Microwave spectral study of 2-fluorophenol: cis conformer

The microwave spectra of 2-fluorophenol and its deuterated species have been observed and analyzed in the frequency ranges 12.5–18.0 GHz (KU band) and 21.5–26.0 GHz (K band) in the ground vibrational state at room temperature. For the normal species, the radio frequency-microwave double resonance spectrum has been recorded in the frequency range 30.0–38.0 GHz. Three rotational and five quartic centrifugal distortion constants for the normal species, $\text{A}\text{?}\text{= 3337.86 ± 0.02}$, $\text{B}\text{?}\text{= 2231.92 ± 0.01}$, $\text{C}\text{?}\text{= 1337.52 ± 0.01}$, d_J = (3.5 ± 2.9) × 10^?4, d_JK = (?4.9 ± 1.5) × 10^?3, d_K = (?3.2 ± 1.0) × 10^?3, d_WJ = (?2.0 ± 1.0) × 10^?7, d_WK = (2.6 ± 0.8) × 10^?6 (in MHz), and three rotational constants for the deuterated species, $\text{A}\text{?}\text{= 3324.70 ± 0.03}$, $\text{B}\text{?}\text{= 2177.95 ± 0.03}$, $\text{C}\text{?}\text{= 1315.96 ± 0.03}$ (in MHz), have been obtained. Consideration of the r_s coordinate of the hydroxyl hydrogen atom leads to the assignment of the spectra to the cis conformer of the molecule. An r₀ structure for the cis conformer has been proposed. The nonbonded OH ? F distance is lower by about 0.3 Å than the sum of the van der Waals radii.     

Experimental comparison of Jψ production by π±, K±, p and p̄ beams at 39.5 GeV/c

Measurements have been made of relative production cross sections of the $\text{J}\text{ψ}$ by π^±, K^±, p and p? at 39.5 GeV/c incident on copper. $\text{J}\text{ψ}$ production rates from π^?, K^? and p? are similar. The $\text{J}\text{ψ}$ relative particle/anti-particle production cross sections for x>0 are $\text{σ(π}{}^{\mathrm{+}}\text{)}\text{σ(π}{}^{\mathrm{?}}\text{)=(0.87±0.14)}$, σ(K⁺)/σ(K^?)=(0.85±0.5) and $\text{σ(}\text{p}\text{)}\text{σ(}\text{p}\text{?}\text{)=(0.15 ±0.08)}$. The small p/p? cross section ratio disagrees with models of J/ψ production by gluon amalgamation.     

Microwave spectrum of dimethyldichlorosilane

The microwave spectrum of dimethyldichlorosilane has been observed and the rotational constants and centrifugal distortion constants have been determined for ³⁵Cl₂ and ³⁵Cl³⁷Cl species. From these constants, the molecular structure is determined as $\text{r(}\text{SiCl}\text{) = 2.055 ± 0.003}\text{A}\text{?}$, $\text{r(}\text{SiC}\text{) = 1.845 ± 0.005}\text{A}\text{?}$, ∠ClSiCl = 107.2 ± 0.3°, ∠CSiC = 114.7 ± 0.3°. An analysis of the ³⁵Cl₂ quadrupole splittings leads to quadrupole coupling constants of χ_aa = ?19.6 ± 0.3 MHz, χ_bb = ?3.7 ± 1.4 MHz, χ_cc = 23.3 ± 1.4 MHz, χ_bond = ?38.0 ± 1.6 MHz, and η_bond = 0.22 ± 0.08.     

The nuclear spectroscopy and structure of 223Ra

The level structure of ²²³Ra is reinterpreted in terms of $\text{3}\text{2}$^±, $\text{5}\text{2}$^±, and $\text{1}\text{2}$^± parity-doub The non-adiabatic rigid reflection-asymmetric rotor model reproduces the main features of the experimental data assuming the presence of octupole deformation β₃ ∼- 0.1. In particular, the experimental E1 transition rates are accounted for by the calculated permanent collective electricdipole moment.     

