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1.
T. E. Kokina L. A. Glinskaya E. A. Novoselova R. F. Klevtsova S. V. Larionov 《Journal of Structural Chemistry》2004,45(5):855-860
Mixed-ligand complexes [Ni(4-NH2Py) (i-Bu2PS2)2] (I) and Ni(4-NH2Py)2(i-Bu2PS2)2 (II) have been synthesized. Single crystals were grown and X-ray diffraction data (CAD-4 diffractometer, MoK
α radiation, 1477 F
hkl
, R = 0.0320) were used to determine the structure of I. The crystals are orthorhombic: a = 10.675(1) Å; b = 21.681(2) Å; c = 26.302(4) Å, V = 6087.5(12) Å3, Z = 8, ρ(calc) = 1.247 g/cm3, space group Pbca. Complex I possesses a mononuclear molecular structure. The coordination polyhedron of the Ni atom is a tetragonal pyramid NS4 whose base is formed by four S atoms of two cyclic bidentate ligands i-Bu2PS
2
−
and the axial position is occupied by the N atom of the 4-NH2Py cycle. According to electron spectroscopy data, complex II has an octahedral N2S4 environment of the Ni atom.Original Russian Text Copyright © 2004 by T. E. Kokina, L. A. Glinskaya, E. A. Novoselova, R. F. Klevtsova, and S. V. Larionov__________Translated from Zhurnal Strukturnoi Khimii, Vol. 45, No. 5, pp. 899–904, September–October, 2004. 相似文献
2.
T. E. Kokina R. F. Klevtsova L. A. Glinskaya E. G. Boguslavskii S. V. Larionov 《Russian Journal of Coordination Chemistry》2010,36(1):53-59
The reaction of Cu(II) complex with 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotet-radeca-4,11-diene (L) and iso-Bu2PS2− or iso-BuOCS2− anions gave stable paramagnetic compounds [CuL](iso-Bu2PS2)2 (I) (μeff = 1.77 μB) and [CuL](iso-BuOCS2)2 (II) (μeff = 1.76 μB). According to X-ray diffraction, the crystal structure of I is composed of discrete centrosymmetric complex cations [CuL]2+ and iso-Bu2Ps2− anions. The CuN4 coordination unit is a square. The Cu...S distance (iso-Bu2PS2−) equal to 3.047 ? attests to possible S-coordination. Compounds I and II were studied by EPR. 相似文献
3.
L. A. Glinskaya T. G. Leonova T. E. Kokina R. F. Klevtsova S. V. Larionov 《Journal of Structural Chemistry》2005,46(4):692-698
Crystal structures of chelate compounds Ni[(iso-C4H9)2PS2]2 (I) and Pd[(iso-C4H9)2PS2]2 (II) have been determined by X-ray diffraction: diffractometer X8-APEX, MoK
α∔
-radiation, 1048 F
hkl
, R = 0.0544 for I and CAD-4 diffractometer, MoK
α∔
-radiation, 1283 F
hkl
, R = 0.0347 for II. The crystals are rhombic: a = 12.921(5) Å, b = 17.094(5) Å, c = 22.971(5) Å; V = 5074(3) Å3, Z = 8, calc = 1.250 g/cm3, space group Pbca for I and a = 13.312(3) Å, b = 16.130(7) Å, c = 23.171(5) Å; V = 4975(3) Å3, Z = 8, ρcalc = 1. 208 g/cm3, space group Pbca for II. The structures of I and II are formed by discrete mononuclear molecules. Coordination cores MS4 (M = Ni, Pd) approach planar square configurations.
Original Russian Text Copyright ? 2005 by L. A. Glinskaya, T. G. Leonova, T. E. Kokina, R. F. Klevtsova, and S. V. Larionov
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 4, pp. 715–720, July–August, 2005. 相似文献
4.
