蒸发相变与界面流动耦合机理研究

本文提出了一种新模型来研究液层在其纯蒸气中的蒸发热动力学特征,尤其是当蒸发界面张力驱动流占主导作用时(如微重力环境中)液层热毛细对流和界面蒸发始终耦合在一起。气-液界面的传热传质规律有待深入研究。本文数值模拟研究了蒸发相变界面热毛细对流与蒸发效应的耦合机质,得到了不同蒸发模式和不同强度热毛细对流蒸发液层的温度分布、蒸发速率以及对流流场分布的数值解。论述了蒸发Biot数和Marangoni数对界面传热传质的影响,发现并解释了蒸发和热毛细耦合的三种模式。     

液滴碰撞对液膜内汽泡运动与换热影响

采用数值模拟的方法,研究了沸腾雾化喷射过程中热壁面薄液膜层受到液滴碰撞扰动时液膜层内汽泡运动,相界面变化和由此引起的壁面换热特性.模拟结果显示汽泡生长初期相界面变化与液膜层内二次核化特征与文献结果吻合良好,汽泡生长后期相界面变化存在滞后.讨论了液滴下降速度.液滴直径与初始位置,多液滴碰撞对液膜层内流动与壁面换热的影响.     

方管内气液两相流界面波统计特性分析

以空气、水为工质，利用电导探针测量技术结合统计分析理论研究了水平矩形管内气液两相流界面波特性．首先对管内气液两相流的界面波进行了分类和定义；其次研究了气液两相流界面波在幅域、时域和频域的统计特性，同时考察了界面波特性参数（波速、频率和波高）等随气液两相流量的变化规律．     

倾斜下降管气液两相分层流截面含气率的计算与液层高度的预测

分层流是气液两相流中常见的流动型式，分层流中液层高度是计算的基本数据，由于界面波的存在，对液层的测量和预测都很困难．Ｖｌａｃｈｏｓ提出了预测气液两相分层流液层厚度的关系式，但这一关系式并不适用于倾斜下降管气液两相流．本文提出了计算倾斜下降管气液两相分层流截面含气率的理论模型，在这种模型下得到的截面含气率和实验结果符合良好．在大量实验的基础上，考虑了倾角、管径、气液各相折算速度的影响，根据实验数据提出了预测液层厚度的关系式。     

流态化固体颗粒对对流沸腾传热的强化

在对流沸腾系统中引入固体颗粒,固体颗粒在液体中呈流态化,从而形成气液固三相对流沸腾过程。对气液固三相流对流沸腾过程的传热特性进行了实验研究,结果表明流态化固体颗粒对液体的对流沸腾传热具有显著的强化作用。基于固体颗粒撞击沸腾气泡时的受力分析,获得了固体颗粒穿透气泡并使气泡破碎的条件,分析了流态化固体颗粒强化沸腾传热的机理。实验结果与理论分析符合良好。     

CO2吸收过程Rayleigh对流传质特性格子-Boltzmann模拟

在化工吸收过程中，浓度梯度导致的Rayleigh对流对气液界面传质具有重要影响，但其强化传质机理尚不明确。本文采用格子Boltzmann方法研究乙醇与甲醇吸收CO2过程Rayleigh对流传质特性，将模拟图像与实验观测结果进行对比，并采用不同传质模型对气液传质通量进行分析。结果表明：模拟得到的Rayleigh对流结构形状、形态演变等与实验结果具有良好的一致性；界面传质扰动是Rayleigh对流发生的必要条件，在扰动强度10^-6≤C_D≤10^-5kg/m³区间内，Rayleigh对流临界时间与理论预测值的最大误差约10%;Rayleigh对流的发生及演化过程可分为三个阶段：扩散传质阶段、Rayleigh对流起始阶段、Rayleigh对流演化阶段；对气液传质通量进行预测时，表面散度模型的预测效果优于小涡模型，但表面散度模型预测结果与模拟传质通量具有1 s的相位差，速度与浓度场并不完全同步；基于Rayleigh对流发生及演化过程的分阶段性，提出混合模型描述Rayleigh对流传质特性，该模型对传质通量预测的...     

