Energies and orbital sizes for some Rydberg and valence states of the nitrogen molecule

Accurate SCF computations are reported on the Rydberg states of N₂ of electron configurations $\text{---1π}{}_{\mathrm{u}}{}^3\text{2π}{}_{\mathrm{u}}$, $\text{---1π}{}_{\mathrm{u}}{}^3\text{3σ}{}_{\mathrm{u}}$, and ---3σ_g2π_g, also on the valence states of the configuration $\text{---1π}{}_{\mathrm{u}}{}^3\text{1π}{}_{\mathrm{g}}$. The Rydberg state calculations supplement those of Lefebvre-Brion and Moser. A comparison is made between the $\text{---1π}{}_{\mathrm{u}}{}^3\text{2π}{}_{\mathrm{u}}$ states and the parallel set of states of the $\text{1π}{}_{\mathrm{u}}{}^3\text{1π}{}_{\mathrm{g}}$ configuration. This comparison shows a sharp difference in the ¹Σ⁺ states of the two configurations, the ¹Σ⁺ state being very high in the latter but relatively low in the former configuration. Recknagel coefficients are given for the several states of the two configurations; as expected, these are much smaller for the $\text{1π}{}_{\mathrm{u}}{}^3\text{2π}{}_{\mathrm{u}}$ configuration. Also, the ¹Δ state is relatively lower for the latter configuration.     

The fine structure of the spectrum of the electronic NO laser

The spectrum of the electronic NO laser has been photographed with high resolution in the region 10 100–10 500 Å. It shows the band system F²Δ-C²Π whose upper and lower states are both Rydberg states configurationally mixed with valence states. Only predissociated rotational levels of the lower state appear in the spectrum. For v = 0 of C²Π a single mixed level $\text{T}{}_{\mathrm{y}}\text{(J = 5}\text{1}\text{2}\text{) = 52431}\text{cm}{}^{\mathrm{?1}}$, very close to the dissociation limit, gives rise to laser lines.     

Absorption spectrum of CO in the Hopfield helium continuum region: Rydberg bands converging to the X2Σ+ state of CO+ in the region 960–1080 Å

The high resolution absorption spectrum of CO has been reinvestigated in the Hopfield helium continuum region, particularly from 960 to 1080 Å. The Rydberg state 3pπE¹Π was extended to v = 2, and other Rydberg states, $\text{3dσ}{}^3\text{Σ}{}^{\mathrm{+}}$ and F¹Σ⁺, $\text{3dπ}{}^1\text{Π}$, and $\text{4sσ}{}^3\text{Σ}{}^{\mathrm{+}}$ and ¹Σ⁺, which are converging to the X²Σ⁺ ground state of CO⁺, have been identified. The rotational structures of only five bands among the observed ten Rydberg bands have been analyzed.     

Rydberg states of carbon dioxide and carbon disulfide

The electronic absorption spectra of carbon dioxide and carbon disulfide have been reexamined. Model potential calculations have been used to calculate the energies of excited states in Rydberg approximation, and (npσ) and (npπ) Rydberg series have been assigned. For both molecules, the lowest excited ¹Π_g and ¹Π_u states are identified as Rydberg states. The lowest ${}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ state is mainly Rydberg for CO₂, but contains some valence character for CS₂, There is no evidence for transitions to additional valence states of these symmetries.It is shown that $\text{LCAO}\text{MO}$ predictions about excited states can be misleading because of near-linear dependencies which arise in multicenter expansions. A consideration of the united atom orbitals for CO₂ and CS₂ predicts that there should be only the number of low-energy excited states which are found from the spectral analysis.     

On the Zeeman effect of 2Π states in diatomic molecules

The theory of the Zeeman effect in ²Π states of diatomic molecules is reconsidered. Second order terms due to the interaction with ²Δ states, which were left out in a previous investigation, are now included. The total correlation between the spin-rotation coupling constant and the centrifugal distortion in the spin-orbit coupling renders the fitted molecular g factors somewhat ambiguous. This problem is handled by a transformation of the basis for the Hamiltonian matrix. The theoretical results are exemplified for the ²Π ground state of OH for which EPR data are available for both the ${}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ and ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ substates. A combination of ab initio predictions and fitted values of the g factors finally yields new information concerning the separate contributions from ²Σ⁺, ²Σ^?, and ²Δ states to the contamination of the ²Π ground state in OH.     

