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1.
Munetaka Nakata Kunio Kohata Tsutomu Fukuyama Kozo Kuchitsu 《Journal of Molecular Spectroscopy》1980,83(1):105-117
The rz structure of phosgene has been determined by a joint analysis of the electron diffraction intensity and the rotational constants as follows: , , ∠z;ClCCl = 111.83 ± 0.11°, where uncertainties represent estimated limits of experimental error. The effective constants representing bond-stretching anharmonicity have been obtained from an analysis of the isotopic differences in the rz structure: , . The equilibrium bond distances have been estimated from the rz structure for the normal species and from the anharmonic constants to be , . 相似文献
2.
From the angular distributions of γ-rays emitted by oriented 129gTe and 129mTe nuclei implanted in iron by isotope separator, unique spin assignments could be made for the excited states of 129I at 487.4 keV , 696.0 keV , 729.6 keV , 768.9 keV , 1050.4 keV and 1111.8 keV . In addition, E2/M1 amplitude ratios for the following 129I γ-rays (energies are in keV) are derived: δ(459.6) = ?(0.076+0.037?0.148); δ(487.4) = 0.50+0.17?0.10 or δ? = 0.35+0.15?0.09; δ(556.7) = 0.06±0.02 or δ? = ?(0.10±0.02); δ(624.4) = 0.10±0.26 or δ? > 0.4; the 696.0 keV γ-ray is pure E2; δ(729.6) = ?(0.34±0.06) or δ?1 = 0.55±0.05; δ(741.1) = ?(0.27±0.10) or δ?1 = ?(0.43±0.12); δ(817.2) = 0.46±0.04 or δ?1 =0.20±0.03 if ; δ(1022.6) = ?(0.02 ±0.02) or δ?1 = ?(0.23±0.02); ; δ(1111.8) = 0.06±0.05 or δ?1 = ?(0.08±0.05). The anisotropy of the 531.8 keV γ-ray excludes as a possible spin assignment for the 559.6 keV level, so that no level is fed in the decay from 129Te. Anisotropies for the 209, 250.7, 278.4 and 281.1 keV γ-rays are also measured. Comparison of the level scheme is made with theoretical predictions from both the pairing-plus-quadrupole model and the intermediate coupling unified model. 相似文献
3.
4.
A millimeter-wave spectrometer having a sensitivity of 4 × 10?10 cm?1 in the 2-mm region has been constructed for observation of extremely weak millimeter-wave spectra of gases. It has been used to measure J → J, K = 0 ← 3 transitions in PH3 and J → J, K = 0 ← 3 as well as K = ±1 ← ±4 transitions in PD3. The B0 and C0 spectral constants (in MHz) are: for PH3, B0 = 133 480.15 ± 0.12 and C0 = 117 488.85 ± 0.16; for PD3, B0 = 69 471.10 ± 0.03 and C0 = 58 974.37 ± 0.05. The effective ground-state values obtained for the bond angle and bond length are: for PH3, and ; for PD3, and . The corresponding zero-point-average values were calculated to be: for PH3, and ; for PD3, and . For both species, the equilibrium values are and . 相似文献
5.
A forward dispersion relation cannot be applied to charged particle scattering amplitudes unless the influence of the Coulomb interaction is explicitly considered. Earlier studies have shown how Coulomb effects can be taken into account when direct (s-channel or bound-state) poles are investigated. In this paper we extend the Coulomb modification to include I = 0 exchange (u-channel) processes as well. We then apply a forward dispersion relation to empirical d + α, p + d and n + d elastic scattering amplitudes which contain both direct and exchange poles with and without Coulomb effects. We obtain detailed and model-independent information on the following vertices: 6Li-α-d (S- and D-state) 4He-d-d, 3He-d-p, 3H-d-n and d-p-n. From the coupling constants we calculate the asymptotic normalization (spectroscopic factors) C21 of the corresponding cluster wave functions, which become: , , C20(α, dd) < 2, , . 相似文献
6.
G. Andersson M. Asghar A. Emsallem E. Hagberg B. Jonson 《Physics letters. [Part B]》1976,61(3):234-236
Using a target prepared by on-line isotope separation, thermal neutron capture in 84Rb (Iπ = 2?) has been shown to induce proton emission to the ground state (0+) and first excited state (2+) of 84Kr. The branching ratio was measured as , favouring a assignment of the capturing state without excluding , and the (nth, p) cross section as 12 ± 2 b. The energy available for the process was determined to be 3.45 ± 0.01 MeV, in agreement with other mass data in the region. 相似文献
7.
