液体碳氢燃料云雾爆轰特性的实验研究

采用升降法和烟迹技术在立式激波管中分别实测了液态燃料（环氧丙烷、硝酸异丙酯、己烷、C5~C6、庚烷、癸烷）与空气混合物直接起爆的临界起爆能和胞格尺寸。数据表明,气液两相云雾爆轰的临界起爆能与当量比呈U形曲线关系,这与气相爆轰得到的结论是一致的;临界起爆能的最小值并不是对应于等化学当量的混合物而是偏向于富燃料;根据三波点运动的烟迹记录,分析了云雾爆轰作用机制,认为液滴的碎解、汽化过程以及燃烧区前导是控制气液两相云雾爆轰的主要步骤。此外,还测定了无限空间下可燃气云的临界起爆能,并将激波管内得到的临界起爆能数据外推到无约束气云的临界起爆能,理论推算结果与实验值吻合较好。     

液体燃料云雾爆轰参数实验

为深入了解液体燃料云雾爆轰机理,借助自行设计和建造的立式爆轰管,并采用升降法和烟迹技 术,对环氧丙烷等液体燃料云雾爆轰参数(爆速、爆压、临界起爆能和爆轰胞格尺寸)与当量比的关系进行了实 验研究。结果表明,环氧丙烷的爆速和爆压随当量比的增加先增大后平缓减小;碳氢液体燃料云雾爆轰的临 界起爆能与当量比呈U型关系,最佳值点偏向富燃料一侧;临界起爆能的大小与燃料的分子结构和挥发性 有密切关系,IPN和PO 临界起爆能相当,而烷烃类临界起爆能均较大。环氧丙烷在25和50 ℃时的爆轰胞 格宽度与当量比皆呈U型关系,最小值点偏向富燃料一侧;气相爆轰胞格宽度比云雾爆轰略小。常温下环 氧丙烷云雾爆轰主要由气相反应所控制。     

环氧丙烷-空气混合物爆轰波胞格结构的研究

对碳氢燃料云雾爆轰波胞格结构的影响因素进行了分析:比较了初始温度在25℃和100℃条件下碳氢燃料胞格尺寸,发现胞格尺寸相差不大;胞格尺寸随初始压力的降低而增大,在相对压力为负压条件下得到清晰的爆轰波胞格结构;起爆能的增大可以导致更加复杂的爆轰波次胞格结构出现。     

气相爆轰波平衡胞格稳定性实验研究

本文详细介绍了研究气体爆轰的烟迹法以及采用所提出的方法得到的爆轰波通过柔性材料壁面前后平衡胞格形成、消失和重新恢复的全过程烟迹照片。实验按初压不同分五组进行。从烟迹照片中各时期的胞格尺寸、横波的变化出发,对上述过程中横波强度变化情况及柔性壁面对横波的作用和影响进行了分析,对平衡胞格恢复的条件进行了讨论。     

C2H4-O2混合气体直接起爆的临界能量

主要基于化学动力学和Ng模型,对C2H4-O2混合气体的爆轰胞格尺寸进行预测;结合Lee表面积能量模型,预测物质在不同初始压力和化学当量比的条件下,直接起爆引起球面爆轰的临界起爆能量。直接起爆实验主要采用高压电点火提供起爆能量,起爆能量通过放电过程中电流的输出信号确定。结果表明,理论预测与实验值较吻合。首先,通过化学动力学计算得出ZND模型的爆轰参数,利用Ng模型得出爆轰胞格尺寸与ZND诱导区长度之间的比例因数A在不同初始压力与当量比的条件下分别为:A=43.815(1+p1/p0)-0.123 71和A=8.531exp(φ/3.135)+28.644,在此基础上对爆轰胞格尺寸进行定量预测。胞格尺寸的理论预测与实验结果吻合。其次,把爆轰胞格尺寸作为中间特征参数并结合Lee的表面积能量模型,提出可以预测临界起爆能量的定量模型,并得出C2H4-O2混合气体直接起爆的临界起爆能量与初始压力和化学当量比的参量拟合关系分别为Ec=0.332(p1/p0)-2.017和Ec=exp[3.951(φ-1.401)2-1.9]。     

