Tomographic representation of kinetic equations in classical statistical mechanics

A tomographic representation of kinetic equations is constructed using the Radon transform. Liouville’s equation is considered for one and many particles. The reduced Liouville’s equation is obtained in the tomographic representation and the Bogolyubov chain is investigated in this representation. An example of the relativistic kinetic equation in the tomographic representation is considered.     

Relativistic quantum and classical kinetic equations in the tomographic-probability representation

Using the Radon integral transform of the relativistic kinetic equation for a spin-zero particle, we obtain the classical and quantum evolution equations for the tomographic probability density (tomogram) describing the states of the particle in both the classical and quantum pictures. The Green functions (propagators) of the evolution equations of a free particle are constructed. The examples of the evolution of Gaussian tomogram is considered.     

A space-time functional formalism for classical field equations

The equations derived by R.L. Levis and R.H. Kraichnan for a space-time functional for turbulence are further investigated in the general case of classical field equations. The compact form of the equations obtained allows for their different transformations and enables to discuss the effect of initial conditions on the final results.     

Initial state dependence of nonlinear kinetic equations: The classical electron gas

The method of nonequilibrium cluster expansion is used to stydy the decay to equilibrium of a weakly coupled inhomogeneous electron gas prepared in a local equilibrium state at the initial time,t=0. A nonlinear kinetic equation describing the long time behavior of the one-particle distribution function is obtained. For consistency, initial correlations have to be taken into account. The resulting kinetic equation-differs from that obtained when the initial state of the system is assumed to be factorized in a product of one-particle functions. The question of to what extent correlations in the initial state play an essential role in determining the form of the kinetic equation at long times is discussed. To that end, the present calculations are compared with results obtained before for hard sphere gases and in general gases with strong short-range forces. A partial answer is proposed and some open questions are indicated.     

Systematic derivation of classical kinetic equations for a three component ionized system

A set of general kinetic classical equations is derived for the correlations between particles and/or fields in an ionized three component system. External electric and magnetic fields may exist as well as the induced fields. In the lowest order the reversible Vlasov equation and the equivalent one oscillator equation result. In the first-order a Fokker-Planck type equation is obtained for both the one-particle and one-oscillator distribution functions.     

Hamilton-Jacobi functional theory for the integration of classical field equations

By employing the terminology of functional differential calculus, Hamilton-Jacobi theory is extended to apply to classical field equations. It is shown that an asymptotic solution to the Hamilton-Jacobi functional differential equation provides an asymptotic general solution to the associated nonlinear classical field equations.Work supported by a National Science Foundation grant.     

Derivation of the classical theory of correlations in fluids by means of functional differentiation

The k-particle, infinite-volume distribution functions $\text{n}\text{?}{}_{\mathrm{k}}\text{(}\text{r}{}_1\text{, …,}\text{r}{}_{\mathrm{k?1}}\text{, γ)}$ and modified Ursell correlation functions $\text{U}\text{?}{}_{\mathrm{k}}\text{(}\text{r}{}_1\text{, …,}\text{r}{}_{\mathrm{k?1}}\text{, γ)}$ of a classical system of particles with the two-body potential $\text{q(}\text{r}\text{) + γ}{}^{\mathrm{\nu }}\text{K(γ}\text{r}\text{)}$ are considered. The limiting values of the functions $\text{n}\text{?}{}_{\mathrm{k}}\text{(}\text{r}{}_1\text{, …,}\text{r}{}_{\mathrm{k?1}}\text{, γ),}\text{n}\text{?}{}_{\mathrm{k}}\text{(}\text{S}{}_1\text{/γ, …,}\text{S}{}_{\mathrm{k?1}}\text{/γ, γ)}$ and $\text{γ(}{}^{\mathrm{1?k}}\text{)ν}\text{U}\text{?}{}_{\mathrm{k}}\text{(}\text{S}{}_1\text{/γ, …,}\text{S}{}_{\mathrm{k?1}}\text{/γ, γ)}$ in the limit γ → 0 are calculated, under fairly weak conditions on q and K, by a method involving functional differentiation. These limiting functions are used to describe the molecular structure of the various states of the system both in the range of the potential q(r) and in the rage of the potential γ^νK(γr). The direct correlation function c? (r, γ) is also considered and it is shown that for $\text{S}\text{≠ 0}$, $\text{lim}{}_{\mathrm{\gamma \to 0}}\text{γ}{}^{\mathrm{?\nu }}\text{c}\text{?}\text{(}\text{S}\text{γ}\text{, γ) = ?βK (}\text{S}\text{)}$, for all one-phase states, where β is the reciprocal temperature. Special cases of our results confirm those of other authors, including the well-known results of Ornstein and Zernike.     

通过完整的麦克斯韦方程导出电磁场的相对论变换

通过完整的麦克斯韦方程和相对性原理导出电场强度、磁感应强度、电位移矢量、磁场强度、电荷体密度和电流密度矢量的相对论变换.     

Multiscaling for classical nanosystems: Derivation of Smoluchowski & Fokker–Planck equations

Using multiscale analysis and methods of statistical physics, we show that a solution to the N-atom Liouville equation can be decomposed via an expansion in terms of a smallness parameter , wherein the long scale time behavior depends upon a reduced probability density that is a function of slow-evolving order parameters. This reduced probability density is shown to satisfy the Smoluchowski equation up to O(²) for a given range of initial conditions. Furthermore, under the additional assumption that the nanoparticle momentum evolves on a slow time scale, we show that this reduced probability density satisfies a Fokker–Planck equation up to O(²). This approach has applications to a broad range of problems in the nanosciences.     

