共查询到20条相似文献,搜索用时 131 毫秒
1.
2.
3.
4.
5.
6.
7.
8.
新试剂4,4′-二(2-氯-4-硝基苯基重氮氨基)联苯的合成及其与镉显色反应的研究 总被引:5,自引:0,他引:5
研究了新三氮烯试剂4,4!@ 二(2 氯 4 硝基苯基重氮氨基)联苯的合成,以及与镉的显色反应。在表面活性剂TritonX 100存在下,于pH8.2的Na2B4O7 HCl缓冲介质中,该试剂与镉生成1∶1的橙红色配合物。其最大吸收波长在510nm处,表观摩尔吸光系数为1.05×105L·mol-1·cm-1。镉量在0~0.64mg/L范围内遵守比尔定律。方法可应用于废水中微量镉的测定。 相似文献
9.
10.
11.
12.
13.
Xiu R Bu Donald Vanderveer Javier Santos Fu-Lian Hsu Jie Wang Kofi Bota 《Analytical sciences》2003,19(3):469-470
A nonlinear optical chromophore, 4,5-bis(4-dimethylaminophenyl)-2-(4-nitrophenyl)imidazole, was investigated by X-ray crystallography. The study focused on coplanarity among several aromatic rings, including phenyls and imidazole. Two phenyl rings with NMe2 groups are twisted by 46.39(3) degrees from each other. However, they are twisted by 23.05(5) degrees and 46.84(3) degrees from the imidazole, respectively. These unequal twists were elucidated by different conjugation pathways from the donors to the acceptor. The phenyl ring with the NO2 group is twisted by only 6.76(6) degrees from the imidazole. 相似文献
14.
15.
9-(4,5-二硫甲基-1,3-二硫杂环戊烯-2甲叉基)蒽-10(9H)-酮的合成及量子化学计算 总被引:3,自引:0,他引:3
设计合成了一种新的具有D-π-A结构的有机分子,9-(4,5-二硫甲基-1,3- 二硫杂环戊烯-2-甲叉基)蒽-10(9H)-酮(C_(19)H_(14)OS_4)。以~1H NMR, FTIR,元素分析和UV-vis进行了表征。运用Gaussian 98量子化学程序包,采用 B3LYP密度泛函(DFT)的方法,在6-31G(d)水平上对分子的几何构型进行了优化 ,在优化的基础上用TDDFT的方法计算了化合物的电了防染印花谱,计算值与实验 值基本吻合,用TDHF的方法计算了它的二阶非线性光学系数,与蒽醌相比,其第一 超给化率β较大,为12.03 * 10~(-30)esu。 相似文献
16.
17.
18.
选取大π共轭体系4-(4-甲氧基苯亚甲基)-2-苯基-5(4H)-噁唑酮作为研究对象,采用再沉淀法制备其纳米晶体,通过研究溶剂、温度、搅拌速度、搅拌时间等因素对所形成的纳米粒子的形貌尺寸的影响,成功制备出了形貌较单一的纳米棒和纳米带结构并进一步考察了它们的紫外吸收和发射光谱,结果表明随着纳米粒子尺寸的增加,其吸收光谱和荧光光谱均出现红移,荧光量子效率随着粒子尺寸的增大略有增大. 相似文献
19.
SynthesisandStructureof4,5-bis(2,4-Dinitrophenylthio)-1,3-Dithiole-2-ThioneQuZheng;CaiJing-Hua;FangQi;YouXiao-Zeng(Coordinati... 相似文献
20.
《合成通讯》2012,42(24):3528-3535
AbstractNonlinear-optical chromophores with N-hydroxyethyl-N-ethylaniline donor, tricyanofuran acceptor moieties and 3,7-divinylquinoxaline π-bridge have been synthesized. The acetyl derivatives of these chromophores exhibit an intense charge transfer band in the visible region of spectrum and a large positive and negative solvatochromism in different solvents. 相似文献