共查询到20条相似文献,搜索用时 15 毫秒
1.
M. Diallo M. Diop P. M. Haba M. Gaye A. S. Sall A. H. Barry C. Beghidja R. Welter 《Journal of chemical crystallography》2008,38(6):475-478
Abstract Single crystals of new open-framework lanthanide sulphate nitrite La(NO2)(SO4)(H2O) has been synthesized, in the presence of 2,6-diformyl-4-chlorophenol. His structure has been determined by X-ray diffraction
data: the complex crystallizes in the tetragonal system, space group P43, with a = 7.0028(2) (?), b = 7.0028(2) (?), c = 11.8341(4) ?, V = 580.34(3) ?3, Z = 4, D
c = 3.582 Mg m−3. The three-dimensional (3D) framework of this compound is built up by the linkages of lanthanide atoms and the oxygen atoms
of the sulphate
and nitrite groups. The lanthanum atom is 9-fold coordinated. The structure is unfamiliar in lanthanide chemistry and this compound represents
the first example of nitrite lanthanide sulphate complex.
Graphical Abstract An unfamiliar structure in lanthanide chemistry represented by the first example of nitrite lanthanide sulphate complex is
described.
相似文献
2.
K. Palani N. Sureshbabu P. C. Srinivasan M. Nethaji M. N. Ponnuswamy 《Journal of chemical crystallography》2006,36(6):349-355
The compounds 3-(1-Benzenesulfonyl-3-phenylsulfanyl-1H-indol-2-yl)-1-[4-methyl (I)/methoxy (II)phenyl)]-2-phenyl-propane-1-one crystallize in triclinic space group P
. The details are: compound I
a = 11.941(6) ?, b = 12.154(7) ?, c = 13.006(7) ?, α = 63.124(8)°, β = 84.464(9)°, γ = 64.810(8)°, V = 1519.7(14) ?3, Z = 2, D
cal = 1.284 Mg m−3, and R = 0.0382 (wR = 0.0978); compound II
a = 11.897(6) ?, b = 12.268(6) ?, c = 13.001(7) ?, α = 61.919(8)°, β = 83.480(8)°, γ = 64.676(7)°, V = 1504.0(14) ?3, Z = 2, D
cal = 1.333 Mg m−3, and R = 0.0422 (wR = 0.1049). The indole ring system in both the molecules I and II are not strictly planar and the dihedral angles formed by the pyrrole and benzo planes are 4.0(7)° and 3.5(8)°, respectively. The C–HO, C–Hπ and ππ types of interactions stabilize the molecules in the unit cell in addition to van der Waal's forces in I and II. 相似文献
3.
Vanessa Renee Little Hilary Jenkins Keith Vaughan 《Journal of chemical crystallography》2008,38(6):447-452
Abstract The crystal structures of methyl 4-{(E)-2-(4-methylpiperazino)-1-diazenyl}benzoate (2a) and 1,4-di[(E)-2-(2-nitrophenyl)-1-diazenyl]piperazine (3a) have been determined by single crystal X-ray diffraction analysis. The bis-triazene (3a) adopts an unusual pseudo-boat conformation in the piperazine ring, with a dihedral angle of 52.20(0.06)° between the two
planes defined within the piperazine ring. The crystal structures of 2a and 3a are compared with the structure of the triazene (4) and the closely related bis-triazene (5). The piperazine ring of 2a adopts a typical chair conformation, whereas the piperazine ring of 3a adopts an unusual boat conformation. Crystal data: 2a C13H18N4O2, monoclinic, space group P21
/n, a = 13.849(3) ?, b = 6.577(1) ?, c = 14.904(3) ?, α = 90°, β = 96.098(3)°, γ = 90° and V = 1,349.8(4) ?3, for Z = 4. 3a C16H16N8O4, triclinic, space group P-1, a = 7.6066(6) ?, b = 8.3741(7) ?, c = 14.507(1) ?, α = 78.673(1)°, β = 81.877(1)°, γ = 73.445(1)° and V = 865.0(1) ?3, for Z = 2.
Index abstract
The crystal structures of methyl 4-{(E)-2-(4-methylpiperazino)-1-diazenyl}benzoate (2a) and 1,4-di[(E)-2-(2-nitrophenyl)-1-diazenyl]piperazine (3a) have been determined by single crystal X-ray diffraction analysis. 相似文献
4.
