ICP—AES同时测定钴酸锂中13个杂质元素

利用全谱直读ICP-AES分析技术,对试样处理方法、元素分析谱线、基体干扰、背景校正、仪器分析参数等进行了研究,综合确定了最佳实验条件。将钴酸锂试样用硝酸、高氯酸处理后,再用盐酸与硝酸溶解残渣,ICP-AES同时测定铜、铁、镍、锰、铂、铋、铅、金、铝、镉、钯、锡、砷等13个杂质元素。样品加标回收率为85.2%—113.0%,相对标准偏差为1.0%—7.7%。方法操作简便、快速、准确。     

The nature of empirical constants in the equation relating the frequency of the stretching vibration of oh-groups to parameters of the [MO n ]-polyhedrons coordinating these groups

Institute of Physicoorganic Chemistry, Academy of Sciences of Belarus, 220603, Minsk, Ul. Surganova, 13, Belarus. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 62, No. 1, pp. 104–107, January–February, 1995.     

Short-pulse Calorimetric Load for High Power Millimeter-wave Beams

A spherical compact matched load, for high vacuum operation suited for short pulses (2 MW, 0.1 s) precise measurement has been designed to test high power gyrotrons Bruschi, Gandini, Muzzini, Spinicchia, Cirant, Gittini, Granucci, Mellera, Nardone, Simonetto, and Sozzi (Fusion Eng. Des. 56–57:649–654, 2001); Bruschi, Cirant, Gandini, Granucci, Mellera, Muzzini, Nardone, Simonetto, Sozzi, and Spinicchia (Nucl. Fusion 43:1513–1519, 2003); Bruschi, Cirant, Gandini, Gittini, Granucci, Mellera, Muzzini, Nardone, Simonetto, Sozzi, Spinicchia, Angella, and Signorelli (Development of CW and short-pulse calorimetric loads for high power millimeter-wave Beams, 23rd Symposium on Fusion Technology, September 20–24, 2004, Venice, Italy). In order to enhance the power handling capability of the load and to reduce the operation problems that may arise from an excessive reflection from the load, a ray tracing code has been written to model the power distribution on the inner surface and the pattern of the reflected radiation. The outcome of this code has been used to select a more convenient profile for the spreading mirror of the load and to optimize a pre-load specially conceived to minimize the power reflected fraction.     

Effect of oxygen on the optical properties of ZnSe in the region of 0.44–20 μm

Moscow Power Engineering Institute, 14, Krasnokazarmennaya Str., Moscow, GSP, 105835, Russia. Translated from Zhurnal Prikladnois Spektroskopii, Vol. 63, No. 4, pp. 646–651, July–August, 1996.     

ICP-AES雾化法氢化法联合测定白族产妇及新生儿发中常微量元素

本文报道用ICP-AES同时测定人发中24种元素的方法。采用10mg/ml样品,4.8mol/L盐酸溶液,用基体匹配法校正干扰,分别用雾化法和氢化法测定,用人发标准检验方法和结果的准确性。较满意地测定了Zn等18种元素。91例母婴发中的Zn、Fe、Sr、Mg、Cd、P、Ni、Se、As和Mo等元素呈显著的正相关性。     

Atomic-emission spectrum analysis of soil

A method of the atomic-emission spectrum analysis of soil has been developed for control of the accumulation of technogenic impurities in environmental objects. A sample, after calcination at 550°C, is evaporated in an arc discharge. Spectra are recorded by a DFS-8 spectrograph. Simultaneously, determination is made of Li, Ba, Sr, Cu, Zn, Cr, Ni, Co, Pb, Bi, Mo, V, Ge, Ga, Y, Nb, Sn, Cd. For the majority of the elements the detection limits are lower than their percent abundance in the crust and their maximum permissible concentrations. Institute for Single Crystals, National Academy of Sciences of Ukraine, 60, Lenin Ave., Khar'kov, 310001, Ukraine. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 3, pp. 396–399, May–June, 1997.     

Recognition of practical speech emotion using improved shuffled frog leaping algorithm

Due to the drawbacks in Support Vector Machine（SVM）parameter optimization,an Improved Shuffled Frog Leaping Algorithm（Im-SFLA）was proposed,and the learning ability in practical speech emotion recognition was improved.Firstly,we introduced Simulated Annealing（SA）,Immune Vaccination（Iv）,Gaussian mutation and chaotic disturbance into the basic SFLA,which bManced the search efficiency and population diversity effectively.Secondly,Im-SFLA Was applied to the optimization of SVM parameters,and an Im-SFLA-SVM method Was proposed.Thirdly,the acoustic features of practical speech emotion,such aS ridgetiness,were analyzed.The pitch frequency,short-term energy,formant frequency and chaotic characteristics were analyzed corresponding to different emotion categories,and we constructed a 144-dimensional emotion feature vector for recognition and reduced to 4-dimension by adopting Linear Discriminant Analysis（LDA） Finally,the Im-SFLA-SVM method Was tested on the practical speech emotion database,and the recognition results were compared with Shuffled Frog Leaping Algorithm optimization-SVM（SFLA-SVM）method,Particle Swarm Optimization algorithm optimization-SVM（PSo-SVM） method,basic SVM,Gaussian Mixture Model（GMM）method and Back Propagation（BP）neural network method.The experimentM resuits showed that the average recognition rate of Im-SFLA-SVM method was 77.8%,which had improved 1.7%,2.7%,3.4%,4.7%and 7.8%respectively,compared with the other methods.The recognition of fidgetiness was significantly improve,thus verifying that Im-SFLA was an effective SVM parameter selection method,and the Im-SFLA-SVM method may significantly improve the practical speech emotion recognition.     

Optical properties of pure and doped Y3Fe5O12 single crystals

Institute of Physics of Solids and Semiconductors, Academy of Sciences of Belarus, 17, P. Brovka Str., GSP, Minsk, 220072. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 63, No. 4, pp. 667–675, July–August, 1996.     

Properties of zinc sulfide luminophores in thin-film structures

Ul'yanovsk State Technical University, 32, Severnyi Venets St., Ul'yanovsk, 432027, Russia. Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 62, No. 3, pp. 182–185, May–June, 1995.     

ICP-AES测定铜电解液中的Fe、Ni、Pb、Bi、Sb、Zn和As

利用ICP-AES分析技术,通过对样品处理、元素分析谱线、酸度等因素进行试验研究,综合确定了分析条件,对铜电解液中杂质元素（Fe、Ni、Pb、Bi、Sb、Zn、As）进行了ICP-AES测定。结果表明,ICP-AES测定铜电解液中Fe、Ni、Pb、Bi、Sb、Zn和As,可以满足铜电解生产的需要,为高纯阴极铜的生产起了指导作用。