高压下Sr2FeMoxNb1-xO6 (x=0, 0.3)的电学性质和结构稳定性

 采用金刚石压砧高压装置，研究了双钙态矿结构化合物Sr₂FeNbO₆及其掺杂物Sr₂FeMo_0.3Nb_0.7O₆在室温下，20 GPa内电阻和电容随压力的变化，并发现Sr₂FeNbO₆在7.5 GPa左右压力下发生了相变，而Sr₂FeMo_0.3Nb_0.7O₆的相变发生在2.8 GPa左右。并结合这两个样品的高压下的同步辐射能散X射线衍射实验，进一步证明了这两种相变是电子结构相变引起的。     

高压下纳米尺寸Sr2FeMoO6粉末的结构稳定性和电学特性的研究

 采用高分子网络凝胶法，通过控制其化学反应过程，合成了高纯的多晶纳米级粉末Sr₂FeMoO₆样品A（50 nm）和样品B（100 nm）。对其在高压下的结构稳定性和电学性质进行了研究，并将样品A和样品B的实验结果与已报道的粒度达微米级的块状Sr₂FeMoO₆样品C的实验结果进行了对比。在实验测量范围内，样品A（50 nm）呈现出最大的体弹模量B₀，并在电阻-压力曲线中，电阻下降区域表现出相对较缓的变化率，晶界效应可以用来很好地解释此结果。电学性质测量实验表明，样品在高压下发生了电子结构相变。     

高压下Sr2FeMoO6的电学性质与相变

 采用电阻和电容测量方法,在金刚石压砧装置上研究了Sr₂FeMoO₆多晶粉末在室温下和20 GPa内的电阻、电容和压力的关系。实验结果表明,样品的电阻和电容在约2.1 GPa的压力下都产生了突然的变化,发生了金属化相变。这些变化可能是由高压下Sr₂FeMoO₆的电子结构相变引起的。     

Sr2Fe1-xCoxMoO6体系中Co的元素替代效应

在成功制备具有双钙钛矿结构Sr2Fe1-xCoxMoO6系列样品的基础上,对其结构、输运性质和磁性质进行了系统研究.结果发现,随着Co替代浓度x值的增加,样品的电阻率-温度关系由半金属行为转变为半导体行为,其室温电阻率从3.9×10-5Ω·cm增大到6.0×10-1Ω·cm;样品由亚铁磁体转变成反铁磁体,其磁相变温度TN值也随之下降;Co对Fe的部分替代使其磁电阻效应受到抑制.基于对其电子结构的分析,其磁电阻效应的起源以及Co的元素替代效应也在文中进行了讨论.     

Sr2Fe1－xCoxMoO6体系中Co的元素替代效应

在成功制备具有双钙钛矿结构Sr₂Fe_1-xCo_xMoO₆系列样品的基础上，对其结构、输运性质和磁性质进行了系统研究.结果发现，随着Co替代浓度x值的增加，样品的电阻率-温度关系由半金属行为转变为半导体行为，其室温电阻率从3.9×10^-5Ω·cm增大到6.0×10^-1Ω·cm；样品由亚铁磁体转变成反铁磁体，其磁相变温度T_N值也随之下降; Co对Fe的部分替代使其磁电阻效应受到抑制.基于对其电子结构的分析，其磁电阻效应的起源以及Co的元素替代效应也在文中进行了讨论. 关键词： 双钙钛矿结构 2FeMoO₆')" href="#">Sr₂FeMoO₆ 磁电阻     

高温高压合成电子型掺杂层状钙钛矿结构锰氧化物La2-2xCa1+2xMn2O7

 用高温高压法、在1 260 ℃和5.0 GPa条件下,成功制备出电子型掺杂层状钙钛矿结构锰氧化物La_2-2xCa_1+2xMn₂O₇（x=1.0～0.8）系列样品。样品的粉末X射线衍射实验和Rietveld精修结构分析表明,所制样品具有Sr₃Ti₂O₇型四方结构,空间群为I4/mmm。随着电子浓度的增加,MnO₆八面体畸变程度增大,晶胞体积增加。同时样品的磁化强度随La的掺入、x的增加而增强,反铁磁有序温度T_N提高。由于双交换作用减小,样品的电阻增加。在测量温度范围内,没有观测到磁电阻效应。     

混价锰氧化物超巨磁电阻材料研究进展

综述了钙钛矿结构锰氧化物超巨磁电阻材料的研究进展，主要包括Ｊａｈｎ－Ｔｅｌｅｒ畸变、磁性、电阻率、热电势、霍尔效应、比热、热膨胀、电荷有序、中子衍射和非弹性散射、电子能谱，以及同位素效应等方面     

钙钛矿结构材料Sr8CaRe3Cu4O24压力效应的研究

 基于密度泛函理论,运用局域轨道密度近似+哈伯德相互作用和平均场方法,研究了新型钙钛矿结构材料Sr₈CaRe₃Cu₄O₂₄在不同压强下的机械、电磁性质,并探讨该材料的居里温度T_C随压强变化的规律。计算结果表明：T_C随着压强的增加而升高,费米面附近能隙逐渐减小。最后通过海森伯模型对此作出了较为合理的解释。     

纳米结构ZnxFe3-xO4-α-Fe2O3多晶材料中的巨隧道磁电阻效应

在具有纳米绝缘层的多晶锌铁氧体体系中,当晶界为α-Fe₂O₃纳米量级(6—7nm)的绝缘层时,则构成(Zn_xFe_3-xO₄)-α-Fe₂O₃非均匀体,高分辨电子显微镜已证实了这种微结构,该体系在0.5T磁场、4.2K温度下,磁电阻效应可达1280%,300℃下为158%. 关键词： 隧道磁电阻效应 锌铁氧体 纳米结构     

