Near-threshold electron attachment as Regge resonances: cross sections for K, Rb, and Cs atoms

We investigate the near-threshold formation of negative ions as Regge resonances in electron-atom scattering, with specific results obtained for e--K, e--Rb, and e--Cs. The complex angular momentum method, implemented within the Mulholland formulation of the total elastic cross sections, is employed. We demonstrate that for e--K, e--Rb, and e--Cs scattering, the near-threshold electron attachment cross sections are characterized by the Wigner threshold behavior, Ramsauer-Townsend minima, and Regge resonances, all discernible only through Regge partial cross section scrutiny. Regge partial, differential, and total elastic cross sections are presented and contrasted, as well as the differential cross section critical minima.     

Scattering lengths for Li-Cs, Na-Cs, K-Cs, and Rb-Cs ultracold collisions

We present triplet and singlet scattering lengths for X--133Cs collisions (X=6,7Li, 23Na, 39,40,41K, and 85,87Rb). We consider the short-range potential-energy curves based on high-quality ab initio calculations and the long-range potential described by accurate dispersion coefficients available in the literature. Using a Fermi function to smoothly connect the short- and long-range terms we construct the potential for all R and evaluate the scattering length for each mixed species X--Cs. In particular, we predict that the cross section for inelastic processes between 23Na and 133Cs and between 40K and 133Cs will be small as compared with the respective elastic cross sections.     

Elastic collisions of heavy ions at intermediate energies

The classical scattering cross section of two colliding nuclei is evaluated. Special attention is given to the influence of relativistic and magnetic field effects as well as retardation corrections on elastic trajectories of heavy ions. An analytical treatment is presented for a light particle impinging on a heavy target.     

Scattering of N(2)O on electron impact over an extensive energy range (0.1 eV-2000 eV)

We report electron impact total cross sections, Q(T), for e-N(2)O scattering over an extensive range of impact energies approximately from 0.1 eV to 2000 eV. We employ an ab initio calculation using R-matrix formalism below the ionization threshold of the target and above it we use the well established spherical complex optical potential to compute the cross sections. Total cross section is obtained as a sum of total elastic and total electronic excitation cross sections below the ionization threshold and above the ionization threshold as a sum of total elastic and total inelastic cross sections. Ample cross section data for e-N(2)O scattering are available at low impact energies and hence meaningful comparisons are made. Good agreement is observed with the available theoretical as well as experimental results over the entire energy range studied here.     

Total (elastic + inelastic) cross sections for electron scattering with bound and free germanium and lead atoms

Spherical complex optical potential (SCOP) approach has been used to compute the differential, total (elastic + inelastic) and momentum transfer cross sections for electrons scattering from the bound and free germanium and lead atoms in the energy range from 100–5000 eV. We find that the present calculated differential scattering cross sections (DCS) exhibit all important features (such as forward peaking, dip at middle angles and enhanced backward scattering) observed in other theoretical calculations and experimental measurements. The effect of absorption potential is generally to reduce the elastic cross section.     

Low-energy electron collisions with gas-phase uracil

We have studied gas-phase collisions between slow electrons and uracil molecules with a view to understanding the resonance structure of the scattering cross section. Our symmetry-resolved results for elastic scattering, computed in the fixed-nuclei, static-exchange and static-exchange-plus-polarization approximations, provide locations for the expected pi* shape resonances and indicate the possible presence of a low-energy sigma* resonance as well. Electron-impact excitation calculations were carried out for low-lying triplet and singlet excitation channels and yield a very large singlet cross section. We discuss the connection between the resonances found in our elastic cross section and features observed in dissociative attachment.     

Effect of orbiting resonance on the elastic differential cross sections

The effects of orbiting resonances on elastic differential cross sections are investigated for the Lennard-Jones (12, 6) model potential. The elastic differential cross section consists of three terms: a resonance term, a potential scattering term and an interference term. The interference term has a significant effect only at small angles of the differential cross section. The importance of the potential scattering term depends proportionally upon the orbiting resonance energy. For the low-lying orbiting resonance states, the resonance term is the dominant term, but at higher energy it appears only in the backward differential cross sections. Generally, by fitting the large angle differential cross sections, the resonance orbital angular momentum can be estimated.     