Qinghai Cai Bin Lu Jiawei Zhang Yongkui Shan 《Journal of chemical crystallography》2008,38(5):321-325
Abstract A new polyoxovanadoborate cluster (H2NCH2CH2NH3)3 {(VO)6[B10O16(OH)6]2} · 11H2O was prepared by hydrothermal technique and characterized by single crystal X-ray diffraction analysis, IR and TGA. The crystal
of the new compound belongs to monoclinic system, space group C2/c with a = 20.198(1) ?, b = 13.4476(8) ?, c = 21.602(1) ?, β = 97.067(1)°, V = 5822.8(5) ?3, Z = 4, D
c
= 1.956 g cm−3, M = 1714.4, μ = 1.066 mm−1, S = 1.905, R = 0.059, R
w
= 0.0966.
Index Abstract A new polyoxovanadoborate cluster (H2NCH2CH2NH3)3{(VO)6 [B10O16(OH)6]2} · 11H2O was prepared by hydrothermal technique and
characterized by single crystal X-ray diffraction analysis, IR and TGA.
相似文献
5.
Davar M. Boghaei Fatemeh Behzadian-Asl Hamid Reza Khavasi 《Journal of chemical crystallography》2008,38(4):311-314
Abstract The chemical preparation and crystal structure for a 4,4′-azodi(phenylcyanamide) salt) in the solid state are reported. This
compound crystallizes in the triclinic space group P
with the following unit cell parameters: a = 9.759(3) ?, b = 11.237(4) ?, c = 11.919(4) ?, α = 95.54(3)°, β = 98.50(3)°, γ = 109.39(2)°, Z = 1 and V = 1204.4(7) ?3. The 4,4′-azodi(phenylcyanamide) dianion, azodicyd2−, is approximately planar, with the cyanamide groups (–N=C=N) in an anti conformation relative to each other and the azo group (–N=N–) adopting the more thermodynamically stable trans conformation. The crystal X-ray analysis shows that there are one azo molecule cation, two tetrabutylammonium cations and
one water molecule in unit cell. Intermolecular O–H···N hydrogen bonds may be effective in the stabilization of the crystal
structure of this compound and to form linear chain structure in the packing.
Index Abstract Synthesis and crystal structure of Bis (Tetrabutylammonium)(4,4′-Azodi(phenylcyanamide)) salt . [(n-Bu)4N]2[Azodicyd2-] · H2O
Davar M. Boghaei 1*, Fatemeh Behzadian-Asl 1 and Hamid Reza Khavasi2
1 Department of Chemistry, Sharif University of Technology, P.O. Box 11155-9616, Tehran, Iran
2 Department of Chemistry, Shahid Beheshti University, Evin, Tehran 1983963113, Iran
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
6.
Abstract The reaction of the organic ligand, 5,6-dicyano-2,3-di(2-pyridyl)pyrazine (L) with AgClO4, leads to the formation of a novel complex {[Ag(L)(CH3CN)](ClO4)}n 1, which has been characterized by elemental analysis, IR and single-crystal X-ray diffraction analysis (monoclinic system,
space group P2(1)/n, with a = 11.290(4), b = 12.660(5), c = 15.202(6) ?, β = 90.141(6)°, V = 13371(2) ?3 and Z = 4). The crystal structure of complex consists of polymeric chains of {[Ag(L)(CH3CN)]+}n cations and
anions. In the cation of 1, each Ag(I) center is coordinated to four N atoms from two symmetry-equivalent L ligands and a CH3CN molecule. The adjacent two Ag(I) ions are linked by L ligands which adopt N3-coordinated bridging mode to form a zig-zag chain.
Index abstract Synthesis and Crystal Structure of a 1D Silver(I) Complex {[Ag (L)(CH3CN)](ClO4)}n [L = 5,6-dicyano-2,3-di(2-pyridyl)pyrazine]
Qian Gao, Ya-Bo Xie*, Sha Chen, and Dao Wang
The crystal structure of complex {[Ag(L)(CH3CN)](ClO4)}n (L = 5,6-dicyano-2,3-di(2-pyridyl)pyrazine) consists of polymeric chains of {[Ag(L)(CH3CN)]+}n cations and anions. Each Ag(I) center is coordinated to four N atoms from two symmetry-equivalent ligands and a CH3CN molecule. The adjacent two Ag(I) ions are linked by ligands which adopt N3-coordinated bridging mode to form a zig-zag chain.
相似文献
7.
