共查询到20条相似文献,搜索用时 15 毫秒
1.
Ueno Y Tate A Niwa O Zhou HS Yamada T Honma I 《Analytical and bioanalytical chemistry》2005,382(3):804-809
The gas selectivities of highly ordered mesoporous silicates and commercially-obtained porous silicates with respect to benzene, toluene and xylene were studied. After studying the porosities, pore uniformities, and surface silanol structures of the silicates and their relationships to gas selectivity in detail, we found that we could achieve high benzene selectivity by controlling the micropore size (less than 1 nm). Concluding that mesoporous silicate has a suitable micropore size and structure for benzene selectivity, we also observed that mesoporous silicate SBA-16 exhibited a high (>6) benzene selectivity from toluene and xylene even in a pseudo-atmospheric environment. A benzene detection limit of about 100 ppb was achieved by introducing SBA-16 into a microfluidic device originally developed for the separate detection of benzene, toluene, and xylene gases. 相似文献
2.
Terahertz time-domain spectroscopy (THz-TDS) is used to study the intra- and intermolecular vibrational modes of aromatic carboxylic acids, for example, o-phthalic acid, benzoic acid, and salicylic acid, which form either intra- or intermolecular hydrogen bond(s) in different ways. Incorporating the target molecules in nano-sized spaces in mesoporous silicate (SBA-16) is found to be effective for the separate detection of intramolecular hydrogen bonding modes and intermolecular modes. The results are supported by an analysis of the differences in the peak shifts, which depend on temperature, caused by the different nature of the THz absorption. Raman spectra revealed that incorporating the molecules in the nano-sized pores of SBA-16 slightly changes the molecular structures. In the future, THz-TDS using nanoporous materials will be used to analyze the intra- and intermolecular vibrational modes of molecules with larger hydrogen bonding networks such as proteins or DNA. 相似文献
3.
We show that a simple model consisting of a binary hard-sphere mixture in a narrow cylindrical pore can lead to strong size selectivity by considering a situation where each species of the mixture sees a different radius of the cylinder. Two mechanisms are proposed to explain the observed results depending on the radius of the cylinder: for large radii the selectivity is driven by an enhancement of the depletion forces at the cylinder walls whereas for the narrowest cylinders excluded-volume effects lead to a shift of the effective chemical potential of the particles in the pore. 相似文献
4.
ZSM-5 monolith of uniform mesoporous channels 总被引:6,自引:0,他引:6
A ZSM-5 monolith of uniform mesopores(meso-ZSM-5) was synthesized with the template method using carbon aerogel of uniform mesopores of great pore volume. The pore size distribution determined by N2 adsorption showed the presence of mesopores with an average pore width of 11 nm and micropores with an average pore width of 0.51 nm. Field emission scanning electron micrograph observation revealed the presence of uniform mesopores. X-ray diffraction and FT-IR provided evidence that the synthesized meso-ZSM-5 monolith has a highly crystalline ZSM-5 structure. 相似文献
5.
F. Fakhfakh L. Baraket J. M. Fraile J. A. Mayoral A. Ghorbel 《Journal of Sol-Gel Science and Technology》2009,52(3):388-397
Hybrid mesoporous silicas functionalized with ethylenediamine groups have been synthesized via sol–gel process under different conditions. The best textural properties, with pore diameters up to 170 Å, have been obtained using carboxylic acids as catalysts in propanol as solvent without the need for any surfactant. The presence of the diamine moiety has been demonstrated by different characterization techniques, and the materials have been used in the adsorption of copper cations. The adsorption capacity of all the solids is high (up to 1.87 mmol/g and up to 2.47 Cu atoms/nm2), with important variations in the properties of the silica surface, besides the role of the immobilized diamine moieties as ligand for copper. In general the surface area seems to be the most important feature controlling the adsorption. 相似文献
6.