Electron scattering with H2S and PH3 molecules

Calculated total, differential and momentum transfer cross sections are reported for the vibrationally elastic scattering of electrons from H₂S and PH₃ molecules in the range of energy 0.1–50 eV. The scattering process is approximated by two incoherent scatterings caused, separately, by a central field and a long-range electric dipole interaction. The central field is calculated with a spherical approximate molecular wave function, in which the exchange interaction is treated in two ways: (i) exactly within the accuracy of the molecular wave function; (ii) approximately by a local model potential. The scattering by the central field is calculated with partial wave expansion technique, while the scattering by the electric dipole potential is calculated by using the first Born approximation for a rotating dipole model with experimental values of the dipole moments of H₂S and PH₃. The total cross sections are approximated by the incoherent sum of the cross section due to the central potential and the cross section of 00→10 rotational transition caused by the electric dipole potential. The effects of the polarization interaction are also tested. The contribution of small-angle scattering to the integral cross section is analyzed for these weakly polar molecules with some quantitative comparison.     

Quantitative analysis of angle‐resolved XPS spectra recorded in parallel data acquisition mode

The effects of anisotropy of the photoionization cross‐section and elastic scattering of photoelectrons in solids are investigated for angle‐resolved XPS spectra (ARXPS) recorded from α–Al₂O₃ substrate in parallel data acquisition mode. It is shown that for quantitative analysis of ARXPS spectra recorded in parallel data acquisition mode it is essential to account for the anisotropies of the photoionization cross‐sections of the detected photoelectrons for the concerned elements in the solid due to variation of the angle between the incident x‐rays and the detected photoelectrons. Neglecting the effect of elastic scattering only leads to minor errors in quantitative analysis of the ARXPS spectra. By adopting experimentally determined values for the relative sensitivity factors of the concerned photoelectrons in the solid as a function of the detection angle, cumbersome corrections for the effects of anisotropy of the photoionization cross‐section and elastic scattering can be avoided. Copyright © 2004 John Wiley & Sons, Ltd.     

Evaluation of Compton scattering and self-attenuation coefficient after <Emphasis Type="Italic">γ</Emphasis>-ray analysis of naturally occurring radioactive elements in environmental samples

Comparison of Compton scattering and Compton scattering cross section with self-attenuation coefficient were explained based on the kinematic equation and Klein-Nishina formula. Naturally occurring elements, ²³⁸U (²²⁶Ra), ⁴⁰K, ²³²Th (²²⁸Ra) and ¹³⁷Cs were determined in sediments and water from Ismailia canal in Egypt which were found in the range of permissible level. Self-attenuation coefficients, K, the ratio between photopeak detection efficiency using solid and liquid standards were determined. They fit well comparing to Compton scattering, Compton scattering cross section while inversely fit to energy-absorption Compton scattering cross section based on the Klein-Nishina formula.     

Model potential calculation of the HHe interaction; application to low energy elastic scattering

Recent model potential calculations of the HHe interaction potential by Valiron et al. are applied to the calculation of the cross section for elastic scattering of H and D by He at very low energies (of the order of several meV). Agreement with the experimental data is excellent. In view of the sensitivity of the cross sections to the interaction potential, it is established that our model potential method is highly accurate in describing long- and intermediate-range interactions.     

Potential energy curves for the interaction of a low-energy positron with matter: The case He+e+

In this introductory exploration of the title theme, we treat a positron as a light nucleus and work within the quasi-molecule approximation to obtain, for the first time, adiabatic potential energy curves for its scattering by the He atom. We then show that different elastic and inelastic processes that contribute to the total scattering cross section can be rationalized in molecular terms as dissociation and non-adiabatic couplings. Particularly, some new insights on positronium yielding are presented.     

Electron scattering by methanol and ethanol: a joint theoretical-experimental investigation

We present a joint theoretical-experimental study on electron scattering by methanol (CH(3)OH) and ethanol (C(2)H(5)OH) in a wide energy range. Experimental differential, integral and momentum-transfer cross sections for elastic electron scattering by ethanol are reported in the 100-1000 eV energy range. The experimental angular distributions of the energy-selected electrons are measured and converted to absolute cross sections using the relative flow technique. Moreover, elastic, total, and total absorption cross sections for both alcohols are calculated in the 1-500 eV energy range. A complex optical potential is used to represent the dynamics of the electron-alcohol interaction, whereas the scattering equations are solved iteratively using the Pade?'s approximant technique. Our calculated data agree well with those obtained using the Schwinger multichannel method at energies up to 20 eV. Discrepancies at high energies indicate the importance of absorption effects, included in our calculations. In general, the comparison between our theoretical and experimental results, as well as with other experimental data available in the literature, also show good agreement. Nevertheless, the discrepancy between the theoretical and experimental total cross sections at low incident energies suggests that the experimental cross sections measured using the transmission technique for polar targets should be reviewed.     

