Temperature and pressure dependence of the elastic property of GeS2 glass

The sound velocities in GeS₂ glass have been measured by means of ultrasonic interferometry as a function of temperature or pressure up to 1.8 kbar. The bulk modulus K_s = 117.6 kbar and shear modulus G = 60.60 kbar were obtained for GeS₂ glass at 15°C and 1 atm. The temperature derivatives of both sound velocities and elastic moduli are negative :

$\text{(}\text{?ν}{}_1\text{?T}\text{)}$

_p =

$\text{?1.54 × 10}{}^{\mathrm{?4}}\text{km}\text{sec}$

°C,

$\text{(}\text{?ν}{}_1\text{?T}\text{)}$

_p =

$\text{?1.27× 10}{}^{\mathrm{?4}}\text{km}\text{sec}$

°C and

$\text{(}\text{?K}{}_{\mathrm{s}}\text{?T}\text{)}$

_p =

$\text{?1.27 × 10}{}^{\mathrm{?2}}\text{kbar}\text{°C}$

,

$\text{(}\text{?G}\text{?T}\text{)}$

_p = ?1.23 × 10^?2 kbar/°C,

$\text{(}\text{?Y}\text{?T}\text{)}$

_p = ?2.93 × 10^?2 their pressure derivatives are positive:

$\text{(}\text{?ν}{}_1\text{?P}\text{)}$

_T = 4.43× 10^?2km/kbar,

$\text{(}\text{?ν}{}_1\text{?P}\text{)}$

_T =

$\text{0.633 × 10}{}^{\mathrm{?2}}\text{km}\text{kbar}$

and (?K_s?P0)_T=6.81,

$\text{(}\text{?G}\text{?P)}{}_{\mathrm{T}}$

= 1.03, (?Y?T_T= 3.57. The Grüneisen parameter, γ_th= 0.298, and the second Grüneisen parameter, δ_s = 3.27, have also been calculated from these data. The elastic behavior of GeS₂ glass has proved to be normal despite the structural similarity among the tetrahedrally coordinated SiO₂, GeO₂ and GeS₂ glasses.     

Surface temperature modulation in molecular beam relaxation spectrometry applied to catalytic decomposition of CH3OH on NiO

A new modification of molecular beam relaxation spectrometry (MBRS) of surface processes is described making use of partial modulation in order to study nonlinear processes: a constant particle beam is directed towards the catalyst surface, the surface temperature is modulated due to absorption of a modulated beam of UV light, reaction products are analyzed by use of phase sensitive mass spectrometric detection. The application of the method is shown by a study of catalytic decomposition of methanol on polycrystalline NiO. Formation of CO was found to be a monomolecular, formation of H₂ and H₂O bimolecular processes. The resulting mechanism may be described as follows:

Rate constants in dependence from surface temperature T₀ are η = 1.8 × 10³$\text{exp(?}\text{46}\text{RT}{}_{\mathrm{o}}\text{kJ}\text{mol}\text{)}$; k_d1 = 1.8 × 10¹⁰$\text{exp(?}\text{92}\text{RTl}{}_0\text{kJ}\text{mol}\text{)}$ s^?1; k_d2 = 1.2 × 10^?2$\text{exp (?}\text{88}\text{RT}{}_0\text{kJ}\text{mol}\text{)}$ cm² particles^?1 s^?1; k_d3 = 3.5 × 10^?4$\text{exp(?}\text{88}\text{RT}{}_0\text{kJ}\text{mol}\text{)}$ cm² particles^?1 s^?1. Average surface residence times of the intermediates are: $\text{27 ?}{}^{\mathrm{\tau }}\text{HCO}\text{}\text{?}\text{1 ms}$ at 550 ? T₀ ? 650 K; $\text{42 ?}{}^{\mathrm{\tau }}\text{H ? 7 ms}$ at 540 ?T₀ ? 610 K; $\text{177 ?}{}^{\mathrm{\tau }}\text{OH ? 19 ms}$ at 550 ? T₀ ? 645 K.     