S. V. Larionov V. L. Varand R. F. Klevtsova T. G. Leonova L. A. Glinskaya E. M. Uskov 《Russian Journal of Coordination Chemistry》2008,34(12):931-937
The heteroligand complex Nd(Phen){(iso-C4H9)2PS2}2(NO3) (I) was synthesized and its IR spectrum was analyzed. The anions (iso-C4H9)2PS2/− and N3/− act as bidentate cyclic ligands. The single crystals of [Nd(Phen){iso-C4H9)2PS2}3] (II) were obtained on evaporation of a solution of complex I in a mixture CH2Cl2-hexane and were studied by X-ray diffraction. Crystals II are triclinic: a = 10.5509(5); b = 14.7432(8), c = 16.8503(10) ?; α = 102.882(2)°, β = 97.211(2)°, γ= 108.087(2)°, V = 2374(2) ?3, Z = 2, ρ(calcd.) = 1.332 g/cm3, space group . The coordination polyhedron of the Nd atom in a separate mononuclear molecule II is a distorted dodecahedron N2S6. The molecules are bound by weak van der Waals and π-π interactions. The photoluminescence spectra of complexes I, II were measured and interpreted.
Original Russian Text ? S.V. Larionov, V.L. Varand, R.F. Klevtsova, T.G. Leonova, L.A. Glinskaya, E.M. Uskov, 2008, published
in Koordinatsionnaya Khimiya, 2008, Vol. 34, No. 12, pp. 944–950. 相似文献
5.
The crystal structures of the Rh[(EtO)2PS2]3 (I) and Co[(PhO)2PS2]3 (II) chelate compounds were determined from X-ray diffraction (XRD) data (CAD-4 diffractometer, MoK
β radiation, 1193 F
hkl
, R = 0.0516 for I and 513 F
hkl
, R = 0.0305 for II). Crystals I are monoclinic: a = 14.233(3) Å, b = 13.570(3) Å, c = 14.272(3) Å; β = 90.66(3)°, V = 2756.3(10) Å3, Z = 4, ρcalc = 1.587 g/cm3, space group C2/c. Crystals II are trigonal: a = 15.149(2) Å, c = 30.306(6) Å; V = 6023.2(16) Å3, Z = 6, ρcalc = 1.493 g/cm3, space group R3ˉ. Structures I and II consist of discrete mononuclear molecules. The coordination polyhedra of the M atoms (M = Rh, Co)
are distorted octahedra formed by six sulfur atoms of three cyclic bidentate (RO)2 PS2− ligands.
Original Russian Text Copyright ? 2008 by R. F. Klevtsova, L. A. Glinskaya, and S. V. Larionov
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 2, pp. 330–334, March–April, 2008. 相似文献
6.
V. L. Varand L. A. Glinskaya R. F. Klevtsova S. V. Larionov 《Journal of Structural Chemistry》2008,49(1):175-180
The [Y(Phen){(i-C4H9)2PS2}2NO3] mixed-ligand compound (I) was synthesized. Its structure was determined by X-ray diffraction analysis (X8 APEX diffractometer, λMoK
α
, 3788 F
hkl
, R = 0.0677). Crystals I are orthorhombic: a = 10.6495(8) Å, b = 20.006(2) Å, c = 35.317(4) Å, V = 7524.4(13) Å3, Z = 8, ρcalc = 1.324 g/cm3, space group Pbca. The structure is built of mononuclear discrete molecules. The N2O2S4 coordination polyhedron of the Y atom is a distorted dodecahedron.
Original Russian Text Copyright ? 2008 by V. L. Varand, L. A. Glinskaya, R. F. Klevtsova, and S. V. Larionov
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 49, No. 1, pp. 182–186, January–February, 2008. 相似文献
7.
R. F. Klevtsova T. G. Leonova L. A. Glinskaya S. V. Larionov 《Journal of Structural Chemistry》2007,48(2):267-274
Mixed-ligand complexes CdPhen(i-BuOCS2)2 (I) and CdPhen(n-BuOCS2)2 (II) have been synthesized. Their structures were solved using X-ray diffraction data (X8 APEX diffractometer, MoK
α radiation, 1641 and 2497 F
hkl
, R = 0.0359 and 0.0389). Crystals I are orthorhombic with unit cell parameters a = 6.5883(3) Å, b = 19.7123(10) Å, c = 20.1936(11) Å, V = 2622.6(2) Å3; Z = 4, space group Pbcn; crystals II are monoclinic, a = 6.5845(2) Å, b = 19.1522(6) Å, c = 20.7091(7) Å, β = 97.106(1), V = 2591.5(1) Å3, Z = 4, space group C2/c. The structures consist of discrete mononuclear molecules in which the coordination polyhedron of the Cd atom is a distorted
N2S4 octahedron. Molecular packing and interactions in the structures are discussed.
