共查询到18条相似文献,搜索用时 115 毫秒
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利用 Schn-Tremblay 理论计算了 Pb、Sn 超导薄膜在注入准粒子且注入电压很小(ev<2△(?))时的能隙微小增加的效应.同时,把此理论扩展到 ev>>2△_i 的大电压情况,计算出能隙明显减小及超导-正常混合态的结果. 相似文献
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MgB2的超导机制不同于传统的金属超导体.最近,来自美国加州大学(Berkeley)的Choi等采用从头计算的理论方法,研究了MgB2的超导能隙,即电荷载流子配对的形成能.研究结果表明,MgB2是一个双能隙超导体.在此基础上,一些可测量物理参数的理论结果被给出,从而解释了MgB2反常的超导特性,这包括:高的超导转变温度Tc,比热对温度的依赖关系,以及角分辨光发射谱和隧穿实验所给出的多能隙证据(小能隙Δ≈1.5-3.5meV,大能隙Δ≈5.5-8meV).MgB2晶体由B原子层和Mg原子层交替堆叠而成,具有六方对称性.B层的结构类似于石墨片,呈峰窝状;从M… 相似文献
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双能隙超导体MgB2的热导 总被引:2,自引:0,他引:2
测量了多晶MgB2的热导,实验温区为5—300K.在双能隙模型下,用基于BCS超导理论的BRT热导理论对实验结果进行了分析,给出MgB2中两个能隙大小分别为16和51meV.对电子热导的分析结果表明σ能带准粒子受到的杂质散射远小于π能带准粒子受到的杂质散射.与单晶MgB2的热导实验结果相比,多晶MgB2的声子热导结果表明在c方向上热传导声子受到来自σ能带准粒子的散射,显示了MgB2在能量输运上的各向异性.关键词:MgB2热导率能隙 相似文献
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测量了在O2中退火不同时间的Sm1.85Ce0.15CuO4单晶样品的热电势S与电阻率ρ的温度依赖关系.所有的样品电阻率高温下呈现线性温度依赖行为.未退火的样品在148K发生超导转变,而退火后的样品在低温下发生金属半导体相变,其超导电性消失,表明退火引起了载流子浓度下降,体系进入欠掺杂态.随着温度降低,所有的样品ST和ρT曲线在200K附近(T)都发生斜率的改变,可以用赝能隙现象解释.热电势S在低温下出现一个正的曳引峰,意味着载流子符号发生改变,由电子型转变为空穴型关键词:电子型超导体热电势赝能隙 相似文献
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新型超导体MgB2和MgCNi3热、电输运性质研究 总被引:1,自引:0,他引:1
报道了两种新型超导体MgB2,MgCNi3和氧化物高温超导体Bi2< /sub>Sr2Ca0.9Ce0.1Cu2O8+y 的热导率-温度关系和电阻率-温度关系.实验发现氧化物高温超导 体在进入超导态后热导有所上升,出现极大值后再下降,而MgB2和MgCNi3 则单调下降. 由Wiedemann-Fra关键词:热导率超导体2')\" href=\"#\">MgB23')\" href=\"#\">MgCNi3 相似文献
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运用紧束缚能带理论,研究拉伸形变下BC3纳米管的能带结构. 研究表明:随着拉伸和压缩强度的不断增加,BC3纳米管的导带能级和价带能级逐渐靠近,最终发生能带交叠. 压缩形变下能带的交叠程度可达05 eV,而拉伸形变下只有02 eV. 对于扶手椅型BC3纳米管,随着拉伸和压缩的不断增加,BC3纳米管首先由直接半导体转化为间接半导体,进而发生能带的交叠,表现出金属性. 在无形变时,扶手椅型BC3纳米关键词:3纳米管')\" href=\"#\">BC3纳米管能隙拉伸形变半导体 相似文献
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Thermoelectric power generators require high-efficiency thermoelectric materials to transform waste heat into usable electrical energy. An efficient thermoelectric material should have high Seebeck coefficient and excellent electrical conductivity as well as low thermal conductivity. Graphene, the first truly 2D nanomaterial, exhibits unique properties which suit it for use in thermoelectric power generators, but its application in thermoelectrics is limited by the high thermal conductivity and low Seebeck coefficient resulting from its gapless spectrum. However, with the possibility of modification of graphene's band structure to enhance Seebeck coefficient and the reduction of its thermal conductivity, it is an exciting prospect for application in thermoelectric power generation. This article examines the electronic, optical, thermal, and thermoelectric properties of graphene systems. The factors that contribute to these material properties in graphene systems like charge carriers scattering mechanisms are discussed. A salient aspect of this article is a synergistic perspective on the reduction of thermal conductivity and improvement of Seebeck coefficient of graphene for a higher thermoelectric energy conversion efficiency. In this regard, the effect of graphene nanostructuring and doping, forming of structural defects, as well as graphene integration into a polymer matrix on its thermal conductivity and Seebeck coefficient is elucidated. 相似文献
