Sm-Nd isotopic geochronology of the Yinachang Fe-Cu-REE deposit at Wuding, Yunnan Province and its genetic significance

Sm-Nd isotope systematics of ores and fluorites places precise time constraints on REE mineralization of the Yinachang Fe-Cu-REE deposit in Yunnan Province which occur in the Proterozoic Kunyan group. The ore-related fluorites contain high abundant REE, and show a strong enrichment of LREE and a positive Eu anomaly, which is in marked contrast to post-ore fluorites that are HREE enriched. The Sm-Nd isochron ages of the ores and fluorites are 1539±40 Ma and 1617±100 Ma, respectively, and calculated εNd（t） are -4.6 and -3.2. Accurate age determinations of the mineralization demonstrate that the REE mineralization took place during early Mesoproterozoic. Together with other geological evidence from the ore deposit, the primary REE-bearing ore-forming fluids are suggested to have been derived from the Enriched Mantle, and the Yinachang Fe-Cu-REE ore deposit is of volcanic exhalation- hydrothermal sedimentary origin. This study also imply that the sudden large-scale REE mineralization in the Mesoproterozoic epoch may have been induced by alkaline-rich anorogenic magmatism which occurred at marginal rifts of the continent in the Mesoproterozoic.     

REE composition in scheelite and scheelite Sm-Nd dating for the Xuebaoding W-Sn-Be deposit in Sichuan

The scheelite with large size and euhedral shape from Xuebaoding, Sichuan Province is an ideal min- eral to study REE patterns and Sm-Nd dating of non-gold deposits. The scheelite has diameters of 1― 10 cm and colors of pale beige to deep orange. Most of these scheelites occur in association with beryl, cassiterite and muscovite. The rare earth elements indicate that scheelite samples from Xuebaoding W-Sn-Be deposits contain high concentrations of rare earth elements with total ΣREE Y contents in the range of 369―1725 μg·g?1 and nearly all of these scheelite samples are enriched in LREE and depleted in HREE and have negative Eu anomalies. The REE patterns of the scheelites are similar to those of A-type granite with obvious tetrad effect, similar to that of type II scheelites. Based on reported fluid inclusion studies, the mineralizing-fluid of the Xuebaoding W-Sn-Be deposit indicates low Na activity. The REE patterns of the scheelite are probably controlled by partition coefficient in hydrothermal fluid. In the 147Sm/144Nd-143Nd/144Nd diagram, the scheelites show a linear array corresponding to an isochron age of 182.0±9.2 Ma (MSWD = 0.52). The Sm-Nd age represents the formation age of the scheelite and can indicate that the W, Sn and Be mineralization at Xuebaoding took place in the Early Yanshanian. The Sm-Nd dating result is important for the study of the multi-metal resources in western Sichuan Province.     

由埋藏史确定成矿深度兼论成矿时代——以晴隆锑矿为例

埋藏史模拟技术已经在油气地质研究领域中被广泛应用,但是在金属矿床中却鲜有探索者.随着对金属需求的日益增加,迫切需要把类似埋藏史模拟技术等在石油行业已经运用成熟的技术引入到金属矿产的相应研究中.恢复了晴隆地区埋藏史,结合流体包裹体均一温度,确定晴隆锑矿成矿深度范围为2 587～4982 m,成矿时间可能为早三叠世到晚三叠...     

云南兰坪-思茅盆地大平掌铜多金属矿床同位素地球化学与成矿年代学

大平掌铜多金属矿床是近年来在兰坪 -思茅盆地新发现的一个重要矿床 .该矿床产出于火山岩中 ,其构造背景及矿床地质特征均比较复杂 ,整个矿床由上部层状或透镜状的块状硫化物矿体和下部脉状及浸染状的矿体组成 .该矿床脉状矿体中石英流体包裹体Rb_Sr等时线年龄为 ( 1 1 8± 1 2 )Ma ,初始锶同位素组成为 ( 0 .70 80 0 7± 0 .0 0 0 0 3 7) ;流体包裹体研究表明成矿流体具有中低盐度 ( 2 .0～ 8.0wt %NaCl)和中低温度 ( 90～ 2 0 0℃ ) ;矿床中主要硫化物矿物的δ34S值在 - 0 .9‰～ 3 .5‰之间 ,集中在零值附近 .结合对以往的氢 -氧同位素和铅同位素研究结果的综合分析可以看出 ,大平掌矿床与区域内的脉状铜矿具有相似的地球化学特征 .因此认为大平掌铜多金属矿床为形成于燕山期的热液矿床 ,而不是前人认为的海底喷流沉积形成的块状硫化物矿床     

