The chemical zeno effect in exchange-bounded radical pairs: 2. Singlet and random radical pairs

Manifestations of the chemical Zeno effect (slowing down of the quantum evolution of radical pairs as a result of spin-selective recombination of exchange-bounded radical pairs) are considered. In radical pairs created in singlet and random spin states, the chemical kinetics is described by the sum of kinetic evolution (exponential) and oscillatory functions. The kinetic function is a superposition of two exponential functions. Recombination monotonically decreases the amplitude of quantum beats in singlet radical pairs. The dependence of the amplitude of quantum beats in noncorrelated radical pairs on the recombination rate constant is not monotonic.     

What does an observed quantum system reveal to its observer?

The evolution of a quantum system under observation becomes retarded or even impeded. We review this “quantum Zeno effect” in the light of the criticism that has been raised upon a previous attempt to demonstrate it, of later reexaminations of both the projection postulate and the significance of the observations, and of the results of a recent experiment on an individual cold atom. Here, the micro-state of the quantum system gets unveiled with the observation, and the effect of measurement is no longer mixed up with dephasing the object's wave function by the reactive effect of the detection. A procedure is outlined that promises to provide, by observation, an upper limit for the delay of even an exponential decay. Received 11 January 2001 and Received in final form 28 February 2001     

A Transactional Analysis of Interaction-Free Measurements

The transactional interpretation of quantum mechanics is applied to the “interaction-free” measurement scenario of Elitzur and Vaidman and to the Quantum Zeno effect version of the measurement scenario by Kwiat et al. It is shown that the non-classical information provided by the measurement scheme is supplied by the probing of the intervening object by incomplete offer and confirmation waves that do not form complete transactions or lead to real interactions.     

Hindered decay of an unstable system: A quantum zeno effect

A direct test of the so-called “quantum Zeno effect” is proposed for a truly decaying system. It is suggested that the lifetime of an unstable atom can be extended by illuminating it with an intense laser beam at the frequency of another of its transitions. The “Zeno” time is also compared to the lifetime     

Watching it boil: Continuous observation for the quantum zeno effect

The quantum Zeno effect (QZE) is often associated with the ironic maxim, “a watched pot never boils”, although the notion of “watching” suggests a continuous activity at odds with the usual (pulsed measurement) presentation of the QZE. We show how continuous watching can provide the same halting of decay as the usual QZE, and, for incomplete hindrance, we provide a precise connection between the interval between projections and the response time of the continuous observer. Thus, watching closely, but not so closely as to halt the “boiling”, is equivalent to—gives the same degree of partial hindrance as—pulsed measurements with a particular pulsing rate. Our demonstration is accomplished by treating the apparatus for the continuous watching as a fully quantum object. This in turn allows us a second perspective on the QZE, in which it is the modified level structure of the combined system/apparatus Hamiltonian that slows the decay. This and other considerations favor the characterization “dominated time evolution” for the QZE.     

Direct bandgap optical transitions in Si nanocrystals

The effect of quantum confinement on the direct bandgap of spherical Si nanocrystals has been modelled theoretically. We conclude that the energy of the direct bandgap at the Γ-point decreases with size reduction: quantum confinement enhances radiative recombination across the direct bandgap and introduces its “red“ shift for smaller grains. We postulate to identify the frequently reported efficient blue emission (F-band) from Si nanocrystals with this zero-phonon recombination. In a dedicated experiment, we confirm the “red“ shift of the F-band, supporting the proposed identification.     

Reality in quantum mechanics,Extended Everett Concept,and consciousness

Conceptual problems in quantum mechanics result from the specific quantum concept of reality and require, for their solution, including the observer’s consciousness into the quantum theory of measurements. Most naturally, this is achieved in the framework of Everett’s “many-world interpretation” of quantum mechanics. According to this interpretation, various classical alternatives are perceived by consciousness separately from each other. In the Extended Everett Concept (EEC) proposed by the present author, the separation of the alternatives is identified with the phenomenon of consciousness. This explains the classical character of the alternatives and unusual manifestations of consciousness arising “at the edge of consciousness” (i.e., in sleep or trance) when its access to “other alternative classical realities” (other Everett’s worlds) becomes feasible. Because of reversibility of quantum evolution in EEC, all time moments in the quantum world are equivalent, while the impression of flow of time appears only in consciousness. If it is assumed that consciousness may influence the probabilities of alternatives (which is consistent in case of infinitely many Everett’s worlds), EEC explains free will, “probabilistic miracles” (observing low-probability events), and decreasing entropy in the sphere of life. The text was submitted by the author in English.     

