Intensities and pressure-broadened widths of CO2 R-branch lines at 15 μm from tunable laser measurements

Intensities and half-widths of individual lines, over the temperature range 200–325°K in the 15 μm bands of ¹²C¹⁶O₂, have been determined with a tunable diode laser spectrometer. Measurements were made on pure CO₂ and on dilute CO₂-in-N₂ mixtures on the R-branches of the 01¹0-00⁰0 and 02²0-01¹0 transitions. Intensities are approximately equal to those listed in the AFGL compilation. The pressure-broadened half-widths follow the general relationship $\text{b}{}_{\mathrm{L}}{}^0\text{(T) = b}{}_{\mathrm{L}}{}^0\text{(T}{}_0\text{) [}\text{T}{}_0\text{T}\text{]}{}^{\mathrm{n}}$ where n varies considerably from line to line but is always greater than $\text{1}\text{2}$.     

Valence band parameters and free exciton reduced mass of zinc telluride derived from free exciton magnetoreflectance

Reflectance spectra were measured on ZnTe in magnetic fields up to 18 T for B ? [100] and B ? [110]. The experiments yield renormalized valence band parameters $\text{γ}{}^1{}_2\text{= 0.83 ± 0.08}$ and $\text{γ}{}^1{}_3\text{= 1.30 ± 0.12}$, corresponding to bare parameters γ₂ = 0.95 ± 0.09 and γ₃ = 1.48 ± 0.14. From the free exciton Rydberg energy $\text{R}{}^1{}_0\text{= 12.8}\text{meV}$ we derive a reduced exciton polaron mass m₀ 0.080 ± 0.005 and a bare reduced mass m₀ 0.074 ± 0.005, corresponding to $\text{γ}{}^1{}_1\text{= 3.9 ± 0.7}$ and γ₁ = 4.4 ± 0.7 for an electron effective polaron mass $\text{m}{}^1{}_{\mathrm{e}}\text{= 0.116 m}{}_0$. We further calculate the exciton diamagnetic shift rate according to existing low-field theories modified by a variational calculation taking into account polaron effects and valid up to γ ? 1. The difference between experiment and theory is 10% and the agreement is considered satisfactory.     

Self-adjointness of the minimal Schrödinger operator with potential belonging to L1, loc

Let $\text{0 ?q(x) ∈L}{}_{\mathrm{1,loc}}\text{(}\text{R}{}^{\mathrm{m}}\text{)}$,m? 1.Consider the operatorT₀ = ?Δ+q with domain consisting of all bounded measurable functions $\text{u(x), x ∈}\text{R}{}^{\mathrm{m}}$, having bounded support, for which the distribution ?Δu+qu belongs to $\text{L}{}_2\text{(}\text{R}{}^{\mathrm{m}}\text{)}$. The main result of the paper is essential self-adjointness of $\text{T}{}_0\text{in L}{}_2\text{(}\text{R}{}^{\mathrm{m}}\text{)}$. The proof is independent of a method due to Kato who recently established the self-adjointness of a maximal Schrödinger operator corresponding to such potential.     

Line parameter measurements and calculations of CO broadened by nitrogen at elevated temperatures

Measurements of the line strengths and collisional broadening widths of CO in a N₂ atmosphere were made from 300 to 600 K. The lines studied were the P(2), P(3), P(7), P(12), P(18), and P(22) lines of the fundamental band at 2100 cm^?1. The absorption spectra were parametrically fit to a Voigt lineshape model. The band strength was determined to be 250±8 cm^?2atm^?1. The broadening results are compared to Anderson-Tsao-Curnutte calculations and to other experimental studies. The possibility of using an equation of the form $\text{γ(T)=γ(T}{}_0\text{(}\text{T}{}_0\text{T}\text{)}{}^{\mathrm{n}}$ to extrapolate the temperature dependence of the half-widths to flame temperatures is discussed.     

Optical detection of cyclotron resonance of electron and holes in CdTe

Cyclotron resonance of electron and holes have been optically detected at 70 GHz and at 1.8 K in n-type CdTe. The bare effective masses, in unit of the free electron mass, are found to be: $\text{m}{}^1\text{= 0.088 ± 0.004}$, $\text{m}{}^1{}_{\mathrm{lh}}\text{= 0.12 ± 0.01}$, $\text{m}{}^1\text{= 0.60 ± for H // <100>}$, and $\text{m}{}^1{}_{\mathrm{e}}\text{= 0.089 0.004}$, $\text{m}{}^1{}_{\mathrm{lh}}\text{= 0.11 ± 0.01}$, $\text{m}{}^1{}_{\mathrm{hh}}\text{= 0.69 ± 0.02}$ for H // <111>. The Luttinger valence band parameters deduced from these measurements are: γ₁ = 5.3 ± 0.5, γ₂ = 1.7 ± 0.3 and γ₃ = 2.0 ± 0.3, in fair agreement with the calculations of Lawaetz.     

