Optimum spectral window for imaging of art with optical coherence tomography

Optical coherence tomography (OCT) has been shown to have potential for important applications in the field of art conservation and archaeology due to its ability to image subsurface microstructures non-invasively. However, its depth of penetration in painted objects is limited due to the strong scattering properties of artists’ paints. VIS–NIR (400–2,400 nm) reflectance spectra of a wide variety of paints made with historic artists’ pigments have been measured. The best spectral window with which to use OCT for the imaging of subsurface structure of paintings was found to be around 2.2 μm. The same spectral window would also be most suitable for direct infrared imaging of preparatory sketches under the paint layers. The reflectance spectra from a large sample of chemically verified pigments provide information on the spectral transparency of historic artists’ pigments/paints as well as a reference set of spectra for pigment identification. The results of the paper suggest that broadband sources at ~2 μm are highly desirable for OCT applications in art and potentially material science in general.     

Ultra-high resolution spectral domain optical coherence tomography using supercontinuum light source

An ultra-high resolution spectral domain optical coherence tomography (SD-OCT) was developed using a cost-effective supercontinuum laser. A spectral filter consists of a dispersive prism, a cylindrical lens and a right-angle prism was built to transmit the wavelengths in range 680–940 nm to the OCT system. The SD-OCT has achieved 1.9 μm axial resolution and the sensitivity was estimated to be 91.5 dB. A zero-crossing fringes matching method which maps the wavelengths to the pixel indices of the spectrometer was proposed for the OCT spectral calibration. A double sided foam tape as a static sample and the tip of a middle finger as a biological sample were measured by the OCT. The adhesive and the internal structure of the foam of the tape were successfully visualized in three dimensions. Sweat ducts was clearly observed in the OCT images at very high resolution. To the best of our knowledge, this is the first demonstration of ultra-high resolution visualization of sweat duct by OCT.     

Optical Coherence Tomography Implemented by Photonic Crystal Fiber

We report a photonic crystal fiber (PCF)-based optical coherence tomography (OCT) system, in which conventional single-mode fiber for the transmission line and the fiber coupler for the beam splitter/combiner are replaced with PCF and PCF coupler. The PCF coupler fabricated using the fused biconical tapered (FBT) method showed a nearly flat coupling ratio over a broad spectral bandwidth of 400 nm, which provided an axial resolution of 3-μm for OCT imaging. With a white-light source, the 8-μm thick air gap between two stacked cover glasses was measured, and with a conventional superluminecent diode (SLD) source, the in vitro images of rat eye and Misgurnus mizolepis skin were successfully obtained. The PCF and PCF coupler might enable a white-light as the source for the cost effective and high-resolution OCT system.     

双狭缝透射光栅软X光时空分辨谱仪

 利用双狭缝、透射光栅配亚仟X光条纹相机做了具有一维空间、时间和能谱分辨的三维软X光测量仪器(双狭缝透射光栅软X光时空分辨谱仪), 并成功地获得了金盘靶的N带X光(中心波长1.7nm)时空分辨图象 。该仪器空间分辨可达23μm, 时间分辨可达003ns, 能谱分辨(当源大小为100～300μm时对波长1.7nm的X光)可达0.4～ 0.7nm, 只需稍加改动, 即可用于其它波段的X光测量。     

Linewidth of collimated wavelength-converted emission in Rb vapour

We present a study of the spectral linewidth of collimated blue light (CBL) that results from wave mixing of low-power continuous-wave laser radiation at 780 and 776 nm and an internally generated mid-IR field at 5.23 μm in Rb vapour. Using a high-finesse Fabry–Perot interferometer, the spectral width of the CBL is found to be <1.3 MHz for a wide range of experimental conditions. We demonstrate using frequency-modulated laser light that the CBL linewidth is mainly limited by the temporal coherence of the applied laser fields rather than the atom–light interaction itself. The obtained result allows the same 1.3 MHz upper limit to be set for the linewidth of the collimated mid-IR radiation at 5.23 μm, which has not been directly detected.     

Spectral Filtering in OCT System Implemented by Mechanically Induced Long-Period Fiber Grating

A spectral filtering method that can enhance the axial resolution and suppress sidelobes of the point spread function in Optical Coherence Tomography (OCT) system is demonstrated. A mechanically induced long-period fiber grating (MLPG) is used to tailor the spectral shape of a homemade Er-doped fiber amplified spontaneous emission (ASE) source. By using a MLPG, the high and narrow characteristic peak, centered at 1533 nm, of the ASE source was fairly well removed, which enabled us to use a broader spectral bandwidth of the source. The experimental results show that the proposed spectral filtering method can suppress the sidelobes in the axial point spread function up to 5.4 dB and thus enhance the axial resolution of an OCT system by four times. The OCT images of an extracted human premolar taken with and without the spectral filtering are presented and compared with each other.     