Study of the photon spectrum in the decay KS0→π+π−γ

The branching ratio $\text{Λ(}\text{K}{}_{\mathrm{<mtext>S</mtext>}}{}^0\text{→π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{γ)}\text{Λ(}\text{K}{}_{\mathrm{<mtext>S</mtext>}}{}^0\text{→π}{}^{\mathrm{+}}\text{π}{}^{\mathrm{?}}\text{)}$ has been determined to be (2.68±0.15)×10^?3 for photon energies $\text{E}{}_{\mathrm{\gamma }}{}^1$ greater than 50 MeV in the K_S⁰ rest frame. The decay K_S⁰→π⁺π^?γ is found to be dominated by the internal bremsstrahlung transition. The branching rato of a possible direct transition is found to be less than 0.06 × 10^?3 at 90% confidence level for $\text{E}{}_{\mathrm{\gamma }}{}^1\text{> 50}\text{MeV}$.     

Polarization spectroscopy of the E0g+-B0u+ band system of Br2

The E-B (0_g⁺-0_u⁺) band system of Br₂ has been investigated at Doppler-limited resolution using polarization labeling spectroscopy. Merged E state data for the three naturally occurring isotopes in the range v_E = 0–16, expressed in terms of the constants for ⁷⁹Br₂, are (in cm^?1) Y_0,0 = 49 777.962(54), Y_1,0 = 150.834(22), Y_2,0 = ?0.4182(28), Y_3,0 = 6.6(11) × 10^?4, Y_0,1 = 4.1876(28) × 10^?2, Y_1,1 = ?1.607(16) × 10^?4, and Y_0,2 = 1.39(39) × 10^?8. The bond distance is $\text{r}{}_{\mathrm{<mtext>e</mtext>}}\text{= 3.194}\text{A}\text{?}$, and the diabatic dissociation energy to $\text{Br}{}^{\mathrm{+}}\text{(}{}^3\text{P}{}_2\text{) +}\text{Br}{}^{\mathrm{?}}\text{(}{}^1\text{S}{}_0\text{)}\text{is 34 700 cm}{}^{\mathrm{?1}}$.     

Excess low frequency conduction noise in a granular composite

Granular composites consisting of 25% nickel as 8 nm diameter particles dispersed in an aluminium oxide matrix display excess conduction noise. Co-deposited films with resistance per square about 10⁵ ohms and negative temperature coefficient show a noise power spectral density $\text{S}{}_{\mathrm{v}}\text{(?) =}\text{S}{}_{\mathrm{v}}\text{(1)}\text{?}{}^{\mathrm{\alpha }}$ where α ? 1.10 ± 0.03 over the accessible spectral range of 0.1 Hz ? ? ? 5000 Hz. The amplitude 3 × 10^?15 ? S_v(1) ? 5 × 10^?12 V²Hz^?1, appears to increase approximately quadratically as the applied voltage V_s up to V_s ? 2.5 V and as the first power of V_s for 2.5 ? V_s < 35 V.     

Vibrational spectra and force constants of symmetric tops: High resolution spectra of monoisotopic H3SiCl in the 2200-cm−1 region and rovibrational analysis of the ν1 and ν4 fundamentals

