Diagnostics of the atmospheric-pressure plasma parameters using the method of near-field microwave sounding

A method of resonant near-field microwave probing is developed for contactless diagnostics of a high-pressure plasma. The efficiency of this method in measuring the parameters of the plasma of an rf capacitive discharge in argon under atmospheric pressure is demonstrated. The experimental results are compared with the data obtained using the independent method, the microwave radiation “cutoff,” and with theoretical estimates.     

CARS difference spectroscopy

Summary In this paper we present a vibrational-spectroscopy technique which combines the advantages of coherent anti-Stokes Raman spectroscopy (CARS) and linear Raman difference spectroscopy. The method which we call CARS difference spectroscopy can be applied for the study of small frequency shifts and/or bandwidth changes in the CARS spectra of liquid mixtures and solutions. First we develop the theory necessary for the interpretation of experimental data obtained from CARS difference measurements of mixtures of two Raman-active liquids and present some model calculations for benzene-toluene mixtures of different concentrations. Then the experimental arrangement used for CARS difference measurements as well as some examples of recorded spectra are described. We show that it is possible to observe the effects of dilution on CARS spectra with high accuracy by applying the discussed technique. Paper presented at the “XI European CARS Workshop”, Florence, Italy, 23–25 March, 1992.     

The role of photoelectronic processes in the formation of a fluorescent plume by 248-nm laser irradiation of single crystal NaNO3

 Visible fluorescent “plumes” are readily produced when nominally transparent ionic materials are exposed to pulsed UV laser irradiation. Over a wide range of laser fluences where plumes are observed, however, the photon and electron densities are inadequate to support multiphoton ionization and inverse bremsstrahlung, which are often used to explain plasma production and excitation of atomic spectral lines. We present evidence that the great majority of charged particles (electrons and positive ions) comprising the plume at the onset of formation in defect-laden NaNO₃ are emitted directly from the surface. A model is described wherein the required electron energy to excite and eventually ionize neutral atoms is provided by electrostatic interactions in the expanding plume. The time evolution of the “overlap” between the expanding charge cloud and thermally emitted neutrals accounts for the time evolution of the atomic line emissions after the laser pulse. Received: 15 August 1996/Accepted: 16 August 1996     

Resonance enhanced coherent anti-stokes raman scattering and laser induced fluorescence applied to CH radicals: a comparative study

Resonance enhanced CARS and LIF have been applied to the CH radicals in a microwave excited Ar/H/CH plasma ( Pa, kW). Both techniques yield similar nonthermal rotational population distributions of CH(X) in its vibrational ground state (), which can be described by two rotational temperatures, K being in the order of the gas temperature for rotational states with , and a considerably higher for the higher rotational states. This result is in good agreement with previous resonance CARS and LIF measurements in similar plasmas. With resonance CARS additional measurements on CH in the state could be performed yielding a vibrational temperature of 2440 K, the total CH density was about m. The detection limits of both techniques are determined, in our case about CH radicals per quantum state in the detection volume, and their advantages and disadvantages are discussed. Received: 29 April 1996 / Accepted: 19 June 1996     

Thermal conductivity of pressure polymerized C60

60 polymerization in the temperature interval at pressures below by measurements of the time dependence of the thermal conductivity. It has been found at that the polymerization process at is slower than the reverse transformation from “polymeric” to “monomeric” phase at . The thermal conductivity of polymerized C₆₀ was measured in the temperature range and found to increase with increasing temperature, which reflects strong phonon scattering. Both the presence of non-bonded C₆₀ molecules and a high degree of structural disorder in the crystalline lattice of the polymeric phase might be responsible for the behaviour of . The results for are qualitatively similar to those reported previously for C₆₀ polymerized at higher , but an order of magnitude smaller. Received: 20 September 1996/Accepted: 11 November 1996     

Water transbilayer diffusion in macroscopically oriented lipid bilayers as studied by pulsed field gradient NMR

