共查询到18条相似文献,搜索用时 78 毫秒
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用三弧Czochralski法和真空电弧熔炼法制备了Ho2Co17-xSix化合物.通过X射线衍射和磁性测量手段研究了化合物的结构与内禀磁性.重点讨论了磁晶各向异性和自旋重取向转变.实验结果表明,Ho2Co17为Th2Ni17型六角结构,在05≤x≤3的化合物均为Th2Zn17型菱方结构,能够获得单相2∶17型化合物的最大Si含量是x=3.在x≤2的浓度范围,化合物的易磁化方向垂直于c轴.随Si含量增加,化合物的居里温度和Co原子平均磁矩单调减少.根据Ho2Co17-xSix化合物的居里温度和自旋重取向温
关键词: 相似文献
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采用经验的紧束缚方法对生长在Si(001)衬底上的应变合金GexSi1-x的光学常数进行了计算。应变对电子能带结构的影响,通过紧束缚参数随键角方向余弦的变化以及键长按经验的标度定则的变化而进行计算。其中标度指数根据对Ge和Si的畸变势常数的实验值进行拟合而确定。计算介电常数虚部时出现的动量矩阵元,根据对Ge和Si的介电常数虚部的实验曲线拟合而决定。列出了当x=0.2和1时的光学常数——介电常数虚部ε2、折射率n、吸收系数α和反射率R的计算结 相似文献
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研究了Mn42Al50-xFe8+x合金的结构、磁性和磁热效应. 通过成分调节, 居里温度TC在室温附近一宽温区连续可调, 分别为270 K (Mn42Al42Fe16), 341 K (Mn42Al40Fe18)和370 K(Mn42Al38Fe20). 磁化强度在相变温度处发生一陡降, 热磁曲线和等温磁化曲线均未观察到热和磁的滞后, 表明发生一可逆的二级相变. 在各自居里温度附近, 0-5 T的外磁场变化下磁熵变峰值分别为2.48, 2.52和2.40 J·kg-1·K-1. Mn50-xAl50-yFex+y合金的磁熵变峰值虽然与许多优良的磁制冷材料相比并不大, 但是制备该化合物的原材料价格非常低廉, 制备工艺简单, 加工成型也较容易, 化合物本身耐腐蚀性、延展性较好, 且在居里温度附近发生的是可逆的二级相变, 无晶格或结构的变化, 有利于制冷剂的多次循环使用.
关键词:
磁性
磁热效应
二级相变 相似文献
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对定向凝固方法制备的Ni47Mn32Ga21多晶合金,通过扫描电镜、金相、电子能谱等手段研究其组份和组织形貌,通过对合金磁化强度与温度关系、等温磁化曲线及磁感生应变曲线等的测量分析,研究了合金结构相变和磁相变过程中的磁熵变及不同压力下的磁感生应变. 研究结果表明:合金组份与设计组份基本一致,室温下合金大部分为马氏体相. 升温过程中合金的磁熵变在居里温度(365 K)附近有最大值,并有较大的磁熵变峰值半高宽,747 kA/m的磁场下该磁熵变最大值为-1.45 J/kg ·K,磁熵变峰值的半高宽为21 K. 合金在室温(298 K)下有较好的双向可恢复磁感生应变,480 kA/m磁场下,无压力时合金的磁感生应变值达到-670×10-6,并趋饱和;而在与磁场方向平行的27.3 MPa外压力作用下合金的磁感生应变值增大到-1300×10-6,且未饱和.