冷水坑矿田层状铅锌银矿稳定同位素特征与矿床成因

赋存于火山岩地层层间破碎带中的层状铅锌银矿是冷水坑矿田重要的矿化类型之一。层状矿体内碳酸盐岩与矿石中金属硫化物碳氧硫铅同位素测定表明,铁锰碳酸盐矿物的δ13CV-PDB变化范围在-4.8‰～-5.5‰之间,δ18OV-SMOW为12.6‰～14.1‰,白云质灰岩分别为-3.3‰～-5.9‰,9.8‰～17.2‰。金属硫化物δ34S值为-3.9‰～+5.6‰,多集中在-1‰～6‰之间,与矿田斑岩型矿床硫同位素组成一致。矿石铅同位素组成比较一致,其中206Pb/204Pb,207Pb/204Pb,208Pb/204Pb分别为17.786～17.809,15.572～15.605,38.281～38.386。层状矿体矿石铅同位素组成位于矿田铅同位素分布范围内且比斑岩型矿石铅分布集中。矿石硫、铅同位素组成表明层状矿床成矿物质来自矿田火山(岩浆)系统。含矿地层内的碳酸盐岩层为火山喷发间歇局限陆相湖正常沉积而成,铁锰碳酸盐为火山(岩浆)热液成因而非喷流沉积。冷水坑层状铅锌银矿为火山热液型矿床。     

Re-Os isotope dating of pyrite from the footwall mineralization zone of the Xinqiao deposit,Tongling, Anhui Province: Geochronological evidence for submarine exhalative sedimentation

The Xinqiao deposit is located in the Tongling area,Anhui Province.This deposit is dominantly composed of stratiform sulfide orebodies,which are restricted to the transitional zone from clastic rocks to carbonates at the base of the Late Carboniferous Huanglong Formation.There are discordant veinlets or networks of mineralization in the footwall rocks below the stratiform sulfide orebodies.The underlying discordant mineralization zones coexist with conformable stratiform sulfide orebodies,which are considered to be the most representative features of massive sulfide deposits formed by submarine exhalative sedimentation.This study reports a pyrite 187Re-187Os isotopic age of 319±13 Ma(MSWD=16) for the footwall mineralization zone.This isochron age is consistent with the interval of strata hosting the conformable stratiform sulfide orebody,and provides direct geochronological evidence for Carboniferous exhalative sedimentary mineralization.     

江南元古宙古岛弧基底变质岩的Sm—Nd同位素研究

江南元古宙古岛弧的基底变质岩主要由浅变质的岛弧火山-沉积岩系组成。根据Sm-Nd同位素年龄资料,古岛弧西段基底变质岩的形成时间为早元古宙,中段为中元古宙中-晚期,东段为晚元古宙早期,形成时间持续长达13亿年左右。在9亿年前左右,江南古岛弧与华夏古陆发生碰撞拼贴,从而结束了江南古岛弧的演化史。     

广东长坑金银矿床矿石类型及矿物组合

长坑金银矿床中金和银分别构成独立的金矿体和银矿体.矿床的主要矿石类型包括原生矿石和次生氧化矿石.氧化矿石的矿物种类简单,主要是石英,其次是粘土矿物,少量的针铁矿、臭葱石,微量的磁铁矿、锆石、黄铁矿和其他硫化物,偶见自然金.原生金矿石包括硅质金矿石、钙硅质金矿石、铝硅质金矿石三种类型,原生银矿石主要是硅质银矿石.原生金矿矿石矿物包括黄铁矿、雄黄、雌黄、重晶石、辉锑矿,其次是白铁矿和极少量毒砂和自然金,为一套浅成低温矿物组合.原生银矿矿石矿物是方铅矿、闪锌矿、银黝铜矿、深红银矿、硫锑铜银矿、硫锑铅银矿、辉锑银矿、辉银矿,次要矿物有黄铁矿、黝铜矿、黄铜矿、脆硫锑银矿、淡红银矿,是一套中深成中温的含银单硫化物和含银硫盐矿物组合.反映金、银矿床分属浅成低温和中深成中温热液交代成因的两次不同成矿作用的产物,金矿成矿在先,银矿成矿在后并叠加改造了金矿.     

