Diffusion and thermal diffusion of semidilute to concentrated solutions of polystyrene in toluene in the vicinity of the glass transition

The approaching glass transition in polystyrene/toluene solutions leads to a sharp decay of both the collective diffusion coefficient D and the thermal diffusion coefficient D(T) at concentrations above 0.2 g/cm(3). The Soret coefficient S(T) = D(T)/D follows power-law scaling from semidilute to concentrated and is not influenced by the slowing down of the dynamics associated with the glass transition. Both D and D(T) are governed by the same friction coefficient. The scaling behavior of S(T) with concentration on approach of the glass transition is compared to the divergence of S(T) near a consolute critical point.     

Determination of inelastic critical scattering at a first order phase transition in the CDW structure of 1TTaS2 using Mössbauer diffraction

We report Mössbauer diffraction measurements of the temperature dependence of the elastic and inelastic intensities at the (100) Bragg reflection in 1TTaS₂. These measurements use a newly developed microfoil conversion electron (MICE) spectrometry. They cover the temperature range from 19°C to 100°C, bracketing the first order 1T₁ to 1T₂ phase transition in the charge density wave structure at 79°C. The elastic Bragg peak shows a discontinuity at the phase transition as reported by Moret and Colella. The inelastic scattering shows a significant peak near the phase transition. This peak is interpreted as inelastic critical scattering at this first order phase transition.     

Novel voltage signal at proximity-induced superconducting transition temperature in gold nanowires

We observed a novel voltage peak in the proximity-induced superconducting gold (Au) nanowire while cooling the sample through the superconducting transition temperature. The voltage peak turned dip during warming. The voltage peak or dip was found to originate respectively from the emergence or vanishing of the proximity-induced superconductivity in the Au nanowire. The amplitude of the voltage signal depends on the temperature scanning rate, and it cannot be detected when the temperature is changed slower than 0.03 K/min. This transient feature suggests the non-equilibrium property of the effect. Ginzburg-Landau model clarified the voltage peak by considering the emergence of Cooper pairs of relatively lower free energy in superconducting W contact and the non-equilibrium diffusion of Cooper pairs and quasiparticles.     

Mri measurements of T1, T2 and D for gels undergoing volume phase transition

Gels consist of crosslinked polymer network swollen in solvent. The network of flexible long-chain molecules traps the liquid medium they are immersed in. Some gels undergo abrupt volume change, a phase transition process, by swelling-shrinking in response to external stimuli changes in solvent composition, temperature, pH, electric field, etc. We report that during volume phase transition changes of NMR longitudinal relaxation time T(1), NMR transverse relaxation time T(2), and diffusion coefficient D of the PMMA gel, and D of the NIPA gel. We describe how the gels were synthesized and the reason of using the snapshot FLASH imaging sequence to measure T(1), T(2), and D. Since T(1), T(2) and D maps have identical field of view and data are extracted from identical areas from their respective maps, these values can be correlated quantitatively on a pixel-by-pixel basis. Thus a complete set of NMR parameters is measured in-situ: the gels are in their natural state, immersed in the liquid, during the phase transition. The results of spectroscopic method agree with that of snapshot FLASH imaging method. For the PMMA gel T(1), T(2) and D decrease when gels undergo volume phase transition between deuterated acetone concentration of 30% and 40%. At its contracted state, T(1) is reduced to a little less than one order of magnitude, T(2) over two orders of magnitude, and D over one order of magnitude, smaller from values of PMMA gel at the swollen state. At an elevated temperature of 54 degrees C the thermosensitive NIPA gel is at a contracted state, with its D reduced to almost one order of magnitude smaller from that of the swollen NIPA at room temperature.     