A new valence 2Π state of PO

Rotational structure of a series of new absorption bands of PO in the region 1850 to 1600 Å has been analyzed from a spectrum taken at high resolution. The bands are attributed to an electronic transition P²Π-X²Π, where P²Π is a new valence state of PO. Some of these bands have been found to be perturbed. A qualitative account of these perturbations is presented. A probable electron-configuration $\text{π}{}^3\text{π}{}^{12}$ has been suggested for the new state. From the predissociation observed in the higher vibrational levels of P an upper limit of 48 885 cm^?1 (X²Π, T₀ = 0) for the ground state dissociation energy has been obtained.     

Predissociation and Λ-doubling in the even-parity Rydberg states of the nitrogen molecule

Predissociations in the y¹Π_g and $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ Rydberg states of N₂ (configurations $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{4pσ}$ and $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{3pπ}$, respectively) and their likely causes, are discussed. Peaking of rotational intensity at unusually low J values, without sharp breaking off, is interpreted as due to case c^? or case cⁱ predissociation. Λ doubling in the y state, attributed to interactions with the $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state and with another, ¹Σ⁺, state of the same electron configuration as x, is analyzed. From this analysis the location of the (unobserved) ${}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ state, here labeled x′, is obtained. It is concluded that the predissociation in the Π⁺ levels of the y state is an indirect one mediated by the interaction with x′ coupled with predissociation of x′ by a ${}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state dissociating to ${}^4\text{S +}{}^2\text{P}$ atoms: combined, however, with perturbation of the y state by the k¹Π_g Rydberg state (configuration $\text{3σ}{}_{\mathrm{g}}{}^{\mathrm{?1}}\text{4dπ}$), whose Π⁺ levels are completely predissociated.     

The electronic states of carbon monofluoride: Low-lying valence states

Multiconfiguration Hartree-Fock calculations are reported on the low-lying valence states, the X²Π, ⁴Σ^?, B²Δ, and ²Σ^± states, of carbon monofluoride. The wavefunctions describe dissociation of the molecule to the correct atomic limits and take account of the atomic 2s-2p near-degeneracy effect. For the ground state the calculations give (with experimental values in parentheses): a bond length of 1.286 Å (1.2667 Å), a fundamental frequency of 1292 cm^?1 (1308 cm¹), and a dissociation energy of 3.93 eV (5.5 ± 0.1 eV). A ⁴Σ^? state arising from the $\text{C}\text{(}{}^3\text{P) +}\text{F}\text{(}{}^2\text{P)}$ manifold is calculated to lie just 2.66 eV above the ground state. The B²Δ state, calculated adiabatic excitation energy 6.59 eV (6.12 eV), is found to dissociate to $\text{C}\text{(}{}^1\text{D) +}\text{F}\text{(}{}^2\text{P)}$ via a potential maximum. Calculations are also reported on a repulsive ²Δ state arising from ground state atoms.     

Observed and calculated interactions between valence states of the NO molecule

No perturbation between two valence states of NO has ever been identified, although many valence-Rydberg and several Rydberg-Rydberg perturbations have been extensively studied. The first valence-valence crossing to be experimentally documented for NO is reported here and occurs between the ¹⁵N¹⁸O B²Π (v = 18) and B′²Δ (v = 1) levels. No level shifts larger than the detection limit of 0.1 cm^?1 are observed at the crossings near $\text{J = 6.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_2\text{)]}$ and $\text{J = 12.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_1\text{)]}$; two crossings involving higher rotational levels could not be examined. Semi-empirical calculations of spin-orbit and Coriolis perturbation matrix elements indicate that although the electronic part of the $\text{B}{}^2\text{Π}\text{～ B′}{}^2\text{Δ}$ interaction is large, a small vibrational factor renders the ¹⁵N¹⁸O B (v = 18) ? B′ (v = 1) perturbation unobservable. Semi-empirical estimates are given for all perturbation matrix elements of the operators $\text{Σ}{}_{\mathrm{i}}\text{a}\text{?}{}_{\mathrm{i}}\text{l}{}_{\mathrm{i}}\text{·s}{}_{\mathrm{i}}$ and $\text{B(L}{}_{\mathrm{\pm }}\text{S}{}_{\mathrm{?}}\text{? J}{}_{\mathrm{\pm }}\text{L}{}_{\mathrm{?}}\text{)}$ which connect states belonging to the configurations $\text{(σ2p)}{}^2\text{(π2p)}{}^4\text{(π}{}^1\text{2p)}$, $\text{(σ2p)(π2p)}{}^4\text{(π}{}^1\text{2p)}{}^2$, and $\text{(σ2p)}{}^2\text{(π2p)}{}^3\text{(π}{}^1\text{2p)}{}^2$.     