The properties of nitrogen, carbon dioxide, and nitrogen dioxide adsorption onto mesoporous chromium silicates were studied by measurements of both the adsorption isotherms and the IR spectra. The pore sizes of two types of chromium silicates, Cr-FSM-16 (Si/Cr=170 (Cr-FSM-16 [170]) and 390 (Cr-FSM-16 [390])), which contain different amount of Cr, were 2.75 nm. BET surface areas of Cr-FSM-16 were 590 m2/g and they were smaller than that onto FSM-16. The initial heat of adsorption of nitrogen onto Cr-FSM-16 was higher than that onto FSM-16. But the initial heat of adsorption of carbon dioxide onto Cr-FSM-16 was smaller than that onto FSM-16. These results indicated that Cr in Cr-FSM-16 decreased adsorption interaction with carbon dioxide. When nitrogen dioxide was adsorbed on FSM-16 and Cr-FSM-16 at 303 K under no light, an absorption band of nitrogen monoxide adsorbed was measured by IR spectroscopy. This decomposition of nitrogen dioxide by FSM-16 and Cr-FSM-16 was caused by SiOH and Cr, respectively. 相似文献
7.
Trukhan NN Panchenko AA Roduner E Mel'gunov MS Kholdeeva OA Mrowiec-Białoń J Jarzebski AB 《Langmuir : the ACS journal of surfaces and colloids》2005,21(23):10545-10554
The surface acidity of different mesoporous titanium-silicates, such as well-organized hexagonally packed Ti-MMM, Ti-MMM-2, Ti-SBA-15, and amorphous TiO(2)-SiO(2) mixed oxides (aerogels and xerogels), was studied by means of FTIR spectroscopy of CO adsorbed at 80 K and CD(3)CN adsorbed at 293 K. The surface hydroxyl groups of mesoporous titanium-silicates with 2-7 wt % Ti revealed a Br?nsted acidity slightly higher to that of pure silicate. TiO(2)-SiO(2) xerogels revealed the highest Br?nsted acidity among the titanium-silicates studied. CO adsorption revealed two additional sites on the surface in comparison to pure silicate, characterized by nu(CO) from 2185 (high pressure) to 2178 (low pressure) cm(-1) and from 2174 (high pressure) to 2170 (low pressure) cm(-1). These bands are due to CO adsorbed on isolated titanium cations in the silica surrounding or having one Ti(4+) cation in their second coordination sphere and due to CO interactions with Ti-OH groups, respectively. CD(3)CN adsorption similarly revealed the existence of two additional sites, which were not detected for pure silicate: at 2289 cm(-1) due to CD(3)CN interaction with titanol groups and from 2306 (low pressure) to 2300 (high pressure) cm(-1) due to acetonitrile interaction with isolated framework titanium cations with probably one Ti(4+) cation in their second coordination shell. The spectroscopic results are compared with computational data obtained on cluster models of titanium-silicate with different titanium content. According to the IR data, the Ti accessibility on the surfaces for mesoporous titanium-silicates with similar Ti loading (2 wt %) was found to fall in the order TiO(2)-SiO(2) aerogel approximately TiO(2)-SiO(2) xerogel > Ti-MMM approximately Ti-MMM-2 > Ti-SBA-15. This order (except TiO(2)-SiO(2) xerogel) correlates with the catalytic activity found previously for titanium-silicates in 2,3,6-trimethylphenol oxidation with H(2)O(2). 相似文献
8.
Catalytic benzene alkylation over mesoporous zeolite single crystals: improving activity and selectivity with a new family of porous materials 总被引:3,自引:0,他引:3
Christensen CH Johannsen K Schmidt I Christensen CH 《Journal of the American Chemical Society》2003,125(44):13370-13371
Mesoporous zeolite single-crystal catalysts are shown to be both more active and more selective than conventional zeolite catalysts in the alkylation of benzene with ethene. The superior catalytic properties are ascribed to improved mass transport in the mesoporous zeolite crystals. Thus, mesoporous zeolite single-crystal catalysts combine the high acidity, shape-selectivity, and hydrothermal stability of zeolites with the efficient mass transport that is typically achieved in mesoporous materials. 相似文献
9.
I. S. Berezovska V. V. Yanishpolskii V. A. Tertykh 《Journal of Thermal Analysis and Calorimetry》2008,94(3):649-653
Template syntheses of mesoporous silicas have been carried out inside large pores of inorganic matrix. Portions of tetraethoxysilane
and cetyltrimethylammonium bromide micellar solution were incorporated step-by-step inside pore volume of silica gel with
large pore size. Synthesized materials were characterized using thermal analysis, adsorption-desorption of nitrogen and X-ray
diffraction scattering. 相似文献
10.