The gas phase infrared spectra of monoisotopic H₃Si³⁵Cl and H₃Si³⁷Cl have been studied in the $\text{ν}{}_1\text{ν}{}_4$ region near 2200 cm^?1 with a resolution of 0.012 and 0.04 cm^?1, respectively, and rotational fine structure for ΔJ = ±1 branches has been resolved. In addition, some information on ν₃ + ν₄ of H₃Si³⁵Cl near 2750 cm^?1 has been obtained. ν₁ and ν₄ are weakly coupled by Coriolis x, y resonance, $\text{B}\text{Ω}{}_{14}\text{ζ}{}_{14}\text{～ 2 × 10}{}^{\mathrm{?3}}\text{cm}{}^{\mathrm{?1}}$, only the upper states K′ = 2, l = 0 and K′ = 1, l = ?1 being substantially affected. Local perturbation due to rotational l(±1, ±1)-type resonance with ν₃ + ν₅⁺¹ + ν₆⁺¹ and ν₃ + ν₅⁺¹ + ν₆^?1 is revealed in the ΔK = +1 and ?1 branches, respectively. From a fit of the experimental line positions, standard deviations of 1.4 and 3.8 × 10^?3 cm^?1, respectively, to a model with five interacting levels conventional excited state parameters and interaction constants have been obtained. In $\text{H}{}_3\text{Si}{}^{35}\text{Cl}\text{H}{}_3\text{Si}{}^{37}\text{Cl}$ the fundamentals are ν₁, $\text{2201.94380(15)}\text{2201.9345(7)}$ and ν₄, $\text{2209.63862(8)}\text{2209.6254(2)}\text{cm}{}^{\mathrm{?1}}$, respectively. Q branches of the “hot” band (ν₃ + ν₄) ? ν₃ and of ν₄ of the ²⁹Si and ³⁰Si species have been detected.     

Ω− produced in K−p reactions at 4.2 GeV/c

Forty $\text{Ω}{}^{\mathrm{?}}$ events have been observed in a large (133 events/βb) experiment at 4.2 GeV/c incident K^? momentum. Thirty nine of the events come from the three-body reaction $\text{K}{}^{\mathrm{?}}\text{p}\text{→Ω}{}^{\mathrm{?}}\text{K}{}^{\mathrm{+}}\text{K}{}^0$. The $\text{Ω}{}^{\mathrm{?}}$ is mainly produced in the forward hemisphere (direction of the incident K^?). The lifetime is measured to be τ = (0.75 _+0.14?0.11 × 10^?10 sec substantially less than the Particle Data Group value of (1.3 _?0.3^+0.2) × 10^?10 sec. The mass is determined to be 1671.7 ± 0.6 MeV, in good agreement with other determinations. The decay asymmetry parameter α (for the decay mode $\text{Ω}{}^{\mathrm{?}}\text{→ Λ}\text{K}{}^{\mathrm{?}}$) is found to be ?0.2 ± 0.4.     

Electrical conductivity and chemical diffusion coefficient measurements in single crystalline nickel oxide at high temperatures

Electrical conductivity measurements on nickel oxide have been performed at high temperatures (1273 K<T< 1673 K) and in partial pressures of oxygen ranging from Po₂ = 1.89 × 10^?4 atm to Po₂ = 1 atm. The $\text{po}{}_2{}^{\mathrm{<mtext>1</mtext><mtext>n</mtext>}}$ dependence of the conductivity decreases from about $\text{1}\text{4}$ for Po₂ = 1 atm to smaller values for lower partial pressures of oxygen. The activation enthalpy for conduction increases for decreasing oxygen partial pressures (from 22.5 kcal mol^?1 at Po₂ = 1 atm to 26.0 kcal mol^?1 for Po₂ = 1.89 × 10^?4 atm). This behaviour can be explained by the simultaneous presence of singly and doubly ionized nickel vacancies, with different energies of formation.Furthermore, chemical diffusion coefficient measurements have been performed in the same temperature range, using the conductivity technique, and leading to the result:

$\text{D}\text{?}\text{= 0.244 exp (?}\text{36,600}\text{RT}\text{) cm}{}^2\text{s}{}^{\mathrm{?1}}$

.     