Water self-diffusion in lipid bilayers macroscopically oriented on glass plates was studied by pulsed field gradient¹H nuclear magnetic resonance technique. Diffusion decays were multicomponent with a distribution of diffusion coefficients ranging from about 10⁻¹⁰ to about 10⁻¹³ m²/s. A number of measurements with variations of the sample orientation, diffusion time and the distance between the glass plates showed that the “fast” component of diffusion corresponds to water in the bilayer “cracks”. The “slow” component of diffusion corresponds to transbilayer water diffusion in the long-diffusion-time regime. For a more reliable separation of parts corresponding to fast and slow diffusion of water, a “component-resolved spectroscopy” method for the global analysis of correlated spectral data (P. Stilbs, K. Paulsen, P.C. Griffiths: J. Phys. Chem. 100, 8180, 1996) was applied.     

A cw room-temperature Ho,Tm:YLF laser pumped at 1.682 μm

We present the results obtained with a Ho,Tm:YLF crystal grown at a new crystal growth facility in Pisa. The optical quality of the sample has been tested by studying its performance as the active medium of a laser operating at 2.06 μm. We employed three different pump laser sources: a Ti:sapphire, a diode (both tuned at 793 nm) and, for the first time, a continuous-wave Co:MgF₂ laser, tuned at 1.682 μm. At room temperature the best slope efficiency was 30 % in the case of “red” pumping, and 59 % in the case of “infrared” excitation. The typical lasing threshold is about 100 mW. Received: 14 March 2001 / Revised version: 15 June 2001 / Published online: 19 September 2001     

Results of 2D numerical simulations of subnanosecond iodine laser interaction with an al foil target

This report presents the results of a theoretical study and 2D numerical simulations of the interaction of subnanosecond iodine laser pulses with an Al-foil target. The target and laser parameters correspond to the experimental conditions of the “PERUN” iodine laser facility (IP, Prague: pulse energy <50 J, ∼300 psec, focal spot d ∼100 μm; target: Al foil of thickness 30 μm). The simulations were made by using the two-dimensional Lagrange code “ATLANT” (FIAN-IMM, Moscow). We varied the diameter of the focal spot and studied the dependence of the plasma parameters (temperature, x-ray yield, etc.) on the laser flux density and the diameter of focal spots. The numerical results were compared with experimental data. Published as Preprint No. 38 of the Lebedev Physics Institute (FIAN), Moscow, 1993.     

Thermal grating and broadband degenerate four-wave mixing spectroscopy of OH in high-pressure flames

2 ∑–X²Π(0,0) band of OH has been studied in premixed methane/air flames using a cw Ar⁺ laser probe. Measurements of flame temperature and pressure were derived from fits of theoretical simulations to the observed time variation of signals over a pressure range of 10 to 40 bar and for different stoichiometry that were in agreement with independent measurements using N₂ CARS and predictions of a one-dimensional flame calculation. Broadband DFWM spectra in the same band of OH were observed up to a pressure of 9 bar, above which signals were obtained only from scattering from thermal gratings. Received: 10 November 1997/Revised version: 28 May 1998     

On “geometric” effects in the microwave radiation of active regions passing through the solar disk

Two basic “geometric” effects manifest themselves as slow variations in the properties of the microwave radiation of the active region passing through the solar disk, namely 1) sign inversions of the circular polarization and 2) characteristic peaks of the brightness temperature at certain longitudes on both sides of the central solar meridian and depression near it. These effects are related to the magnetic directivity of the cyclotron radiation governing in the centimeter wavelength range above large spots. The concept of “normal” passage of the active region through the solar disk is introduced in this paper on the basis of studying the mentioned effects observed at two wavelengths, 5.2 cm (Siberian Solar Radiotelescope, Buryatiya) and 1.76 cm (Radioheliograph in Nobeyama, Japan), to separate the “normal,” or “geometric” effects, in the behavior of the microwave radiation from the evolutional effects that may cause high-power solar flares. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 51, No. 8, pp. 641–659, August 2008.     

