Laboratory Bounds for the Cosmological Term Gradient

Effects of a spatially variable cosmologicalterm on the equation of motion are investigated, and itshown that these lead to density-dependentaccelerations. Using known data it is shown that thegradient of the cosmological term is bounded byapproximately 10^-59 cm^-3. Effectsof variable G are also discussed.     

Variations on a Constant Theme

We describe how theories incorporating time-varying coupling constants can drive the Universe to a late-time near-flat attractor in which the cosmological constant is very small. We also discuss some consequences of allowing time-varying constants to vary in space as well.     

Space Videophotometric System for Recording Optical Radiations in the Earth Atmosphere

This paper describes the VFS-3M videophotometric system designed for automatic remote recording of images and parameters of optical radiations following lightning discharges from aboard the Russian segment of the International space station. The characteristics of the system and the possibilities of recording such types of radiation as Red Sprites and Blue Jets are given.     

Bianchi Type I Viscous Universe with Variable G and Λ

Exact solutions for an anisotropic Bianchi type I model with bulk viscosity and variable G and are obtained. We have found some solutions that correspond to our earlier work for the isotropic one. Unlike Kalligas et al., an inflationary solution with a variable energy density has been found where the anisotropy energy decreases exponentially with time. There is a period of hyper-inflation during which the energy density remains constant.     

Time-Dependent Vacuum Energy Induced by {\mathcal{D}}–Particle Recoil

We consider cosmology in the framework of a material reference system of particles, including the effects of quantum recoil induced by closed-string probe particles. We find a time-dependent contribution to the cosmological vacuum energy, which relaxes to zero as 1/t ² for large times t. If this energy density is dominant, the Universe expands with a scale factor R(t)t ². We show that this possibility is compatible with recent observational constraints from high–redshift supernovae, and may also respect other phenomenological bounds on time variation in the vacuum energy imposed by early cosmology.     

Kinetics of Atomic Cascade in Light Exotic Atoms

The magnetic hyperfine field B _hf for Cd in the Heusler alloy Pd₂MnSn at the site of chemically introduced Ag has been investigated by PAC following the ^– decay of ¹¹¹Ag. Sign and temperature dependence of B _hf have been determined. Comparison of the result B _hf(T=0)=+8.0(1) T with earlier data and ab-initio band structure calculations leads to the conclusion that the Ag activity has been incorporated at the Mn site.     

Manifestation of Intermolecular Interactions in the IR Spectra of 8-Azasteroids

We have investigated the intermolecular interactions of 8-aza-D-homogona-1,3,5(10),13-tetrane-12,17a-dione and 2,3-dimethoxy-8-azagone-1,3,5(10),13-tetran-12,17-dione with CHCl₃, binary solvents CHCl₃–CH₃OH, CCl₄–CHCl₃, and CCl₄–CH₃OH and also in the solid phase, which manifest themselves in the IR spectra. When the C=O groups of the studied 8-azasteroids form hydrogen bonding with the OH groups of alcohol, the frequencies (C=O) change insignificantly. We have found that they are higher than the corresponding frequencies in the IR absorption spectra of solid-phase samples, which is attributable not only to the effect of the medium but also to the possible shortened contacts of the C=O groups with the CH₃ and CH₂ groups of the molecules under study.     

Bulk Viscous Cosmological Models with Variable G and Λ

Einstein's equations with variable gravitational and cosmological constants are considered in the presence of bulk viscosity for the spatially flat homogeneous and isotropic universe in a way which conserves the energy momentum tensor. A solution is found in which the cosmological term varies inversely with the square of time. Our approach is compared with that of Arbab.     

Thickness dependence of temperature coefficient of resistance of MnBi films

In-situ measurements of the temperature coefficient of resistance of electron-beam evaporated MnBi films are reported for the thickness range 30–180 nm. The thickness dependence of the temperature coefficient of resistance curves are plotted for different weight ratios, annealing times and substrate temperatures. The temperature coefficient of resistance shows marked size effect, and is negative for lower thicknesses (<100nm) and positive for higher thicknesses. The experimental data is in good agreement with the Mayadas-Shatzkes theory. The thickness dependence of the Curie temperature also indicates marked size effect.     

