Abrupt change of ionic conductivity induced by an electric field

A theory of abrupt disordering of one of ionic crystal sublattices in an external electric field is developed. It is shown that it is possible to transfer a crystal into a high-conductivity state without heating by means of a field-induced phase transition.     

Electric field of an isolated charged impurity in an ionic crystal

The character of the behavior of the electric field created by a charged impurity in an ionic crystal is studied on the basis of both cluster and analytical approaches. In the cluster approach about 30 000 ions surrounding the impurity are taken into account. These ions are described in a model of polarizable sites. A direct calculation shows that the asymptote of the electric field of a charged impurity at lattice points can differ strongly from the one given by the Coulomb equation written for a homogeneous polarizable medium. The behavior of the electric field at intermediate distances, where the asymptotic behavior cannot yet be used, is studied in detail. It is found that the electric field is increased significantly in comparison to the Coulomb field in the region near the defect. The size of this (strongly polarized) region increases as the dielectric constant increases. These data are in qualitative agreement with the results obtained by Vikhnin et al. and account for the results of recent experiments designed to investigate polarization in reduced virtual ferroelectrics. Fiz. Tverd. Tela (St. Petersburg) 40, 662–667 (April 1998)     

The motion of crystal electrons in an electric field

Crystal electrons in an electric field are described by Houston-wave functions. Their group velocity is averaged over the relaxation timeτ. This yields the current to be ohmic in weak fields and to be inversely proportional to electric fields which are strong enough to drive the electrons through the whole Brillouin-zone in a timeT<τ.     

Paramagnetic resonance study of a nematic liquid crystal oriented by an electric field

We perform experiments similar to the previously unexplained experiments of Schara and Sentjurc in which we observe the paramagnetic resonance spectra of a probe dissolved in p-azoxyanisole. Our experiments employ a nitroxide probe rather than vanadyl acetylacetonate. The numatic is aligned by an electric field and the resonance spectra are observed as a function of orientation of the magnetic field. The results obtained, though different from those of Schara and Sentjurc, are explained in a conventional manner. A result of dielectric measurements made by others is also shown to be in agreement with our results.     

Dislocations used to probe the defect state of an ionic crystal lattice excited by a pulsed magnetic field

This paper presents the results of an investigation into the effect of a pulsed magnetic field on the state of linear and point defects in ionic crystals. For different amplitudes (1–7 T) and pulse lengths (3×10⁻⁵ to 10² s) of the pulsed field the kinetics of the transformation of defects into a new state and their relaxation after the field is turned off are studied in the temperature range 77–400 K. It is found that the relaxation of the states of point defects is mainly through recombination, and the change of state of the dislocations and of the point defects contribute nonadditively to the change in the dislocation mobility. The exposure of the crystal to a magnetic field leads to an increase in the dislocation mobility when the sample is mechanically stressed and to a decrease in the dislocation displacement with a second field pulse. Fiz. Tverd. Tela (St. Petersburg) 39, 634–639 (April 1997)     

Frequency-dependent deformation of liquid crystal droplets in an external electric field

Nematic droplets suspended in the isotropic phase of the same substance were subjected to alternating electrical fields of varying frequency. To keep the system at a constant nematic/isotropic volume ratio with constant droplet size, we carefully kept the temperature in the isotropic/nematic coexistence region, which was broadened by adding small amounts of a non-mesogenic liquid. Whereas the nematic droplets remained spherical at low (in the order of 10 Hz) and high frequencies (in the order of 1 kHz), at intermediate frequencies we observed a marked flattening of the droplets in the plane perpendicular to the applied field. Droplet deformation occurred both in liquid crystals (LCs) with positive and negative dielectric anisotropy. The experimental data can be quantitatively modelled with a combination of the leaky dielectric model and screening of the applied electric field due to finite conductivity.     

Raman spectra of KTP crystal in an in situ electric field

Raman spectra of the KTP single crystal are recorded in electric fields (dc and ac) applied along the polar axis c. Spectra with the laser beam focused near the cathode end, anode end and the centre of the crystal are recorded. The cathode end of the crystal develops a spot ‘grey track’ where the laser beam is focused after a lapse of 5 h from the application of a dc electric field of 38 V/cm. The spectra recorded at the cathode end after the application of field show variations in intensity of bands. A new band appears at 177 cm⁻¹. Changes in band intensities are explained on the basis of changes in polarizability of the crystal due to the movement of K⁺ ions along the polar axis. K⁺ ions accumulate at the cathode end, where the ‘Grey track’ formation occurs. The intensity enhancement observed for almost all bands in the ac field is attributed to the improvement of crystalline quality.     

Anomalous orientation of ferroelectric liquid crystal films in an electric field

An anomalous orientation of ferroelectric liquid crystals in an electric field is observed. The tilt planes of the molecules are oriented in a direction parallel to the electric field. The anomalous orientation is observed in freely suspended films above the smectic-C*-smectic-A bulk phase transition temperature. The effect is explained by the appearance of giant flexoelectric polarization, 10⁴ times greater than that in bulk liquid-crystal samples, in the film. Pis’ma Zh. éksp. Teor. Fiz. 66, No. 6, 414–418 (25 September 1997)     

Driving liquid crystal lens without LC molecular orientation defects induced by an electric field

Optical Review - Using the finite element method, we numerically investigated the transient behavior of molecular orientations of a liquid crystal (LC) lens with a circular electrode beside a...     