Hande Petek Çiğdem Albayrak Nazan Ocak İskeleli Erbil Ağar İsmet Şenel 《Journal of chemical crystallography》2007,37(4):285-290
The single crystal X-ray diffraction analysis of the title compound, C14H20N2O3, reveals that the structure is adapted to its zwitterionic form and centrosymmetric dimers are formed by N+–H···O− type ionic weak hydrogen bonds in the crystal structure. The title compound crystallizes in the triclinic space group P−1 with a = 5.9255(13) ?, b = 9.853(3) ?, c = 12.248(3) ?, α = 101.793(19)°, β = 94.941(17)°, γ = 104.36(2)°, Z = 2, Dx = 1.308 g/cm3, μ (Mo-Kα) = 0.092 mm−1. The structure was solved by direct methods and refined to a final R = 0.0371 for 2183 reflections with I > 2σ (I). The crystal structure is stabilized by N+–H···O− type intra-molecular hydrogen bonds and N+–H···O− type packing interactions referred to as weak hydrogen bonds. To elucidate conformational flexibility of the title molecule,
the selected torsion angle is varied from −180° to +180° in every 10° separately and then molecular energy profile is calculated
and construed. In addition, charge-population analysis of the crystallographically observed structure confirms its zwitterionic
form. 相似文献
8.
M. Ramos Silva A. J. F. N. Sobral J. A. Silva A. C. Santos S. M. Melo A. Matos Beja 《Journal of chemical crystallography》2007,37(10):695-698
Abstract A new substituted pyrrole, a precursor of meso-free-porphyrins, has been synthesised and characterised by single-crystal X-ray
diffraction: monoclinic, P21/c with a = 14.607(9) ?, b = 5.136(2) ?, c = 25.832(17) ?, β = 108.14(5)°, Mr = 349.41, V = 1841.6(18) ?3, Z = 4. The molecules are assembled in centrosymmetric dimers via strong N–H...O hydrogen bonds. The dimers are gathered
into chains via C–H...π intermolecular interactions.
Graphical abstract The molecules in 4-benzyl-5-methoxymethyl-3-methyl-1H-pyrrole-2-carboxylic acid benzyl ester are joined in dimmers by strong
hydrogen bonds. The dimmers are aggregated in chains running along the b axis through C-H...?€ intermoleculear interactions.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
9.
Xiao Han Zhong-Lu You Yong-Ting Xu Xiao-Min Wang 《Journal of chemical crystallography》2006,36(11):743-746
Colourless block-shaped crystals of Dichloro{2-methoxy-6-[(3-cyclohexylaminopropy-limino)methyl]phenolato}zinc(II) methanol, [Zn(C17H26N2O2)Cl2].CH3OH, have been obtained and characterized by elemental analysis, IR and X-ray single crystal determination. The complex crystallizes in the monoclinic space group P21/n with unit cell dimensions a=12.980(3) ?, b=13.139(3) ?, c=13.277(3) ?, β=107.00(3)°, V=2165.4(8) ?3, Z=4, R
1=0.0631 and wR2=0.1110. X-ray structure determination revealed that the complex consists of a [Zn(C17H26N2O)Cl2] moiety and a lattice MeOH molecule. In the crystal structure, molecules are linked through intermolecular N–HO, C–HCl and O–HCl hydrogen bonds, forming chains. It is the first complex derived from the Schiff base ligand 2-methoxy-6-[(3-cyclohexylaminopropylimino)methyl]phenol.Supplementary materialCCDC-606067 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge at http://www.ccdccam.ac.uk/const/retrieving.html or from the Cambridge Crystallographic Data Centre (CCDC), 12 Union Road, Cambridge CB2 1EZ, UK; fax: +44(0)1223-336033 or e-mail: deposit@ccdc.cam.ac.uk. 相似文献
10.
