 10−6/°C. That value was slightly larger than that of silica glass. The α value of this glass-ceramic was smaller than that of silica glass. 相似文献
8.
E. Mansour 《Journal of Non》2011,357(5):1364-3380
Fourier transformation infrared spectra, density and DC electrical conductivity of 30Li2O · xCeO2⋅(70 − x)B2O3 glasses, where x ranged between 0 and 15 mol%, have been investigated. The results suggested that CeO2 plays the role of network modifier up to 7.5 mol%. At higher concentrations it plays a dual role; where most of ceria plays the role of network former. The density was observed to increase with increasing CeO2 content. The effect on density of the oxides in the glasses investigated is in the succession: B2O3 < Li2O < CeO2. Most of CeO2 content was found to be associated with B2O3 network to convert BO3 into B O4− units. The contribution of Li+ ions in the conduction process is much more than that due to small polarons. The conductivity of the glasses is mostly controlled by the Li+ ions concentration rather than the activation energy for CeO2 > 5 mol%. Lower than 5 mol% CeO2 the conductivity is controlled by both factors. The dependence of W on BO4− content supports the idea of ionic conduction in these glasses. 相似文献
9.
Bulk glasses of the system Ga20SbxS80−x (x = 5 and 40) were prepared for the first time by the known melt quenching technique. Non-isothermal differential scanning calorimetric (DSC) measurements of as-quenched Ga20SbxS80−x (x = 5 and 40) chalcogenide glasses reveal that the characteristic temperatures e.g. the glass transition temperature (Tg), the temperature corresponding to the maximum crystallization rate (Tp) recorded in the temperature range 400-650 K for x = 5 and 480-660 K for x = 40 are strongly dependent on heating rate and Sb content. Upon heating, these glasses show a single glass transition temperature (Tg) and double crystallization temperatures (Tp1 and Tp2) for x = 5 which overlapped and appear as a single crystallization peak (Tp) for x = 40. The activation energies of crystallization Ec were evaluated by three different methods. The crystallization data were examined in terms of recent analysis developed for non-isothermal conditions. The crystalline phases resulting from (DSC) have been identified using X-ray diffraction. 相似文献
10.
Electronegativity difference Δx, atomic size parameter δ and width of supercooled liquid region (ΔTx = Tx − Tg, where Tx is the onset crystallization temperature and Tg the glass transition temperature) are analysed for glasses of the ternary system Sb2S3-As2S3-Sb2Te3 as a function of arsenic atomic percentage.Correlation is investigated between the two bonds parameters (Δx and δ) and the width of supercooled liquid region ΔTx (which is generally reliable in estimating the stability against the crystallization of the glasses). It is found that this width of supercooled liquid region of the glasses in Sb2S3-As2S3-Sb2Te3 system depends on electronegativity difference and atomic size parameter. 相似文献
11.
Saswati Ghosh 《Journal of Non》2008,354(34):4081-4088
Several compositions based on BaO-CaO-Al2O3-SiO2 (BCAS) glass system have been studied in this investigation to see their applicability as sealant for solid oxide fuel cell (SOFC). The glasses as well as the corresponding glass-ceramics have been systematically characterized by differential thermal analysis, dilatometry, X-ray diffractometry, electron microscopy and impedance analysis to examine their suitability as sealant. While the glass transition temperature (Tg) determined from DTA are within 600-665 °C, the coefficient of thermal expansion (CTE) can be tailored between 9.5 and 13.0 × 10−6 K−1. These glasses are found to be well adhered with metallic interconnects, such as commercial ferritic steel (Crofer22APU), at an optimum sealing temperature of 850 °C. The shrinkage behavior of the developed glasses in their pellet form has also been investigated. The resistivities of the glass-ceramics, as obtained from impedance analysis, are found to be within 104-106 Ω cm at 800 °C. Under sandwiched condition between two metals, some of the developed compositions are found to maintain this high resistivity even after 100 h of operation. One of the glass compositions has shown a low leak-rate of the order of ∼10−7 Pa m2 s−1. 相似文献
12.