Particle Creation in Cosmological Models with Varying Gravitational and Cosmological “Constants”

Einstein's field equations with variablegravitational coupling G = G(t) and decaying vacuumenergy density = (t) are considered asdescribing matter creation in a cosmological framework.The particle creation rate is determined by thevariation rate of both G and . By consideringsimple phenomenological evolution laws for G and Lambda,an exact solution of the gravitational field equationsfor a flat Friedmann-Robertson-Walker (FRW)space-time is obtained leading to a self-consistentcosmological model describing matter and entropygeneration in the very early Universe.     

Synthesis of peptidomimetics using a polymer-bound Boc-linker

Boc-resin-bound -hydroxy--amino-aldehydes are accessible starting from N-terminally bound amino acidesters by using Dondoni's C₁-homologationreaction sequence. The conversion of these synthons totwo different peptide mimetics – 2-hydroxy-1,3-ethyl-diamines and -hydroxy--amino-vinyl sulfones – hasbeen investigated. The successful transfer of thecomplex -amino acid homologation reactionsequence into solid-phase chemistry demonstrates thepotentials of the Boc-resin for synthesis of peptidomimetics.     

Calculation of the Tautomeric Properties of 3‐Formyl‐Tetrinic Acid by the ab initio and DFT Methods

We have carried out a nonempirical quantumchemical calculation with full optimization of the geometry of all theoretically possible tautomeric forms of 3formyltetrinic acid (FTRA) according to the Møller–Plesset secondorder perturbation theory with the use of a 6–31G(d) double zeta basis set. The correlation corrections to the total energy of molecules for optimized geometric configurations were calculated in the 631G(d,p) basis. All the possible tautomeric forms of FTRA and the harmonic vibrational frequencies were also calculated within the density functional theory (DFT) with the use of the Perdew–Burke–Ernzerhof (PBE) functional in a threeexponent basis. It is shown that FTRA in vapors (in the perfect gas approximation) exists in the form of a mixture of three enol forms, among which two exoforms predominate. The frequencies and forms of normal vibrations for each cisenol tautomer in the region of vibrations of ketogroups and double bonds differ widely, which permits identification of the tautomers present in the mixture. The possible mechanisms of enolenol transformations of 3acyltetrinic acids are discussed.     

The Quantum Evolution of the Closed Friedman Universe with “Bouncing Off”

The homogeneous and isotropic closed Friedmanuniverse evolution in higher-order gravity theories isconsidered. The model takes into account vacuumpolarisation of conformal and nonconformal fields. That leads to the following addition in the Einsteinlagrangian: R² ln |R/R₀|. Near theregular minimum of the scale factor the model has ananalytical solution depending on an integration constantC. If |R/R₀| > 1, the solution passes through the regularminimum, experiences inflation with a decreasing valueof R and approaches to the critical value R =R₀. In the interval |R/R₀| < 1,the solutions have non-linear oscillations (i.e. the scalaronstage). On this stage of the evolution the universe isfilled with relativistic plasma. The continuoustransition through the critical point R = R₀is possible in only one type of solution, the separatrix.Though other solutions have no features in this point,they experience the discontinuity in derivatives of R.It is unsuitable since higher-order gravity theories are considered. Thus the measure of continuoussolutions giving a hot universe is negligible. Howeversolutions of the model can be continued in the imaginarytime. In such a case the Euclidean action will have a non-zero value because of the spaceclosed boundedness of the universe and the finiteness ofthe imaginary time interval (instanton). The last allowsus to calculate the probability of the quantum tunnelling of the Friedman universe from theinflation region into the scalaron region.     