Yonghong Liu Xiangqian Dai Xiaolan Liu Wei Xu Rong Guo 《Journal of chemical crystallography》2008,38(2):109-113
Abstract The title compound, 2-Ferrocenylmethylidenehydrazono-1,3-dithiolane was synthesized by ferrocene- carboxaldehyde with 2-hydrazono-1,3-dithiolane
and characterized by elemental analysis, 1H NMR, IR, UV-Vis and single crystal XRD. The crystal belongs to orthorhombic, space group Fdd2 with unit cell parameters a = 27.487(4) ?, b = 35.239(6) ?, c = 6.0517(9) ?, V = 5861.7(16) ?3, Z = 16, Dc = 1.497, Mr = 330.24, μ = 1.300 mm−1, F(000) = 2720, R
1
= 0.0413, and wR
2
= 0.0753. The molecule is the anti-rotamer of the trans-isomer and every molecule joins each other to a zig-zag chain through
the intermolecular unclassical hydrogen-bonds of C(7)–H(7)···N(1) (3.449(8) ?, 172°). Further every chain self-assembles into
a three-dimensional networking structure via another intermolecular unclassical hydrogen-bonds of C(1)–H(1A)···π/Cg (3.597(7) ?,
143°) and the weak inter molecular interaction forces of C(4)–H(4)···S(1) (3.742(7) ?, 139°) and C(14)–H(14)···H(6) (3.080(7) ?,
134°).
Graphical Abstract
Synthesis and Structure of 2-Ferrocenylmethylidenehydrazono-1,3-dithiolane
Yonghong Liu, Xiangqian Dai, Xiaolan Liu, Wei Xu, and Rong Guo
College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, P.R. China
The title compound was synthesized and characterized by elemental analysis, 1H NMR, 13C NMR, IR, UV-Vis and single crystal
XRD.
相似文献
11.
Bidhan A. Shinkre Dwayaja H. Nadkarni Samuel B. OwensJr. Gary M. Gray Sadanandan E. Velu 《Journal of chemical crystallography》2008,38(3):205-209
Abstract Details of the synthesis of the E isomer of 3-(2,5-dimethoxyphenyl)-2-(4-methoxyphenyl)acrylonitrile, and the X-ray crystal structures of both the E and Z isomers of this compound are presented. The E isomer crystallizes in the P21/c space group with cell parameters, a = 8.5659(17) ?, b = 16.399(3) ?, c = 11.224(2) ?, α = 90°, β = 95.27(3)°, γ = 90°and Z = 4. The Z isomer crystallizes in the Pca21 space group with cell parameters, a = 4.1223(8) ?, b = 19.113(4) ?, c = 19.453(4) ?, α = 90°, β = 90°, γ = 90° and Z = 4.
Index Abstract Synthesis of E isomer and X-ray crystal structure determination of both E and Z isomers of 3-(2,5-dimethoxyphenyl)-2-(4-methoxyphenyl)acrylonitrile
are presented.
相似文献
12.
Huafeng Shen Jian Cheng Wang Simon G. Bott Michael G. Richmond 《Journal of chemical crystallography》1994,27(11):649-656
Thermolysis of Ru3(CO)12 with 2,3-bis(diphenylphosphino)maleic anhydride (bma) in toluene solution gives the new compounds Ru3(CO)10(bma) (2), Ru2(CO)6(bma) (3), and
(4). All compounds have been isolated and characterized in solution by IR and31P NMR spectroscopy. The solid-state structures of2, as the monohydrate, and4 were established by X-ray crystallography. Ru3(CO)10(bma)·H2O crystallizes in the monoclinic space groupC2/c,a=12.741(2) ?,b=19.548(2) ?,c=32.973(4) ?, β=96.847(9)°,V=8154(2) ?3,Z=8,d
calc=1.740 g cm−3;R=0.046,R
w
=0.051 for 2541 observed reflections withl>3σ(l). The bma ligand in2 is bound to the triruthenium frame in a bridging fashion, with equatorially disposed PPh2 groups. The X-ray structure of2 reveals an extreme twisting of the maleic anhydride ring away from the plane defined by the plane of the three ruthenium
atoms, along with a significant lengthening of the maleic anhydride C=C π bond.
crystallizes in the monoclinic space groupP21/c,a=9.3113(5) ?,b=18.164(1) ?,c=20.097(1) ?, β-102.021(4)°,V=3324.5(3) ?3,Z=4,d
calc=1.671 g cm−3;R=0.024,R
w
=0.030 for 3499 observed reflections withl>3σ(l). The presence of the μ2 moiety and P−C (maleic anhydride) bond cleavage attendant in the formation of4 are confirmed by X-ray analysis. The relationship of the compounds3 and4 to the dimeric compounds Ru2(CO)6(bpcd) and
[where bpcd=4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione] is discussed. Independent studies dealing with Ru3(CO)10(bma) (bridging isomer) have shown that cluster2 is stable in toluene solution at elevated temperature and does not afford compounds3 and4, suggesting the intermediacy of the putative chelating isomer of Ru3(CO)10(bma) (1) as the source of3 and4. 相似文献
13.
