柔性可穿戴电子传感器研究进展

随着智能终端的普及,可穿戴电子设备呈现出巨大的市场前景.传感器作为核心部件之一,将影响可穿戴设备的功能设计与未来发展.柔性可穿戴电子传感器具有轻薄便携、电学性能优异和集成度高等特点,使其成为最受关注的电学传感器之一.综述了近年来柔性可穿戴电子传感器的研究进展,包括压阻、电容、压电、力致发光和摩擦电等信号转换机理,金属、无机半导体、有机和碳材料等柔性可穿戴电子的常用材料,柔性电子传感器的印刷制造及其在体温和脉搏检测、表情识别和运动监测等方面的最新应用,最后提出了柔性可穿戴电子传感器面临的挑战与未来发展方向.     

可视化柔性可穿戴传感器研究进展

柔性可穿戴传感器具有轻质、共形性好和生物安全性高等特点,在军事、医疗健康和运动等领域展现出广阔的应用前景。可视化是柔性可穿戴传感器的一个重要发展方向,对于丰富传感器功能和扩展其应用领域具有重要意义。本文综述了近年来可视化柔性可穿戴传感器的研究和应用进展,总结了现有的可视化传感器种类及其作用机理,重点介绍了基于发光或变色进行可视化传感的柔性可穿戴传感器。最后,讨论了可视化柔性可穿戴传感器所面临的机遇和挑战。     

柔性可穿戴传感器及其应用研究

可穿戴传感器可以贴合人体皮肤或与纺织品整合用于监测人体生理状况,具有较高灵敏度和集成性。近年来,可穿戴传感器已被广泛应用于汗液、呼吸、心率和血氧等生理状况的监测。由于可穿戴传感器需要长时间舒适穿戴于人体,并且需要避免人体活动产生的形变影响,因此,柔性是评价和改良可穿戴传感器的一个重要参数。本文首先综述了不同柔性材料的研究进展,概括了基于不同柔性材料的可穿戴传感器的构建及应用,最后讨论了这些柔性可穿戴传感器当前面临的挑战、应对策略以及未来的发展方向。     

可穿戴电化学传感器件的研制及其应用

可穿戴电化学传感器件是一种可直接穿戴在身体特定部位、甚至植入用户体内的柔性电化学传感器。其具有简易性、便携性、灵活性等特点,可实时电化学监测与跟踪分析待测物,被广泛用于医疗保健、人体健康和环境监测等领域。该综述概括了可穿戴电化学传感器件的硬件设计与研制,及其在汗液检测、神经化学监测、现场分析检测（POCT）中的应用,总结和展望了可穿戴电化学传感器件的未来发展趋势,以期为可穿戴电化学传感领域的进一步发展提供参考。     

基于聚二甲基硅氧烷的可穿戴柔性传感器的研究进展

可穿戴柔性传感器是一种紧密附着在人体的皮肤或组织上,可实时收集、分析人体生理参数的设备,在医疗保健、诊断治疗等领域具有重要的应用价值,近年来引起极大关注。聚二甲基硅氧烷(PDMS)不仅化学性质稳定、热稳定性强、透明性和生物相容性好,还可通过表面改性和整体特性定制以实现不同功能,这使得PDMS成为了可穿戴柔性传感器基底材料的最佳选择。本文综述了近年来基于PDMS的可穿戴柔性传感器的研究进展,对导电修饰材料、传感器的工作原理和性能比较等方面进行了回顾和总结,重点对比了不同导电修饰层材料的性能参数与优缺点,介绍了光敏传感器、温度传感器、应变传感器、压力传感器和生化传感器,最后对可穿戴传感器的研究和应用中存在的挑战进行了分析,对其发展方向进行了展望。     

可穿戴柔性触觉传感器的研究进展

可穿戴柔性触觉传感器是用来模仿人类触觉的器件, 可以感知人体以及外界环境的运动、 形变和压力等信息, 在智慧医疗和智能机器人等领域具有广泛的应用前景. 近年来, 大量柔性触觉传感器的研究使其性能得到了巨大的提升, 并在很多领域得到了应用. 本文首先简述了柔性触觉传感器的结构和基本性能; 然后重点介绍了具有自愈合、 自驱动以及可视化等新型高性能触觉传感器的研究进展; 接下来讨论了柔性触觉传感器在可穿戴电子技术、 医疗保健以及人机交互界面等方面的应用; 最后展望了柔性触觉传感器未来所面临的机遇与挑战.     