钙钛矿(La1-yTby)0.67Sr0.33MnO3的超巨磁电阻效应

采用固相反应烧结法制成了钙钛矿(La_1-yTb_y)_0.67Sr_0.33MnO₃(y=0—1)多晶样品.研究了样品的微观结构,常温、低温下的磁性,样品的磁电阻随温度、成分的变化关系,电阻随温度变化特性等.并在y=0.40样品中,170K附近、最大磁化场为7T时,观察到了900%的巨磁电阻. 关键词：     

Sr2FeMoO6: A Prototype to Understand a New Class of Magnetic Materials

We propose a new mechanism to explain the magnetic structure of a recently discovered magnetoresistive double perovskite oxide system, Sr₂FeMoO₆, with the help of detailed experimental and theoretical results. This model, based on a strong antiferromagnetic coupling between the local moment and the charge carriers arising from local hopping interactions, can give rise to ferromagnetic metallic as well as ferromagnetic insulating ground states. The relevance of this mechanism in understanding the magnetism in dilute magnetic semiconductors such as Ga_{1 − x} Mn _x As, is also discussed.     

LaB_6 Work Function and Structural Stability under High Pressure

The work functions of the(110) and(100) surfaces of LaB_6 are determined from ambient pressure to 39.1 GPa.The work function of the(110) surface slowly decreases but that of the(100) surface remains at a relatively constant value. To determine the reason for this difference, the electron density distribution(EDD) is determined from high-pressure single-crystal x-ray diffraction data by the maximum entropy method. The EDD results show that the chemical bond properties in LaB_6 play a key role. The structural stability of LaB6 under high pressure is also investigated by single-crystal x-ray diffraction. In this study, no structural or electronic phase transition is observed from ambient pressure to 39.1 GPa.     

Sign reversal of anisotropic magnetoresistance and anomalous thickness-dependent resistivity in Sr2CrWO6/SrTiO3 films

High-quality Sr₂CrWO₆ (SCWO) films have been grown on SrTiO₃ (STO) substrate by pulsed laser deposition under low oxygen pressure. With decrease of the film thickness, a drastic conductivity increase is observed. The Hall measurements show that the thicker the film, the lower the carrier density. An extrinsic mechanism of charge doping due to the dominance of oxygen vacancies at SCWO/STO interfaces is proposed. The distribution and gradient of carrier concentration in SCWO films are considered to be related to this phenomenon. Resistivity behavior observed in these films is found to follow the variable range hopping model. It is revealed that with increase of the film thickness, the extent of disorder in the lattice increases, which gives a clear evidence of disorder-induced localization charge carriers in these films. Magnetoresistance measurements show that there is a negative magnetoresistance in SCWO films, which is considered to be caused by the magnetic scattering of magnetic elements Cr³⁺ and W⁵⁺. In addition, a sign reversal of anisotropic magnetoresistance (AMR) in SCWO film is observed for the first time, when the temperature varies across a characteristic value, T_M. Magnetization—temperature measurements demonstrate that this AMR sign reversal is caused by the direction transition of easy axis of magnetization from the in-plane ferromagnetic order at T > T_M to the out-of-plane at T < T_M.     

双钙钛矿Sr_2CrWO_6的磁性与输运性质研究

研究了双钙钛矿Sr2 CrWO6的磁性和输运性质 .Sr2 CrWO6多晶在Ar气及真空气氛中经固相烧结而形成 .X射线衍射分析表明主相为Sr2 CrWO6,少量杂相为SrWO4 .热磁测量表明样品的居里温度为 480K左右 .电阻随温度降低而升高 ,类似于绝缘体 ,在外场 5T ,低温下 (2 5K)磁致电阻 (MR)可达 2 0 % ,但MR随温度升高而趋于零 .较大的矫顽力 (5 97× 10 4 A/m)以及低场部分MR H曲线偏离高场下的线性曲线显示样品可能有较强的磁各向异性     

双钙钛矿Sr2CrWO6的磁性与输运性质研究

研究了双钙钛矿Sr₂CrWO₆的磁性和输运性质.Sr₂CrWO₆多晶在Ar气及真空气氛中经固相烧结而形成.X射线衍射分析表明主相为Sr₂CrWO₆,少量杂相为SrWO₄.热磁测量表明样品的居里温度为480K左右.电阻随温度降低而升高,类似于绝缘体,在外场5T,低温下(25K)磁致电阻(MR)可达20%,但MR随温度升高而趋于零.较大的矫顽力(5.97×1 关键词： 双钙钛矿氧化物 磁性质 磁致电阻     

Effect of preparation procedure on the magnetic and transport properties of double perovskite Sr2FeMoO6

Ordered and disordered double perovskite Sr2FeMoO6 ceramics have been investigated by powder x-ray diffraction,magnetic and transport measurements, as well as Moessbauer spectroscopy. The heavily disordered sample can be acquired by annealing the ordered samples in argon. The annealing procedure affects not only the nature of grain boundaries but also the grain itself. The evidence of Moessbauer spectra performed at 77 and 300K indicates that there exist small oxygen deficient clusters of SrFeO3-y in the disordered sample. The paramagnetic Fe^4 and Fe^3 ions in the compound subsist down to 77K and the ratio of Fe^4 /Fe^3 increases with decreasing temperature.     

双钙态矿Sr_2Fe_(1-x)Mn_xMoO_6体系的磁性和磁输运性质的研究(英文)

我们用X射线光电子能谱、以及相关的电性和磁性测量研究了Sr2Fe1-xMnxMoO6(0相似文献