Spouge's Conjecture on Complete and Instantaneous Gelation

We investigate the stochastic counterpart of the Smoluchowski coagulation equation, namely the Marcus–Lushnikov coagulation model. It is believed that for a broad class of kernels, all particles are swept into one huge cluster in an arbitrarily small time, which is known as a complete and instantaneous gelation phenomenon. Indeed, Spouge (also Domilovskii et al. for a special case) conjectured that K(i, j)=(ij) , >1, are such kernels. In this paper, we extend the above conjecture and prove rigorously that if there is a function (i, j), increasing in both i and j such that _j=1 1/(j(i, j))< for all i, and K(i, j)ij(i, j) for all i, j, then complete and instantaneous gelation occurs. Evidently, this implies that any kernels K(i, j)ij(log(i+1)log(j+1)) , >1, exhibit complete instantaneous gelation. Also, we conjuncture the existence of a critical (or metastable) sol state: if lim _i+j ij/K(i, j)=0 and _{i, j=1} 1/K(i, j)=, then gelation time T _g satisfies 0<T _g<. Moreover, the gelation is complete after T _g.     

Fock representations of the affine Lie algebraA 1 (1)

The aim of this note is to show that the affine Lie algebraA ₁ ⁽¹⁾ has a natural family _, ,v of Fock representations on the spaceC[x _i,y _j;i andj ], parametrized by (,v) C ². By corresponding the highest weight _, of _, to each (,), the parameter spaceC ₂ forms a double cover of the weight spaceC₀C –₁ with singularities at linear forms of level –2; this number is (–1)-times the dual Coxeter number. Our results contain explicit realizations of irreducible non-integrable highest wieghtA ₁ ⁽¹⁾ -modules for generic (,v).     

Cluster size distributions in equilibrium

Equilibrium size distributions for finite system containingM monomers in a volumeV undergoing coagulation (polymerization)/fragmentation, are determined for coagulation rateK _ij and fragmentation rateF _ij , corresponding to the processA _i +A _j A _i+j (hereA _k denotes a cluster containingk monomeric units). It is shown that microscopic detailed balance impliesF _ij /K _ij =a _i a _j /a _i+j , where anda _k are arbitrary. The mean and most probable size distributionc _k = ^–1 a _k e ^–k coincide in the thermodynamic limitM, V, =M/V fixed. If , 2<<3, then the theory predicts a (solgel) phase transition at a well defined value ofq = ^–1, with critical exponents = and = –2. The gel fraction exponent assumes its classical value unity, probably due to the neglect of spatial fluctuations. Finally it is indicated how the theory can in principle be extended to account for isomerism and cyclization.     

Symmetry properties of nonlinear barrier coefficients

This paper concerns the properties of a symmetric barrier between two reservoirs. The barrier can passK conserved quantities. The current of theith quantity is assumed to satisfy the nonlinear relationJ _i=A _ijj+B_ijkljkl where the _i's are the affinity differences across the barrier andA _ij andB _ijkl are functions of the average affinities of the reserviors. It is shown thatB _ijkl is symmetric in all indices.     

The slow passage through a steady bifurcation: Delay and memory effects

We consider the following problem as a model for the slow passage through a steady bifurcation: dy/dt = (t) y – y³ +, where is a slowly increasing function oft given by= _i + t ( ⁱ,<0). Both and are small parameters. This problem is motivated by laser experiments as well as theoretical studies of laser problems. In addition, this equation is a typical amplitude equation for imperfect steady bifurcations with cubic nonlinearities. When=0, we have found that=0 is not the point where the bifurcation transition is observed. This transition appears at a value = ^j > 0. We call ^j the delay of the bifurcation transition. We study this delay as a function of ⁱ, the initial position of, and, the imperfection parameter. To this end, we propose an asymptotic study of this equation as 0, small but fixed. Our main objective is to describe this delay in terms of the relative magnitude of and. Since time-dependent imperfections are always present in experiments, we analyze in the second part of the paper the effect of a small-amplitude but time-periodic imperfection given by (t) = cos(t).     