Some anomalies in the electronic spectra of GeH,GeD, SnH,and SnD related to Hund's coupling case (c)

Expressions for the rotational energy and fine structure based on Hund's coupling case (c) are applied to the ²Π, ⁴Σ^?, and ²Δ states of the heavy hydrides and deuterides GeH, GeD, SnH, and SnD. The ²Π ground state is found to be very well described by the case (a) coupling model, while a considerable case (c) character is found for the ⁴Σ^? state, thus accounting for the observation of the forbidden ${}^2\text{Π}\text{-}{}^4\text{Σ}{}^{\mathrm{?}}$ transition. For the ²Δ state the case (c) model yields very reasonable explanations for several apparent anomalies, in particular for the irregular isotopic shifts of the coupling constants.     

Stereoelectronic properties of photosynthetic and related systems: Ab initio configuration interaction calculations on the ground and lower excited singlet and triplet states of magnesium chlorin and chlorin

Ab initio configuration interaction wavefunctions and energies are reported for the ground state and many low-lying singlet and triplet states of magnesium chlorin and chlorin, and are employed in an analysis of the electronic absorption spectra of these systems.In chlorin, the calculated visible spectrum consists of two ${}^1\text{(π, π}{}^1\text{)}$ states, the lower energy, y-polarized state exhibiting moderate absorption intensity in contrast to the very weak absorption of the higher energy x-polarized state. The configurational composition of both states is well described by the four-orbital model. Five ${}^1\text{(π, π}{}^1\text{)}$ states are responsible for the Soret band envelope. A moderately intense y-state lies under the low energy edge of the band envelope, while two x-polarized states of moderate and strong intensity, respectively, are responsible for the band maximum. The final two ${}^1\text{(π, π}{}^1\text{)}$ states lie at the high energy edge of the Soret band and introduce a measure of asymmetry into the band envelope. Two ${}^1\text{(n, π}{}^1\text{)}$ states of very weak oscillator strength are also found in this region of the spectrum. All the Soret states are of complex configurational composition, and several of the higher lying states contain contributions from doubly excited configurations.The calculated visible spectrum of magnesium chlorin also consists of two ${}^1\text{(π, π}{}^1\text{)}$ states, with the weakly absorbing x-polarized state lying approximately 200 cm^?1 lower in energy than the moderately intense y-polarized state. The configurational composition of both states is well described by the four-orbital model. Four ${}^1\text{(π, π}{}^1\text{)}$ states constitute the bulk of the intensity in the Soret band envelope. In distinction to chlorin, the moderately intense ${}^1\text{(π, π}{}^1\text{)}$ state at the low energy edge of the band envelope is x-polarized. Two intense ${}^1\text{(π, π}{}^1\text{)}$ states of y- and x-polarization, respectively, constitute the band maximum region, and a single x-polarized state of moderately strong intensity can be assigned to the high energy shoulder of the band envelope. Two other weakly absorbing ${}^1\text{(π, π}{}^1\text{)}$ states are also found in this region, along with another weakly absorbing state of mixed in-plane and out-of-plane polarization. No clearly defined ${}^1\text{(n, π}{}^1\text{)}$ states are observed. As was the case for chlorin, all the Soret states are of complex configurational composition, and some of the higher energy states contain significant contributions from doubly excited configurations.Chlorin and magnesium chlorin both possess three ${}^3\text{(π, π}{}^1\text{)}$ states which lie below S₁ and a single ${}^3\text{(π, π}{}^1\text{)}$ which lies slightly above S₂. All four of the low-lying ${}^3\text{(π, π}{}^1\text{)}$ states in each molecule are well described by the four-orbital model, with T₁ being essentially a single configuration in each case. The remainder of the ${}^3\text{(π, π}{}^1\text{)}$ states are clustered in the same energetic region as the comparable ${}^1\text{(π, π}{}^1\text{)}$ Soret states, with comparably complex configurational compositions.Dipole moments and charge distributions for low-lying singlet and triplet states are also reported, and are used to rationalize chemical reactivity characteristics.     