基于二维材料的柔性可穿戴传感器件研究进展

柔性可穿戴传感器是附着于人体皮肤或组织上的监测装置,可以持续监测和量化特定微环境变化所产生的电信号或化学信号,在医学诊断和治疗方面具有广泛的应用前景.二维材料具有原子薄层的平面结构、优异的机械柔性和电学性能,非常适合用于构建可穿戴传感器.近年来,基于二维材料的柔性传感器在材料制备、工艺设计和设备集成等方面取得了巨大的进...     

可穿戴生物电化学传感器的研究与应用进展

随着物联网的发展,可穿戴生物电化学传感器受到了广泛关注。可穿戴传感器件采用液体导体、导电聚合物薄膜、水凝胶等材料作为柔性电极,集优异的机械性能与传感性能于一体,为人们的生产和生活带来了极大的便利,已被广泛用于医疗诊断、健康监测和环境监测等领域。然而,目前可穿戴生物电化学传感器在美观隐形性和生物亲和性等方面仍存在一些问题。本文从可穿戴传感器件的制备工艺及柔性材料入手,概括分析了近年来可穿戴生物电化学传感器件的研究与应用进展,对其所面临的挑战与困难进行了总结,并展望了可穿戴生物电化学器件未来的发展方向,为进一步改进可穿戴传感器件的集成方法、提高其传感性能以及实现智能化信号传输等提供了参考。     

柔性可穿戴传感器件与储能器件的发展现状与挑战

随着人们生活质量与对可穿戴监测设备需求的提高以及物联网、人工智能和人机交互等科技水平的发展,能够对人体生命体征信号采集、转化与识别的可穿戴柔性电子装置成为连接智能生物与非智能机械装置的桥梁. 可穿戴柔性电子器件对人体生命体征信号的采集包括人体脉搏、温度、皮肤应变、呼吸和心跳等指标. 本文总结概述了近年来可穿戴柔性传感器对人体生命信号采集的现状以及存在的问题和挑战,并对可穿戴柔性供能器件做了简要的总结和展望.     

Wearable Electrochemical Sensors Based on Nanomaterials for Healthcare Applications

Wearable electrochemical sensors have attracted great interest in health care applications because of their flexibility, biocompatibility, low cost and light weight. This review briefly focuses on the main concepts and methods that are related to the application of nanoparticles (NPs) in wearable electrochemical sensors. Moreover, attempts to bring together different perspectives and terms that are commonly used in NPs-based wearable electrochemical sensors along with the introduction and discussion of common manufacturing methods and recent achievements. In the end, future challenges and prospects are also discussed on the development of wearable electrochemical sensors based on nanoparticles.     

新型二氧化硫气体电化学传感器的研究

SO2 是大气的主要污染物 ,并能与环境中的 NOx,O3等协同作用 ,产生更严重的污染 .因此 ,SO2的测定在环境保护、职业健康、工业排放控制等方面起着非常重要的作用 .SO2 的测定方法包括气相色谱法 [1]、离子色谱法 [2 ]、电导测定 [3]和电解电导率 [4]、光纤传感器 [5 ,6 ]等 ,但这些方法所需仪器昂贵、操作繁琐、灵敏度较低、难以实时连续测定 .一些研究者致力于 SO2 电化学传感器的开发 [7～ 8] ,但存在着灵敏度低、需在高温下使用、稳定性差等缺点 .我们成功地研制了一种微型 SO2 气体电化学传感器 ,该传感器稳定性好、灵敏度高、价…     

Research Progress on Nitrite Electrochemical Sensor

Nitrite has been widely used in industrial and agricultural production and is commonly found in food, drinking water, biology and environment. However, nitrite is a toxic inorganic pollutant that is very harmful to the health of human and other organisms. A variety of strategies have been proposed for nitrite detection in recent years. Among which, electrochemical approaches have gained more and more attention owing to the characteristics of simplicity, speediness, high sensitivity, and low cost, etc. The principle of nitrite electrochemical sensor is recommended in this review. The research progresses of nanocomposite material sensor for electrochemical nitrite detection based on carbon material, metal material, metal organic framework, conducting polymer and enzyme in recent years are also introduced from the perspective of composite electrode modification layer. The construction approaches and sensing performances of modified electrode are put special emphasis. At last, future trends of nitrite electrochemical sensor are discussed.     

Highly Sensitive Electrochemical Sensor for Determination of Vitamin D in Mixtures of Water‐Ethanol

This paper describes the electrochemical determination of vitamin D₂ (ergocalciferol) and D₃ (cholecalciferol) in mixed organic/water solvent, using a glassy carbon electrode (GCE). The mixing ratio of organic/water solvent has an important influence on the electrocatalytic response of D vitamins on the surface of the glassy carbon electrode. Well‐defined peaks for Vitamin D₂ and D₃ were observed in a 40 % ethanol/60 % water solution with lithium perchlorate as the support electrolyte. This study demonstrated that the glassy carbon electrode is highly sensitive for the determination of vitamin D₂ and D₃, with a limit of detection of 0.13 and 0.118 µmol L^?1, respectively. No significant interference was seen for vitamins A, E and K in the detection of vitamin D.     