Stationary states of an electron in the field of a hole in an ionic crystal

An approximate solution is given of the Schrödinger equation for S-states of an electron in the field of a hole, when the potential energy of the electron has the form — e²/r [1+exp (–qr].

---

s- , –e²/r [1+exp (–qr].

     

Diffraction behavior of an azo-dye-doped nematic liquid crystal without applied electric field

We investigate the dependence of the two-beam coupling diffraction efficiency on the experimental parameters, and hence achieve the optimum experimental conditions for holographic recording in planar Methyl Red-doped nematic liquid crystal film without external electric field. Under the optimum experimental conditions, the diffraction efficiency of a holographic grating is improved to 21.4%, and holographic image with long-term stability is stored in the film. These results provide an experimental basis for holographic data storage in this liquid crystal film.     

Dynamic behaviors of ferroelectric liquid crystal molecules under an applied electric field

The dynamic changes in ferroelectric liquid crystal (FLC) molecular alignments under an applied electric field are examined by observing the formation of conoscopic figures with a time resolution of 0.1 ms. Close agreements between observed and simulated conoscopic figures under low voltage (30 V) were obtained. Under high voltage (120 V), however, the observed conoscopic figures became blurred between 0.8 ms and 1.1 ms after reversal of the electric field. The light scattering producing the blurriness occurred due to the development of fast transient molecular alignments during the switching transition above the applied voltage 70 V.     

Deformation of a pretilted nematic liquid crystal layer in an electric field

The deformation of the optical axis of a nematic liquid crystal layer under the influence of an electric field is caused by the dielectric torque. This momentum counteracts with an elastic torque generated by interfacial forces between the surface of the electrode and the liquid crystal. By means of a variational analysis, the deformation profiles within the liquid crystal layer are calculated, assuming large interfacial energies and various angles of pretilt of the liquid crystal directors with respect to the electrodes. Both the extreme case of a homeotropic (vertical) alignment on one electrode and a homogeneous (parallel) alignment on the opposite electrode, as well as the general case of arbitrary and different alignments on both electrodes, lead to heavily pretilted liquid crystal layers, resulting in definite deformation profiles without disclinations. Liquid crystal cells prepared in this way neither show threshold voltages nor delay times when electrical fields are applied. Measured and calculated characteristics of such liquid crystal cells are presented, they show good agreement.     

Relaxation stimulated in the domain structure of a triglycine sulfate crystal by an alternating-current electric field

The relaxation of the domain structure in a triglycine sulfate crystal from a nonequilibrium state induced by an alternating-current electric field has been investigated. The distributions of the activation energy of the processes under consideration and the energy of interaction of domain walls with defects over the exciting fields have been obtained.     

Absorption measurements in InSe:Ho single crystal under an electric field

InSe:Ho single crystal was grown by Bridgman-Stockberger method. Electric field effects on the absorption measurements have been investigated as a function of temperature in InSe:Ho single crystal. The absorption edge shifted towards longer wavelengths and a decrease of intensity in absorption spectra occurred under an electric field of 7.5 kV/cm. Using absorption measurements, steepness parameter and Urbach energy were calculated under electric field. Applied electric field caused an increase in the Urbach energy. At 10 K and 320 K, the first exciton energies were calculated as 1.322 and 1.301 eV for zero voltage and 1.245 and 1.232 eV for applied electric field, respectively.     

Incommensurate phases induced by an electric field

All magnetic symmetry classes for which the two-dimensional representations are physically irreducible are enumerated. These representations admit of the Lifshitz invariant induced by an external electric field aligned parallel to the principal axis of the crystal. In the majority of the cases, this field does not split two-dimensional representations into one-dimensional representations and, therefore, an incommensurate phase arises in an arbitrarily weak field. The representations of the magnetic classes C _4h and C′_4h are considered in close detail. The components of the toroidal momentum are chosen as the components of the order parameter.     

Dimensional crossover driven by an electric field

We study the steady-state dynamics of the Hubbard model driven out of equilibrium by a constant electric field and coupled to a dissipative heat bath. For a very strong field, we find a dimensional reduction: the system behaves as an equilibrium Hubbard model in lower dimensions. We derive steady-state equations for the dynamical mean-field theory in the presence of dissipation. We discuss how the electric field induced dimensional crossover affects the momentum resolved and integrated spectral functions, the energy distribution function, as well as the steady current in the nonlinear regime.     

Formation and structure of a soliton in an antiferroelectric liquid crystal in an electric field

The soliton structure in an antiferroelectric liquid crystal in an electric field is calculated in the discrete phenomenological Landau model for phase transitions. The anticlinic structure of the antiferroelectric crystal gives rise to nontrivial features of the soliton structure and the stability of the soliton. The soliton is topologically stable in a metastable state if the electric field is much higher than the field of antiferroelectric-helix unwinding. A structural transition with a step-like change in the orientation of molecules occurs as the soliton field varies. A peculiar soliton (synclinic pair) can be formed if the barrier between the anti- and ferroelectric structures is large. The calculation shows the possibility of a large electroclinic effect in the soliton, i.e., a variation in the molecular tilt angle in an electric field in the vicinity of the transition of the structure to the synclinic state.