Mean lifetimes of excited levels of Ar II. I. Time correlation measurements

Mean Lifetimes of excited levels of Ar II have been measured using the method of time-correlated photons in cascade. The following results were obtained: for 4p⁴S^°_{$\text{3}\text{2}$}, τ = 7·2±0·3ns; for 4p′²F^°_{$\text{7}\text{2}$}, τ = 8·8±0·2 ns; for 4p′²F^°_{$\text{5}\text{2}$}, τ = 8·0±0·2 ns. These results are compared with experimental and theoretical values.     

Microwave spectrum of 35ClO in the excited vibrational state and a comment on the centrifugal distortion constant

The $\text{J =}\text{3}\text{2}\text{←}\text{1}\text{2}$ transitions of ³⁵ClO in v = 1 of the ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ state were measured and analyzed to obtain the following constants (in megahertz: B = 18 444.86 ± 0.18, p_eff = 669.32 ± 1.08, $\text{a ? (b + c)}\text{2}\text{= 157.05 ± 0.97}$, d = 169.77 ± 0.99, and eqQ = ? 84.78 ± 0.30. The equilibrium bond length is calculated to be 1.56954 ± 0.00005 Å. The transitions in the ground vibrational state, which were reported previously, were reanalyzed by taking into account the matrix elements off diagonal in J of the hyperfine interactions, and led to a refined centrifugal distortion constant, 0.0476 ± 0.0154 MHz. The vibrational frequency increased accordingly to 782 ± 126 cm^?1, which agreed with the value 870 ± 90 cm^?1 obtained from a relative-intensity measurement, and also with other optical spectroscopic data.     

Determination of A0 for CH335Cl and CH337Cl from the ν4 infrared and Raman bands

The ν₄ infrared and Raman bands of CH₃Cl were analyzed simultaneously. A direct fit yielded a complete set of constants for CH₃³⁵Cl, including A₀ = 5.20530 ± 0.00010 cm^?1 and D_K = (8.85 ± 0.13) × 10^?5cm^?1. For CH₃³⁷Cl an incomplete set of constants was obtained from the infrared band, and A₀ = 5.2182 ± 0.0010 cm^?1 was estimated by curve fitting of the Raman spectrum. The resulting equilibrium structure is $\text{r(}\text{CH) = 1.0854 ± 0.0005}\text{A}\text{?}$, $\text{r(}\text{CCl) = 1.7760 ± 0.0003}\text{A}\text{?}$, and <(HCH) = 110°.35 ± 0°.05.     

Inclusive strange particle production in π−p interactions at 6 GeV/c

The inclusive production of Λ, K_S⁰, Σ^±(1385) and $\text{K}{}^{\mathrm{1\pm }}\text{(892)}$ in π^?p interactions at 6 GeV/c has been studied. The observed cross sections are: σ(Λ)=0.94±0.06 mb, σ(K_S⁰)=0.98±0.06 mb, σ(Σ⁺(1385))=60±7 μb, σ(Σ^?(1385))=90±9 μb, $\text{σ(}\text{K}{}^{\mathrm{1+}}\text{(892))=216±28 μ}\text{b and}\text{σ(}\text{K}{}^{\mathrm{1?}}\text{(892))=41±8 μ}\text{b}$, respectively. The inclusive spectra of these particles are presented as functions of squared transverse momentum and Feynman scaling variable x. The polarization of Λ has also been investigated. It is found from a comparison with higher-energy data that the inclusive cross sections for Σ^±(1385) and the production ratios Σ^±(1385)/Λ in π^?p at 6 GeV/c have not reached the high-energy limiting values.     