Cyclotron resonance of electron and holes have been optically detected at 70 GHz and at 1.8 K in n-type CdTe. The bare effective masses, in unit of the free electron mass, are found to be: , , , and , , for H // <111>. The Luttinger valence band parameters deduced from these measurements are: γ1 = 5.3 ± 0.5, γ2 = 1.7 ± 0.3 and γ3 = 2.0 ± 0.3, in fair agreement with the calculations of Lawaetz. 相似文献
8.
Dependence of static dielectric susceptibility and correlation length of charge density waves (CDW) with weak defects on parameter of incommensurability with lattice is investigated. In almost commensurate phase (h?hchc), and Rc ~ (h ? hc). In. Far from commensurability , , where a is the dimensionless ratio of random potential intensities, corresponding to backward and forward scattering impurities. 相似文献
9.
B.J. Jansen Tj. Hollander H. Van Helvoort 《Journal of Quantitative Spectroscopy & Radiative Transfer》1977,17(2):193-196
The quantum efficiency of fluorescence, Y, of the 4607.33 Å Sr line was measured in four pre-mixed, laminar, shielded CO/N2O flames of about 2700 K, with different quantitative compositions at 1 atm. From these data, the specific quenching cross sections for O2, CO2, CO and N2 were found to be (152±20 Å2), (30±5 Å2), (49±8 Å2) and (16±3 Å2), respectively. 相似文献
10.
The chemiluminescence spectrum of atomic Pb reacting with O3 under single-collision conditions includes a series of 55 bands in the regions 450–850 nm. A vibrational analysis is obtained which shows emission is to the ground state of PbO from excited electronic states not previously analyzed. Forty-nine of the bands are assigned to the a(1)-X(0+) transition and the remaining six are tentatively identified as the forbidden b(0?)-X(0+) transition. Both the a and b states are believed to be Hund's case (c) components of the 3Σ+ states arising from the configuration . The vibrational parameters of the a state are ν4 = 16 029 ± 8, ωe′ = 478.7 ± 1.9, and ωexe′ = 2.292 ± 0.128 cm?1, where the uncertainties represent two standard deviations of the least-squares fit. Emission is also observed from the PbO B state produced in the reaction of metastable Pb atoms with O3. Using pulsed laser excitation, an attempt is made to determine radiative lifetimes. We find for the PbO A(0+) state τ = 3.74 ± 0.3 μsec, and for the PbO B(1) state τ = 2.58 ± 0.3 μsec, while for the a(1) state τ is estimated to be greater than 10 μsec. From the vibrational analysis, energy conservation arguments place a lower limits to the ground state dissociation energy of (86.2 ± 0.7 kcal/mole). For the Pb + O3 reaction we find less than 1% of the products are PbO1 molecules that emit in the visible. Correlations are made with the low-lying states of other Group IV chalconides based on the assignment of the PbO state and the correspondence between the low-lying triplet states of PbO and CO. 相似文献
11.
The J = 2?1 microwave spectrum of six isotopic species of HSiF3 has been observed and assigned in excited states of five of the six fundamental vibrations. The assignment is based on relative intensities, double resonance experiments, and trial anharmonic force constant calculations. Analysis of the spectra leads to experimental values for five of the constants, all three l-doubling constants qt, one Fermi resonance constant φ233, and one zeta constant .The harmonic force field has been refined to all the available data on vibration wavenumbers, centrifugal distortion constants, and zeta constants. The cubic anharmonic force field has been refined to the data on and qt constants, using two models: a valence force model with two cubic force constants for SiH and SiF stretching, and a more sophisticated model. With the help of these calculations, the following equilibrium structure has been determined: , , ∠HSiF = 110.64(±3)°, 相似文献
12.