Properties of quantum Markovian master equations

In this paper we give an essentially self-contained account of some general structural properties of the dynamics of quantum open Markovian systems. We review some recent results regarding the problem of the classification of quantum Markovian master equations and the limiting conditions under which the dynamical evolution of a quantum open system obeys an exact semigroup law (weak coupling limit and singular coupling limit). We discuss a general form of quantum detailed balance and its relation to thermal relaxation and to microreversibility.     

Projection method of solving the Bogolyubov equation for the generating functional in classical statistical physics

An approximate method is considered for the solution of the Bogolyubov equation, which is characterized from the physical viewpoint by successively taking account of corrections of ever higher order. In the zeroth approximation the known Vlasov equation is obtained, in the first approximation a system of equations for the unary distribution and second-order correlation functions, and in the second approximation, a system of three equations for the appropriate correlation functions. The properties of the first approximation equations are investigated.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 4, pp. 95–99, April, 1984.The authors are grateful to É. A. Arinshtein and N. M. Placid for useful discussions.     

Derivation of transport equations for anharmonic lattices

Non-equilibrium properties of dielectric crystals are described using a Green function approach which represents transport phenomena by correlation functions of the equilibrium system. The equation which is equivalent to a Boltzmann equation for phonons is the integral equation for the vertex part corrections. Including all irreducible diagrams quadratic in the cubic and linear in the quartic anharmonicities the vertex part equation is reduced to a form which could be used as a starting point for numerical studies of microscopic models. The vertex part is also used to express the space and time variation of the phonon density and the frequency change of the phonons in response to an external displacement field. We also relate the integral equation for the vertex part to a form of the transport equation which is used in Landau's theory of quantum liquids.     

Derivation of Cahn-Hilliard equations from Ginzburg-Landau models

The generalized Cahn-Hilliard equation is obtained as the hydrodynamic limit from a stochastic Ginzburg-Landau model. The associated large-deviation principle is also proved. In the one-dimensional case, we prove a related result about the scaling limit of conservative Langevin dynamics of an SOS surface.     

Stratified quantization approach to dissipative quantum systems: Derivation of the Hamiltonian and kinetic equations for reduced density matrices

A technique for describing dissipative quantum systems that utilizes a fundamental Hamiltonian, which is composed of intrinsic operators of the system, is presented. The specific system considered is a capacitor (or free particle) that is coupled to a resistor (or dissipative medium). The microscopic mechanisms that lead to dissipation are represented by the standard Hamiltonian. Now dissipation is really a collective phenomenon of entities that comprise a macroscopic or mesoscopic object. Hence operators that describe the collective features of the dissipative medium are utilized to construct the Hamiltonian that represents the coupled resistor and capacitor. Quantization of the spatial gauge function is introduced. The magnetic energy part of the coupled Hamiltonian is written in terms of that quantized gauge function and the current density of the dissipative medium. A detailed derivation of the kinetic equation that represents the capacitor or free particle is presented. The partial spectral densities and functions related to spectral densities, which enter the kinetic equations as coefficients of commutators, are evaluated. Explicit expressions for the nonMarkoffian contribution in terms of products of spectral densities and related functions are given. The influence of all two-time correlation functions are considered. Also stated is a remainder term that is a product of partial spectral densities and which is due to higher order terms in the correlation density matrix. The Markoffian part of the kinetic equation is compared with the Master equation that is obtained using the standard generator in the axiomatic approach. A detailed derivation of the Master equation that represents the dissipative medium is also presented. The dynamical equation for the resistor depends on the spatial wavevector, and the influence of the free particle on the diagonal elements (in wavevector space) is stated.     

Nonunique solutions of kinetic equations

Two very hard particle models are solved and the nonuniqueness of the initial value problem for these (model) kinetic equations is explicitly demonstrated, when distribution functions decaying sufficiently slowly are permitted. The intimate connection between nonuniqueness and violation of conservation laws is made evident. The associated eigenvalue problems are solved. Finally, the general implications of these results for kinetic equations with transition rates that are increasing functions of the state variable, are stated in the form of a number of conjectures. They affect the solution of the Boltzmann equation for realistic intermolecular interactions when the collision rategI(g, ) is an increasing function of the relative velocityg.     

Renormalized kinetic theory of nonequilibrium many-particle classical systems

The far-from-equilibrium statistical dynamics of classical particle systems is formulated in terms of self-consistently determined phase-space density response, fluctuation, and vertex functions. Collective and single-particle effects are treated on an equal footing. Two approximations are discussed, one of which reduces to the Vlasov equation direct interaction approximation of Orszag and Kraichnan when terms that are explicitly due to particles are removed.Work performed under the auspices of the U.S. Department of Energy.     

LMG model: Markovian evolution of classical and quantum correlations under decoherence

We have investigated the quantum phase transition in the ground state of collective Lipkin-Meshkov-Glick model (LMG model) subjected to decoherence due to its interaction, represented by a quantum channel, with an environment. We discuss the behavior of quantum and classical pair wise correlations in the system, with the quantumness of correlations measured by quantum discord (QD), entanglement of formation (EOF), measurement-induced disturbance (MID) and the Clauser-Horne-Shimony-Holt-Bell function (CHSH-Bell function). The time evolution established by system-environment interactions is assumed to be Markovian in nature and the quantum channels studied include the amplitude damping (AD), phase damping (PD), bit-flip (BF), phase-flip (PF), and bit-phase-flip (BPF) channels. One can identify appropriate quantities associated with the dynamics of quantum correlations signifying quantum phase transition in the model. Surprisingly, the CHSH-Bell function is found to detect all the phase transitions, even when quantum and classical correlations are zero for the relevant ground state.     

A new expansion of kinetic equations

A small expansion parameter is investigated which is useful in cases where the dependence of average values of slowly-varying variables on the initial conditions is very small for the long time scale.