Centrifugal distortion effects in the hyperfine spectrum of KCl

The hyperfine spectrum of KCl has been examined at near-zero electric field and zero magnetic field using a molecular beam electric resonance spectrometer. Rotational as well as vibrational shifts have been observed in both nuclear quadrupole interactions. With $\text{eqQ = Q}{}_{00}\text{+ Q}{}_{10}\text{(v +}\text{1}\text{2}\text{) + Q}{}_{20}\text{(v +}\text{1}\text{2}\text{)}{}^2\text{+ Q}{}_{01}\text{J(J + 1)}$, we find (all in units of kHz) for K in ³⁹K³⁵Cl: Q₀₀ = ?5691.47 ± 0.04, Q₁₀ = 51.32 ± 0.06, Q₂₀ = ?0.205 ± 0.020, Q₀₁ = 0.014 ± 0.007, Q₀₀(K³⁷Cl) ? Q₀₀(K³⁵Cl) = ?0.03 ± 0.07; for Cl in ³⁹K³⁵Cl: Q₀₀ = 137.0 ± 0.3, Q₁₀ = ?163.2 ± 0.5, Q₂₀ = 1.57 ± 0.15, Q₀₁ = 0.07 ± 0.03, $\text{[}\text{Q(}{}^{35}\text{Cl}\text{)}\text{Q(}{}^{37}\text{Cl}\text{)}\text{]Q}{}_{00}\text{(}\text{K}{}^{37}\text{Cl}\text{) ? Q}{}_{00}\text{(}\text{K}{}^{35}\text{Cl}\text{) = ?0.5 ± 0.6}$; and magnetic constants c_K = 0.154 ± 0.007, c_Cl = 0.435 ± 0.010, c₃ = 0.035 ± 0.012, and c₄ = 0.009 ± 0.006. These have been used to provide a mapping of the field gradients at both nuclear sites to fourth order in $\text{ξ =}\text{(r ? r}{}_{\mathrm{e}}\text{)}\text{r}{}_{\mathrm{e}}$. We find eQq_K(ξ) = (?5692.5 ± 2.5) + (1.7 ± 0.8) × 10⁴ξ + (?2. ± 4.) × 10⁴ξ² + (?8. ± 18.) × 10⁵ξ³ + (8. ± 15.) × 10⁶ξ⁴ and eQq_Cl(ξ) = (120. ± 22.) + (8. ± 4.) × 10⁴ξ + (?5.8 ± 2.0) × 10⁵ξ² + (?1.1 ± 1.6) × 10⁷ξ³ + (1.1 ± 1.3) × 10⁸ξ⁴.     

Critical behaviour of a uniaxial ferromagnet,ErCl3·6H2O with predominant dipolar interactions

The parallel magnetic susceptibility χ of a uniaxial ferromagnet ErCl₃·6H₂O has been measured between 0.3 and 4.2K and specially near T_c = 0.353 K. The predominant contribution to the Curie-Weiss temperature is due to the dipolar interactions. χ is proportional to ?^?γ with $\text{? =}\text{T}\text{T}{}_{\mathrm{c}}\text{?1}$ in the range 10^?3 < ? < 5 × 10^?2. The γ value, γ = 1.01 ±0.03 is consistent with the theoretical prediction for a uniaxial dipolar ferromagnet.     

Nuclear spin-lattice relaxation of Co59 in CoB

We report the result of the Co⁵⁹ nuclear spin-lattice relaxation time T₁ measurements in the diamagnetic monoboride CoB. The analysis of the data, in the 4.2–300 K temperature range, allows us to separate three contributions to the relaxation rate: first a Korringa process, (T_1KT)^?1= 0.21 sec^?1K^?1 (in good agreement with the temperature independent isotropic Knight shift) from which we deduced the Co⁵⁹ hyperfine constant A=6.2 ×10^?6eV, second an impurity contribution independent of temperature and third a quadrupolar term, $\text{T}{}^{\mathrm{?1}}{}_{\mathrm{1Q}}\text{=3560 (}\text{T}\text{θ}{}_{\mathrm{D}}\text{)}{}^2\text{E(}\text{T}\text{θ}{}_{\mathrm{D}}\text{) sec}{}^{\mathrm{?1}}$, which is predominant at high temperature and well explained by the Van Kranendonk theory. It seems that it was the first time that such a quadrupolar effect was detected in a metallic compound. A remarkable coherency between Lundquist's three bands model and our experimental results has to be noted.     