Line parameter measurements and calculations of CO broadened by H2O and CO2 at elevated temperatures

Measurements of collisional broadening of four fundamental CO lines in atmospheres of CO₂ and H₂O at 300–600 K were made. The Voigt line-shape model was fitted parametrically to the absorption spectra line-shapes. The results are compared with other experimental studies and with theoretical calculations for CO₂ broadening. Absorption spectra of the exhaust gases of a flat flame were recorded and analyzed to yield CO concentration, temperature, and line half-widths. The flame spectra half-widths were compared with extrapolations of lower temperature data using the simple power law approximation $\text{γ(T)=γ(T}{}_0\text{) (}\text{T}{}_0\text{T}\text{)}{}^{\mathrm{n}}$. The utility of this approximation in the development of combustion diagnostic techniques is discussed.     

Polarization and polarization transfer in the 2H(d,n)3He reaction at 10 MeV

Angular distributions of six polarization transfer coefficients $\text{K}{}_{\mathrm{x}}{}^{\mathrm{x\prime }}\text{(θ), k}{}_{\mathrm{x}}{}^{\mathrm{z\prime }}\text{(θ), K}{}_{\mathrm{z}}{}^{\mathrm{<mtext>x</mtext><mtext>?</mtext>}}\text{(θ), K}{}_{\mathrm{z}}{}^{\mathrm{<mtext>z</mtext><mtext>?</mtext>}}\text{(θ),}\text{and}\text{K}{}_{\mathrm{yy}}{}^{\mathrm{<mtext>y</mtext><mtext>?</mtext>}}\text{(θ)}$; of the four analyzing powers A_y(θ), A_xx(θ), A_yy(θ), and A_zz(θ); and of the polarization function P^ý(θ), have been measured atE_d = 10.00 MeV for the reaction ²H(d, n)³He. Measurements were made for neutron lab angles between 0° and 80° in 10° steps. Additionally the y-axis associated quantities were measured at θ_1ab = 99°. Most of the measured coefficients are large at some angles and all show considerable variation with angle.     

Collision widths of CO lines broadened by water vapor at elevated temperatures

The collisional broadening by water vapor of the P(2), P(3), and P(7) absorption lines of the fundamental band of CO was studied at 7 temperatures ranging from 400 to 1000 K. The Lorentz halfwidth was determined by a parametric fit of the measured lineshape to the Voigt profile. The halfwidth at standard temperature was found by fitting the data for each line to $\text{γ(T}{}_0\text{)=γ(T)(}\text{T}\text{T}{}_0\text{)}{}^{\mathrm{-N}}$. The value of N for the P(2) line was found to be 0.7343±0.0067, for the P(3) line 0.70168±0.00073, and for the P(7) line 0.76686±0.00006.     

Determination of the fermi surface of monoclinic SrAs3 by Shubnikov dehaas effect

The electronic properties of single crystals of monoclinic SrAs₃ have been studied by investigating the temperature dependence of electrical conductivity, Hall effect and Shubnikov de Haas (SdH) oscillations. At 4.2 K, SrAs₃ is predominantly p-conducting with a typical hole concentration of 6 × 10¹⁷cm^-3. The Hall coefficient changes its sign near 80 K. The angular dependence of the SdH oscillations was used to map out the shape of the Fermi-surface of holes. Two asymmetric, quasi-ellipsoidal Fermi-bodies are located in the first Brillouin zone. The cyclotron effective masses $\text{m}{}^1$ for two crystallographic directions were calculated from the temperature dependence of the amplitude of the oscillations: $\text{m}{}^1\text{(B6a)=(0.70± 0.002)m}{}_0$and $\text{m}{}^1\text{(B6c}{}^1\text{)=(0.095±0.003)m}{}_0$, respectively. There are indications for a third Fermi-surface which is attributed to electrons.     