We have investigated the ionic transport in the 0.2[XNa2O · (1−X)Rb2O] · 0.8B2O3 mixed-alkali system with X=0.0, 0.2, 0.4, 0.6, 0.8, and 1.0 in the glassy and the undercooled-liquid state by means of impedance spectroscopy and tracer diffusion experiments. The calorimetric glass-transition temperature Tg obtained by differential scanning calorimetry shows a minimum with composition. The composition dependence of the electrical conductivity below Tg exhibits a minimum, as well. These deviations from an ‘ideal’ linear mixing rule are usually denoted as mixed-alkali effect. The dc conductivities times temperature σdc×T follow the Arrhenius law in the range below and above Tg, respectively. The glass transition appears as a kink in the Arrhenius presentation of σdc×T. Below the glass-transition temperature the onset frequency νon of the conductivity dispersion has an Arrhenius-like temperature dependence. According to ‘Summerfield scaling’ the activation enthalpies of σdc×T and νon are expected to be the same. This is indeed observed but only for the single-alkali compositions. The activation enthalpies of σdc×T as a function of composition show a classical mixed-alkali maximum, however the activation enthalpies of the onset frequencies as a function of composition exhibit a nearly constant behavior in contrast to the expectation from Summerfield scaling. The tracer diffusion measurements reveal a major difference in diffusion of 86Rb and 22Na in mixed-alkali glasses. A diffusivity crossover of tracer diffusion coefficients of 22Na and 86Rb occurs near X=0.2. By comparison of tracer and conductivity diffusivities the Haven ratio is deduced which shows a maximum near the conductivity minimum composition. 相似文献
13.
The optical properties of Cr3+ ions in lithium metasilicate (Li2O · SiO2) transparent glass-ceramics were investigated. The main crystalline phase precipitated was the lithium metasilicate (Li2O · SiO2) crystal. The percent crystallinity and crystalline size were ranging 65-75% and 20-35 nm, respectively. The color changes drastically to deep pink from emerald green upon crystallization. New and strong absorption bands appeared and the absorption intensity increases by about 10 times that in glass. These new absorption bands are found to be derived from Cr3+ ions in octahedral sites in the lithium metasilicate crystal lattice. Cr3+ ions substitute for three Li+ ions and occupy the distorted octahedral site between single [SiO4]n chains of lithium metasilicate crystal. The ligand field parameters can be estimated: 10Dq = 13 088 cm−1, B = 453 cm−1, Dq/B = 2.89 and C = 2036 cm−1. The near-infrared luminescence centered at 1250 nm was not detected in the deep pink glass-ceramics unlike emerald green glass. 相似文献
14.
The crystal growth kinetics of antimony trisulfide in (GeS2)0.1(Sb2S3)0.9 glass has been studied by microscopy and DSC. The linear crystal growth kinetics has been confirmed in the temperature range 492 ? T ? 515 K (EG = 405 ± 7 kJ mol−1). The applicability of standard growth models has been assessed. From the crystal growth rate corrected for viscosity plotted as a function of undercooling it has been found that the most probable mechanism is interface controlled 2D nucleated growth. The non-isothermal DSC data, corresponding to the bulk sample, can be described by the Johnson-Mehl-Avrami equation. 相似文献
15.
G. Paramesh 《Journal of Non》2011,357(5):1479-1484
Transparent glasses in the system 0.5Li2O-0.5M2O-2B2O3 (M = Li, Na and K) were fabricated via the conventional melt quenching technique. The amorphous and glassy nature of the samples was confirmed via the X-ray powder diffraction and the differential scanning calorimetry, respectively. The frequency and temperature dependent characteristics of the dielectric relaxation and the electrical conductivity were investigated in the 100 Hz-10 MHz frequency range. The imaginary part of the electric modulus spectra was modeled using an approximate solution of Kohrausch-Williams-Watts relation. The stretching exponent, β, was found to be temperature independent for 0.5Li2O-0.5Na2O-2B2O3 (LNBO) glasses. The activation energy associated with DC conduction was found to be higher (1.25 eV) for 0.5Li2O-0.5K2O-2B2O3 (LKBO) glasses than that of the other glass systems under study. This is attributed to the mixed cation effect. 相似文献
16.
Nobuaki Terakado 《Journal of Non》2008,354(18):1992-1999
Oxy-chalcogenide glasses with compositions of xGeO2-(100 − x)GeS2, where 0 ? x ? 100 mol%, have been prepared and studied in terms of their structures and optical properties. X-ray fluorescence spectroscopy shows that Ge:S ratio can deviate from GeS2 by ∼10 at.%, depending critically upon the preparation conditions. Raman scattering spectroscopy suggests that stoichiometric GeO2-GeS2 glasses have a heterogeneous structure in the scale of 1-100 nm. The optical gaps are nearly constant at 3.0-3.5 eV for glasses with 0 ? x ? 80 mol% and abruptly increase to ∼6 eV in GeO2. This dependence suggests that the optical gap is governed by GeS2 clusters, which are isolated and/or percolated. Composition-deviated glasses appear as orange and brown, and these glasses seem to have more inhomogeneous structures. 相似文献
17.