A. Possoz Ph. Deschepper L. Grenacs P. Lebrun J. Lehmann L. Palffy A. De Moura Gonçalves C. Samour V.L. Telegdi 《Physics letters. [Part B]》1977,70(2):265-268
The helicity, h?, of μ? in π-decay has been determined as positive (h??+0.90) from the average polarization, Pav≡〈JB·sμ〉, of 12B produced in the reaction. We obtain also dynamical information on μ-capture: (i) the weak magnetism form factor, μ=4.5±1.1, and (ii) the sum of the induced pseudoscalar (gp) and the 2nd class induced tensor (gT) couplings versus gA, (. The latter result, adopting the “canonical” value of , leads to which is compatible with zero and in strong contradiction with the value ?—6 recently advocated by Kubodera, Delorme and Rho. 相似文献
13.
R. Sugahara F. Ochiai Y. Fukui A.M. Cooper M. Fukawa S. Kabe H. Kichimi A. Ono T. Sato A. Suzuki Y. Yoshimura K. Takahashi T. Okusawa K. Tanahashi S. Sasaki M. Teranaka O. Kusumoto T. Konishi 《Nuclear Physics B》1979,156(2):237-251
The inclusive production of Λ, KS0, Σ±(1385) and in π?p interactions at 6 GeV/c has been studied. The observed cross sections are: σ(Λ)=0.94±0.06 mb, σ(KS0)=0.98±0.06 mb, σ(Σ+(1385))=60±7 μb, σ(Σ?(1385))=90±9 μb, , respectively. The inclusive spectra of these particles are presented as functions of squared transverse momentum and Feynman scaling variable x. The polarization of Λ has also been investigated. It is found from a comparison with higher-energy data that the inclusive cross sections for Σ±(1385) and the production ratios Σ±(1385)/Λ in π?p at 6 GeV/c have not reached the high-energy limiting values. 相似文献
14.
Excitation functions at θ = 90° have been measured for , , and , in the range E3He = 3–19 MeV. The first reaction has also been studied at θ = 40°. Excitation functions at 90° have also been measured for and for E3He = 19–26 MeV. Angular distributions have been measured for the first four reactions.For the most excitation functions, a broad peak is observed, several MeV wide, centred at about Ex≈ 20 MeV. Superimposed on this, in some cases, are narrower peaks, with width ≈ 1 MeV. Energies and widths have been extracted for all resonances.Cluster-model calculations have been carried out, using methods similar to those which have proved successful for low-lying states in A= 18–19 nuclei. No satisfactory correspondence with the present results was found. The shell model has been used to calculate Γ3He and Γγ for 1?ω excitations in the final nuclei. These generally show good agreement with the trends of the experimental data. The results are consistent with the excitation of the giant dipole resonance in 3He capture, but much more weakly than in proton capture. 相似文献
15.
Excitation functions of the capture reaction 12C(p, γ0)13N have been obtained at θγ = 0° and 90° and Ep = 150–2500 keV. The results can be explained if a direct radiative capture process, E1(s and d → p), to the ground state in 13N is included in the analysis in addition to the two well-known resonances in this beam energy range and 1699 . The direct capture component is enhanced through interference effects with the two resonance amplitudes. From the observed direct capture cross section, a spectroscopic factor of C2S(l = 1) = 0.49 ± 0.15 has been deduced for the ground state in 13N. Excitation functions for the reaction have been obtained at θγ = 0° and 90° and Ep = 610–2700 keV. Away from the 1699 keV resonance the capture γ-ray yield is dominated by the direct capture process E1 (p → s) to the unbound state. Above Ep = 1 MeV, the observed excitation functions are well reproduced by the direct capture theory to unbound states (bremsstrahlung theory). Below Ep = 1 MeV, i.e., Ep → 457 keV, the theory diverges in contrast to observation. This discrepancy is well known in bremsstrahlung theory as the “infrared problem”. From the observed direct capture cross sections at , a spectroscopic factor of C2S(l = 0) = 1.02 ± 0.15 has been found for the unbound state. A search for direct capture transitions to the and unbound states resulted in upper limits of C2S(l = 1) ≦ 0.5 and C2S(l = 2) ? 1.0, respectively. The results are compared with available stripping data as well as shell-model calculations. The astrophysical aspect of the 12C(p, γ0)13N reaction also is discussed. 相似文献
16.