载气蒸发气-液两相流传热特征与过程模拟

本文首先说明了载气蒸发气-液两相流传热特征,并以载气与沸腾液体相接触时液体向载气泡内快速汽化所产生的“界面汽化热阱”说明了其对传热的强化作用;进而建立载气蒸发过程流体流动与传热的数学模型,并进行了模拟计算。     

活性剂浓度分布对液膜排液过程的影响

针对含不溶性活性剂的垂直液膜排液过程,考虑分离压和表面黏度的作用,应用润滑理论建立液膜厚度、活性剂浓度和表面速度的控制方程组,分析初始活性剂浓度及梯度对排液过程的影响.结果表明：当液膜表面不含活性剂时,其排液历程很短,很快发生破断.当液膜表面添加活性剂时,可以延长液膜存续时间.而当液膜表面活性剂浓度较低时,其诱发的Marangoni效应不足以克服重力的排液作用,其形成的"黑膜"不能稳定存在.随活性剂浓度增大,液膜表面流动速度减小,液膜表面更加"坚固",所形成的"黑膜"非常稳定.当考虑初始活性剂浓度梯度时,其影响主要体现在减缓排液初期的表面速度.     

表面活性剂添加对水平管内气液两相流含液率的影响

应用电导断层测量技术研究表面活性剂添加对水平管内气液两相流含液率的影响,实验工质为空气/水、空气/100 mg/kg十二烷基硫酸钠(SDS)水溶液。结果表明,空气/水气液两相流动在光滑分层流型区,表面活性剂添加对平均截面含液率基本没有影响。随着液体流速的增加,空气/水气液两相流动进入波状分层流型区域,添加表面活性剂可以抑制或消除界面波动,增大平均截面含液率。表面活性剂的添加使弹状流含液率下降,气液流速较低时这一现象尤为明显。     

基于格子Boltzmann方法的液液不混溶两相流动数值模拟

具有介观特性的格子Boltzmann方法能够准确方便地捕捉相界面细节,在两相流动领域具有广泛的应用前景.本文在简要介绍格子Boltzmann方法的基础上,利用格子Boltzmann方法的颜色模型对四类经典两相流动问题进行了模拟,界面张力的Laplace定律验证、单液滴松弛过程、两个液滴融合过程、水平通道内不混溶液液两相流动.结果表明,液滴界面张力符合Laplace定律;黏性越大,液滴松弛过程越稳定;界面张力越大,液滴融合速度越快;格子Boltzmann方法能够有效描述液液两相流动的界而信息。研究工作为应用格子Boltzmann方法分析两相流动问题奠定了理论基础.     

不相溶系统内酸碱中和反应驱动动力学的不稳定性

采用含Mach-Zehnder干涉光路和Hele-Shaw反应器的实验系统,研究了重力场作用下,在Hele-Shaw系统内沿水平界面发生的由酸碱中和反应驱动的动力学不稳定性.反应器内包含上下两层反应物,即下层密度较大的四甲基氢氧化铵水溶液和上层密度较小的溶解于有机相的丙酸溶液. 研究了在伴随有界面传质的中和反应过程中,化学组分对于动力学不稳定性的影响. 观察发现了由于反应物初始浓度不均引起的多种形式的Marangoni对流结构,包含有胞状结构和各种震动波形式的结构.测量了不稳定性发生过程中碱溶液的浓度. 结果表明不稳定性对流的产生可以显著提高系统内的传质效率,并造成传质结 构的剧烈变形.     

水平磁场对双层流体热毛细对流的影响

三维数值研究了零重力时水平温度梯度作用下,B2O3封闭液与InP熔液组成的双层流体系统在水平磁场作用下的热毛细对流.结果显示,当磁场强度较小时,上层流体中对流涡的结构变化其微,而下层流体中的逆对流涡得到了抑制;随着磁场的增强,温度场分布逐渐趋于均匀,涡量强度逐渐减小,表明热毛细对流强度逐步地得到削弱.当磁场增强列Bx=0.4 T时,上层流体中的对流涡较均匀地充满上层流体区,而下层流体中对流涡紧贴着交界面.     

Instability in Two-Sided Thermocapillary-Buoyancy Convection with Interfacial Phase Change

A new model of two-phase thermocapillary-buoyancy convection with phase change at gas-liquid interface in an enclosed cavity subjected to a horizontal temperature gradient is proposed,rather than the previous onesided model without phase change.We study the onset of multicellular convection and two modes of convective instability,and find four different flow regimes.Their transition map is compared with the non-phase-change condition.Our numerical results show the stabilizing effect of interfacial phase change on the thermocapillarybuoyancy convection.     

Preliminary study of two immiscible liquid layers subjected to a horizontal temperature gradient

Marangoni convection, driven by interfacial instability due to a surface tension gradient, presents a significant problem in the crystal growth process. To achieve better materials processing, it is necessary to suppress and control this convection, especially in crystal growth using Liquid Encapsulated Czochralski techniques in which the melt is encapsulated in an immiscible medium. Marangoni convection can occur at the liquid-liquid interface and at the gas-liquid free surface. Buoyancy driven convection can also affect and complicate the flow. The present report studied Marangoni convection in a two-liquid layer system in an open and enclosed cavity. Flow in the cavity was subjected to a horizontal temperature gradient. Interactive flow near the liquid-liquid interface was measured by the Particle Image Velocimetry (PIV) technique. The measured flow field is in good agreement with numerical predictions.     