Quenching of rotationally excited CO by collisions with H2

Quantum close-coupling and coupled-states approximation scattering calculations of rotational energy transfer in CO due to collisions with H2 are presented for collision energies between 10(-6) and 15,000 cm(-1) using the H2-CO interaction potentials of Jankowski and Szalewicz [J. Chem. Phys. 123, 104301 (2005); 108, 3554 (1998)]. State-to-state cross sections and rate coefficients are reported for the quenching of CO initially in rotational levels j2 = 1-3 by collisions with both para- and ortho-H2. Comparison with the available theoretical and experimental results shows good agreement, but some discrepancies with previous calculations using the earlier potential remain. Interestingly, elastic and inelastic cross sections for the quenching of CO (j2 = 1) by para-H2 reveal significant differences at low collision energies. The differences in the well depths of the van der Waals interactions of the two potential surfaces lead to different resonance structures in the cross sections. In particular, the presence of a near-zero-energy resonance for the earlier potential which has a deeper van der Waals well yields elastic and inelastic cross sections that are about a factor of 5 larger than that for the newer potential at collision energies lower than 10(-3) cm(-1).     

Positron backscattering from an Al target: analytical calculation and Monte Carlo simulation

Positron backscattering coefficients are analytically calculated and numerically simulated for an Al target in the positron energy range 0.50–4 keV and for incident angles between 0° and 80° . The differential elastic scattering cross section has been obtained using the Bentabet and Bouarissa approximation (Phys. Lett. 2006; A 355: 390). Both the analytical and simulated results show good agreement with the experiment and previous theoretical work. Copyright © 2007 John Wiley & Sons, Ltd.     

H++Xe low-energy collisions: Opposite-phase oscillations of the elastic and charge transfer differential cross sections

Elastic as well as charge transfer collisions of H⁺+Xe have been investigated in a crossed beam experiment atE _CM ≈30 and 50 eV. Opposite-phase oscillations have been observed in the elastic differential cross section with respect to the charge transfer differential cross section for the formation of Xe⁺(² P _1/2). Taking advantage of the asymptotic quasi-degeneracy of the channels in question, this behavior has been qualitatively interpreted in terms of a simplified two-curve crossing model. The conditions of the validity of the model are discussed and its relation to the potential symmetry scattering in homonuclear systems is pointed out.     

An endogenous multiple scattering method for the calculation of the elastic scattering cross sections of electron shape resonances in polyatomic molecu

A procedure is described for obtaining the scattering potential for elastic electron—molecule scattering within the one-electron overlapping sphere multiple scattering Xα method. The method has been used to calculate the total elastic electron scattering cross sections for the nitrogen, ethylene and 1,3,5-trifluorobenzene molecules, which compare well with experimental data.     

Absorption and scattering of light by Pt, Pd, Ag, and Au nanodisks: absolute cross sections and branching ratios

Localized surface plasmons (LSPs) of metallic nanoparticles decay either radiatively or via an electron-hole pair cascade. In this work, the authors have experimentally and theoretically explored the branching ratio of the radiative and nonradiative LSP decay channels for nanodisks of Ag, Au, Pt, and Pd, with diameters D ranging from 38 to 530 nm and height h=20 nm, supported on a fused silica substrate. The branching ratio for the two plasmon decay channels was obtained by measuring the absorption and scattering cross sections as a function of photon energy. The former was obtained from measured extinction and scattering coefficients, using an integrating sphere detector combined with particle density measurements obtained from scanning electron microscopy images of the nanoparticles. Partly angle-resolved measurements of the scattered light allowed the authors to clearly identify contributions from dipolar and higher plasmonic modes to the extinction, scattering, and absorption cross sections. Based on these experiments they find that absorption dominates the total scattering cross section in all the examined cases for small metallic nanodisks (D<100 nm). For D>100 nm absorption still dominates for Pt and Pd nanodisks, while scattering dominates for Au and Ag. A theoretical approach, where the metal disks are approximated as oblate spheroids, is used to account for the trends in the measured cross sections. The field problem is solved in the electrostatic limit. The spheroid is treated as an induced dipole for which the dipolar polarizability is calculated based on spheroid geometry and the (bulk) dielectric response function of the metal the spheroid consists of and the dielectric medium surrounding it. One might expect this model to be inappropriate for disks with D>100 nm since effects due to the retardation of the incoming field across the metallic nanodisk and contributions from higher plasmonic modes are neglected. However, this model describes quite well the energy dependence of the dipolar resonance, the full width at half maximum, and the total extinction cross section for all four metallic systems, even when 100相似文献