The dependence of inclusive cross sections of the production of hadrons on p⊥ (and also on x and √s) is calculated at high energy in the region of small p⊥ ? 1–2 GeV. The model of production and decay of quark-gluon strings is used under the simplest assumptions about the k⊥ dependence of the quark distributions in nucleons ~ exp(?γ1k2⊥) and about the form of the string fragmentation function where γ1 and γh are some constants. The theory reproduces all existing experimental data and yields the “seagull effect” for the dependence of 〈p⊥〉 on x. Predictions are given for the p⊥ dependence of the spectra of π± mesons produced at high energies at SPS and other future colliders. 相似文献
17.
Internal rotation A-E splittings have been observed in the ground state for both 35Cl and 37Cl isotopic species of S-methylchlorothioformate. The values and have been obtained. The anaalysis of the hyperfine structure gave , and , . Only the syn-conformation of the methyl group with respect to the carbonyl group has been observed. A partial r0 structure is given. 相似文献
18.
G. Tarrago M. Dang-Nhu G. Poussigue G. Guelachvili C. Amiot 《Journal of Molecular Spectroscopy》1975,57(2):246-263
High resolution spectra of the ν3 band of methane, 12CH4, were recorded by using a “third generation vacuum Fourier interferometer”; a large pressure range (from 0.009 to 10 Torr) with a sample path fixed at eight meters was used, enabling observation of transitions with intensity ratios as low as . More than 350 forbidden transitions of the ν3 band, including about 125 transitions of the Q+ branch, were unambiguously identified. Of the 277 transitions retained for computations, one-hundred have 11 ≤ J ≤ 16. From combination difference relations using pairs of transitions having the same upper state energy level (forbidden-allowed and forbidden-forbidden pairs were used), 276 independent differences between ground state energy levels could be determined with uncertainties of about 0.001 cm?1.These data yielded the following values for the ground state structure constants of 12CH4 along with their standard deviations (in cm?1): , , , , , , Thus, for the first time, the scalar constant π0 has been evaluated and ir values have been obtained for the two tetrahedral constants ?0 and ξ0; furthermore, these values are in very good agreement with the ones recently determined from radiofrequency data, i.e., in cm?1: , , From these values, the 276 differences can be reproduced with an overall rms deviation equal to 0.0009 cm?1.Finally, the ground state energies of 12CH4 have been calculated for J ≤ 16. 相似文献
19.
C.V.K. Baba D.B. Fossan T. Faestermann F. Feilitzsch P. Kienle C. Signorini 《Physics letters. [Part B]》1973,43(6):483-486
The difference in g-factors for the 61+ and 81+ states in 210Po has been measured as . This result represents a small violation of additivity. A value of g8 = 0.909 ± 0.011, independent of g6, was also obtained. 相似文献
20.
David Nitz James Cederberg Arthur Kotz Keith Hetzler Thor Aakre Timothy Walhout 《Journal of Molecular Spectroscopy》1984,108(1):6-16
The hyperfine spectrum of KCl has been examined at near-zero electric field and zero magnetic field using a molecular beam electric resonance spectrometer. Rotational as well as vibrational shifts have been observed in both nuclear quadrupole interactions. With , we find (all in units of kHz) for K in 39K35Cl: Q00 = ?5691.47 ± 0.04, Q10 = 51.32 ± 0.06, Q20 = ?0.205 ± 0.020, Q01 = 0.014 ± 0.007, Q00(K37Cl) ? Q00(K35Cl) = ?0.03 ± 0.07; for Cl in 39K35Cl: Q00 = 137.0 ± 0.3, Q10 = ?163.2 ± 0.5, Q20 = 1.57 ± 0.15, Q01 = 0.07 ± 0.03, ; and magnetic constants cK = 0.154 ± 0.007, cCl = 0.435 ± 0.010, c3 = 0.035 ± 0.012, and c4 = 0.009 ± 0.006. These have been used to provide a mapping of the field gradients at both nuclear sites to fourth order in . We find eQqK(ξ) = (?5692.5 ± 2.5) + (1.7 ± 0.8) × 104ξ + (?2. ± 4.) × 104ξ2 + (?8. ± 18.) × 105ξ3 + (8. ± 15.) × 106ξ4 and eQqCl(ξ) = (120. ± 22.) + (8. ± 4.) × 104ξ + (?5.8 ± 2.0) × 105ξ2 + (?1.1 ± 1.6) × 107ξ3 + (1.1 ± 1.3) × 108ξ4. 相似文献