Study of the Kππ system produced in K−p → KππN reactions at 14.3 GeV/c

We have studied the $\text{K}\text{ππ}$ system in the 14.3 GeV/c reactions K^?p → K^?π⁺π^?p, $\text{K}{}^{\mathrm{?}}\text{p}\text{→}\text{K}{}^0\text{π}{}^{\mathrm{?}}\text{π}{}^0\text{and}\text{K}{}^{\mathrm{?}}\text{p}\text{→}\text{K}{}^0\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{n}$. The data have been obtained from a 500 000 picture exposure of the CERN 2m HBC. The first two final states are dominated by Q-production in the Kππ system; there is also an L-signal at M (Kππ) ～ 1.75 GeV. The reaction cross sections are compared to K^?p data at other energies. We discuss the Kππ mass dependence of the diffractive production slope. Evidence is presented for a Q^?p versus Q⁺p differential cross section cross-over around |t| = 0.17 GeV². A t-channel isospin analysis for the $\text{KN}\text{→}\text{K}\text{1(890)π}\text{N}$ channels in the Q-region shows that the I = 1 exchange amplitude is $\text{? 10\%}$ of the dominant I = 0 exchange amplitude. The Kππ decay distributions indicate a predominant J^P = 1⁺ state in the Q-region, and an important J^P = 2^? contribution in the L-region. We find neither s-channel nor t-channel helicity conservation at the meson vertex in the Q- or L-regions. The Kπ angular correlation moments within the Kππ diffractive system are characteristic of Kπ elastic scattering, suggesting a π-exchange Deck-type production mechanism. There is evidence for a Kf⁰ and κπ contribution (where κ is the J^P(Kπ) = 0⁺ state) to the diffractive Kππ system. A fit to the $\text{K}{}^{\mathrm{?}}\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{and}\text{K}{}^0\text{π}{}^{\mathrm{?}}\text{π}{}^0$ Dalitz-plot distributions for the Q-re gion indicates that the ratio of $\text{K}\text{?}\text{to K}{}^1\text{π}$ decay amplitudes decreases with increasing Kππ mass.     

The lower excited states of CS: A study of extensive spin-orbit perturbations

We present previously unpublished data on the A¹Π, e³Σ^?, d³Δ_i, $\text{a′}{}^3\text{Σ}{}^{\mathrm{+}}$, and a³Π states of CS from uv emission and absorption transitions to the X¹Σ⁺ ground state. Term values obtained from d³Δ_i ← a³Π ir emission bands are also included. Rotational analyses are presented for about 50 new fine-structure components in some 30 new vibrational levels, together with extended data and analyses for many of the previously observed levels. The data now availabe for these five electronic states more than triples that previously published. Vibrational numbering for the e, d, and a′ states is established by data for minor isotopes. In a Hund's case a-b basis, off-diagonal spin-orbit elements (incipient case c effects) produce extensive coupling among these levels, not only for perturbation crossings but also between levels widely separated in energy. A systematic deperturbation requires two stages, which are iterated. Term values computed from the spectral lines are used to fit parameters of Hamiltonian matrices for groups of nearby, coupled levels. Additional shifts are computed by second-order perturbation theory from the electronic interactions deduced from vibronic coupling elements. The resultant parameters satisfy certain tests for self-consistency; they conform to low-order polynomials in $\text{v +}\text{1}\text{2}$, and vibrational overlap factors from wave-functions computed with RKR potential curves are proportional to the vibronic coupling elements, to within experimental error in most cases. To obtain this self-consistency, we have computed and applied normally neglected centrifugal distortion effects in the off-diagonal coupling elements and in the second-order perturbation sums. We also present and interpret the diagonal spin-orbit fine structure in the a and d states, including the centrifugal distortion parameters, A_D, for the latter, and values for several fitted second-order elements. Possible assignments for three additional perturbations of the A¹Π state and one faint band are discussed in view of ¹Δ, ¹Σ^?, and ⁵Π states that are also expected to occur in the region studied. Tentative parameters for the D¹Δ state are obtained from one possible set of assignments.     

