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用337nm、380nm和510nm脉冲激光照射着色NaF和NaF:Mg~(++)晶体,皆能产生大量F_2~+心.在照射过的NaF:Mg~(++)晶体中,观测到了F_2~+ 心向(F_2~+)~*心的转型现象. 相似文献
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在Visual C++开发环境下,通过龙格库塔方法求解非线性电路微分方程组,得到数值解并模拟显示李萨茹图形。在相同线路参数下模拟结果与实验室实验中观察到的结果一致,同时模拟显示可以容易地得到稳定的X,Y方向上的输出波形。通过该模拟实验可以很好地观察研究非线性电路中的混沌现象。 相似文献
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美国国家标准技术研究所(NIST)的数据加密标准DES连续使用了20年之后,庞大的并行网络电脑攻击和特定的“DES—Cracking”硬件攻克使其安全性受到了威胁,因此NIST决定用AES(高级加密标准)替代DES,并选择Rijndael作为AES的算法。来自比利时的两位密码专家开发的Rijndael算法汇聚了安全,性能,效率,易用和灵活等优点,使它成为AES最合适的:选择,Rijndael在不同硬件和软件运行环境下表现出始终如一的良好性能,而无论这些环境是否有反馈模式,它的密钥设置时间相当出色,密钥的灵敏性也不错。Rijndael非常低的内存需求也使它很适合用于受限环境中。Rijndael的操作简单,并可抵御强大和实时的攻击。 相似文献
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纳米晶ZrO2:Pr^3+与ZrO2:Pr^3+,Sm^3+发光研究 总被引:10,自引:0,他引:10
采用化学共沉淀法制备了纳米晶ZrO2:pr^3+粉体,所制备的纳米晶ZrO2:Pr^3+粉体中Pr^3+的强室温特征发射的两个主发射带为^1D2-^2H4和^3P0-^3H4跃迁。不同热处理温度下纳米晶ZrO2:Pr^3+晶体结构不同,因此它们的发光不同;ZrO2基质向Pr^3+有能量传递,在高温煅烧得到的单斜相配位场中能量传递较好。荧光强度与Pr^3+浓度的关系研究表明:^3P0和^1D2功能级有不同的猝灭规律,由于[^1D2,^3H4]→[^1G4,^3F4]的交叉弛豫,使得^1D2-^3H4跃迁的猝灭浓度很低,在我们的实验中,掺0.1mol%Pr^3+时^1D2-^3H4地跃迁发射最强,掺2mol%Pr^3+时^3R0-^3H4跃迁发射最强。文章制备的纳米晶ZrO2:Pr^3+,Sm^3+中Sm^3+的^4G(5-2)~^6H(7/2)跃迁荧光峰因Pr^3+加入而增强,这除了两种离子某些能级相近产生荧光发射的叠加效应外,还存在Pr^3+→Sm^3+的能量传递。 相似文献
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对Ce^3 :Eu^3 :Cr^3 :Sm^3 :YAG外延层中的荧光敏经现象进行了报道和分析,在较高浓度的Ce^3 离子掺杂时,外处层在蓝色、绿色波段出现了新的荧光谱线,可解释为在Ce^3 离子每化作用下,Eu^3 离子产生了由高位激发态能级^5Di(i=1,2,3)直接到基态能级^7Fj(j=0,1,2,3)的辐射跃迁过程,并且这种Ce^3 :Eu^3 :Cr^3 :Sm^3 :YAG外延层还是一种新颖的白色单晶荧光材料。 相似文献
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A novel yb^3+-Er^3+ codoped phosphate glass for high power flashlamp pumping and high repetition rate laser at 1.54μm, designated EAT5-2, is developed. The weight-loss rate of is 1.3 × 10^-5 gcm^-2h^-1 in boiling water, which is comparable to Kigre's QX-Er glass. Some spectroscopic parameters are analysed by Judd-Ofelt theory and McCumber theory. The emission cross section is calculated to be 0.73 × 10^-20 cm^2. The thermo-mechanical properties of EAT5-2 are modified after an ion-exchange chemical strengthening process in a KNO3/NaNO3 molten salt bath. The thresholds for optical damage from the flashlamp pumping are tested on glass rods. A repetition rate of 15 Hz is achieved for chemically strengthened glass. The laser experimental results at 1.54 μm from flashlamp pumping are also reported. 相似文献
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YAG晶体中Cr~(3+)→Tm~(3+),Er~(3+)→Tm~(3+)的能量 总被引:1,自引:1,他引:0
研究了加入敏化离子Cr3+和Er3+的Tm:YAG晶体的吸收谱和荧光谱,计算了Cr3+、Er3+、Tm3+离子的2E、4I13/2、3F4能态的平均寿命及能量;转移效率、转移速率.得出Cr3+→Tm3+转移效率为80%,转移速率为2.1×103s-1.由(Er,Tm):YAG的荧光谱可见存在Er3+→Tm3+的有效的能量转移.讨论了Cr3+→Tm3+和Er3+→Tm3+能量转移的不同. 相似文献
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针对现有的地表温度反演研究基本上都是利用IDL或MATLAB语言编程实现、计算效率低的问题,利用Visual C++语言编程实现"喀斯特城市地表温度遥感反演系统",快速反演桂林喀斯特城市Landsat TM遥感图像的地表温度场和NDVI空间分布,分析NDVI变化对地表温度的影响。结果表明,系统具有独立运行、运行速度快等特点;NDVI在0.1~0.7范围时,地表温度随归一化植被指数的增加而降低,呈现负相关的关系,地表植被覆盖可降低地表温度、降低城市热岛现象。系统快速获取的地表温度场可揭示喀斯特城市热环境状况、城市热岛的规模和程度、喀斯特山峰植被的凉岛效应,为喀斯特城市的可持续发展提供科学数据。 相似文献