Oscillation of the convective flow around an air bubble in a vertically stratified surfactant solution

The appearance of oscillatory modes of the concentration convection around an air bubble in an aqueous solution with a vertical gradient of surfactant concentration was revealed experimentally. The solution filled a thin vertical layer containing an air bubble in the form of a short horizontal cylinder with a free lateral surface. Due to a small layer thickness, two-dimensional flows and concentration distributions were generated in the liquid. Their evolution was investigated using an interferometric technique. It was found that the flow oscillation was caused by a specific interaction between the diffusion and two solutal (capillary and gravitational) mechanisms of convective mass transfer, which had quite different characteristic times. The time variation of the oscillation period was analyzed in relation to the surfactant concentration gradient, the average solution concentration, and the concentration Marangoni number. It was shown that the ratio of the dimensionless oscillation frequency to the Marangoni number is time independent and is the same for different liquids and various orientations of the concentration gradient. Published in Russian in Zhurnal éksperimental’noĭ i Teoreticheskoĭ Fiziki, 2006, Vol. 130, No. 2, pp. 363–370. The text was translated by the authors.     

Analysis of coherent structures in Rayleigh–Bénard convection

Using direct numerical simulation, we investigate characteristics of coherent structures in Rayleigh–Bénard convection in a soft turbulence regime. The role of thermal plumes, essential structures in Rayleigh–Bénard convection, is studied by splitting flow regimes into thermal plume and background by investigating joint probability density function (PDF) of invariants of velocity gradient tensor. The contribution to thermal dissipation rate by these two regions is analysed separately. Through the joint PDF of invariants, we also examine the thermal effect on velocity structures.     

添加剂对LiBr溶液吸收蒸汽过程中的强化机理

利用吊板法测量了加有正辛醇和异辛醇这两种添加剂的溴化锂溶液的表面张力 ,利用激光照相的可视化方法研究了在静池吸收过程中添加剂对溴化锂溶液吸收水蒸汽的强化影响 .实验结果显示液体添加剂和蒸汽添加剂都能显著地降低溴化锂溶液的表面张力 ;蒸汽添加剂不仅和液体添加剂一样可以在吸收表面引起马拉戈尼对流 ,而且对吸收具有更好的强化效果 .根据对实验现象的分析 ,得出了添加剂对吸收的强化机理 :由于溶液表面层对液体添加剂或蒸汽添加剂的表面吸附作用 ,造成吸收界面处表面张力分布不均匀 ,从而在吸收界面引起马拉戈尼对流现象 ,强化了吸收过程中的传热、传质性能     

Energy transport enhancements in a transitional thermal plasmaplume

The evolution of heat and mass transfer in the initial region of a transitional plasma plume is investigated and discussed. The results show that these transport processes are controlled and limited by the plume shear layer instability. This process of laminar-turbulent transition is consecutively controlled by the plume core shear layer instability, by the “jet mode” induced by unstable shear layer, and by resonance in the jet and arc chamber. These three processes are manifested in three events. Between the first and second phase, there is a maximum of average enthalpy. The other two thresholds occur at maximum and minimum stagnation heat flux from the plume core. It seems that these processes also influence the thermal energy production in the arc chamber cavity     

Coupling between aging and convective motion in a colloidal glass of Laponite

We study thermal convection in a colloidal glass of Laponite in formation. Low concentration preparation are submitted to destabilizing vertical temperature gradient, and present a gradual transition from a turbulent convective state to a steady conductive state as their viscosity increases. The time spent under convection is found to depend strongly on sample concentration, decreasing exponentially with mass fraction of colloidal particles. Moreover, at fixed concentration, it also depends slightly on the pattern selected by the Rayleigh Bénard instability: more rolls maintain the convection state longer. This behavior can be interpreted with recent theoretical approaches of soft glassy material rheology.     

微细管碳纳米管悬浮液强制对流换热实验研究

测量了水平微细圆管内蒸馏水和不同质量浓度的水基多壁碳纳米管纳米流体在低雷诺数下的强制对流换热特性。实验结果表明,与蒸馏水相比,纳米流体的对流换热系数显著提高,且随质量浓度和管内雷诺数的增大而增大;并且研究了流体管内流动阻力特性,得到的泊肃叶数f·Re值随着雷诺数的变化不明显,但纳米流体的f·Re值要明显小于纯水。