气相爆轰波在90矩形弯管中传播时胞格结构的演化

利用烟迹技术实验获得气相爆轰波在90矩形弯管中传播时留下的胞格图案，详细分析了胞格结构在矩形弯管中的演化规律。同时分析了90矩形弯管的曲率半径和预混气体初始压力对胞格结构演化的影响。实验所采用的预混气体初始压力为33.3、26.7、24.0、16.0、10.7 kPa，90矩形弯管的曲率半径分别为100、50 mm。研究爆轰波胞格结构在弯管中的演化过程有助于深入了解气相爆轰波绕射机理和石油天然气等管道设计。     

直管内胞格爆轰的基元反应数值研究

基于基元反应和二维欧拉方程，对直管内胞格爆轰进行了数值模拟。采用5阶WENO(weighted essentially nonoscillatory scheme)求解对流项，采用2阶附加半隐的龙格-库塔法处理化学反应源相引起的刚性。获得了密度、压力、温度和典型组元质量分数流场及数值胞格结构等。结果表明:网格精度的差异明显影响胞格的规则性和爆轰的平衡模数，随着网格尺度的减小，胞格由不规则变为规则。预混气组成、初压、初温及管道宽度给定，三波点数收敛为确定值。足够强度的初始扰动可再现胞格爆轰，最终形成的自持胞格爆轰模数与初始扰动的形状、大小、位置均无关。沿胞格中心线，爆轰波速度变化范围为0.88DCJ~1.5DCJ，爆轰波平均速度与CJ爆轰速度仅偏差0.88％。峰值压力与初压之比为14~50。计算爆轰波平均速度、胞格宽长比与实验值基本一致，但计算胞格宽度比实验值略小。数值模拟加深了对横波的产生和发展、未反应气囊、爆轰胞格的二次起爆等胞格爆轰特性的认识。     

气相爆轰波在半圆形弯管中传播现象的实验研究

对气相(2H2/O2/Ar系统)爆轰波在半圆形弯管中的传播现象进行实验研究。用烟迹膜记录了弯管中爆轰波的胞格结构,采用压电传感器测量了沿弯管内外母线指定点的压力时间曲线,得到了爆轰波沿弯管内、外母线的平均速度和胞格尺寸的变化。结果表明:当平面爆轰波进入弯管后,受壁面的几何形状作用,诱导激波阵面发生弯曲。沿诱导激波阵面,自内母线到外母线方向,激波强度逐渐增大。同时,爆轰波后的化学反应区也受到影响,胞格尺寸发生较明显的变化。在本文条件下,当初压p08.00kPa,受扰动的爆轰波在弯管出口下游仍恢复为强度不变的稳定爆轰。胞格记录的三波点迹线表明:受扰动的爆轰波在出口段发生了马赫反射。实验结果还表明:当p0降至5.33kPa,平面稳定爆轰波经过半圆形弯管后,其强度发生衰减并直至出现熄灭。     

孔板扰动对爆轰波胞格结构特性影响的实验研究

实验采用稳定预混气2H₂+O₂+3Ar及不稳定预混气C₂H₂+5N₂O和CH₄+2O₂,在圆形爆轰管内通过烟膜手段记录了爆轰波的胞格结构,得到了胞格尺寸与初始压力之间的关系式;研究了胞格结构在扰动上下游的变化过程,分析了胞格不稳定性对胞格结构特征的影响,获得了爆轰波经过扰动后重新恢复至平衡状态的特征尺度。结果表明:爆轰波经过扰动后,对于稳定预混气,在扰动下游主胞格结构变得不规则,没有出现次生胞格;对于不稳定预混气,扰动下游伊始爆轰波的次生模态被抑制,由于爆轰波自身的不稳定性,随后出现了局部爆炸点及精细胞格结构;爆轰波在扰动下游传播了一段距离后恢复至平衡状态,该长度在8～15倍之间的胞格尺寸范围内变化,并且随初始压力的变化趋势并不明显。研究结果反映出爆轰波经过孔板扰动后恢复至平衡态所需的长度与爆轰波流体动力学厚度相当。     

多相燃料空气炸药爆炸压力场研究

采用高速运动分析系统对固态燃料FAE（Fuel Air Explosive）分散、爆轰过程进行光学测量,用压电传感器等组成的压力测试系统对FAE爆炸压力场进行测量,对固态燃料FAE燃料分散、爆轰波及冲击波进行了研究。分析了气-固-液多相爆轰的特征和压力波形的特点,研究了其冲击波峰值超压及比冲量随传播距离变化的规律。在云雾区内,多相爆轰波压力波形具有多峰结构,爆炸波峰值超压及冲量为一恒定值;爆轰区外,爆轰波转变成爆炸冲击波,峰值压力和比冲量迅速衰减,得到了峰值超压、比冲量随传播距离的变化规律。     