The bending vibration bands ν4 and ν5 of HCCI

The bending vibration bands ν₄ and ν₅ of HCCI were studied. From the observed rotational structure the rotational constant B₀ and the centrifugal distortion constant D₀ were obtained. The results were B₀ = 0.105968(7) cm^?1 and D₀ = 1.96(7) × 10^?8 cm^?1 from ν₄ and B₀ = 0.105948(8) cm^?1 and D₀ = 1.96(11) × 10^?8 cm^?1 from ν₅. The structure of the hot bands 2ν₅(Δ) ← ν₅(Π) and 3ν₅(φ) ← 2ν₅(Δ) was also resolved and hence the values α₅ = ?3.033(8) × 10^?4 cm^?1 and q₅ = 9.3(3) × 10^?5 cm^?1 could be derived. The other most intense hot bands following ν₅ could be explained in terms of the Fermi diads $\text{ν}{}_3\text{2ν}{}_5{}^0$ and $\text{ν}{}_3\text{+}\text{ν}{}_5{}^{\mathrm{\pm 1}}\text{3ν}{}_5{}^{\mathrm{\pm 1}}$. Of the numerous hot bands accompanying ν₄, only those between different excited states of ν₄ could be assigned. Then estimates for α₄ and q₄ were also obtained. In addition, several vibrational constants were derived.     

Pressure dependence of superconductivity in the pseudo-one-dimensional compound Tl2Mo6Se6

Measurements of the temperature and pressure dependences of the resistivity of the pseudo-one-dimensional ternary compound Tl₂Mo₆Se₆ are presented. We find that the conductivity parallel to the highly conducting c-axis is enhanced by pressure and the superconducting transition temperature T_c is suppressed by pressure at a rate $\text{?T}{}_{\mathrm{c}}\text{?P}\text{=?7.6×10}{}^{\mathrm{?5}}$ kbar^?1. These results are discussed in relation to the current models of transport in one-dimensional conductors.     

X-ray compressibility measurements of the graphite intercalates KC8 and KC24

The isothermal compressibilities of pristine graphite and stages 1 and 2 potassium-graphite have been measured at room temperature. Diamond anvil X-ray diffraction techniques were employed to determine the c-axis lattice constant as a function of hydrostatic pressure up to 12 kbar. The compressibilities $\text{k}{}_{\mathrm{c}}\text{?}\text{1}\text{C}{}_{33}$ were found to be (2.73±0.09)×10^-12, (2.13±0.09)×10^-12, (5.3±0.8)×10^-12 and $\text{(1.6±0.2)×10}{}^{-12}\text{cm}{}^2\text{dyn}$ for graphite, KC₈, stage 2 KC₂₄ and stage 3 KC₂₄, respectively. The compressibility of KC₈ was comparable to that of RbC₈ deduced from neutron scattering experiments.     