Generalized Bethe ansatz solution of a one-dimensional asymmetric exclusion process on a ring with blockage

We present a model for a one-dimensional anisotropic exclusion process describing particles moving deterministically on a ring of lengthL with a single defect, across which they move with probability 0 p 1. This model is equivalent to a two-dimensional, six-vertex model in an extreme anisotropic limit with a defect line interpolating between open and periodic boundary conditions. We solve this model with a Bethe ansatz generalized to this kind of boundary condition. We discuss in detail the steady state and derive exact expressions for the currentj, the density profilen(x), and the two-point density correlation function. In the thermodynamic limitL the phase diagram shows three phases, a low-density phase, a coexistence phase, and a high-density phase related to the low-density phase by a particle-hole symmetry. In the low-density phase the density profile decays exponentially with the distance from the boundary to its bulk value on a length scale . On the phase transition line diverges and the currentj approaches its critical valuej _c = p as a power law,j _c – j ^–1/2. In the coexistence phase the width of the interface between the high-density region and the low-density region is proportional toL ^1/2 if the density f 1/2 and=0 independent ofL if = 1/2. The (connected) two-point correlation function turns out to be of a scaling form with a space-dependent amplitude n(x₁, x₂) =A(x₂)A ^Ke^–r/ withr = x ₂ –x ₁ and a critical exponent = 0.     

Fine Structures of the Permittivity and Characteristic Losses of Electrons in Fluorite

Experimental-computational spectra of the permittivity and characteristic losses –Im^–1 for energies in the range 5–21 eV at a temperature of 4.2 K and theoretical spectra of and –Im^–1 of a fluorite crystal are resolved into elementary transition bands. The parameters of transition bands (energies of their maxima E _i, band halfwidths H _i and areas S _i, and oscillator forces f _i) are determined. A correlation of the spectral bands of and –Im^–1is established, and their specific features are elucidated.     

Correlation inequalities for the truncated two-point function of an Ising ferromagnet

We establish the following new correlation inequalities for the truncated twopoint function of an Ising ferromagnet in a positive external field: _j ; _l ^T _j ; _k ^T _k ; _l ^T , and _j ; _l ^T _{k K j} ; _k ^T _{k l} , whereK is any set of sites which separatesj froml. The inequalities are also valid for the pure phases with zero magnetic field at all temperatures. Above the critical temperature they reduce to known inequalities of Griffiths and Simon, respectively.NSERC Postgraduate Fellow, 1978–1981. Research supported in part by NSF Grant No. PHY-78-25390-A02.     

Analytic study of power spectra of the tent maps near band-splitting transitions

Successive band-splitting transitions occur in the one-dimensional map x_i+1=g(x_i),i=0, 1, 2,... withg(x)=x, (0 x 1/2) –x +, (1/2 <x 1) as the parameter is changed from 2 to 1. The transition point fromN (=2ⁿ) bands to 2Nbands is given by=(2)^1/N (n=0, 1,2,...). The time-correlation function _i=x_ix₀/(x₀)²,x_i x_i–x_i is studied in terms of the eigenvalues and eigenfunctions of the Frobenius-Perron operator of the map. It is shown that, near the transition point=2, _i–[(10–42)/17] _i,0-[(102-8)/51]_i,1 + [(7 + 42)/17](–1)ⁱe^–yi, where2(–2) is the damping constant and vanishes at=2, representing the critical slowing-down. This critical phenomenon is in strong contrast to the topologically invariant quantities, such as the Lyapunov exponent, which do not exhibit any anomaly at=2. The asymptotic expression for _i has been obtained by deriving an analytic form of _i for a sequence of which accumulates to 2 from the above. Near the transition point=(2)^1/N, the damping constant of _i fori N is given by _N=2(^N-2)/N. Numerical calculation is also carried out for arbitrary a and is shown to be consistent with the analytic results.     

On an internal symmetry for arbitrary dislocations in solids

We discuss an arbitrary distribution of dislocations moving in an anisotropic finite linear elastic solid. The field equations for theelastic strain tensor are decomposed into two independent systems of equations, the equations for acompatible elastic displacement fields and the equations for anincompatible elastic strain ^v . This can be done in such a way thats contains the full information on anisotropy, external forces, and boundaries, whereas ^v contains only a single material constant , which is related to a signal velocity , wherep is the mass density. In order to understand the symmetries of the ^v -field equations we introduce ac _T -relativistic space-time. As a consequence of certain hypothesis concerning the balance of eigenstresses for moving dislocations the Lorentz group becomes the symmetry group for the ^v -field equations. We call this aninternal symmetry. Thematerial symmetry of the field equations for the elastic displacement vectors which is defined by Hooke's tensor breaks this Lorentz symmetry for the complete elastic strain . Some conclusions for the dynamics of dislocations are discussed. It is found that Seeger's theory of kinks on dislocations describes elementary processes of this dynamics. Within the limits of the continuum model plasticity becomes a field theory with broken Lorentz symmetry.     