Partial-wave analysis of the low-mass (π+π−p) system produced in K−p interactions at 4.2 GeV/c

A partial-wave analysis of the low-mass (π⁺π^?p) system produced in the reaction K^?p → K^?(π⁺π^?p) at 4.2 GeV/c incident momentum is performed in order to study the two (π⁺π^?p) enhancements around 1500 and 1700 MeV. It is found that the low-mass (π⁺π^?p) system can be described using the spin-parity states $\text{J}{}^{\mathrm{P}}\text{=}\text{1}\text{2}{}^{\mathrm{+}}\text{,}\text{3}\text{2}{}^{\mathrm{?}}$ and $\text{5}\text{2}{}^{\mathrm{+}}$ only. In the 1500 MeV region contributions are observed from the $\text{1}\text{2}{}^{\mathrm{+}}$ wave decaying into p? and the $\text{3}\text{2}{}^{\mathrm{?}}$ wave decaying into Δ⁺⁺π^?; in the 1700 MeV region contributions are found from the $\text{1}\text{2}{}^{\mathrm{+}}$ wave decaying into Δ⁺⁺π^?, the $\text{3}\text{2}{}^{\mathrm{?}}$ wave decaying into p?, and the $\text{5}\text{2}{}^{\mathrm{+}}$ wave decaying into p?.     

Spin determination of states with stretched configurations in 16N and 32P via the (d, α) reaction at 52 MeV

The reactions ${}^{12}\text{C}\text{(}\text{d}\text{, α)}{}^{10}\text{B}\text{,}{}^{18}\text{O}\text{(}\text{d}\text{, α)}{}^{16}\text{N and}{}^{34}\text{S}\text{(}\text{d}\text{, α)}{}^{32}\text{P}$ have been investigated at E_d = 52 MeV. Vector analyzing powers as large as $\text{¦iT}{}_{11}\text{¦=0.85}$ are observed. They exhibit patterns characteristic for final spins I = |L?1|, L or L + 1 and provide spin determinations at least for states of unique L-transfer. Local, zero-range DWBA calculations assuming deuteron-cluster pick-up reproduce qualitatively the observed effects. The method has been tested for states of known spin, and then has been applied to determine spins of states with stretched coupling in ¹⁶N: J^π = 3⁺(3.96 MeV), 4^?(6.17 MeV) and in ³²P: J^π = 5⁺(4.75 MeV). There is strong evidence for further 5⁺ states in ³²P at 6.43, 7.96, 8.09 and 8.54 MeV.     

Theoretical prediction of the vertical electronic spectrum of the C2H radical

The vertical transition energies and oscillator strengths from the $\text{X}\text{?}{}^2\text{Σ}{}^{\mathrm{+}}$ ground and $\text{A}\text{?}{}^2\text{Π}$ excited states of the ethynyl radical C₂H to all higher-lying states resulting from excitation out of π and σ into $\text{π}{}^1$ and $\text{σ}{}^1$ valence-shell MO's, respectively, as well as into 3s and 3p Rydberg species, are calculated by large-scale CI techniques. It is found that the first excited states all result from $\text{π → π}{}^1$ excitations (the lowest three with quartet character), and not from the 4σ → 5σ counterparts favored in the case of isoelectronic CN. This distinction can be explained on the basis of orbital stability differences caused by the effects of hydrogen mixing. The first six states of the C₂H⁺ ion are also treated, and the correspondence with the various associated Rydberg series is discussed. Dipole moments for the $\text{X}\text{?}{}^2\text{Σ}{}^{\mathrm{+}}$ and $\text{A}\text{?}{}^2\text{Π}$ states are also calculated.     

Spin-parity analysis of the nπ+ system produced in the reaction π+p → π+π+n at 16GeV/c

A spin-parity analysis of the nπ⁺ system produced in the reaction π⁺p → π⁺π⁺n at 16 MeV/c has shown apart from the mass enhancements associated with the known resonances Δ⁺(1238), N¹(1520) and N¹(1688) there is an enhancement peaked at M(nπ⁺) ? 1.35 GeV, ∑0.2 GeV wide. For masses below M(nπ⁺) ? 1.35 GeV this enhancement is predominantly due to $\text{J}{}^{\mathrm{P}}\text{=}\text{1}\text{2}{}^{\mathrm{?}}$ states, predominate. The presence of $\text{J}{}^{\mathrm{P}}\text{=}\text{1}\text{2}{}^{\mathrm{?}}$ states indicates that the rule ΔP = (?1)^ΔJ is strongly violated in the diffractive process N → Nπ, and hence it cannot be considered a specific characteristic of all diffractive processes.     