Cathodoluminescence Spectral Characteristics of Quartz and Feldspars in Unaltered and Hydrothermally Altered Volcanic Rocks (Almeria,Spain)

The volcanic rocks of the Cabo de Gata region have been transformed by hydrothermal alteration, forming in some areas, highly silicified and feldspatized rocks. Various samples from outcrops of unaltered and hydrothermally altered volcanic rocks were studied by conventional transmitted-light microscopy to determine their genesis (magmatic, inherited or neoformed) and scanning electron microscope cathodoluminescence to define their spectral features. The magmatic quartz shows emission bands at 400, 440, and 480nm., and these bands disappear or decrease in the secondary hydrothermal quartz, characterized also by an intense emission band at around 570–580 nm, and another around 460 nm. The inherited magmatic plagioclase and neoformed anorthoclase have some similar emission bands and their genesis is not marked by cathodoluminescence features. The magmatic K-feldspars (sanidine), have emission bands at around 425, 440, and 490 nm, constituting a strong blue emission (420–500 nm). This emission is weaker in the neoformed K-feldspars that, however, have a strong emission band at around 570 nm. These data show that some cathodoluminescence spectral characteristic can be used to determine the petrogenesis of rock.     

Oxygen spectral lines for diagnostics of atmospheric laser-induced plasmas

In the present study OI spectral lines are measured, tested, and developed for diagnostics of laser-induced plasma experiments in air. The plasma plume was generated by the interaction of a 6-ns 750-mJ Nd:YAG laser at the fundamental wavelength of 1.06 µm with a standard Al target of known elemental composition in air. The emitted spectrum was in the range 200–1000 nm and was recorded using an Echelle spectrograph equipped with a time-gated ICCD camera. The measurements were performed at several delay times (0–10 µs). Based on LTE assumption, the excitation temperature is derived using a Boltzmann plot of OI emission lines. The FWHM of the Stark broadened OI line at 844.65 nm is used for electron density measurements at different times.     

Single particle size and fluorescence spectra from emissions of burning materials in a tube furnace to simulate burn pits

A single-particle fluorescence spectrometer (SPFS) and an aerodynamic particle sizer were used to measure the fluorescence spectra and particle size distribution from the particulate emissions of 12 different burning materials in a tube furnace to simulate open-air burning of garbage. Although the particulate emissions are likely dominated by particles <1 μm diameter, only the spectra of supermicron particles were measured here. The overall fluorescence spectral profiles exhibit either one or two broad bands peaked around 300–450 nm within the 280–650 nm spectral range, when the particles are illuminated with a 263-nm laser. Different burning materials have different profiles, some of them (cigarette, hair, uniform, paper, and plastics) show small changes during the burning process, and while others (beef, bread, carrot, Styrofoam, and wood) show big variations, which initially exhibit a single UV peak (around 310–340 nm) and a long shoulder in visible, and then gradually evolve into a bimodal spectrum with another visible peak (around 430–450 nm) having increasing intensity during the burning process. These spectral profiles could mainly derive from polycyclic aromatic hydrocarbons with the combinations of tyrosine-like, tryptophan-like, and other humic-like substances. About 68 % of these single-particle fluorescence spectra can be grouped into 10 clustered spectral templates that are derived from the spectra of millions of atmospheric aerosol particles observed in three locations; while the others, particularly these bimodal spectra, do not fall into any of the 10 templates. Therefore, the spectra from particulate emissions of burning materials can be easily discriminated from that of common atmospheric aerosol particles. The SFFS technology could be a good tool for monitoring burning pit emissions and possibly for distinguishing them from atmospheric aerosol particles.     

Synthesis and optical properties of pencil-like and shuttle-like ZnO microrods

The pencil-like and shuttle-like ZnO microrods have been fabricated on Si (100) substrates by chemical vapor deposition. Structure characterization results show that the microrods are perfect single crystals with the wurtzite structure along the [0001] growth direction and have diameters ranging from 100 nm to 2 μm and lengths up to 10 μm. Room-temperature photoluminescence measurements of ZnO microstructures exhibit an intensive ultraviolet peak at 390 nm and a broad peak centered at about 526 nm, which can be attributed to the free exciton emission and the deep level emission, respectively. Cathodoluminescence measurements show the same ultraviolet and green emissions as seen in the photoluminescence results. A possible growth mechanism of ZnO microrods is finally proposed.     