K1−xRbxSb5S8 (x = 0.25, 0.5, 0.75) is a well-defined single-phase system that undergoes a reversible phase-change. We determined the activation energy of glass transition and crystallization, respectively, for the three compositions using the Kissinger and Ozawa-Flynn-Wall equations. The results have shown that for K0.25Rb0.75Sb5S8 the crystallization mechanism could be interpreted in terms of a single-step reaction. For the other two compositions the glass-to-crystal transformation is a process of increasing mechanistic complexity with time and it involves simultaneously several different nucleation and growth events. The slope of the lines in the Avrami plots was observed to be independent of heating rate for K0.25Rb0.75Sb5S8 and the mean value of the activation energy was found to be 262 ± 6 kJ/mol. For the other two compositions, the slope varies with the heating rate. In the K0.25Rb0.75Sb5S8 glasses, bulk nucleation with three-dimensional crystal growth appears to dominate the phase-change process. 相似文献
18.
Yanmin Yang Baojiu Chen Cheng Wang Qingyu Meng Xiaoxia Zhao Weihua Di Xiaojun Wang Lihong Cheng Yong Peng 《Journal of Non》2008,354(31):3747-3751
Erbium-doped glasses with composition xGeO2-(80 − x)TeO2-10ZnO-10BaO were prepared by melt-quenching technique. The phonon sideband spectra and the optical absorption band edges for the host matrix were confirmed by means of the spectral measurements. Standard Judd-Ofelt calculations have been completed to these glasses. The dependence of up-conversion and infrared emission under 980 nm excitation on the glass composition was studied. The quantum efficiencies for the 4I13/2 → 4I15/2 transition of trivalent erbium in the glasses were estimated. 相似文献
19.
Glasses in the ternary system ZnO-Sb2O3-P2O5 were investigated as potential alternatives to lead based glasses for low temperature applications. The glass-forming region of ZnO-Sb2O3-P2O5 system has been determined. Structure and properties of the glasses with the composition (60 − x)ZnO-xSb2O3-40P2O5 were characterized by infrared spectra (IR), differential thermal analysis (DTA) and X-ray diffraction (XRD). The results of IR indicated the role of Sb3+ as participant in glass network structure, which was supported by the monotonic and remarkable increase of density (ρ) and molar volume (VM) with increasing Sb2O3 content. Glass transition temperature (Tg) and thermal stability decreased, and coefficient of thermal expansion (α) increased with the substitution of Sb2O3 for ZnO in the range of 0-50 mol%. XRD pattern of the heat treated glass containing 30 mol% Sb2O3 indicated that the structure of antimony-phosphate becomes dominant. The improved water durability of these glasses is consistent with the replacement of easily hydrated phosphate chains by corrosion resistant P-O-Sb bonds. The glasses containing ?30 mol% Sb2O3 possess lower Tg (<400 °C) and better water durability, which could be alternatives to lead based glasses for practical applications with further composition improvement. 相似文献
20.
Phannee Saengkaew Armin DadgarJuergen Blaesing Thomas HempelPeter Veit Juergen ChristenAlois Krost 《Journal of Crystal Growth》2009,311(14):3742-3748
We present MOVPE-grown, high-quality AlxGa1−x N layers with Al content up to x=0.65 on Si (1 1 1) substrates. Crack-free layers with smooth surface and low defect density are obtained with optimized AlN-based seeding and buffer layers. High-temperature AlN seeding layers and (low temperature (LT)/high temperature (HT)) AlN-based superlattices (SLs) as buffer layers are efficient in reducing the dislocation density and in-plane residual strain. The crystalline quality of AlxGa1−xN was characterized by high-resolution X-ray diffraction (XRD). With optimized AlN-based seeding and SL buffer layers, best ω-FWHMs of the (0 0 0 2) reflection of 540 and 1400 arcsec for the (1 0 1¯ 0) reflection were achieved for a ∼1-μm-thick Al0.1Ga0.9N layer and 1010 and 1560 arcsec for the (0 0 0 2) and (1 0 1¯ 0) reflection of a ∼500-nm-thick Al0.65Ga0.35N layer. AFM and FE-SEM measurements were used to study the surface morphology and TEM cross-section measurements to determine the dislocation behaviour. With a high crystalline quality and good optical properties, AlxGa1−x N layers can be applied to grow electronic and optoelectronic device structures on silicon substrates in further investigations. 相似文献