Spin relaxation in the presence of electron-electron interactions

The D'yakonov-Perel' spin relaxation induced by the spin-orbit interaction is examined in disordered two-dimensional electron gas. It is shown that, because of the electron-electron interactions, substantially different spin relaxation rates may be observed depending on the technique used to extract them. It is demonstrated that the relaxation rate of a spin population is proportional to the spin-diffusion constant D(s), while the spin-orbit scattering rate controlling the weak-localization corrections is proportional to the diffusion constant D, i.e., the conductivity. The two diffusion constants get strongly renormalized by the electron-electron interactions, but in different ways. As a result, the corresponding relaxation rates are different, with the difference between the two being especially strong near a magnetic instability or near the metal-insulator transition.     

Evidence for a quasi-two-dimensional proton glass state in Cs5H3(SO4)(4); xH(2)O Crystals

We describe damping of hypersonic and ultrasonic longitudinal acoustic (LA) phonons in crystals of Cs 5H (3)(SO (4))(4);xH 2O (PCHS) between 100 and 360 K. The damping of LA phonons exhibits strong dispersion caused by relaxation processes in the region of transformation into the glasslike phase (T(g) approximately 260 K). Near T(g) the damping of ultrasonic phonons propagating in the basal plane reflects the cooperative freezing of acid protons. The damping of LA phonons propagating perpendicular to the basal plane can be fit by the Debye model and is due to the interaction between protons and LA phonons. This suggests that the proton glass state that is realized at T相似文献   

Detailed study of the de Haas-van Alphen effect in the Shubnikov state of LuNi2B2C

We present de Haas-van Alphen (dHvA) measurements in the normal and in the superconducting state of LuNi₂B₂C. Inside the superconducting state, we observe quantum oscillations of a spherical Fermi-surface sheet in all crystallographic directions. Apart from the field region close to the phase transition where a strong peak effect hampers the analysis of the dHvA signal, the additional damping of the quantum oscillations inside the superconducting state is much smaller than expected from theory. For the magnetic field aligned along the [100] direction, three different dHvA frequencies are visible in the superconducting state. In particular, the orbit related to a cushion-like Fermi surface does not show any additional damping at and below the upper critical field contrary to theoretical expectations of simple effective one-band theories. Consequently, the superconducting gap on this Fermi-surface sheet can only evolve at lower fields than the observed bulk critical field, B _c2 ≈ 8 T, which clearly points to a Fermi-surface-sheet-dependent gap opening in LuNi₂B₂C.     

Evidence of a reentrant peierls distortion in liquid GeTe

We report a detailed study of the ultrasonic damping near the nematic-smectic- A phase transition of terephtal-bis- p-p(')-butylaniline (TBBA). Two mechanisms contribute to the damping. One is isotropic; it is associated with the critical fluctuations, and leads to a scaling behavior of the 3D- XY type which is observed up to 15 degrees C from the transition, even though the transition is first order. The other is anisotropic; it appears only in the smectic- A phase, and is associated with the relaxation of the order-parameter modulus.     

Test of the Stokes-Einstein relation in a two-dimensional Yukawa liquid

The Stokes-Einstein relation, relating the diffusion and viscosity coefficients D and eta, is tested in two dimensions. An equilibrium molecular-dynamics simulation was used with a Yukawa pair potential. Regimes are identified where motion is diffusive and D is meaningful. The Stokes-Einstein relation, Deta proportional k(B)T, was found to be violated near the disordering transition; under these conditions collective particle motion exhibits dynamical heterogeneity. At slightly higher temperatures, however, the Stokes-Einstein relation is valid. These results may be testable in strongly coupled dusty plasma experiments.     

Melting at alkyl side chain comb polymer interfaces

Infrared visible sum frequency generation (SFG) spectroscopy has been used to study structure and melting transition temperatures of alkyl-side chain-acrylate comb polymers at air and solid interfaces. At the air interface, the SFG spectra show methyl bands and two transitions are observed: the first, near the bulk melting temperature, T(m), and the second 10-20 degrees C higher than T(m). The shorter the alkyl side chain, the larger the difference between the two transition temperatures. In contrast, methylene bands are observed at sapphire interface with a single transition near T(m) (C18).     