Original Russian Text Copyright ? 2007 by R. F. Klevtsova, T. G. Leonova, L. A. Glinskaya, and S. V. Larionov
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No. 2, pp. 274–281, March–April, 2007. 相似文献
8.
V. I. Belomestnykh L. B. Sveshnikova A. V. Churakov A. S. Kanishcheva Yu. N. Mikhailov 《Russian Journal of Inorganic Chemistry》2011,56(12):1899-1907
Single crystals of diammonium tetranitratouranylate (NH4)2[UO2(NO3)4] (I) and a new diammonium tetranitratouranylate complex with 18-crown-6 [(NH4)(18C6)]2[UO2(NO3)4] (II) have been synthesized by the reaction of diaquadinitratouranyl tetrahydrate with ammonium nitrate in a nitric acid solution
and the reaction of the same reagents with 18C6 in an ethanol solution, respectively. The X-ray diffraction analysis of compounds
I and II has been performed. Crystals of compounds I and II are monoclinic, Z = 2, space group P21/n, a = 6.4075(5) ?, b = 7.7851(7) ?, c = 12.4461(12) ?, β = 101.239(1)°, V = 608. 94(9) ?3 for compound I and a = 10.542(9) ?, b = 8.590(8) ?, c = 22.5019(19) ?, β = 101.632(1)°, V = 2058.3(3) ?3 for compound II. The [UO2(NO3)4]2− complex anion in compounds I and II contains two monodentate and two bidentate cyclic nitrato groups, and the coordination number of uranyl is 6. The 18C6 molecule
in the structure of compound II has the classic crown conformation and combined with the ammonium ion by three hydrogen bonds. Compounds I and II formed by electrostatic attraction forces between counterions are stabilized by (NH4+)NH...O(NO3−) interionic hydrogen bonds. 相似文献
9.
10.
Two copper(I) complexes [Cu(Cin2bda)2]ClO4 (I) and [Cu(Ncin2bda)2]ClO4 (II) have been prepared by the reaction of the ligands N2,N2′-bis(3-phenylallylidene)biphenyl-2,2′-diamine (L1) and N2,N2′-bis[3-(2-nitrophenyl)allylidene]biphenyl-2,2′-diamine (L2) and copper(I) salt. These compounds were characterized by CHN analyses, 1H NMR, IR, and UV-Vis spectroscopy. The C=N stretching frequency in the copper(I) complexes shows a shift to a lower frequency
relative to the free ligand due to the coordination of the nitrogen atoms. The crystal and molecular structure of II was determined
by X-ray single-crystal crystallography. The coordination polyhedron about the copper(I) center in the complex is best described
as a distorted tetrahedron. A quasireversible redox behavior was observed for complexes I and II.
The article is published in the original. 相似文献
11.
O. A. Plyusnina V. A. Emel’yanov I. A. Baidina I. V. Korol’kov S. A. Gromilov 《Journal of Structural Chemistry》2007,48(1):114-121
Double complex [RuNO(NH3)4OH][PtCl4] (I) and [RuNO(NH3)4OH][PdCl4] (II) salts have been prepared and explored with TGA, IR spectroscopy, powder and single crystals X-ray diffraction. Crystal phases
of I and II are isostructural (space group Cmc21) and have the following crystal chemical characteristics: a = 8.106 Å, b = 18.190(3) Å, c = 8.097 Å, V = 1194.0 Å3, Z = 4, ρcalc = 3.077 g/cm3 (I), and a = 8.116 Å, b = 18.135 Å, c = 8.062 Å, V = 1186.5 Å3, Z = 4, ρcalc = 2.600 g/cm3 (II). The product of thermal decomposition of I in inert and hydrogen atmospheres is a substitution solid solution Pt0.5Ru0.5 with the parameter of the FCC unit cell a = 3.856(3) Å. Thermolysis of II affords two-phase mixtures of limited solid solutions of the metals featuring Ru-based HCP and Pd-based FCC cells.