Inclusive Λ, Λ and Σ±(1385) production in 405 GeV/c pp interactions

We have investigated inclusive Λ, $\text{Λ}$ and Σ^±(1385) productions in 405 GeV/c pp interactions. The observed cross sections are σ(Λ)=4.05±0.39 mb, $\text{σ(}\text{Λ}\text{=0.63±0.17}$ mb, σ(Σ⁺(1385))=0.74±0.17 mb and σ(Λ^?(1385))=0.56±0.17 mb. $\text{Λ}$ production is dominant in a central region of ∣x∣≤0.4. The $\text{Λ/}\text{Λ}$ production ratio at ∣x∣≈0 is found to be 1.2±0.5. The excess, about 0.2 mb, of σ(Λ⁺(1385)) over σ(Λ^?(1385)) is most likely attributed to proton fragmentations (∣x∣≥0.4), and gives an evidence for scaling.     

Measurement of Cl and N quadrupole coupling in ClCN

J = 1 ← 0 and J = 2 ← 1 transitions in ³⁵ClCN and ³⁷ClCN were measured using a C-band waveguide spectrometer and phase-locked sources. Parameters obtained from the data are: $\text{B(}{}^{35}\text{ClCN) = 5 970.820 ± 0.010 MHz}$, $\text{B(}{}^{37}\text{ClCN) = 5 847.246 ± 0.008 MHz}$, $\text{eqQ(}{}^{35}\text{Cl) = ?83.26 ± 0.04 MHz}$, $\text{eqQ(}{}^{37}\text{Cl) = ?65.61 ± 0.04 MHz}$ and $\text{eqQ(}{}^{14}\text{N) = ?3.60 ± 0.08 MHz}$.     

Non-cubic Mn2+-centers in BaF2

The EPR spectra of thermally treated BaF₂: Mn samples is reported. After thermal annealing at 900 K a trigonal Mn²⁺ center with g=2.000±0.005, |D|=2725±40MHz, |A|=265±10MHz, $\text{D}\text{A}\text{>0}$, is observed. Annealing at 1200 K produces an orthorhombic Mn²⁺ center with g=2.00±0.01, |D|=2430±40MHz, |E|=570±20MHz, |A|=265±10MHz, $\text{D}\text{A}\text{<0}$. The superhyperfine (SHF) structures due to interactions with the neighbouring fluorines indicates that the trigonal manganese interacts with four fluorines, three of them equivalent. The orthorhombic Mn²⁺ shows interaction with four equivalent fluorine nuclei.     

Spins of the levels and multipole mixing ratios of transitions in 125Sb determined from γ-γ directional correlation and polarization-directional correlation measurements

In order to resolve several discrepancies in spin assignments to levels in ¹²⁵Sb, directional correlations and polarization-directional correlations have been measured for several γ-γ cascades in ¹²⁵Sb populated from the decay of ¹²⁵Sn. Earlier results obtained from using NaI and Ge(Li) and NaI detectors were difficult to interpret due to the complex structure of the decay scheme. To improve the experimental situation, we have used two coaxial Ge(Li) detectors for the angular correlation measurements and a coaxial Ge(Li)-planar Ge(Li) combination for the polarization-directional correlations. Combination of the results of these measurements give unique spin assignments of $\text{11}\text{2}$^?, $\text{11}\text{2}$^?, $\text{9}\text{2}$⁺, $\text{11}\text{2}$⁺ and $\text{9}\text{2}$⁺ to the 1982 keV, 1890 keV, 1420 keV, 1089 keV and 1067 keV levels, respectively. The determined E2/M1 mixing ratios are : δ(470) = 0.010±0.027, δ(1067) = ?0.86±0.18, and δ(916) = ?0.02±0.01.     