非图案化法制备柔性连续葡萄糖监测传感器

以聚多巴胺作为前驱体,在聚酰亚胺薄膜表面化学沉积一层牢固致密的金层,以该镀金薄膜两面的金层作为基体电极,在其中一面镀铂黑作为参比-对电极,在另一面依次电沉积铂黑层、电泳形成Nafion/碳纳米管网络层、电吸引形成葡萄糖氧化酶层构成工作电极,并整体涂覆聚氨酯外膜,制备了一种柔性葡萄糖传感器.考察了此传感器对葡萄糖的检测性能,以及各层表面形态结构对传感器性能的影响.传感器在0.3V的工作电位下对葡萄糖的线性响应范围是2.0 ～ 32.0 mmol/L,响应灵敏度为25 μA· (mmol/L)-1·cm-2,检出限为0.05 mmol/L (S/N=3),且传感器有良好的长期稳定性和抗干扰性,可用于皮下连续血糖监测.     

Molecularly Imprinted Poly-o-phenylenediamine Electrochemical Sensor for Entacapone

We have developed a molecularly imprinted polymer (MIP) electrochemical sensor for entacapone (ETC) based on an electropolymerised polyphenylenediamine (Po-PD) on a glassy carbon electrode (GCE) surface. The direct electropolymerisation of the o-phenylenediamine monomer (o-PD) was carried out with ETC as a template. The steps of electropolymerization process, template removal and binding of the analyte were tested by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) using [Fe(CN)₆]³⁻/[Fe(CN)₆]^{4 −} as a redox probe. The operation of the sensor has been investigated by differential pulse voltammetry (DPV). Under optimal experimental conditions, the response of the DPV was linearly proportional to the ETC concentration between 1.0×10⁻⁷ and 5.0×10⁻⁶ M ETC with a limit of detection (LOD) of 5.0×10⁻⁸ M. The developed sensor had excellent selectivity without detectable cross-reactivity for levodopa and carbidopa. The MIP sensor was successfully used to detect ETC in spiked human serum samples.     

分子印迹电化学传感器测定L-色氨酸的研究

报道了一种由溶胶-凝胶法制备的分子印迹电化学传感器,并用于L-色氨酸的测定.印迹聚合物是由四乙氧基硅烷、甲基三甲氧基硅烷、苯基三甲氧基硅烷等聚合而成,L-色氨酸为模板分子.通过循环伏安法验证了印迹膜与模板分子的结合和去除.该传感器对L-色氨酸具有良好的选择性以及高的灵敏度,线性范围为1.0×10-9～1.0×10-5m...     

Polydopamine-modified MWCNTs-glassy Carbon Electrode,a Selective Electrochemical Morphine Sensor

An electrochemical sensor based on a glassy carbon electrode was prepared using f-MWCNTs and polydopamine. Several techniques were used to investigate the surface features. Voltammetric techniques were used to evaluate the electrocatalyst efficiency, and it was used for morphine determination using differential pulse voltammetry. Different parameters affecting the method‘s sensitivity and selectivity were optimized. The linear dynamic range was 0.075–75.0 μM with a detection limit of 0.06 μM morphine. Also, the method‘s selectivity was tested, which was proved to be satisfactory. Finally, the sensor was successfully used for morphine determination in human plasma and urine samples with acceptable results.     

胺菊酯分子印迹电化学传感器的制备及性能

以邻氨基酚(OAP)为单体,胺菊酯为印迹分子,采用循环伏安法在玻碳电极上电化学聚合制备了胺菊酯分子印迹敏感膜。采用场发射扫描电镜(FESEM)和电化学方法对该印迹传感器进行了表征。结果表明:分子印迹传感器敏感膜洗脱前和洗脱后在形貌结构和电化学特性方面有明显的不同。以铁氰化钾为电化学探针,利用差分脉冲法(DPV)研究了传感器的响应性能,胺菊酯浓度在10.0～100nmol·L~(-1)范围内,传感器峰电流变化(△i)与胺菊酯浓度c呈线性关系,检出限(3σ)为5.8nmol·L~(-1)该传感器的响应时间为10min,测定相对标准偏差(n=7)为2.76%,回收率在96.0%～103.0%之间。