Determination of temperature and concentration of molecular nitrogen,oxygen and methane with coherent anti-stokes raman scattering

Temperature and concentration measurements by Coherent Anti-Stokes Raman Scattering (CARS) of molecular nitrogen, oxygen and methane were carried out. A comparison of corrected thermocouple and CARS temperature measurements in a high-temperature furnace up to 2000 K is presented. The temperature dependent CARS spectra of N₂ and O₂ are evaluated by a simulation program. Agreement between CARS and thermocouple temperatures is obtained within 40 K for N₂ and 80 K for O₂. Good agreement is found between measurements and calculations of the decrease of CARS intensity with temperature. Various quick-fit methods for N₂-and O₂-temperature measurements from temperature sensitive spectral parameters were tested. Temperature dependent CARS spectra of thev ₁-fundamental of methane are recorded and the methane CARS intensity as function of temperature is measured.     

Anomalous absorption of intense electromagnetic radiation in a non-uniform overdense plasma

In this work, we present numerical computation of anomalous absorption of a powerful electromagnetic wave incident normally, on an isothermal plasma with a linear density gradient. We consider first, the “intensity” dependence of anomalous absorption treating two important cases: one that of a typical high temperature, high density fusion plasma occurring in a laser-pellet application and the other that of an ionospheric (F-layer) plasma. It is found that for low incident powers, reflection is almost constant, corresponding essentially, to classical electronion collisions. As we increase the incident power, however, we find that the reflection starts dropping and the absorption takes over. This result is interpreted in terms of the instability generated anomalous absorption of the incident wave. Next, we consider the “wavelength” dependence of anomalous absorption, wherein we observe that the effect of anomalous absorption is increasing for longer wavelengths of the incident laser radiation.     

Modeling of time-resolved laser-induced incandescence transients for particle sizing in high-pressure spray combustion environments: a comparative study

In this study experimental single-pulse, time-resolved laser-induced incandescence (TIRE-LII) signal intensity profiles acquired during transient Diesel combustion events at high pressure were processed. Experiments were performed between 0.6 and 7 MPa using a high-temperature high-pressure constant volume cell and a heavy-duty Diesel engine, respectively. Three currently available LII sub-model functions were investigated in their performance for extracting ensemble mean soot particle diameters using a least-squares fitting routine, and a “quick-fit” interpolation approach, respectively. In the calculations a particle size distribution as well as the temporal and spatial intensity profile of the heating laser was taken into account. For the poorly characterized sample environments of this work, some deficiencies in these state-of-the-art data evaluation procedures were revealed. Depending on the implemented model function, significant differences in the extracted particle size parameters are apparent. We also observe that the obtained “best-fit” size parameters in the fitting procedure are biased by the choice of their respective “first-guess” initial values. This behavior may be caused by the smooth temporal profile of the LII cooling curve, giving rise to shallow local minima on the multi-parameter least squares residuals, surface sampled during the regression analysis procedure. Knowledge of the gas phase temperature of the probed medium is considered important for obtaining unbiased size parameter information from TIRE-LII measurements. PACS 42.62.-b; 51.30.+i; 82.20.Wt     

VLBI studies of the solar-wind plasma irregularities at 18 and 92 CM wavelengths in 1994–1996

We discuss the capabilities of VLBI studies of irregularities of the solar-wind plasma using multi-element radio interferometric facilities. We analyze the data obtained during international VLBI experiments at decimeter wavelengths (92 and 18 cm) in 1994–1996 and supposed that the irregularities have a “stream” structure. The “streams” are strongly elongated in the solar-wind direction (longitudinal size of about a few hundred thousand kilometers) and have the transverse size of about 0.5–2.0 thousand kilometers. The irregularities inside a single “stream” are almost isotropic. We discuss the restrictions imposed on operation of decimeter VLBI systems due to effects of the interplanetary medium. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 43, No. 3, pp. 197–206, March, 2000     