The reactions K−p → K1− + nucleon at 3.13 and 3.3 GeV/c

Results are presented of a 12 event/μb bubble-chamber experiment; the reactions discussed in detail are $\text{K}{}^{\mathrm{?}}\text{p}\text{→}\text{K}{}^1\text{(890)}{}^{\mathrm{?}}\text{p, K}{}^1\text{(1420)}{}^{\mathrm{?}}\text{p and K}{}^1\text{(890)}{}^{\mathrm{?}}\text{Δ}{}^{\mathrm{+}}$.The K¹ (890)^?p channel is dominated by the forward peak. The suggestion of flattering at cos θ = 1 is more pronounced in $\text{(?}{}_{11}\text{+ ?}{}_{\mathrm{1?1}}\text{)}\text{d}\text{σ}\text{d}\text{t}$; which is mainly natural-parity exchange. Pseudoscalar exchange contributes to $\text{?}{}_{00}{}^{\mathrm{J}}\text{d}\text{σ}\text{d}\text{t}$; this is more sharply peaked in t. The value of $\text{(?}{}_{11}\text{? ?}{}_{\mathrm{1?1}}\text{)}\text{d}\text{σ}\text{d}\text{t}$ is somewhat larger than the upper limit from the dominant natural-parity exchange. There is significant structure in $\text{?}{}_{00}{}^{\mathrm{H}}\text{d}\text{σ}\text{d}\text{t}\text{at}\text{t ≈ ?0.6 (}\text{GeV}\text{/c)}{}^2$.The K¹ (1420)^?p channel is much more pronounced at 3.3 GeV/c than at 3.13 GeV/c, but is not markedly peripheral. The width of the K¹ (1420) in the 3.3 GeV/c data is 42 ± 12 MeV/c².The cross section for $\text{K}{}^{\mathrm{1?}}\text{Δ}{}^{\mathrm{+}}$ agrees with that expected from $\text{K}{}^{\mathrm{+}}\text{p}\text{→}\text{K}{}^1\text{Δ}$, assuming a single t-channel exchange. Our measured density matrix elements are consistent with a strong pseudoscalar exchange.     

Infrared bands of 12C2HD

The rotational structure of about 40 bands of ¹²C₂HD observed in the region 6000?600 cm^?1 has been measured and interpreted with the purpose of determining a comprehensive set of molecular constants for this isotopic variety of acetylene. Combining these data with the results for ¹²C₂H₂ and ¹²C₂D₂, a reevaluation of the equilibrium internuclear distances for the acetylene molecule has been made: $\text{r}{}_{\mathrm{e}}\text{(CH) = 1.06215 ± 17 × 10}{}^{\mathrm{?5}}\text{A}\text{?}$ and $\text{r}{}_{\mathrm{e}}\text{(CC) = 1.20257 ± 9 × 10}{}^{\mathrm{?5}}\text{A}\text{?}$ were obtained. This paper presents all the molecular constants derived in this study.     

Optical absorption spectrum of hematite, αFe2O3 near IR to UV

Optical absorption spectra have been measured on thin (011) single crystal platelets and on highly oriented (110) thin films of αFe₂O₃. We have observed and assigned some of the absorption bands predicted by ligand field theory and SCF-Xα calculations. The temperature dependence of the 11760 cm^?1 single crystal band has been fitted to the function $\text{? = ?}{}_0\text{(1 + exp (?}\text{θ}\text{T}\text{))}$ with $\text{?}{}_0\text{= 0.85 × 10}{}^{\mathrm{?4}}$ and θ = 200 K (139 cm^?1). We have measured the photocurrent as a function of wavelength and have found several peaks that coincide with optical absorption bands.     

A partial-wave analysis of the reaction π−p → K+K−n measured on a polarized target at ∼18 GeV/c

The reaction π^?p→K⁺K^?n has been studied on a hydrogen target (27 000 events) at 18.4 GeV/c and on a polarized target (54 000 events) at 17.2 GeV/c. A combination of results of both experiments allows a partial-wave analysis of the K⁺K^? system between 1.1 and 1.74 GeV mass without any model assumptions. In general our fits yield unique solutions. Using results of our previous analysis of π⁺π^? final states and assuming the dominance of the positive G-parity states in the K⁺K^? system, the branching ratios $\text{BR}\text{(}\text{K}\text{K}\text{/ππ)}$ of partial waves into $\text{K}\text{K}\text{and}\text{ππ}$ are determined. The S-wave appears to be mainly a broad ε (1300) with $\text{BR}\text{(}\text{K K}\text{/ππ) = 0.068}{}_{\mathrm{?0.021}}{}^{\mathrm{+0.017}}$. The weak P-wave can be described by a tail of the $\text{?(770)}\text{with BR}\text{(}\text{K K}\text{/ππ) = 0.081}{}_{\mathrm{?0.025}}{}^{\mathrm{+0.029}}$. The D-wave is interpreted in terms of a superposition of f(1270) + A₂(1310) + f′(1515) resonances. The fit yields $\text{BR}\text{(}\text{K K}\text{/ππ) = 0.069}{}_{\mathrm{?0.031}}{}^{\mathrm{+0.023}}$ for the f(1270) and BR(ππ/all) = 0.027_?0.013^+0.071 for the f′(1515). The F-wave shows the g(1690) meson with $\text{BR}\text{(}\text{K K}\text{/ππ) = 0.191}{}_{\mathrm{?0.037}}{}^{\mathrm{+0.040}}$. All the above values refer to the t bin between 0.01 and 0.20 (GeV/c)². Some results are also given for the high-t region.     