Nonlinear dynamic filtering of logarithmically amplified fringe signals in optical coherence tomography applied to paper measurements

Application of the nonlinear Kalman filtering method to logarithmically amplified low-coherence fringe signals measured from paper samples is considered. Experimental results of dynamic fringe envelope recovery in optical coherence tomography (OCT) systems are presented. The analog fringe envelope and digital dynamic fringe envelope recoveries from noisy signals are compared. The results show that the nonlinear discrete Kalman filtering method can be applied to estimate envelopes of logarithmically transformed low-coherence fringe signals with high noise immunity. Logarithmic amplification reduces quantization error in dealing with small signal values. The experimental results obtained demonstrate the possibility of purely digital signal processing in OCT. The text was submitted by the authors in English.     

Watt-level, all-fiber supercontinuum source based on telecom-grade fiber components

Supercontinuum (SC) generation in a standard telecom fiber using 1 ns pulses of a 1,550-nm DFB laser amplified in a cascade of erbium and erbium/ytterbium fiber amplifiers is reported. The SC source operated at 200 kHz repetition rate and delivered up to 2 W of average output power in the band of 1,300–2,500 nm with a diffraction limited beam. For the wavelengths over 1,650 nm, the output power of 1.1 W was recorded. The spectrum was very flat with the flatness of <5 dB in the wavelength interval of 1.6–2.18 μm. To the best of our knowledge, it is the first report on W-level SC generation obtained only in a standard single-mode fiber (SMF-28) with almost the entire spectrum in the eye-safe spectral region (λ > 1.4 μm) permitted by silicate glass transparency.     

Optical quantum transmitter with finesse of 30 at 800-nm central wavelength using microring resonators

A microring resonator (MRR) system incorporating an add/drop system is presented. The finesse of the proposed system can be determined using the full width at half maximum (FWHM) and free spectrum range (FSR) of the generated multiple soliton pulses. The central wavelength of the bright input soliton pulse has been selected as 800 nm, at which a ring system with better sensitivity shows high finesse that is suitable for applications to many optical communication systems such as optical transmitters and sensors. Simulation results show that FSR of 0.3 nm and 1.1 ns and FWHM of 10 pm and 36.6 ps could be obtained. Therefore, a system with finesse of 30 can be obtained; in such a system, the MRR system shows high performance. This system can be used in optical communication networks as a transmitter system for optical soliton pulses with finesse of 30, and theses pulses can be detected via an optical receiver.     

Ultra-compact TDLAS humidity measurement cell with advanced signal processing

In this paper, tunable diode laser absorption spectroscopy humidity measurements with an ultra-compact measurement cell are presented. The optical path length is 2 cm. The system uses a vertical cavity surface emitting laser at 1.854 μm. The main limiting factor of the humidity resolution is not the noise but interference fringes produced by reflecting surfaces. Next to the system setup, a novel rejection method to eliminate these fringes, based on Fourier domain analysis of the absorption line, is described. In contrast to other fringe rejection methods, the presented method is able to handle fringes, whose free spectral range is in the range of the half width of the absorption line. The achievable humidity resolution for the presented cell is below 0.25 % relative humidity at room temperature.     

Validation of Photodynamic Action via Photobleaching of a New Curcumin-Based Composite with Enhanced Water Solubility

Motivated by the photochemical and photophysical properties of curcumin-based composites, the characteristics of a new curcumin-based water-soluble salt were investigated via absorption and fluorescence spectroscopy. Photobleaching was investigated using a set of LEDs in three different wavelengths (405 nm, 450 nm and 470 nm) to illuminate an aqueous solution of curcumin, evaluating its degradation for five different exposure times (0, 5, 15, 45 and 105 minutes). The results were compared with equivalent measurements of dark degradation and illumination in the presence of a singlet-oxygen quencher. Three solution concentrations (50, 100 and 150 μg/ml) were studied. To measure the fluorescence, it was used low power 405 nm excitation laser source. Time dependent photodegradation of curcumin was observed, as compared to the natural degradation of samples maintained on a dark environment. Two main absorption peaks were detected and their relation responded to both concentration and wavelength of the illumination source. A spectral correlation between absorption of curcumin and the emission bands of the sources showed an optimal spectral overlap for the 450 nm LED. For this source, photobleaching showed a less intense degradation on the presence of singlet oxygen quencher. This last result confirmed singlet oxygen production in vitro, indicating a strong potential of this composite to be used as a blue-light-activated photosensitizer.     