Experimental study on detonation parameters and cellular structures of fuel cloud

In this paper,detonation parameters of fuel cloud,such as propylene oxide(PO),isopropyl nitrate(IPN),hexane,90 # oil and decane were measured in a self-designed and constructed vertical shock tube.Results show that the detonation pressure and velocity of PO increase to a peak value and then decrease smoothly with increasing equivalence ratio.Several nitrate sensitizers were added into PO to make fuel mixtures,and test results indicated that the additives can efficiently enhance detonation velocity and pressure of fuel cloud and one type of additive n-propyl nitrate(NPN) played the best in the improvement.The critical initiation energy that directly initiated detonation of all the test liquid fuel clouds showed a U-shape curve relationship with equivalence ratios.The optimum concentration lies on the rich-fuel side(φ > 1).The critical initiation energy is closely related to molecular structure and volatility of fuels.IPN and PO have similar critical values while that of alkanes are larger.Detonation cell sizes of PO were respectively investigated at 25 C,35 C and 50 C with smoked foil technique.The cell width shows a U-shape curve relationship with equivalence ratios at all temperatures.The minimal cell width also lies on the rich-fuel side(φ > 1).The cell width of PO vapor is slightly larger than that of PO cloud.Therefore,the detonation reaction of PO at normal temperature is controlled by gas phase reaction.     

Existence of the detonation cellular structure in two-phase hybrid mixtures

The cellular detonation structure has been recorded for hybrid hydrogen/air/aluminium mixtures on 1.0 m 0.110 m soot plates. Addition of aluminium particles to the gaseous mixture changes its detonation velocity. For very fine particles and flakes, the detonation velocity is augmented and, in the same time, the cell width diminishes as compared with the characteristic cell size of the mixture without particles. On the contrary, for large particles, the detonation velocity decreases and the cell size becomes larger than . It appears that the correlation law between the cell size and the detonation velocity in the hybrid mixture is similar to the correlation between the cell size and the rate of detonation overdrive displayed for homogeneous gaseous mixtures. Moreover, this correlation law remains valid in hybrid mixtures for detonation velocities smaller than the value D of the mixture without particles. Received 10 May 2001 / Accepted 12 August 2002 Published online 19 December 2002 Correspondence to: B. Veyssiere (e-mail: veyssiere@lcd.ensma.fr)     

气相爆轰在T形管中传播新现象的实验研究

对2H2/O2/Ar系统爆轰波在T形管(截面为40mm×40mm)中传播现象进行了实验研究.用烟迹片记录了T形管中爆轰波的胞格结构,用压电传感器记录了分叉口附近指定点压力时间曲线,得到了爆轰波在分叉口附近的平均速度和胞格图案演变.结果表明:初压P0≥2.67kPa,在水平和垂直支管下游区域(距离分叉口约3.5—6倍方管截面边长),分叉口影响消失,爆轰波恢复稳定,且强度基本保持不变.在分叉口绕射过程中,爆轰波在膨胀区中衰减,诱导激波阵面弯曲.两个支管中发生马赫反射,三波点迹线清晰可见.该传播特性是爆轰波的诱导激波和横波共同作用的结果.分叉口附近的胞格结构先消失再恢复,在无胞格和平衡胞格之间的区域存在细密胞格的过渡区,表征了在诱导激波与化学反应阵面分离后的区域中出现二次点火.P0=2.00kPa,水平支管中稳定自持爆轰能重建,垂直支管中爆轰熄灭.P0<2.00kPa,分叉口上游已不能形成稳定爆轰.还对胞格结构中的几个特征参数进行了测量,并初步分析了P0对这些参数的影响.     

Structure and stability of one-dimensional detonationsin ethylene-air mixtures

The propagation of one-dimensional detonations in ethylene-air mixtures is investigated numerically by solving the one-dimensional Euler equations with detailed finite-rate chemistry. The numerical method is based on a second-order spatially accurate total-variation-diminishing scheme and a point implicit, first-order-accurate, time marching algorithm. The ethylene-air combustion is modeled with a 20-species, 36-step reaction mechanism. A multi-level, dynamically adaptive grid is utilized, in order to resolve the structure of the detonation. Parametric studies over an equivalence ratio range of for different initial pressures and degrees of detonation overdrive demonstrate that the detonation is unstable for low degrees of overdrive, but the dynamics of wave propagation varies with fuel-air equivalence ratio. For equivalence ratios less than approximately 1.2 the detonation exhibits a short-period oscillatory mode, characterized by high-frequency, low-amplitude waves. Richer mixtures ( 1.2$" align="middle" border="0"> ) exhibit a low-frequency mode that includes large fluctuations in the detonation wave speed. At high degrees of overdrive, stable detonation wave propagation is obtained. A modified McVey-Toong short-period wave-interaction theory is in excellent agreement with the numerical simulations.Received: 13 September 2004, Revised: 1 November 2004, Published online: 3 March 2005[/PUBLISHED]Correspondence to: S. Yungster     