Luke R. Odell Adam McCluskey Timothy W. Failes Edward R. T. Tiekink 《Journal of chemical crystallography》2007,37(12):817-824
Abstract Crystal structures for the isomeric compounds benzyl-(2-chloro-6-methylpyrimidin-4-yl)amine (1), as its hemi-hydrate, and benzyl-(4-chloro-6-methylpyrimidin-2-yl)amine (2) have been determined. Conformational differences lead to multiple molecules, i.e. two and three, in their respective structures.
Layers feature in each of the crystal structures and are stabilized by substantial hydrogen-bonding interactions. Compound
(1) crystallizes as a hemi-hydrate in the triclinic space group P-1 with a = 8.667(5) ?, b = 11.421(7) ?, c = 12.954(8) ?, α = 78.330(10)°, β = 84.553(10)°, γ = 75.510(9)°, and Z = 4. Compound (2) crystallizes in the monoclinic space group P21/c with a = 10.740(3) ?, b = 21.487(6) ?, c = 14.914(4) ?, β = 95.014(5)°, and Z = 12.
Index Abstract Substantial hydrogen-bonding interactions leading to layer structures feature in each of the crystal structures of the isomeric
title compounds.
Electronic supplementary material The online version of this article (doi: ) contains supplementary material, which is available to authorized users. 相似文献
14.
Abstract The title compound containing two metal centers each complexes to one enantiopure chiral norephedrine-derived pyridyl-(bis)
oxazoline (pybox) ligand and linked by two hydroxide bridges, crystallizes to give rodlike form in the space group P21(# 4). Cell Parameters are a = 10.2344(18) ?, b = 13.952(3) ?, c = 23.371(4) ?, β = 94.586(4)°, V = 3326.6(10) ?3. The metal-hydroxide motif forms a square plane at the center of the structure with the scandium centers exhibiting a distorted
pentagonal bipyramid coordination sphere consisting of the chelating ligand and two additional triflouromethyl sulfonyloxy
species positioned anti to each other.
Graphical abstract The complex contains two metal centers each complexes to one enantiopure chiral norephedrine-derived pyridyl-(bis) oxazoline
(pybox) ligand and linked by two hydroxide bridges.
Structural report for Sc[(R,R)-norephedrine-pybox](OTf)3 dimeric complex
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
15.
Poonam Kaushik Dejan-Krešimir Bučar Leonard R. MacGillivray 《Journal of chemical crystallography》2007,37(10):713-715
Abstract The crystal and molecular structure of trans-1,2-bis(2-benzothiazolyl)ethene is reported. Crystal data for 1: monoclinic, space group C 2/c, a = 24.926(3) ?, b = 4.843(1) ?, c = 11.164(1) ?, β = 105.274(5) °, V = 1300.0(3) ?3, and D
c
= 1.50 g/cm3 for Z = 4 and R = 0.028. The molecule crystallizes in the form of a colorless plate and forms one-dimensional slipped π-stacks.
Graphical Abstract The title compound crystallizes to form 1D slipped π-stacks in the solid state.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
16.
Xian-Feng Huang Lei Shi Huan-Qiu Li Hai-Liang Zhu 《Journal of chemical crystallography》2007,37(11):739-742
Abstract The title compound, 3, 6-dihydroxy-2-[2-(4-hydroxy-phenyl)-vinyl]- benzene-1,3-dicarbaldehyde was synthesized by Vilslmeier reaction from resveratrol
(trans-3,4′,5-trihydroxystilbene). Its structure was determined by X-ray single crystal diffraction. The crystal belongs to monoclinic,
space group P21/n with crystallographic parameters: a = 7.2950(15) ?, b = 14.781(3) ?, c = 12.202(2) ?, β = 96.57(3)°, μ = 0.108 mm−1, V = 1307.1(5) ?, Z = 4, Dx = 1.445 g/cm3, F(000) = 592, T = 293(2) K, 2.17°≤ θ ≤ 26.00°. The X-ray results demonstrated that the Vilslmeier reaction of resveratrol with DMF, POCl3 and CH3CN yielded 4,6-dhydroxy-2-[2-(4-hydroxy-phenyl)-vinyl]-benzene-1,3-dicarbaldehyde.
Graphical Abstract In this article, a resveratrol derivative was prepared and structurally characterized by single crystal X-ray diffraction.
相似文献
17.