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The SrZnP2OT:Eu^2+, Mn^2+ phosphor is synthesized by high temperature solid state reaction. The luminescence properties and the energy transfer between Eu^2+ and Mn^2+ are investigated. The emission bands of this phosphor peaked at 42Ohm and 67Ohm are originated from the 5d → 4f transition of Eu^2+ and from the 4T1 (4G) --〉 6A1 (6S) transit/on of Mn^2+, respectively. With the increasing Mn^2+ concentration, the intensity of fixed concentra- tion Eu^2+ decreases and the intensity of Mn^2+ also increases. It is suggested that there is an energy transfer from Eu^2+ to Mn^2+ in SrZnP2O7 host. According to Dexter's energy transfer formula of multipolar interaction, the energy transfer between Eu^2+ and Mn^2+ is due to the electric dipole-quadrupole interaction of the resonance transfer. 相似文献
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Luminescence spectra of SrAl12O19:Pr^3+,Mn^2+ under VUV-UV excitation are investigated. The characteristic emissions between 4f levels and the excitation of 5d for Pr^3+ are observed. The emission of Mn^3+ peaks at 517nm and the excitations clue to the ground to multiplets are observed at 276, 360, 386 and 426nm. However, the spectral overlap between the emission of Pr^3+ and excitation of Mn^2+ is absent, suggesting that the quantum splitting cannot be achieved via a Pr^3+ Mn^2+ ion pair in the host SrAl12O19. 相似文献
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Novel oxyfluoride glasses are developed with the composition of 30SiO2-15Al2O3-28PbF2-22CdF2-0.1TmF3 - xYbF3 - (4.9 - x) AlF3(x=0, 0.5, 1.0, 1.5, 2.0) in tool fraction, Furthermore, the upconversion luminescence characteristics under a 970nm excitation are investigated. Intense blue, red and near infrared luminescences peaked at 453nm, 476nm, 647nm and 789nm, which correspond to the transitions of Tm^3+: ^1D2 →^3F4, ^1G4 →^3H6, ^1G4 →^3F4, and ^3H4 →^3H6, respectively, are observed. Due to the sensitization of Yb^3+ ions, all the upconversion luminescence intensities are enhanced considerably with Yb^3+ concentration increasing. The upconversion mechanisms are discussed based on the energy matching rule and quadratic dependence on excitation power. The results indicate that the dominant mechanism is the excited state absorption for those upconversion emissions. 相似文献
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Er^3+/Yb^3+ Codoped Phosphate Glass Fibre with Gain per Unit Length Greater Than 3.0 dB/cm
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We experimentally study a novel fibre with high gain per unit length based on the homemade erbium-ytterbium codoped phosphate glass. The gain and noise characterizations with different pump powers at different wavelengths are investigated. The 1.8-cm-long fibre, dual-pumped by two single mode 980-nm fibre-pigtailed laser diodes, provides a gain per unit length greater than 3.0dB/cm and a noise figure less than 6.SdB. The gain saturation behaviour at 1535nm is obtained and the saturation output power (3 dB compression) is greater than 5 dBm. 相似文献
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用高温固相法合成了Sr3B2O6:Tb^3+,Li^+绿色荧光粉,并研究粉体的发光性质。发射光谱由位于黄绿区的4个主要荧光发射峰组成,峰值分别位于495,548,598,625nm,对应了Tb^3+的^5D4→^7F6,^5D4→^7F5,^5D4→^7和^5D4→^7F3特征跃迁发射,548nm的发射最强。激发光谱表现从200—400nm的宽带,可以被近紫外光辐射二极管(near-ultraviolet light-emitting diodes,UVLED)管芯产生的350-410nm辐射有效激发。研究了Tb^3+掺杂和电荷补偿剂对样品发光亮度的影响。Sr3B2O6:Tb^3+,Li^+是一种适用于白光LED的绿色荧光粉。 相似文献