关键词:
Ni-Mn-Ga
铁磁形状记忆合金
磁熵变
磁感生应变 相似文献
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The crystal structure and magnetic properties of R2Fe17-xCrx(R=Dy,Er,0≤x≤3) compounds have been investigated by me ans of X-ray diffraction and magnetization measurements. These compounds have hexagonal Th2Ni17-type structure. The unit-cell volumes decrease with the increase of Cr concentration x. The Curie temperature Tc of the Er2Fe17-xCrx compounds increases from 320 K for x=0 to 403 K for x=1.0 and then decreases with further increase of x. The Cur ie temperat ure Tc of Dy2Fe17-xCrx compounds increases from 364 K for x=0 to 435 K for x=1.0 and then decreases with further increase of x. The saturation magnetization of these compounds shows an approximately linear decrease with the increase of x. Spin reorientation transitions occur s in Er2Fe17-xCrx(x=2.0 and 3.0). 相似文献
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F. Semari F. Dahmane N. Baki Y. Al-Douri S. Akbudak G. Uğur Ş. Uğur A. Bouhemadou R. Khenata C.H. Voon 《Chinese Journal of Physics (Taipei)》2018,56(2):567-573
First-principles calculations were used to calculate the structural, electronic and half-metallic ferromagnetism of Mn2RuGe1-xSnx (x?=?0, 0.25, 0.50, 0.75, 1) Heusler alloys. The Hg2CuTi-type structure is found to be energetic more than Cu2MnAl-type structure for both Mn2RuGe and Mn2RuSn compounds. The calculated lattice constants for Mn2RuGe and Mn2RuSn are 5.91?Å and 6.17?Å, respectively. The electronic band structures and density of states of Mn2RuGe show a half metallic character with total magnetic moments, 2 μB per formula unit that are in good agreement with Slater-Pauling rule with indirect band gap, 0.31?eV along the direction Γ –X. It is observed that the total magnetic moment per cell increases as Sn concentration increases in the Heusler alloys. 相似文献
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Gap Structure of 12442-Type KCa2(Fe1-xCox)4As4F2(x=0,0.1) Revealed by Temperature Dependence of Lower Critical Field 下载免费PDF全文
We report an in-depth investigation on the out-of-plane lower critical field Hc1 of the KCa2(Fe1-xCox)4As4F2(12442-type,x=0,0.1).The multi-gap feature is revealed by the kink in the temperature-dependent Hc1(T)curve for the two samples with different doping levels.Based on a simplified two-gap model,the magnitudes of the two gaps are determined to be Δ1=1.2 meV and Δ2=5.0 meV for the sam... 相似文献
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A. R. Ball D. Gignoux F. E. Kayzel D. Schmitt A. de Visser 《Journal of magnetism and magnetic materials》1992,110(3):337-342
Magnetization measurements in fields up to 38 T performed at low temperature on single crystals of the hexagonal Pr(Ni1-xCox)5 compounds for x = 0, 0.05, 0.10 and 0.20 are presented. In PrNi5 we observe highly original behaviour predicted by the knowledge of the Crystalline Electric Field parameters and arising from the existence of a non-magnetic singlet ground state; namely transitions associated with the field induced “anticrossing” and “crossing” of the two lowest states along the [100] and [120] directions, respectively. The measurements performed on the other compounds have allowed us to study the dependence of this behaviour on Co substitutions. 相似文献
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J.M. Levingston R. Valente A.A. Ghilarducci L.M. Fabietti H.R. Salva S.E. Urreta 《Physica B: Condensed Matter》2012,407(16):3291-3294
The Nd60Fe30Al10 alloy exhibits a large glass forming ability which allows to obtain relatively thick cast rods containing large volume fractions of amorphous phases. In this work the microstructure and the hard magnetic properties of as-cast rods are characterized. The alloy is processed by suction casting into a chilled copper mould to obtain cylinders 5 mm diameter and 50 mm length. This diameter is selected because it is an upper limit for this processing route, beyond which the hard properties largely deteriorate. A room temperature coercivity of 0.34 T is obtained. The sample microstructure is heterogeneous, with very different size scales near the surface and along the central zone. However, in both regions a large fraction of an amorphous ferromagnetic phase is observed; it is found that paramagnetic nanocrystalline phases – mainly Nd or Nd-rich particles, embedded in the amorphous matrix – are somewhat coarser in the central zone. These larger nanocrystals, less efficient to pin domain walls, are proposed to be responsible for the lower coercive fields observed, as compared with those found in cylinders 1–3 mm diameter where no inhomogeneities are found. This conclusion is supported by microstructure, calorimetric and magnetic observations. 相似文献
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测量了Ni52Mn24Ga24单晶样品在磁场加载和未加载情 况下马氏体相变时的相变应变.分析结果表明:用提拉法生长单晶时在晶体内部引入了单一取向的内应力,该取向内应力可诱导马氏体变体择优取向,从而导致马氏体相变时产生大的相变应变.从理论上计算了该内应力的大小.另外,对样品在马氏体态单纯磁诱导应变的热动力学研究,表明取向内应力在马氏体态依然存在.
关键词:
马氏体相变
磁感生应变
内应力 相似文献