Specific heat of around the glass transition

Dynamic calorimetric measurements are performed for the quaternary metallic glass Zr₆₅Al_7.5Cu_17.5Ni₁₀ in order to analyse the dependence on different heating rates for the glass transition temperature T_g. We compare two different temperature programs used for sample relaxation, to estimate the influence of the thermal history on T_g. A lower limit for the glass transition temperature T_g was calculated according to two different models based on the fact, that width and temperature of the glass transition depend on the experimental time scale set by the heating rate: One model assumes a Vogel-Fulcher-Tammann type behaviour, as used to describe more or less “fragile” glass formers and the other assumes an Arrhenius-like behaviour, which is related to “strong” glass formers. The values obtained from both models differ by about 80K. From additional absolute specific heat capacity measurements we calculate the Kauzmann temperature T_K, as a lower limit for the temperature of the glass transition from thermodynamic aspects. Comparing T_K with the temperature values obtained from the two evaluation models we can classify the quaternary metallic glass Zr₆₅Al_7.5Cu_17.5Ni₁₀, to behave more like a “strong” glass former. Received: 23 January 1998 / Received in final form and Accepted: 31 August 1998     

Deeply undercritical microwave discharge excited by the field of a quasi-optical electromagnetic beam in a supersonic air jet

Electric discharge in a supersonic air jet is studied. It is ignited in a linearly polarized quasi-optical microwave electromagnetic beam the initial field intensity of which is much lower than the breakdown level. Electric breakdown is initiated by a tubular electromagnetic vibrator, one end of which has spikes and is covered by a quartz tube. Atmospheric air enters into a low-pressure working chamber through the inner channel of the vibrator. As a result, an immersed supersonic air jet forms in the chamber at the outlet from the quartz tube. A microwave discharge ignited in this jet is “attached” to aft spikes of the vibrator. The energy deposit into the discharge plasma and the effective area of energy interaction between the discharge and excited microwave field are estimated from the temperature and stagnation pressure distributions in the wake of the discharge.     

Distribution of Overlap Profiles in the One-Dimensional Kac--Hopfield Model

We study a one-dimensional version of the Hopfield model with long, but finite range interactions below the critical temperature. In the thermodynamic limit we obtain large deviation estimates for the distribution of the “local” overlaps, the range of the interaction, , being the large parameter. We show in particular that the local overlaps in a typical Gibbs configuration are constant and equal to one of the mean-field equilibrium values on a scale . We also give estimates on the size of typical “jumps”, i.e. the regions where transitions from one equilibrium value to another take place. Contrary to the situation in the ferromagnetic Kac-model, the structure of the profiles is found to be governed by the quenched disorder rather than by entropy. Received: 14 February 1996 / Accepted: 30 September 1996     

A contribution to the characterization of laser-hardened steel surfaces

The article deals with the possibility to characterize the laser heat-treatment of steel surface by means of X-ray diffraction and microhardness measurements. For tensometric analysis the X-ray one-tilt method with no reference substance was used. It is shown that hardened surface layers of the carbon steel are affected by compressions reaching in the middle of the laser beam track up to ≈ 350 MPa. The microhardness increased by as much as 350 %. Presented at the 6th Joint Seminar “Development of Materials Science in Research and Education”, Karlštejn, Czech Republic, 17–19 September 1996. This research is a part of the research project supported by Grant Agency of the Czech Republic (Grant No. 106/95/0080).     

Energetic and thermal performance of high-gain diode-side-pumped Nd:YAG rods

We investigated the energetic and thermal performance of a diode-side-pumped Nd:YAG rod laser with up to 50 W power deposited as excess heat into a 3-mm-diameter, 10-cm-length rod. The rod design produces an extremely flat gain profile resulting in “textbook” expressions of thermal lensing and birefringence. Thermal and energetic measurements are compared to corresponding “textbook” theoretical expressions. Discrepancies between various published thermo-mechanical YAG parameters are resolved by a self-consistent set of measured and calculated data for rod thermal lens focal lengths, birefringence depolarization and ratio of heat to stored energy (χ). Measured thermal and energetic performance under lasing and nonlasing conditions are presented, which agree with published theoretical expressions and measurements. Compensation of rod thermal lensing with simple spherical concave lenses is demonstrated. In addition various methods for compensating birefringence depolarization are theoretically and experimentally analyzed and compared. Received: 19 July 1999 / Revised version: 22 October 1999 / Published online: 23 February 2000