Rotation-vibration analysis of the Coriolis-coupled ν5g, ν6g, ν8g and ν9 bands of H2CCO

Medium resolution infrared grating spectra of gaseous ketene, H₂CCO were recorded between 1000 and 400 cm^?1, both at instrument temperature (40°C) and with cooling (?40°C). Interferometric Fourier spectra were also measured at ?70°C with resolution 0.22 cm^?1 between 450 and 330 cm^?1. The K structure of the fundamentals ν₅, ν₆, ν₈, and ν₉ was assigned. These fundamentals are coupled by a-axis Coriolis interactions. These couplings were analysed on the symmetric top basis for setting up the perturbation matrix and by utilizing the K-dependent Coriolis shifts of levels. A preliminary analysis of the Coriolis intensity anomalies was also undertaken.Band center values from combination differences are $\text{ν}{}_5{}^0\text{= 587.30 (27)}$ and $\text{ν}{}_6{}^0\text{= 528.36 (39)}\text{cm}{}^{\mathrm{?1}}$. Synthetic spectra indicate the band origins of ν₈ and ν₉ to be close to 977.8 and 439.0 cm^?1, respectively. Estimates of Coriolis coupling constants obtained from synthetic spectra are $\text{ζ}{}_{58}{}^{\mathrm{a}}\text{= + 0.33 (5)}$, $\text{ζ}{}_{68}{}^{\mathrm{a}}\text{= + 0.714 (20)}$, $\text{ζ}{}_{59}{}^{\mathrm{a}}\text{= ? 0.774 (20)}$, and $\text{ζ}{}_{69}{}^{\mathrm{a}}\text{= ? 0.30 (2)}$. Approximate ratios of unperturbed vibrational transition moments obtained from spectral simulations are $\text{M}{}_8{}^0\text{:±iM}{}_5{}^0\text{:±iM}{}_6{}^0\text{:M}{}_9{}^0\text{≈ +2:?9:+10:+0.5}$.     

Microwave optical double resonance and continuous wave dye laser excitation spectroscopy of NO2: Rotational assignment of the K = 0−4 subbands of the 593 nm band

A rotational assignment of approximately 80 lines with K_a′ = 0, 1, 2, 3, and 4 has been made of the 593 nm ${}^2\text{A}{}_1\text{→}{}^2\text{B}{}_2$ band of NO₂ using cw dye laser excitation and microwave optical double-resonance spectroscopy. Rotational constants for the ²B₂ state were obtained as A = 8.52 cm^?1, B = 0.458 cm^?1, and C = 0.388 cm^?1. Spin splittings for the K_a′ = 0 excited state levels fit a simple symmetric top formula and give $\text{(?}{}_{\mathrm{bb}}\text{+ ?}{}_{\mathrm{cc}}\text{)}\text{2}\text{= ?0.0483}\text{cm}{}^{\mathrm{?1}}$. Spin splittings for K_a′ = 1 (N′ even) are irregular and are shown to change sign between N′ = 6 and 8. Assuming that the large inertial defect of 4.66 amu Ų arises solely from A, a structure for the ²B₂ state is obtained which gives $\text{r}\text{(NO) = 1.35}\text{A}\text{?}$ and an ONO angle of 105°. Alternatively, weighting the three rotational constants equally gives $\text{r = 1.29}\text{A}\text{?}$ and θ = 118°.