Kronecker products of matrices and an application to Fermi systems

An identity for the trace of an exponential function of Kronecker products of matrices is proved. This identity plays an important role for the calculation of the grand potential of interacting Fermi systems. For the HamiltonianH= _i n _i n _i wheren _i =c _i ⁺ n _i (c _i ⁺ : Fermi creation operator at the ith site with spin) we calculate the specific heat for different numbers of electrons per lattice site. Finally, we extend our calculations to find approximative solutions of the Hubbard model.     

Absence of absolutely continuous spectrum of Floquet operators

The spectrum of the Floquet operator associated with time-periodic perturbations of discrete Hamiltonians is considered. If the gap between successive eigenvalues _j of the unperturbed Hamiltonian grows as _j - _j-1 j and the multiplicity of _j grows asj with >0 asj tends to infinity, then the corresponding Floquet operator possesses no absolutely continuous spectrum provided the perturbation is smooth enough.     

Some jacobi matrices with decaying potential and dense point spectrum

We discuss doubly infinite matrices of the formM _ij= _i,j+1+ _i,j–1+V _{i ij} as operators on ². We present for each >0, examples of potentialsV _n with |V _n|=O(n ^–1/2+) and whereM has only point spectrum. Our discussion should be viewed as a remark on the recent work of Delyon, Kunz, and Souillard.Research partially supported by USNSF under grant MCS 81-20833     

Approximate ground state in a model with spontaneous symmetry breakdown

The spontaneous symmetry breakdown is treated by means of a variational approach. Use is made of coherent states of Glauber and of pairing states of BCS-type as the translationally invariant vacuum states for the discussion of the real scalar field ⁴ withm ₀ ² 0. The first type of trial states reproduces the usual approach to spontaneous symmetry breakdown (-) in the tree approximation (which is possible only form ₀ ² <0), while the second type of trial states offers the possibility of spontaneous symmetry breakdown even form ₀ ² =0.     

Gauge invariance of the Euler-Lagrange expressions

We prove, for a Lagrangian density L(g_ij;A _i ⁱ ;A _i ^j ), that the gauge invariance of the Euler-Lagrange expressionsE ⁱ (L) implies the existence of a gauge-invariant scalar densityL ₁, such thatE ⁱ (L) =E ⁱ (L₁). We then prove the uniqueness of the Yang-Mills field equations.     

Parametric relaxation of spectra

We study the change of an quasienergy spectrum upon variation of the weight of a perturbation in the Floquet operatorF=F ₀e^–iV . Employing ideas from level dynamics and random matrix-theory we show that the distribution of nearest-neighbor spacings can display effectively irreversible behavior. Small deviations from equilibrium relax in a certain collision time which scales with the numberN of levels as _collN ^–3/2.     

Deformations of quantum hyperplanes

We consider the quantum hyperplanex ⁱ x ^j =q _ij x ^j x ⁱ (i,j = 1..n) and define and consider deformations of the formx ⁱ x ^j =q _ij x ^j x ⁱ + _{k k} ^ij x ^k + ^ij , where _k ^ij and ^ij are complex numbers. We prove that for genericq _ij no nontrivial deformations exist forn 3.     

Some properties of an “aesthetic” field theory

We continue our study of the Lorentz-invariant field theory based on the equations _jk;l ⁱ =0 and g_ij;k=0. To first order in a perturbation expansion, we find _jk;l ⁱ =0 reduces to the wave equation. In orders higher than the first, we find that _jk;l ⁱ =0 cannot be linearized. We also find that the simple wave-type equation g^ij2g/xⁱx^j=0 is contained in the theory when an appropriate choice is made for the parameters at the origin point.     

Logically independent von Neumann lattices

Three definitions of logical independence of two von Neumann latticesP₁,P₂ of two sub-von Neumann algebras ₁, ₂ of a von Neumann algebra are given and the relations of the definitions clarified. It is shown that under weak assumptions the following notion, called logical independence is the strongest:A B 0 for any 0 A P₁, 0 B P₂. Propositions relating logical independence ofP₁,P₂ toC ^*-independence,W ^* independence, and strict locality of ₁, ₂ are presented.