Temperature variation of the magnetic cluster structures in an iron-nickel invar alloy

Small-angle scattering of long wavelength neutrons $\text{(λ = 6.42}\text{A}\text{?}\text{)}$ from an Fe₆₅Ni₃₅ single crystal has been measured with the applied magnetic field (6.2 kG) parallel and perpendicular to the scattering vector $\text{K}$ of the elastic scattering over the temperature range from 25 to 422°C (T_c = 227°C). The scattering cross sections due to the longitudinal spin fluctuation have been analyzed by means of Guinier's approximation $\text{(dσ/dω)}{}_0\text{exp}\text{(?κ}{}^2\text{R}{}_{\mathrm{<mtext>g</mtext>}}{}^2\text{3}\text{)}$, where the forward cross section (dσ/dω)₀ is proportional to n, which is the number of atoms in a paramagnetic cluster, and R_g is the radius of gyration of the cluster. The empirical relation between n and R_g is = 0.298 × R_g^2.34 to be compared with that calculated for a simple spherical cluster model n = 1.274 R_g³.     

Hopping conductivity in amorphous carbon films

The electrical resistivity of amorphous carbon films getter-sputtered at 95°K is well fitted between 300 and 20°K by the relation $\text{? = ?}{}_0\text{exp}\text{[(T}{}_0\text{/T)}{}^{\mathrm{<mtext>1</mtext><mtext>4</mtext>}}\text{]}$ with T₀ ? 7 × 10⁷K. This behavior suggests a hopping conductivity very similar to that found in other amorphous semiconductors.     

Strengths and lorentz broadening coefficients for spectral lines in the ν3 and ν2 + ν4 bands of 12CH4 and 13CH4

Line strengths and self- and nitrogen-broadened half-widths were measured for spectral lines in the ν₃ and ν₂ + ν₄ bands of ¹²CH₄ and ¹³CH₄ from 2870–2883 cm^?1 using a tunable diode laser spectrometer. From measurements made over a temperature range from 215 to 297 K, on samples of ¹²CH₄ broadened with N₂, we deduced that the average temperature coefficients n, defined as $\text{b}{}_{\mathrm{<mtext>L</mtext>}}{}^0\text{(T) = b}{}_{\mathrm{<mtext>L</mtext>}}{}^0\text{(T}{}_0\text{)(}\text{T}\text{T}{}_0\text{)}{}^{\mathrm{?n}}$, of the Lorentz broadening coefficients for the ν₃ and ν₂ + ν₄ bands of ¹²CH₄ were 0.97 ± 0.03 and 0.89 ± 0.04, respectively. A smaller increase is observed in line half-width with increasing pressure for E-species lines, for both self- and nitrogen-broadening, than for other symmetry species lines over the range of pressures measured, 70 to 100 Torr.     

Nuclear matrix elements from L/K electron capture ratios in 59Ni decay

Using a recent theoretical method, the ratio of nuclear matrix elements $\text{R = (}{}^{\mathrm{v}}\text{F}{}^0{}_{220}\text{?√}\text{3}\text{2}{}^{\mathrm{A}}\text{F}{}^0{}_{221}\text{/}{}^{\mathrm{v}}\text{F}{}^0{}_{211}\text{)}$ was determined to be either 20.50^+0.35_?0.55 or 25.22^+0.28_?0.17 in the second-forbidden nonunique decay of 8 × 10⁴ y ⁵⁹Ni. These values of R were obtained from a value of L₃/K = 0.008 ± 0.002 found by subtracting the theoretical ratio $\text{(L}{}_1\text{+ L}{}_2\text{)}\text{K}$ = 0.113 (based on Q_PEC = 1070 ± 8 keV) from the total ratio L/K = 0.121 ± 0.002, which was measured with a reactor-produced, doubly-mass-separated ⁵⁹Ni source introduced as gaseous nickel-ocene, (C₅H₅)₂, into a wall-less, anticoincidence, multiwire proportional counter. The 854–1008 eV L and the 8.33 keV K peaks were measured simultaneously.     

A study of 3He capture in light nuclei

Excitation functions at θ = 90° have been measured for ${}^{16}\text{O}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0?2,\; 3?5,\; 6}}\text{)}{}^{19}\text{Ne}$, ${}^{15}\text{N}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0,\; 1?4}}\text{)}{}^{18}\text{F}\text{,}{}^{14}\text{N}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0,\; 1,2,3}}\text{)}{}^{17}\text{F}$, and ${}^{20}\text{Ne}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0\; +\; 1}}\text{)}{}^{23}\text{Mg}$, in the range E_{3He = 3–19 MeV}. The first reaction has also been studied at θ = 40°. Excitation functions at 90° have also been measured for and ${}^4\text{He}\text{(}{}^3\text{He}\text{, γ}{}_{\mathrm{0\; +\; 1}}\text{)}{}^7\text{Be}$ for E_3He = 19–26 MeV. Angular distributions have been measured for the first four reactions.For the most excitation functions, a broad peak is observed, several MeV wide, centred at about E_x≈ 20 MeV. Superimposed on this, in some cases, are narrower peaks, with width ≈ 1 MeV. Energies and widths have been extracted for all resonances.Cluster-model calculations have been carried out, using methods similar to those which have proved successful for low-lying states in A= 18–19 nuclei. No satisfactory correspondence with the present results was found. The shell model has been used to calculate Γ_3He and Γ_γ for 1?ω excitations in the final nuclei. These generally show good agreement with the trends of the experimental data. The results are consistent with the excitation of the giant dipole resonance in ³He capture, but much more weakly than in proton capture.     