Nanoscale periodicity in stripe-forming systems at high temperature: Au/W(110)

We observe using low-energy electron microscopy the self-assembly of monolayer-thick stripes of Au on W(110) near the transition temperature between stripes and the nonpatterned (homogeneous) phase. We demonstrate that the amplitude of this Au-stripe phase decreases with increasing temperature and vanishes at the order-disorder transition (ODT). The wavelength varies much more slowly with temperature and coverage than theories of stress-domain patterns with sharp boundaries would predict, and maintains a finite value of about 100 nm at the ODT. We argue that such nanometer-scale stripes should often appear near the ODT.     

Self-diffusion of tris-naphthylbenzene near the glass transition temperature

We present a direct measurement of self-diffusion of a single-component glass-forming liquid at the glass transition temperature. Forward recoil spectrometry is used to measure the concentration profiles of deuterio and protio 1,3-bis-(1-naphthyl)-5-(2-naphthyl)benzene (TNB) following annealing-induced diffusion in a vapor-deposited bilayer. These experiments extend the range of measured diffusion coefficients in TNB by 6 orders of magnitude. The results indicate a decoupling of translational diffusion coefficients from viscosity or rotation. At T(g), D(T) is 400 times larger than expected from the Stokes-Einstein equation.     

Effect of the alpha-gamma phase transition on the stability of dislocation loops in bcc iron

Body-centered-cubic iron develops an elastic instability, driven by spin fluctuations, near the alpha-gamma phase transition temperature T(c) = 912 degrees C that is associated with the dramatic reduction of the shear stiffness constant c' (c(11)-c(12))/2 near T(c). This reduction of c' has a profound effect on the temperature dependence of the anisotropic elastic self-energies of dislocations in iron. It also affects the relative stability of the a[100] and a/2[111] prismatic edge dislocation loops formed during irradiation. The difference between the anisotropic elastic free energies provides the fundamental explanation for the observed dominant occurrence of the a[100], as opposed to the a/2[111], Burgers vector configurations of prismatic dislocation loops in iron and iron-based alloys at high temperatures.     

Refractive damping of Fraunhofer diffraction in light ion-nucleus elastic scattering at high energy

Angular distributions for elastic scattering of 100 MeV and 140 MeV alpha particles by heavy nuclei are characterized by strong damping of the Fraunhofer diffraction oscillations at large angles. This effect is attributed to refraction by the real part of the alphanucleus potential. It is shown that this can be accounted for through a technical modification of Frahn's closed formalism for strong absorption scattering together with a suitable parameterization of the nuclear scattering coefficients. The result exhibits not only the characteristic filling in of the Fraunhofer minima at large angles, but also a subtle interplay of Coulomb and nuclear effects which produce a characteristic dip and hump in the lower Fraunhofer envelope at smaller angles. It is shown that less structured 180 MeV proton-nucleus elastic angular distributions can also be accounted for. Finally, it is suggested that the refractive damping of the Fraunhofer oscillations does not appear at lower energies because of the masking of refraction by quantal surface reflection from the complex nuclear potential, and it is shown how this effect can be included in the formalism.     

Resistance noise scaling in a dilute two-dimensional hole system in GaAs

We have measured the resistance noise of a two-dimensional (2D) hole system in a high mobility GaAs quantum well, around the 2D metal-insulator transition (MIT) at zero magnetic field. The normalized noise power S(R)/R(2) increases strongly when the hole density p(s) is decreased, increases slightly with temperature (T) at the largest densities, and decreases strongly with T at low p(s). The noise scales with the resistance, S(R)/R(2) approximately R2.4, as for a second order phase transition such as a percolation transition. The p(s) dependence of the conductivity is consistent with a critical behavior for such a transition, near a density p(*) which is lower than the observed MIT critical density p(c).     