H. Sepehrian A. R. Khanchi M. K. Rofouei S. Waqif Husain 《Journal of the Iranian Chemical Society》2006,3(3):253-257
A simple and rapid method for synthesis of mesoporous zirconium silicate with high thermal stability has been developed using sodium silicate in place of costly silicon alkoxides as a silica source. The product was characterized by means of X-ray diffraction, Nitrogen sorption isotherms, FT-IR spectroscopy, transmission electron microscopy (TEM) and thermogravimetry analysis (TGA). 相似文献
11.
Hudson S Tanner DA Redington W Magner E Hodnett K Nakahara S 《Physical chemistry chemical physics : PCCP》2006,8(29):3467-3474
TEM analysis of mesoporous materials is generally undertaken to give qualitative results. Accurate quantitative analysis is demonstrated in this study. A systematic image analysis of a powder form of a hexagonal mesoporous material known as KIT-6 is conducted using a transmission electron microscope (TEM). Three types of image contrast typically appear in this material (a hexagonal honeycomb structure, wide and narrow parallel lines). The honeycomb face is used to characterise this material in terms of a conventional 2-D hexagonal structure and the d-spacings for the (100) and (110) planes are experimentally measured in varying focus conditions. A tilting experiment is conducted to determine how the angle of tilt affects the line spacing and their visibility. Tilting has very little effect on the line spacing, whereas it affects the visibility of both the wide and narrow lines by limiting an angle range of visibility. The hexagonal lattice structure parameter determined by TEM method is found to be approximately 7% lower than that calculated by low-angle X-ray diffraction. Thus we conclude that TEM data can be used to determine the geometry and dimensions of hexagonal mesoporous silica materials, with a small error in the hexagonal lattice parameter. 相似文献
12.
Thuy-Duong Nguyen-Phan Chae Young Lee Jin Suk Chung Eun Woo Shin 《Research on Chemical Intermediates》2008,34(8-9):743-753
Mesoporous molecular sieve SBA-15 modified by titanium has been utilized for removing organic pollutants, such as benzene, from air. Titanium was impregnated inside SBA-15 by wetness impregnation after synthesis of SBA-15 (impregnation method) or was doped into the SBA-15 framework by the direct addition of Ti precursor into the sol during synthesis (doping method). In the breakthrough curves for gas-phase benzene adsorption, Ti addition into SBA-15 resulted in the enhancement of benzene adsorption capacity, depending on Ti loading amounts. An increase in adsorption temperature remarkably reduced the benzene adsorption capacity, indicating that the interaction between benzene and the materials was weak. 相似文献
13.
Synthesis and characterization of nanoparticulate MnS within the pores of mesoporous silica 总被引:1,自引:0,他引:1
Louse Barry Mark Copley Justin D. Holmes David J. Otway Olga Kazakova Michael A. Morris 《Journal of solid state chemistry》2007,180(12):3443-3449
Mesoporous silica was loaded with nanoparticulate MnS via a simple post-synthesis treatment. The mesoporous material that still contained surfactant was passivated to prevent MnS formation at the surface. The surfactant was extracted and a novel manganese ethylxanthate was used to impregnate the pore network. This precursor thermally decomposes to yield MnS particles that are smaller or equal to the pore size. The particles exhibit all three common polymorphs. The passivation treatment is most effective at lower loadings because at the highest loadings (SiO2:MnS molar ratio of 6:1) large particles (>50 nm) form at the exterior of the mesoporous particles. The integrity of the mesoporous network is maintained through the preparation and high order is maintained. The MnS particles exhibit unexpected ferromagnetism at low temperatures. Strong luminescence of these samples is observed and this suggests that they may have a range of important application areas. 相似文献
14.