Super Universality of the Quantum Hall Effect and the?“Large N Picture” of the ? Angle

It is shown that the “massless chiral edge excitations” are an integral and universal aspect of the low energy dynamics of the ϑ vacuum that has historically gone unnoticed. Within the SU(M+N)/S(U(M)×U(N)) non-linear sigma model we introduce an effective theory of “edge excitations” that fundamentally explains the quantum Hall effect. In sharp contrast to the common beliefs in the field our results indicate that this macroscopic quantization phenomenon is, in fact, a super universal strong coupling feature of the ϑ angle with the replica limit M=N=0 only playing a role of secondary importance. To demonstrate super universality we revisit the large N expansion of the CP ^N−1 model. We obtain, for the first time, explicit scaling results for the quantum Hall effect including quantum criticality of the quantum Hall plateau transition. Consequently a scaling diagram is obtained describing the cross-over between the weak coupling “instanton phase” and the strong coupling “quantum Hall phase” of the large N theory. Our results are in accordance with the “instanton picture” of the ϑ angle but fundamentally invalidate all the ideas, expectations and conjectures that are based on the historical “large N picture.”     

Addressing the Clumsiness Loophole in a Leggett-Garg Test of Macrorealism

The rise of quantum information theory has lent new relevance to experimental tests for non-classicality, particularly in controversial cases such as adiabatic quantum computing superconducting circuits. The Leggett-Garg inequality is a “Bell inequality in time” designed to indicate whether a single quantum system behaves in a macrorealistic fashion. Unfortunately, a violation of the inequality can only show that the system is either (i) non-macrorealistic or (ii) macrorealistic but subjected to a measurement technique that happens to disturb the system. The “clumsiness” loophole (ii) provides reliable refuge for the stubborn macrorealist, who can invoke it to brand recent experimental and theoretical work on the Leggett-Garg test inconclusive. Here, we present a revised Leggett-Garg protocol that permits one to conclude that a system is either (i) non-macrorealistic or (ii) macrorealistic but with the property that two seemingly non-invasive measurements can somehow collude and strongly disturb the system. By providing an explicit check of the invasiveness of the measurements, the protocol replaces the clumsiness loophole with a significantly smaller “collusion” loophole.     

Quantum sets and clifford algebras

The mathematical language presently used for quantum physics is a high-level language. As a lowest-level or basic language I construct a quantum set theory in three stages: (1) Classical set theory, formulated as a Clifford algebra of “S numbers” generated by a single monadic operation, “bracing,” Br = {…}. (2) Indefinite set theory, a modification of set theory dealing with the modal logical concept of possibility. (3) Quantum set theory. The quantum set is constructed from the null set by the familiar quantum techniques of tensor product and antisymmetrization. There are both a Clifford and a Grassmann algebra with sets as basis elements. Rank and cardinality operators are analogous to Schroedinger coordinates of the theory, in that they are multiplication or “Q-type” operators. “P-type” operators analogous to Schroedinger momenta, in that they transform theQ-type quantities, are bracing (Br), Clifford multiplication by a setX, and the creator ofX, represented by Grassmann multiplicationc(X) by the setX. Br and its adjoint Br* form a Bose-Einstein canonical pair, andc(X) and its adjointc(X)* form a Fermi-Dirac or anticanonical pair. Many coefficient number systems can be employed in this quantization. I use the integers for a discrete quantum theory, with the usual complex quantum theory as limit. Quantum set theory may be applied to a quantum time space and a quantum automaton. This material is based upon work supported in part by NSF Grant No. PHY8007921.     

A global version of the quantum duality principle

The “quantum duality principle” states that a quantisation of a Lie bialgebra provides also a quantisation of the dual formal Poisson group and, conversely, a quantisation of a formal Poisson group yields a quantisation of the dual Lie bialgebra as well. We extend this to a much more general result: namely, for any principal ideal domainR and for each primepεR we establish an “inner” Galois’ correspondence on the categoryHA of torsionless Hopf algebras overR, using two functors (fromHA to itself) such that the image of the first and the second is the full subcategory of those Hopf algebras which are commutative and cocommutative, modulop, respectively (i.e., they are“quantum function algebras” (=QFA) and“quantum universal enveloping algebras” (=QUEA), atp, respectively). In particular we provide a machine to get two quantum groups — a QFA and a QUEA — out of any Hopf algebraH over a fieldk: apply the functors tok[ν] ⊗k H forp=ν. A relevant example occurring in quantum electro-dynamics is studied in some detail. Presented at the 10th International Colloquium on Quantum Groups: “Quantum Groups and Integrable Systems”, Prague, 21–23 June 2001     