Valence band parameters of cubic zinc selenide derived from magnetoreflectance of the Γ6 − Γ8 exciton

Magnetoreflectance measurements on the Γ₆ ? Γ₈ free exciton ground state in cubic ZnSe in magnetic fields up to 18 Tesla are reported. The diamagnetic shift rate of the ground state components: $\text{|}\text{3}\text{2}\text{>β}$, $\text{|?}\text{3}\text{2}\text{>α}$, $\text{|}\text{1}\text{2}\text{>β}$ and $\text{|?}\text{1}\text{2}\text{>α}$ yield γ₂ = 0.53 ± 0.07 and an exciton reduced mass μ₀ = 0.117 ± 0.003, corresponding to γ₁ = 2.30 ± 0.45 for m_e¹ = 0.16 m₀. γ₁, γ₂ and an effective hole g-value $\text{κ}\text{tilde}\text{= -0.21}$ yield γ₃ = 0.82 ± 0.16 in the parabolic approximation and in agreement with the observed splitting of the $\text{|?}\text{3}\text{2}\text{>α}$, $\text{|?}\text{1}\text{2}\text{>β}$ states for B ∥ [110]. Taking into account polaron effects we derive bare valence band parameters γ₁^L = 2.71 ± 0.60, γ₂^L = 0.63 ± 0.09 and γ₃^L = 0.97 ± 0.21 from the renormalized parameters γ_i. The present results are considerably smaller than earlier theoretical calculations suggest, however they are in good agreement with a recent detailed analysis of two-photon absorption data for 2P exciton states.     

Measurements of elastic scattering in alpha-alpha and alpha-proton collisions at the CERN intersecting storage rings

We measured the elastic scattering of $\text{αα}\text{at}\text{s}\text{= 126}\text{GeV}$ and of αp at $\text{s}\text{= 89}\text{GeV}$. For αα, the differential cross section dσ/dt has a diffractive pattern minima at |t| = 0.10 and 0.38 GeV². At small |t| = 0.05?0.07 GeV², this cross section behaves like exp[(100 ± 10) t]. Extrapolating a fit to the data to the optical point, we obtained for the total cross section α_tot(αα) = 250 ± 50 mb and an integrated elastic cross section σ_e1(αα) = 45 ± mb. Another method of estimating σ_tot(αα), based on measuring the interaction rate, yielded 295 ± 40 mb. For αp, dσ/dt has aminimum at |t| = 0.20 GeV², and for 0.05 < |t| < 0.18 GeV² behaves like exp[(41 ± 2) t]. Extrapolating this slope to |t| = 0, we found σ_tot(αp) = 130 ± 20 and σ_e1(αp) = 20 ± 4mb. Results on pp elastic scattering at $\text{s}\text{= 63}\text{GeV}$ agree with previous ISR experiments.     

Ground-state α-decay of N = 128 isotones 216Ra, 217Ac and 218Th

The α-decay properties of very short-lived N = 128 isotones, ²¹⁶Ra, ²¹⁷Ac and ²¹⁸Th, were investigated by the pulsed-beam method. Alpha emitters of interest were produced in the bombardment of ²⁰⁸Pb or ²⁰⁹Bi with 65–96 MeV ¹²C or ¹⁴N ions and α-decays were measured between natural beam bursts of the cyclotron. The results obtained are _Eα = 9.349±0.008 MeVand $\text{t}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 182±10}\text{ns for}{}^{216}\text{Ra}\text{, 9.650±0.010}\text{MeV}$ and $\text{111±7}\text{ns for}{}^{217}\text{Ac}\text{, 9.665±0.010}\text{MeV}$ and $\text{96±7}\text{ns for}{}^{218}\text{Th}$. The experimental reduced α-widths of N = 128 isotones from ²¹²Po to ²¹⁸Th are shown to agree well with the simple shell model calculation.     