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 48, No.1, pp.114–121, January–February, 2007. 相似文献
12.
Double complex salts (DCSs) [Co(NH3)6][Fe(CN)6] (I) and [Co(NH3)6]2[Cu(C2O4)2]3 (II) and complex [Co(NH3)6]2(C2O4)3·4H2O (III) are synthesized and investigated by single crystal XRD, crystal optics, and elemental analysis. The crystalline phases of
I, II, and III (R-3, P21/c, and Pnnm space groups respectively) have the following crystallographic characteristics: a = 10.9804(2) ?, b = 10.9804(2) ?, c = 10.8224(3) ?, V = 1130.03(4) ?3, Z = 3, d
x = 1.65 g/cm3 (I); a = 9.6370(2) ?, b = 10.2452(2) ?, c = 13.2108(3) ?, V = 1932.90(9) ?3, Z = 2, d
x= 1.97 g/cm3 (II), and a = 11.7658(3) ?, b = 11.7254(3) ?, c = 14.1913(4) ?, V = 1304.34(5) ?3, Z = 2, d
x = 1.68 g/cm3 (III). This paper investigates the products of DCS thermolysis in a hydrogen atmosphere: the intermetallic compound CoFe with
the bcc parameter a = 2.852 ? for I and a heterogeneous mixture of Co and Cu in the decomposition of II. The coordinated CN− and C2O42− groups then turn into NH3, hydrocarbons, and CO2. The dominant hydrocarbon is methane. 相似文献
13.
S. V. Larionov L. A. Glinskaya T. G. Leonova R. F. Klevtsova 《Journal of Structural Chemistry》2005,46(6):1023-1030
Mixed-ligand complexes Cd(2,2′-Bipy)(i-PrOCS2)2 (I) and Cd(2,2′-Bipy)(i-BuOCS2)2 (II) have been prepared. Their structures were solved using the X-ray diffraction technique (X8 APEX diffractometer, MoK
α radiation, 1941 and 4244 F
hkl
, R = 0.0188 and 0.0379). The crystals are orthorhombic with unit cell parameters a = 18.1404(4) Å, b = 6.9513(1) Å, c = 17.5835(4) Å; V = 2217.27(8) Å3, Z = 4, space group Pccn (for complex I) and a = 11.7890(3) Å, b = 12.1859(3) Å, c = 17.5335(5) Å; V = 2518.9(1) Å3, Z = 4, space group P212121 (for complex II). The structures consist of isolated mononuclear molecules. The cadmium atoms have distorted octahedral N2S4 environments. Molecular packings and intermolecular interactions in the structures are considered.
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 46, No. 6, pp.1064–1071, November–December, 2005.
Original Russian Text Copyright ? 2005 by S. V. Larionov, L. A. Glinskaya, T. G. Leonova, and R. F. Klevtsova 相似文献
14.
Larionov S. V. Kokina T. E. Glinskaya L. A. Klevtsova R. F. 《Russian Journal of Coordination Chemistry》2001,27(7):493-501
Diamagnetic [Ni(i-Bu2PS2)2] compound (I) in ethanol reacts with 2,2"-bipyridine or pyrazine to give the paramagnetic complexes [Ni(2,2"-Bipy)(i-Bu2PS2)2] (II), [Ni(Pz)2(i-Bu2PS2)2] (III), and [Ni(Pz)(i-Bu2PS2)2]
n
(IV) (eff= 2.91–3.12 B). Single crystals of IIwere grown for X-ray diffraction study. The crystals are monoclinic, a= 14.669(3) Å, b= 19.693(4) Å, c= 12.155(2) Å, = 107.51(3)°, V= 3348(1) Å3, Z= 4; calcd= 1.257 g/cm3, space group P21/c. The structure is built from monomeric molecules. The coordination polyhedron of the Ni atom is a distorted octahedron formed by four S atoms of two bidentate chelating i-Bu2PS–
2ligands and by two N atoms of bidentate cyclic 2,2"-Bipy. Preliminary data for complexes IIIand IVindicate that they also contain an octahedral NiN2S4fragment. The structures of complexes I(square planar) and ofII–IV(octahedral) were confirmed by data from electron spectroscopy. Electronic absorption spectra were used to determine the rankings of the i-Bu2PS–
2ions and Pz on a spectrochemical scale. 相似文献
15.