First-principles investigation on diffusion behaviours of H isotopes: From W(110) surface into bulk and in bulk W

The diffusion behaviours of hydrogen (H), deuterium (D), and tritium (T) from W(110) surface into bulk and in bulk W are investigated using a first-principles calculations combined with simplified models. The diffusion energy barrier is shown to be 1.87 eV from W(110) surface to the subsurface, along with a much reduced barrier of 0.06 eV for the reverse diffusion process. After H enters into the bulk, its diffusion energy barrier with quantum correction is 0.19 eV. In terms of the diffusion theory presented by Wert and Zener, the diffusion pre-exponential factor of H is calculated to be 1.57×10^-7 m²·s^-1, and it is quantitatively in agreement with experimental value of 4.1×10^-7 m²·s^-1. Subsequently, according to mass dependence (√1/m ) of H isotope effect, the diffusion pre-exponential factors of D and T are estimated to be 1.11×10^-7 m²·s^-1 and 0.91×10^-7 m²·s^-1, respectively.     

Resistivity of a non-galilean-invariant Fermi liquid near Pomeranchuk quantum criticality

We analyze the effect of the electron-electron interaction on the resistivity of a metal near a Pomeranchuk quantum phase transition (QPT). We show that umklapp processes are not effective near a QPT, and one must consider both interactions and disorder to obtain a finite and T dependent resistivity. By power counting, the correction to the residual resistivity at low T scales as AT((D+2)/3) near a Z=3 QPT. We show, however, that A=0 for a simply connected, convex Fermi surface in 2D, due to the hidden integrability of the electron motion. We argue that A>0 in a two-band (s-d) model and propose this model as an explanation for the observed T((D+2)/3) behavior.     

金属钨三键多核金属有机配合物高压拉曼及红外光谱研究

研究了金属钨三键多核金属有机配合物 [Cl(CO) 2 (DPPE)WCC6 H4CCC6 H4NC]2 ReCl(CO) 3(DPPE =bis(diphenylphosphino)ethane,(Ph) 2 PCH2 CH2 P(Ph) 2 )不同压力下的拉曼和红外光谱 (最高压力约 5 0kbar)。配合物在 3 0kbar存在一压力诱导二级相变。金属钨三键伸缩振动ν(WC)压力相关 (dν/dp)在低压相区 ( 0 5 9cm-1·(kbar) -1)与高压相区 ( 0 0 4cm-1·(kbar) -1)差别很大 (约 15倍 )。在高压下 ,从基团Cl(CO) 2 (DPPE)WC中的金属钨W向COπ 轨道的π 反馈明显增强 ,WC的键强度减弱 ,力常数减小和ν(WC)降低 ;此效应与压力缩短WC键 ,增大力常数和增加ν(WC)的效应互相竞争。     

Infrared spectroscopy of the charge ordering transition of Na0.5CoO2

We report infrared reflectivity study of charge ordering in a Na0.5CoO2 single crystal. In comparison with x=0.7 and 0.85 compounds, we found that the effective carrier density increases systematically with decreasing Na contents. The charge ordering transition only affects the optical spectra below 1000 cm(-1). A hump near 800 cm(-1) develops below 100 K, which is accompanied by the appearance of new lattice modes as well as the strong antiresonance feature of phonon spectra. These observations signify a polaronic characteristic of charge carriers. Below T(co), an optical gap develops at the magnitude of 2Delta approximately 3.5k(B)T(co) (T相似文献   

Scanning tunneling spectroscopic evidence of crossover transition in the two-impurity Kondo problem

To explore the crossover transition in the two-impurity Kondo problem, we calculate the differential conductance (dI / dV) corresponding to scanning tunneling spectroscopy (STS) measurements of a magnetic dimer adsorbed on a metal surface covered by a decoupling layer. With the aid of the numerical renormalization group (NRG) technique, we find that the peak structure of the dI / dV spectra near the Fermi level changes gradually as a function of the adatom separation and the coupling between the adatom localized spins and the metal surface conduction band. When the coupling becomes small, the peak disappears and, instead, a dip structure appears near the Fermi level. This dip structure is the manifestation of the strong antiferromagnetic correlation between the localized spins. We conclude that the gradual change of the dI / dV structure from a peak structure to a dip structure is an evidence of the crossover transition in the two-impurity Kondo problem.