气相爆轰波传播过程中的自点火效应

基于基元反应模型和单步反应模型,对直管道中H₂-air混合气体中爆轰波的传播过程进行了数值模拟,揭示了气相爆轰波传播过程中的自点火效应。利用数值模拟方法计算了不同爆轰模型的点火延迟时间,并得到了爆轰波三波点的传播过程以及所形成胞格结构的尺寸。结果表明,胞格宽度与点火延迟时间成正比;爆轰波诱导区内气体的点火延迟时间与三波点的运动周期基本一致。进一步对结果分析可知,爆轰波的自维持传播取决于点火延迟时间(表征化学反应的特征时间)和三波点的运动周期(表征流动的特征时间)的匹配;当二者相匹配时,经过前导激波压缩后形成的高温高压爆轰气体,在短时间内实现了自点火,同时释放出大量的能量推动了爆轰波的前进,即爆轰波的稳定自维持传播依靠其自点火机制。     

The influence of detonation cell size and regularity on the propagation of gaseous detonations in granular materials

This paper presents results from an experimental study of transmission of gaseous detonation waves through various granular filters. Spherical glass beads of 4 and 8 mm diameter and crushed rock of 7.5 mm volume averaged diameter were used as filter material. Varying the initial pressure of the detonating gas mixture controlled the detonation cell size. Dilution with argon was used to vary the detonation cell regularity. The complete range from almost no detonation velocity deficit to complete extinction of the combustion wave was observed. The existing correlation for gaseous detonation velocity deficit where is the critical diameter for the gaseous detonation and is the pore size, is found to be applicable for both smooth spherical particles and irregular crushed rock when considering irregular detonation structures. Soot films and pressure measurements show that as the detonation cell size is increased, reinitiation of a reanular filter until it finally no longer occurs at . Complete extinction of the combustion wave occurs at . These two limits appear to be about the same for irregular and regular detonation cell structures. For irregular structures without argon dilution, can be found for detonation wave failure, and can be found for complete extinction of the combustion wave. For argon dilution these limits are changed to and , respectively. The data are a bit scarce as a basis for proposing a new correlation for regular structures, but as a first approximation log is suggested for regular structures. The detonation or combustion wave is found to approach a constant velocity in the granular filter if not extinguished. Received 31 October 2001 / Accepted 15 July 2002 Published online 4 November 2002 Correspondence to: T. Slungaard (e-mail: slung@maskin.ntnu.no) An abridged version of this paper was presented at the 18th Int. Colloquium on the Dynamics of Explosions and Reactive Systems at Seattle, USA, from July 29 to August 3, 2001     

Blast wave propagation in air from a gaseous charge

In the point explosion problem it is assumed that an instantaneous release of finite energy causing shock wave propagation in the ambient gas occurs at a space point. The results of the solution of the problem of such blasts are contained in [1–4]. This point model is applied for the determination of shock wave parameters when the initial pressure in a sphere of finite radius exceeds the ambient air pressure by 2–3 orders of magnitude. The possibility of such a flow simulation at a certain distance from the charge is shown in papers [4, 5] as applied to the blast of a charge of condensed explosive and in [6, 8] as applied to the expansion of a finite volume of strongly compressed hot gas. In certain practical problems the initial pressure in a volume of finite dimensions exceeds atmospheric pressure by a factor 10–15 only. Such cases arise, for example, in the detonation of gaseous fuel-air mixtures. The present paper considers the problem of shock wave propagation in air, caused by explosion of gaseous charge of spherical or cylindrical shape. A numerical solution is obtained in a range of values of the specific energy of the charge characteristic for fuel-air detonation mixtures by means of the method of characteristics without secondary shock wave separation. The influence of the initial conditions of the gas charge explosion (specific energy, nature of initiation, and others) is investigated and compared with the point case with respect to the pressure difference across the shock wave and the positive overpressure pulse.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 110–118, May–June, 1986.