Z. M. Dzhabieva S. V. Topilin G. V. Shilov T. S. Dzhabiev 《Russian Journal of Inorganic Chemistry》2012,57(1):46-51
A new zirconocene ansa-Me2Si-(2Me-4-p-Tol-cyclopenta[b]indol-3-yl)2ZrCl2 complex (I), in which the Cp ligand is fused with the indole ring, has been synthesized and studied by X-ray diffraction analysis. Light
brown crystals are triclinic, space group P
[`1]\bar 1; M = 734.92, a = 9.252(2) ?, b = 12.914(3) ?, c = 15.619(3) ?, α = 111.83(3)°, β = 81.03(3)°, γ = 117.77(3)°, V = 1569(3) ?3, Z = 2, ρcalc = 1.525 g/cm3. The structural parameters of complex I are compared with the known bis-indenyl zirconium complexes: rac-Me2Si(Ind)2ZrCl2 (II) and rac-Me2Si(2Me-2Ph-1-Ind)2ZrCl2 (III) and analogous substituted rac-Me2Si(2,5-Me2-3Ph-6-Cp[b]Tp)2ZrCl2 (IV) and rac-Me2Si(2,5-Me2-1Ph-4-Cp[b]Py)2ZrCl2 (V). Complex I alkylated by the Grignard reagent (MgMe2) in the presence of the Al-iso-Bu3 cocatalyst is an efficient catalyst for the polymerization of propylene into isotactic polypropylene. 相似文献
16.
Larionov S. V. Kokina T. E. Glinskaya L. A. Klevtsova R. F. 《Russian Journal of Coordination Chemistry》2002,28(8):560-564
The paramagnetic compounds [Ni2(HMTA)(i-Bu2PS2)4] (I) and [Ni2(TEDA)(i-Bu2PS2)4] (II) (eff = 3.11 and 3.23 B, respectively) were synthesized by reacting diamagnetic Ni(i-Bu2PS2)2 with hexamethylenetetramine (HMTA) and triethylenediamine (TEDA) in ethanol. The crystal structure of I was established by single-crystal X-ray diffraction analysis (CAD4 diffractometer, MoK
radiation, 1483 F
hkl, R = 0.0648). The crystals are monoclinic: a = 35.212(7) Å, b = 9.313(2) Å, c = 22.622(5) Å; = 129.97(3)°, V = 5685(2) Å3, Z = 4, (calcd) = 1.281 g/cm3, space group C2/c. The structure is built of discrete binuclear molecules. The coordination polyhedron of the Ni atom is a distorted tetragonal pyramid with four S atoms of two bidentate cyclic ligands i-Bu2PS2
– in the base and the N atom of the bidentate bridging ligand HMTA at the axial vertex. Complexes I and II have similar electronic reflection spectra, which agrees with the C
4v
symmetry of the ligand field. 相似文献
17.
Yu. V. Kokunov Yu. E. Gorbunova V. V. Kovalev 《Russian Journal of Inorganic Chemistry》2009,54(10):1603-1610
New complex chlorides [ZnCl2(ODA)] (I) (ODA=oxydianiline, C12H12N2O) and [ZnCl2(H2O)2](Me4Pyz)2 (II) (Me4Pyz = 2,3,5,6-tetramethylpyrazine) were synthesized and crystallographically characterized. Crystals of I are monoclinic, space group C2/c, a = 22.682(2) ?, b = 12.646(1) ?, c = 9.951(1) ?, β = 93.23(2)°, V = 2849.7(5) ?3, ρcalc = 1.569 g/cm3, Z = 8. Structure I contains cyclic fragments consisting of two tetrahedral complexes (ZnCl2N2) and two coordinated bridging oxydianiline ligands. Crystals of II are monoclinic, space group P2(1)/c, a = 8.972(2) ?, b = 13.862(3) ?, c = 17.528(4) ?, β = 101.72(3)°, V = 2134.5(7) ?3, ρcalc = 1.384 g/cm3, Z = 4. In structure II, supramolecular pseudo-metallocycles are formed due to formation of hydrogen bonds O(w)-H…N between coordinated water molecules
and noncoordinated nitrogen atoms of tetramethylpyrazine molecules. 相似文献
18.