Search for long-lived particles in 200 GeV/c proton-nucleon collisions

A search for long-lived particles (τ ? 10^?8 sec), with changes $\text{±}\text{2}\text{3}\text{, ± 1, ±}\text{4}\text{3}\text{and}\text{± 2}$, produced in 200 GeV pN collisions was performed at the CERN-SPS in a secondary beam equipped with superconducting r.f. separators. Upper limits were obtained for the production of long-lived hadrons and leptons. For charge - 1 particles the limits are at the level of 10^?7 of the pions at a mass m = 0.2 GeV and reach the 10^?11 level from $\text{3}\text{to}\text{8}\text{GeV}$. The production of light antinuclei was measured. The cross sections for ³He production are (1.3 ± 0.3) and (1.9 ± 0.3) × 10^?34 cm²/sr · GeV/c at 21 and 47.4 GeV/c respectively; for t the cross section is (7.6 ± 0.9) × 10^?34 cm²/sr · GeV/c at 23.7 GeV/c.     

Particle ratios in inclusive electroproduction from hydrogen and deuterium

We present a high statistics study of particle ratios in electroproduction of forward hadrons. The π⁺/π^? ratios for a proton target rise monotonically to a value of 2.4 ± 0.2 at Q² of 3 (GeV/c)² and for a neutron target average 1.16 ± 0.04 from Q² of 0.35 to 3 (GeV/c)². We report the first data on electroproduction of $\text{p}$, and measure the cross sections of K^±, p, and $\text{p}$ relative to pions as a function of Q².     

Rotational spectrum of sulfuryl bromide fluoride

The rotational spectra of SO₂⁷⁹BrF and SO₂⁸¹BrF have been obtained between 18 and 40 GHz. Both molecules are near-prolate symmetric rotors with a and b-type dipole components. A least-squares fit of the observed moments of inertia obtained by correcting for the bromine quadrupole interaction yields $\text{r}\text{(SBr) = 2.155 ± 0.006}\text{A}\text{?}$ and ? FSBr=100.6°±1.5° structural parameters when $\text{r}\text{(SO) = 1.407}\text{A}\text{?}$, $\text{r}\text{(SF) = 1.56}\text{A}\text{?}$, and ? OSO=123.7° are assumed.     

The microwave spectrum,structure, and quadrupole coupling constants of boron chloride difluoride,BCIF2

The microwave spectrum of boron chloride difluoride, BClF₂, has been investigated in the region 26.5–40.0 GHz. R-branch transitions belonging to the isotopic species ¹¹B³⁵Cl¹⁹F₂, ¹¹B³⁷Cl¹⁹F₂, and ¹⁰B³⁵Cl¹⁹F₂ have been observed and the derived rotational constants yield the following ground-state structural parameters: $\text{r}{}^0\text{(BF) = 1.315 ± 0.006}\text{A}\text{?}$, $\text{r}{}^{\mathrm{s}}\text{(BCl) = 1.728 ± 0.009}\text{A}\text{?}$, < FBF = 118.1 ± 0.5°. The ground-state rotational constants of the most abundant species ¹¹B³⁵Cl¹⁹F₂ are: A₀ = 10 449.32 ± 0.13, B₀ = 4705.811 ± 0.020, C₀ = 3239.702 ± 0.026 MHz, Δ_JK = 8.9 ± 1.7, and Δ_J = 1.86 ± 0.48 KHz. The asymmetry parameter κ = ?0.593291 and the inertial defect δ⁰ = 0.2361 amu Ų which is consistent with that expected for this type of molecule if planar. The ³⁵Cl quadrupole coupling constants for ¹¹B³⁵Cl¹⁹F₂ are χ_aa = ?42.8 ± 1.0, χ_bb = 30.2 ± 1.5, χ_cc = 12.6 ± 1.5 MHz with the asymmetry parameter η = 0.41.     

Structure of cyclobutanone

The microwave spectra of the ¹⁸O and the α,α,α′,α′-tetradeuterated isotopic species of cyclobutanone have been investigated. Structural parameters determined are $\text{r}{}_{\mathrm{<mtext>CO</mtext>}}\text{= 1.204 ± 0.006}\text{A}\text{?}$, , ∠ H_αCH_α = 109.2 ± 1° with the methylene group tilted toward the carbonyl group by 4.6 ± 0.8°.