Magnetization,magnetocrystalline anisotropy,magnetostriction and elastic constants of the Heusler alloy: Cu2Mn Al

Three kg of stoichiometric single crystals of Cu₂Mn Al have been grown by the Bridgman method. The thermal variations of their magnetization, anisotropy, magnetostriction and elastic constants have been measured between 4.2 and 300 K. This alloy exhibits a small magnetocrystalline anisotropy, but a large elastic anisotropy $\text{(}\text{C}{}^{\mathrm{?}}\text{C}{}^{\mathrm{\gamma }}\text{= 4.9)}$ which explains the strong anisotropy of the magnetostriction $\text{(}\text{λ}{}^{\mathrm{\gamma ,2}}\text{λ}{}^{\mathrm{?,2}}\text{= 10)}$. The magnetic moment per Mn atom at 0 K is 3.6 μ_B.     

Luminescence decay of distant donor-acceptor pairs in phosphorous-doped ZnTe

Luminescence decay of isolated donor-acceptor pairs has been measured over the range of pair distance R ～ 180 Å in phosphorous-doped ZnTe. Analysis of the recombination rate as a function of the pair distance suggests an asymptotic behaviour of the acceptor envelope function of the type exp(-r/a_A), with $\text{a}{}_{\mathrm{A}}\text{= 40 ± 10}\text{A}\text{?}$. This effective Bohr radius would correspond to an hydrogenic mass $\text{m}{}^1\text{= (0.13 ± 0.03)}\text{m}{}_{\mathrm{o}}$, which is close to the light hole mass as measured from cyclotron resonance experiments, $\text{m}{}^1\text{= (0.154 ± 0.005)}\text{m}{}_{\mathrm{o}}$. A discussion on the validity of the isolated donor-acceptor pair model is also given.     

Surface cyclotron resonance in Si under uniaxial stress

The cyclotron resonance of inversion-layer electrons on (100)p-type Si is found to depend sensitively on an externally applied compressive stress. At low temperatures (T ? 10 K) we observe a considerable increase of the cyclotron mass m¹_c with stress S along the [001] direction. The effect is most strongly observed at low electron densities n_s. For $\text{S～1.5 × 10}{}^9\text{dyne}\text{cm}{}^2$ and n_s～2 × 10¹¹cm^-2 we obtain $\text{m}{}^1{}_{\mathrm{c}}\text{～0.4 m}{}_0$ instead of the expected 0.2m₀. Along with this change of $\text{m}{}^1{}_{\mathrm{c}}$ a strong narrowing of the resonance is noted. Raising the temperature gives an additional n_s- dependent increase of $\text{m}{}^1{}_{\mathrm{c}}$.     

Cyclotron resonance observation on the electron lenses of molybdenum Fermi surface

Using a previously described transmission method, cyclotron resonance of electrons on the lens of the Fermi surface of molybdenum was observed. The resonance signals were recorded in Azbel-Kaner configuration with the magnetic field B parallel to the (110) plane of a monocrystal of thickness d = 0.15 mm.The effective mass of the electrons was determined as $\text{m>}{}^1\text{= (0.183 ± 0.002)m}{}_0\text{; m}{}^1\text{= (0.261 ± 0.008)m}{}_0$ and $\text{m}{}^1\text{= (0.29 ± 0.02)m}{}_0$ for B at angles of 0°; 3°; and 7.4° with respect to the crystallographical 〈110〉 direction. For these orientations of B and applying the method of cyclotron resonance cut-off observation, the dimensions of the electron lens were determined.     

Measurement of the background energy content of Nd-glass picosecond pulses with saturable absorbers

The background energy content of a mode-locked Nd-glass laser is determined with photodetectors and saturable absorbers. By comparing the signal height of a fast detector with the readout of an integrating energy meter the noise energy E_u2 outside the rise-time of the fast detector is measured. The background energy E_u1 within the rise-time is analysed by transmission measurements through two subsequent absorber cells. The obtained mean background to pulse energy (and intensity) ratios of ( and indicate a high degree of mode-locking.