Coordination polymers [Ag(Me4Pyz)] PF6(I) and [Ag2(Me4Pyz)3](BF4)2·H2O (II) have been synthesized, and their structures have been determined. The crystals of I are monoclinic, space group C2/c, a = 9.440(2) ?, b = 10.587(2) ?, c = 13.165(3) ?, β= 107.19(3)°, V = 1257.0(5) ?3, d = 2.056 g/cm3, Z = 4. The crystals of II are monoclinic, space group P21/n, a = 13.062(3) ?, b = 12.259(2) ?, c = 18.996(4) ?, β = 97.73(3)°, V = 3014.1(11)?3, ρ = 1.798 g/cm3, Z = 4. The structure of I is built of linear polymeric cations [Ag(C8H12N2)]
∞
+
and octahedral anions [PF6]−. Upon the interaction of tetramethylpyrazine molecule with Ag+ ions, intersecting polymeric chains [Ag(C8H12)]
∞
+
(1D polymer) are formed extending in mutually perpendicular diagonal directions. The structure of II consists of layers (2D polymers) formed by fused sixmembered rings. These rings consist of Ag+ ions linked by bridging ligands Me4Pyz.
Original Russian Text ? Yu.V. Kokunov, Yu.E. Gorbunova, 2007, published in Zhurnal Neorganicheskoi Khimii, 2007, Vol. 52,
No. 5, pp. 743–750. 相似文献
19.
I. A. Zamilatskov E. V. Savinkina D. V. Albov 《Russian Journal of Coordination Chemistry》2007,33(6):396-399
The complexes of CdI2 with acetamide (AA) and propaneamide (PrA) of the composition [Cd(AA)6][Cd2I6] (I) and [Cd(PrA)6][Cd2I6] (II) were synthesized and studied by X-ray diffraction. Isostructural crystals I and II are triclinic: a = 7.285(3) and 8.066(6), b = 11.266(4) and 11.649(3), c = 11.554(3) and 12.063(2) ?, α = 100.96(2)° and 102.74(2)°, β = 91.59(2)° and 91.73(4)°, γ = 100.76(3)° and 101.05(4)°, V = 912.5 and 1081.9 ?3, respectively; space group
, Z = 1.
Original Russian Text ? I.A. Zamilatskov, E.V. Savinkina, D.V. Al’bov, 2007, published in Koordinatsionnaya Khimiya, 2007,
Vol. 33, No. 6, pp. 407–410. 相似文献
20.
S. B. Artemkina M. S. Tarasenko A. V. Virovets N. G. Naumov 《Russian Journal of Coordination Chemistry》2012,38(4):257-263
Heterometallic chloride complexes [Mo5NbI8Cl6]
n− (n = 2, 3) are synthesized. The crystal structures of their salts are determined: for (Ph4P)2[Mo5NbI8Cl6] (I), triclinic crystal system, spacegroup P
[`1]\bar 1, a = 10.9886(6), b = 11.4604(5), c = 13.4343(7) ?, α = 66.124(2), β = 86.892(2), γ = 86.490(2)°, Z = 1, V = 1543.35(13) ?3; and for (4-MePyH)5[Mo5NbI8Cl6]Cl2 (II), monoclinic crystal system, space group C2/m, a = 16.4937(4), b = 14.7335(3), c = 11.6534(3) ?, β = 99.8750(10)°, Z = 2, V = 2789.94(11) ? The geometric parameters of compounds I and II and the conditions for the formation of the complexes with the charges −2 and −3 are discussed. 相似文献