钛宝石泵浦的Yb:YAG晶体的激光性能

测量了Yb:YAG晶体的光谱特性,用Ar⁺离子泵浦钛宝石激光器作为泵浦源泵浦Yb:YAG晶体,采用平平腔设计,当输出耦合镜T_1.053μm=4.26%,泵浦功率为1410mW时,得到320mW1.053μm的高效CW激光输出,斜率效率为54%,外推阈值功率为203mW。     

Theoretical and experimental study of single mode-locking pulse generation with low repetition rate in a dual-loss-modulated QML YVO4/Nd:YVO4 laser with EO and GaAs

Using electro-optic (EO) modulator and GaAs saturable absorber, a diode-pumped doubly Q-switched and mode-locked (QML) YVO₄/Nd:YVO₄ laser at 1.06 μm is realized. The experimental results show that the number of the mode-locking pulses underneath the Q-switched envelope decreased with increasing pump power. With an output coupling of 6.5 %, the single mode-locking pulse underneath the Q-switched envelope with 1 kHz repetition rate was obtained when the pump power exceeded 4.65 W. At a pump power of 8.25 W for an output coupling of 10 %, a stable mode-locking pulse train at a repetition rate of 1 kHz was achieved with pulse energy as high as 582 μJ and pulse duration of about 580 ps, corresponding to a peak power of 1 MW. Using a hyperbolic secant square function and considering the Gaussian distribution of the intracavity photon density, the coupled rate equations for diode-pumped doubly QML YVO₄/Nd:YVO₄ laser are given and the numerical solutions of the equations are basically in accordance with the experimental results.     

Graphene-based passively Q-switched Nd:KLu(WO4)2 eye-safe laser operating at 1,425 nm

With graphene as saturable absorber, an Nd:KLu(WO₄)₂ eye-safe laser operating at 1,425 nm is demonstrated. To the best of our knowledge, this is the first demonstration that an Nd:KLu(WO₄)₂ laser operates at the eye-safe 1.4-μm region. A maximum total average output power of 170 mW is obtained under the pump power of 9.6 W, corresponding to an optical–optical efficiency of 1.77 %. The minimum pulse width and the highest pulse repetition rate are 153 ns and 97 kHz, respectively. Also the characteristics of the graphene used as saturable absorber for a 1.4-μm laser were studied for the first time.     

A ring ZnGeP2 optical parametric oscillator pumped by a Ho:LuAG laser

We have demonstrated that we believe to be the first ring ZnGeP₂ (ZGP) optical parametric oscillator (OPO) pumped by a pulsed Ho:LuAG laser. The maximum output power of the ring ZGP OPO laser was 5.51 W at 13.1 W incident Ho pump power, corresponding to a slope efficiency of 59.0 %. The ZGP OPO laser produced 14 ns mid-infrared pulses in the 3.72–4.01 and 4.37–4.75 μm spectral regions simultaneously. In addition, the continuous wave Ho:LuAG laser generated 26.5 W of linearly output at 2,094.4 nm at the absorbed Tm pump power of 49.9 W.     

Study on the Fluorescence Quenching Reaction of Amitriptyline and Clomipramine Hydrochlorides with Eosin Y and its Analytical Application

Amitriptyline.HCl (AMI) and clomipramine.HCl (CMI) react with eosin Y (EY) in pH 3.8 NaAc-AcH buffer solution to form ion association complex which results in quenching of fluorescence of EY and appearance of a new resonance Rayleigh scattering (RSS) spectrum at 620 nm. The spectral characteristics of absorption, fluorescence and RSS spectra have been investigated. The factors influencing the reaction were studied and optimum conditions for the reaction have been determined. Based on fluorescence quenching, a simple and sensitive spectrofluorimetric method for determination of AMI and CMI has been developed. The fluorescence quenching intensity was measured at 550 nm using an excitation wavelength of 310 nm. The calibration graph was found to be rectilinear in the range 0.08–2.0 μg?mL^?1 with detection limit of 0.017 μg?mL^?1 for AMI and 0.06–2.0 μg?mL^?1 with detection limit of 0.015 μg?mL^?1 for CMI. The method can be satisfactorily applied to the determination of AMI and CMI in tablets without interference from commonly occurring exicipients. The recovery and RSD values obtained indicate good accuracy and precision of the method. The mechanism of the reaction and fluorescence quenching has also been discussed.