Coherent production of multimeson final states on A ∼ 20 nuclei by K− of 5.5, 10.0, 12.7 GeV

Coherent production of $\text{K}\text{π,}\text{K}\text{2π}\text{and}\text{K}\text{3π}$ final states from A ～ 20 nuclei by K^? beams of 5.5, 10.0 and 12.7 GeV is analyzed. Final states with ? 2π^O are included. Coherent $\text{K}\text{π}$ production occurs (although forbidden via 0⁺ exchange) and is dominated by the $\text{K}$¹ (890). The shape of the t distribution, the alignment of the produced meson and the ratio of the cross section on nuclei to that on hydrogen are consistent with optical model predictions assuming that $\text{K}$¹ (890) are produced on single nucleons by exchange of isoscalar trajectories of natural parity (J^P = 1^?, 2⁺, etc.) and that the $\text{K}$¹ (890) absorption in nuclear matter equals that of the K^?. Coherent $\text{K}\text{ππ}$ production (allowed via 0⁺, 1^?, 2⁺, etc. exchange) is dominated by the Q phenomenon. A Dalitz plot and angular correlation analysis yields values for $\text{K}\text{?/}\text{K}{}^1\text{π}$ fractions, and shows that $\text{J}{}^{\mathrm{P}}\text{= 1}{}^{\mathrm{+}}\text{S-wave}\text{K}{}^1\text{π}$ dominates the coherently produced Q. The helicity of the Q is found to be compatible with 0. The Q^? -nucleaon total cross section is estimated to be 0.98_?0.37⁺⁰²⁴ times the $\text{K}$^? -nucleon total cross section from a comparison of the coherent Q-production cross section with corresponding hydrogen cross sections at 10 and 12.7 GeV. We observe coherent production of $\text{K}$ω. The ration $\text{K}\text{ω/}\text{K}\text{ππ}$ coherently produced in the Q mass region is (4 ± 1)%. Coherent production of $\text{K}{}^{\mathrm{?}}\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{and}\text{K}{}^{\mathrm{<mtext>O</mtext>}}\text{π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{π}{}^{\mathrm{<mtext>O</mtext>}}$ is observed in the L region. Coherent production is not observed in the K4π channels.     

A test of factorisation predictions for the fragmentation processes pp→π± at p momenta of 9.1 and 4.6 GeV/c

Relations have been derived between the invariant cross sections for various inclusive processes by assuming factorisation of the leading (pomeron) and non-leading (meson) trajectories. In this paper predictions for the invariant cross sections $\text{f(}\text{p}\text{p}\text{→π}{}^{\mathrm{\pm }}\text{)(2E}{}^1\text{/π√s)}\text{d}{}^2\text{σ/}\text{d}\text{x}\text{d}\text{p}{}^2{}_{\mathrm{\perp }}{}^2$ have been tested using data from $\text{p}\text{p}$interactions at 4.6 and 9.1 GeV/c.A large discrepancy between experiment and theory is apparent for the π^? data: in the π⁺ case the discrepancy is less marked but still present.     

Photoproduction of charged π mesons from protons and neutrons in the energy range between 250 and 790 MeV

The differential cross sections for γp→π⁺n from hydrogen and the $\text{π}{}^{\mathrm{?}}\text{π}{}^{\mathrm{+}}$ ratios from deuterium were measured at nine c.m. angles between 30° and 150° for laboratory photon energies between 260 and 800 MeV. A magnetic spectrometer with three layers of scintillation hodoscope was used to detect charged π mesons. The cross section for γn→π^?p was obtained as a product of $\text{d}\text{σ}\text{d}\text{Ω}\text{(γ}\text{p}\text{→π}{}^{\mathrm{+}}\text{n}\text{)}$ and the $\text{π}{}^{\mathrm{?}}\text{π}{}^{\mathrm{+}}$ ratio. The overall features in the cross sections of the two reactions, γp→π⁺n and γn→π^?p, and in the ratios, $\text{π}{}^{\mathrm{?}}\text{π}{}^{\mathrm{+}}$, agree with predictions by Moorhouse, Oberlack and Rosenfeld, and Metcalf and Walker. An investigation of the possible existence of an isotensor current was made and a negative result was found. In detailed balance comparison with the new results on the inverse reaction π^?p→γn, no apparent violation of time-reversal invariance was observed.