The maximum entropy principle as a consequence of the principle of Laplace

The maximum entropy principle states that the probability distribution which best represents our information is the one which maximizes the entropy with the given evidence as constraints. We prove that this principle is implied from the Laplace principle of equiprobabilities applied to the setS of allN-term sequences of results which are compatible with the given evidence. We generalize to the information gain method of Kullback.     

Analysis of the Tautomeric Properties of 2-Formylcyclopentane-1,3-Dione Using the Data of IR Spectroscopy and Nonempirical (ab initio and DFT) Quantum-Chemical Calculations

The tautomerism, spectral properties, and properties of intramolecular hydrogen bonds in 2-formylcyclopentane-1,3-dione (FCPD) have been investigated by the methods of nonempirical quantum chemistry (calculations by the ab initio and DFT methods) and IR and ¹³C NMR spectroscopy. It is shown that FCPD in a crystalline form, as also does malonic dialdehyde, exists as self-associated enolized molecules with an open chelate ring. It is found that in solutions in CCl₄ the compound investigated exists as an equilibrium mixture of its exo- and endoenolic forms, with predominance of the former. The IR spectra of the solutions of FCPD in CCl₄ fix the presence of small amounts of the associate formed from the anionic and protonated forms of the substance. For the first time, the energies of the intramolecular H bonds of the endo- and exoenolic tautomeric forms in FCPD have been estimated theoretically. They appeared to be equal to 3.69 and 4.91 kcal·mole^–1, respectively. The possible mechanisms of enol-enolic interconversions of FCPD have been discussed.     

Causal Viscous Cosmological Models With Variable G and Λ

Einstein's equations with variable gravitational and cosmological constants are considered in the presence of a bulk viscous fluid source described by the truncated causal theory of Israel–Stewart, for the spatially flat homogeneous and isotropic universe. A solution is found in which the cosmological term varies inversely with the square of time. However, the gravitational constant G is found to be increasing with time.     

Amplification Coefficient of the Anti‐Stokes Component of Raman Scattering

The theory of intracavity parametric interaction of the components of Raman scattering is developed in the prescribedintensity approximation, which takes into account the reverse reaction of the excited waves to the pumpingwave phase. It is shown that one can substantially improve the conversion efficiency or the amplification coefficient of the antiStokes component by selection of the intracavity geometry, the optimum phase relation between the interacting waves, the pumping level, and the phase mismatch.     

α-Particle Loss from Cylindrical Magnetized DT Plasma

-particles from fusion reactions in a DT magnetized plasma are confined inside the plasma not only by magnetic fields but also by induced electric fields which are due to the different mobilities of -particles and electrons. Criteria are derived for the -confinement in a cylindrical plasma, inertially confined by a heavy liner. It is observed that the suprathermal population in the DT plasma will influence the overall dynamics.     

Gravitational Waves in Matter

The theory of gravitational waves in matter is given. This covers the questions of constitutive relation, number of independent polarizations, index of refraction, reflection and refraction at an interface, etc. The theory parallels the familiar optics of electromagnetic waves in material media, but there are some striking differences. The use of the Campbell-Morgan formalism in which the gauge-invariant tidal force dyads E and B rather than the gauge-dependent metric perturbations are the unknowns is essential. The main justification of the theory at the moment is as a theoretical exercise worth doing. The assumption: size L of the medium gravitational wave length (infinite medium) rules out application to the already well-understood detection problem, but there may be an application to gravitational wave propagation through molecular gas clouds of galactic or inter-galactic size.     

Specific Fluorescence Properties and Picosecond Transient Absorption of 8-Azasteroids

The specific fluorescence properties as well as picosecond transient absorption features have been studied for two 8-azasteroids. It is shown that at various excitation wavelengths the essentially different final excited electronic states are realized. Because of the multicenter character of 8-azasteroids the spectroscopic data obtained may be analyzed on a basis of the mesomeric tautomerism model taking into account the dynamic combination of cis- and trans-configurations. The dependence of fluorescence spectral characteristics on the solvent nature is a manifestation of intermolecular H-bond interactions.