Raza Murad Ghalib Rokiah Hashim P. S. Pereira Silva Sayed Hasan Mehdi Othman Sulaiman Manuela Ramos Silva 《Journal of chemical crystallography》2011,41(11):1688-1693
Abstract
2-Chloro-1,3-dioxo-2,3-dihydro-1H-inden-2-yl acetate, C11H7ClO4 (Fig. 1), has been synthesized and the structure has been solved by IR and X-ray diffraction studies. The crystals are triclinic, space group P [`1] \bar{1} , with a = 7.62060(10) ?, b = 11.5944(2) ?, c = 13.0753(3) ?, α = 97.2820(10)°, β = 101.5740(10)°, γ = 101.7930(10)°, Mr = 238.62, V = 1090.82(3) ?3, Z = 4 and R = 0.0557. In the title compound there are two molecules in the asymmetric unit. The molecules are linked via weak C–H···O hydrogen bonds forming R44(28) rings. The intermolecular interactions were analysed by means of the fingerprint plots derived from the Hirshfeld surfaces. The fingerprint plots evidenced subtle differences in the intermolecular contacts for the two independent molecules. 相似文献18.
William R. Gemmill Mark D. Smith Hans-Conrad zur Loye 《Journal of chemical crystallography》2007,37(12):793-795
Abstract Single crystals of the lanthanum-containing ruthenate, trilanthanum ruthenium septaoxide, La3RuO7, were prepared via high-temperature flux growth and structurally characterized by single-crystal X-ray diffraction. The compound
crystallizes in the orthorhombic space group Cmcm with a = 11.2077(6) ?, b = 7.4531(4) ?, and c = 7.6042(4) ? and is a member of a well-known family of compounds with the general formula Ln3MO7.
Graphical abstract
Synthesis and crystal structure of the fluorite-related ruthenate, trilanthanum ruthenium septaoxide La
3
RuO
7
William R. Gemmill, Mark D. Smith and Hans-Conrad zur Loye*
Single crystals of La3RuO7 were isolated from a high-temperature KCl flux and characterized by single crystal X-ray diffraction. A view of the crystal
structure approximately along [001] of La3RuO7 and displacement ellipsoids drawn at 50% probability level. The vertex-sharing RuO6 octahedra are shown in blue, La3+ are shown in yellow, and O2− are shown in red.
相似文献
19.
E. B. Seena M. R. Prathapachandra Kurup E. Suresh 《Journal of chemical crystallography》2008,38(2):93-96
Abstract The crystal structure of salicylaldehyde N(4)-phenyl thiosemicarbazone is described. The compound crystallizes in the triclinic crystal system, space group P
Z = 6, V = 2002.1(5) ?3 with unit cell parameters a = 10.6733(15) ?, b = 13.8856(19) ?, c = 14.052(2) ?, α = 81.851(2)°, β = 77.061(2)° and γ = 83.482(2)°. There are three independent molecules in the asymmetric unit. The crystal structure reveals that the compound
exists in the thione form and S1 and N3 are at E configuration to each other with respect to N2–C7 bond. Similarly, S2 and N6 are trans to each other with respect to N5–C21
bond in the second molecule of the asymmetric unit and S3 and N9 are trans to each other with respect to N8–C35 bond in the
third molecule of the asymmetric unit. The packing of the molecules in the crystal lattice is stabilized by intermolecular
hydrogen bonds.
Index Abstract The compound salicylaldehyde N(4)-phenyl thiosemicarbazone crystallizes in the triclinic crystal system, space group P
Z = 6, V=2002.1(5) ?3 with unit cell parameters a = 10.6733(15) ?, b = 13.8856(19) ?, c = 14.052(2) ?, α = 81.851(2)°, β = 77.061(2)° and γ = 83.482(2)°.
The structure of the compound salicylaldehyde N(4)-phenylthiosemicarbazone 相似文献
20.
Reaction of 2-amino-4,6-dimethylpyridine with cadmium chloride, HBr and Br2 in ethanol yeilds bis(2-amino-3,5-dibromo-4,6-dimethylpyridinium) tetrabromocadmate(II). The complex crystallizes in the
monoclinic space group P21/c, with tetrahedral distortion of the ion. The cations are arranged in a zig-zag chains that are held together via Br···Br, Br···π, π···Br···π and π-π interactions.
Extensive ···cation interactions were found and represented in different Br···HN (pyridinic and aminic) and Br···HCH2 hydrogen bonding along with Br···Br motifs. 相似文献