固体金属同位素在油气运移研究中的应用

固体地球化学中常用的Ｐｂ－Ｐｂ、Ｒｂ－Ｓｒ同位素方法被用于测定石油生成、运移的年龄。对准噶尔盆地乌尔禾沥青脉、塔里木盆地志留系固体沥青的Ｐｂ－Ｐｂ、Ｒｂ－Ｓｒ同位素年龄测定表明,油气生成、运移均与重大地质事件有关,这种方法可以用来测定石油生成、运移的年龄,从而解决了石油生成机制、运移动力等研究难题。说明用固体金属同位素定年方法可以解决石油地质的重大问题。     

宁夏卫宁北山二人山地区热液型多金属矿找矿多维异常方法的新尝试和效果

宁夏卫宁北山二人山地区位于阿拉善微陆块南缘,是宁夏境内重要的热液成因多金属矿产成矿区之一。 为服务该地区下一步在外围及深部的找矿,在钻孔岩石地球化学测量的基础上,对该地区多维异常体系进行探讨。 结果表明:在该地区已知多金属矿(化)体中,发育着以常量元素 Na2 O 为主要特征的负异常体系、以 S 为代表的矿化剂元素异常体系、成矿及其伴生元素异常体系等,证实了多维异常体系的存在,并进一步在多维异常体系理论的指导下圈定了研究区成矿条件和成矿潜力有利区域。 研究成果是卫宁北山地区热液型多金属矿找矿优选地球化学勘查方法的新尝试,对该区地质找矿具有重要的实用价值。     

西秦岭铀矿床热液石英Pb同位素组成及其应用

作者分析了西秦岭地区各类岩石、花岗岩、含铀黄铁矿及早阶段热液石英Ｐｂ同位素组成，并将热液石英Ｐｂ同位素组成作为联系母源Ｐｂ与矿床Ｐｂ同位素组成的桥梁，与母源Ｐｂ及矿床Ｐｂ同位素组成进行了对比，花岗岩－石英－含铀黄铁矿Ｐｂ同位素组成具有线性演化关系，从而提出矿床中的铀来自隐伏构造－岩浆岩，而不是地层岩石。     

固体金属同位素在油气运移研究中的应用

:固体地球化学中常用的Pb Pb和Rb Sr同位素方法被用于测定石油生成、运移的年龄。对准噶尔盆地乌尔禾沥青脉、塔里木盆地志留系固体沥青的Pb Pb和Rb Sr同位素年龄测定表明 ,油气生成、运移均与重大地质事件有关 ,这种方法可以用来测定石油生成、运移的年龄 ,从而解决了石油生成机制、运移动力等研究难题。说明用固体金属同位素定年方法可以解决石油地质的重大问题     

桃园钼矿床围岩蚀变特征及其研究意义

桃园钼矿床属中温热液脉型矿床，围岩蚀变具线型对称特征。蚀变以钾化与硅化和成矿关系最为密切。根据蚀变岩在空间上的分带特征与矿化强度之间的规律，可以确定成矿范围，指导找矿。     

美国Wallapai矿区Mineral Park斑岩型矿床早期矿脉中硬石膏的氧同位素组成

本文报道了美国亚利桑那Wallapai矿区Mineral Park斑岩型矿床早期矿脉(AM和AC)中硬石膏的氧同位素组成,依据包体均一温度及硫同位素温度计算成矿溶液的δ~(12)O值(纯水),运用同位素分馏理论讨论AM和AC矿脉成矿溶液的来源和演化。