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C.I. Lee K.E. Lee Y.Y. Song H.J. Im S. Kimura Y.S. Kwon 《Infrared Physics & Technology》2008,51(5):488-490
Reflectivity spectra of CeIn3 are measured at 7, 30, 50, 100, 150, 200 and 300 K in wild energy regions from 6 meV to 30 eV. Optical conductivity spectra are obtained from a Kramers–Kronig’ relation. A hump in the optical conductivity σ1 is observed at about 500 cm−1 below 100 K, resulting from strong hybridization between conduction electrons and Ce 4f electronic states. The low frequency plasmon indicating the existence of heavy particles is also observed below coherence temperature T* 100 K. 相似文献
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S.J. Singh J. Prakash S. Patnaik A.K. Ganguli 《Physica C: Superconductivity and its Applications》2010,470(21):1928-1932
Electron-doping of the semimetal (CeOFeAs) by either fluorine (max Tc ∼ 43 K) or cobalt (max Tc ∼ 11 K) leads to superconductivity. Here we show the effect of transition metal (Co) substitution at the iron site on the superconducting properties of CeO0.9F0.1FeAs (Tc ∼ 38 K) to understand the interplay of charge carriers in both the rare earth-oxygen and Fe–As layers. Simultaneous doping of equivalent number of charge carriers in both layers leads to a Tc of 9.8 K which is lower than the Tc obtained when either the conducting layer (FeAs) or charge reservoir layer (CeO) is individually doped. This suggests a clear interplay between the two layers to control the superconductivity. Resistivity upturn and negative magnetoresistance are observed with Co doping that is interpreted in the gamut of Kondo effect. Hall coefficient and thermoelectric power indicate increased carrier concentration with cobalt doping in CeO0.9F0.1FeAs. The rf penetration depth both for CeO0.9F0.1Fe0.95Co0.05As and CeO0.9F0.1FeAs show an exponential temperature dependence with gap values of ∼1.6 and 1.9 meV respectively. 相似文献
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揭示了低温流体~3He的热导率在液态区随温度和压力两个状态参数变化的反常规律。综合该反常规律以及热导率在临界点附近的突变特性,首次提出了~3He在0.003 K至临界温度3.3157 K温区内完整的饱和线热导率方程以及压力高至20 MPa的压缩液相区热导率方程。方程计算值与实验数据相对偏差小于±1.5%,与高精度实验数据偏差小于±0.4%,并且在极低温条件下光滑过渡为由量子理论预测的理论极限. 相似文献
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利用水热法生成了形状规则、粒径均匀的球形ZnO纳米颗粒, 并超声分散于水中, 制备得到稳定的水基ZnO纳米流体. 实验测量水基ZnO纳米流体在体积分数和温度变化时的电导率, 并测试室温下水基ZnO纳米流体在不同体积分数下的热导率. 实验结果表明, ZnO纳米颗粒的添加较大地提高了基液(纯水)的热导率和电导率, 水基ZnO纳米流体的电导率随纳米颗粒体积分数增加呈非线性增加关系, 而电导率随温度变化呈现出拟线性关系; 纳米流体的热导率与纳米颗粒体积分数增加呈近似线性增加关系. 本文在经典Maxwell热导模型和布朗动力学理论的基础上, 同时考虑了吸附层、团聚体和布朗运动等因素对热导率的影响, 提出了热导率修正模型.将修正模型预测值与实验值对比, 结果表明修正模型可以较为准确地计算出纳米流体的热导率.关键词:水热法电导率热导率热导模型 相似文献