Yu. D. Fomin 《Journal of computational chemistry》2013,34(30):2615-2624
It is well known that confining a liquid into a pore strongly alters the liquid behavior. Investigations of the effect of confinement are of great importance for many scientific and technological applications. Here, we present a study of the behavior of benzene confined in carbon slit pores. Two types of pores are considered–graphite and amorphous carbon ones. We show that the effect of different pore structure is of crucial importance for the benzene behavior. © 2013 Wiley Periodicals, Inc. 相似文献
15.
Schuster J Keilbach A Köhn R Döblinger M Dörfler T Dennenwaldt T Bein T 《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(34):9463-9470
Cubic and circular hexagonal mesoporous carbon phases in the confined environment of the pores of anodic alumina membranes (AAM) were obtained by organic-organic self-assembly of a preformed oligomeric resol precursor and the triblock copolymer templates Pluronic F127 or P123, respectively. Casting and solvent evaporation were followed by self-assembly and the formation of a condensed wall material by thermopolymerization of the precursor oligomers, thus resulting in mesostructured phenolic resin phases. Subsequent thermal decomposition of the surfactant and carbonization were achieved through thermal treatment at temperatures up to 1000 °C under an inert atmosphere. The resulting hierarchical mesoporous composite materials were characterized by small-angle X-ray scattering and nitrogen-sorption measurements. The structural features were directly imaged in TEM cross-sections of the composite membranes. For both structures, the AAM pores were completely filled and no shrinkage was observed due to strong adhesion of the carbon-wall material to the AAM pore walls. As a consequence, the pore size of the mesophase system stays almost constant even after thermal treatment at 1000 °C. 相似文献
16.
Adsorption and desorption of benzoic and salicylic acids and phenol from a series of synthesized mesoporous carbons is measured and analyzed. Equilibrium adsorption isotherms are best described by the Langmuir–Freundlich isotherm. Intraparticle diffusion and McKay’s pore diffusion models, as well as mixed 1,2-order (MOE), integrated Langmuir kinetic equation (IKL), Langmuir–Freundlich kinetic equation and recently derived fractal-like MOE (f-MOE) and IKL models were compared and used to analyze adsorption kinetic data. New generalization of Langmuir kinetics (gIKL), MOE and f-MOE were used to describe desorption kinetics. Analysis of adsorption and desorption half-times shows simple relation to the size of carbon pores. 相似文献
17.
Cott DJ Petkov N Morris MA Platschek B Bein T Holmes JD 《Journal of the American Chemical Society》2006,128(12):3920-3921
Oriented mesoporous carbon nano-filaments were prepared as replicas of Fe-containing silica mesostructures deposited inside the channels of anodic alumina membranes (AAMs). Due to the confinement imposed by the channels of the AAMs, rather unusual mesophase structures showing "circular" or "columnar" mesoscopic channels were formed that were replicated as pure carbon analogues after removal of the templating hosts. These structures are assembled in the forms of macroscopic membranes and are hierarchically ordered first due to the arrangement of the channels of the AAMs and second due to the mesophase counterparts. 相似文献
18.
I. S. Berezovskaya V. V. Yanishpolskii V. A. Tertykh 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2008,82(9):1442-1446
Structure-related adsorption characteristics of ordered mesoporous silicas with spherical particles were studied depending on the conditions of their synthesis, including pH of the medium, the type of the alcohol, and the concentrations of the initial components of micelle solutions. The special features of the template synthesis of mesoporous silica in large silica gel pores were studied. The synthesized silicas were characterized by low-temperature nitrogen sorption-desorption, X-ray diffraction, and scanning electron microscopy measurements. 相似文献
19.
Synthesis of micrometer-sized hard silica spheres with uniform mesopore size and textural pores 总被引:1,自引:0,他引:1
Micrometer-sized silica spheres were prepared using a new pH-induced rapid colloid aggregation method in water-in-oil (W/O) emulsion separately with F127 and the mixture of Pluronic triblock copolymer (F127, P123, or P105) and PEG20000 as templates. All the mesoporous silica spheres exhibited high surface areas (657-1145 m2/g) and large pore volumes (0.46-2.16 ml/g). Through optimizing the synthetic conditions, hard silica spheres with narrow particle size distribution, uniform pore size, and textural pores were obtained. Finally, the mechanism of this synthetic route is discussed. 相似文献