Simulation of Topological Field Theories¶by Quantum Computers

Quantum computers will work by evolving a high tensor power of a small (e.g. two) dimensional Hilbert space by local gates, which can be implemented by applying a local Hamiltonian H for a time t. In contrast to this quantum engineering, the most abstract reaches of theoretical physics has spawned “topological models” having a finite dimensional internal state space with no natural tensor product structure and in which the evolution of the state is discrete, H≡ 0. These are called topological quantum field theories (TQFTs). These exotic physical systems are proved to be efficiently simulated on a quantum computer. The conclusion is two-fold: 1. TQFTs cannot be used to define a model of computation stronger than the usual quantum model “BQP”. 2. TQFTs provide a radically different way of looking at quantum computation. The rich mathematical structure of TQFTs might suggest a new quantum algorithm. Received: 4 May 2001 / Accepted: 16 January 2002     

Shiva diagrams for composite-boson many-body effects: how they work

The purpose of this paper is to show how the diagrammatic expansion in fermion exchanges of scalar products of N-composite-boson (“coboson”) states can be obtained in a practical way. The hard algebra on which this expansion is based, will be given in an independent publication. Due to the composite nature of the particles, the scalar products of N-coboson states do not reduce to a set of Kronecker symbols, as for elementary bosons, but contain subtle exchange terms between two or more cobosons. These terms originate from Pauli exclusion between the fermionic components of the particles. While our many-body theory for composite bosons leads to write these scalar products as complicated sums of products of “Pauli scatterings” between two cobosons, they in fact correspond to fermion exchanges between any number P of quantum particles, with 2 ≤P≤N. These P-body exchanges are nicely represented by the so-called “Shiva diagrams”, which are topologically different from Feynman diagrams, due to the intrinsic many-body nature of the Pauli exclusion from which they originate. These Shiva diagrams in fact constitute the novel part of our composite-exciton many-body theory which was up to now missing to get its full diagrammatic representation. Using them, we can now “see” through diagrams the physics of any quantity in which enters N interacting excitons — or more generally N composite bosons —, with fermion exchanges included in an exact — and transparent — way.     

Limited Holism and Real-Vector-Space Quantum Theory

Quantum theory has the property of “local tomography”: the state of any composite system can be reconstructed from the statistics of measurements on the individual components. In this respect the holism of quantum theory is limited. We consider in this paper a class of theories more holistic than quantum theory in that they are constrained only by “bilocal tomography”: the state of any composite system is determined by the statistics of measurements on pairs of components. Under a few auxiliary assumptions, we derive certain general features of such theories. In particular, we show how the number of state parameters can depend on the number of perfectly distinguishable states. We also show that real-vector-space quantum theory, while not locally tomographic, is bilocally tomographic.     

On the superfluidity of classical liquid in nanotubes,I. Case of even number of neutrons

We show that the superfluidity effect in nanotubes arises in a classical liquid (regarded as the limit as h → 0 of the quantum liquid) and involves not only the Bogolyubov “running waves,” but also a “standing wave.” This is obtained from the variational equations in the context of ultrasecondary quantization. It is stressed that the “atomic” size of the nanotube plays a crucial role in the phenomena.     

On the superfluidity of classical liquid in nanotubes,II. Case of odd number of neutrons

We show that the superfluidity effect in nanotubes arises in a classical liquid (regarded as the limit as h → 0 of the quantum liquid) and involves not only the Bogolyubov “running waves,” but also a “standing wave.” This is obtained from the variational equations in the context of ultrasecondary quantization. We consider cases of Bose and Fermi liquids.     

Experimental investigation of ligand effects on the conversion electron spectrum of the 22.5 keV M1 + E2 nuclear transition in <Superscript>149</Superscript>Sm

The conversion electron spectrum of the 22.5keV M1 + E2 nuclear transition in ¹⁴⁹Sm from the electron capture decay of ¹⁴⁹Eu was experimentally studied for the “Eu₂O₃” and “EuF₃” compounds in which ¹⁴⁹Eu ions have the same assumed oxidation number +3 . While the energies of the L, M, N, O, and P₁ conversion lines for “EuF₃” were lower, on average, by 1.7(1), 2.7(2), 2.3(3), 4.1(2), and 5.7(9)eV, respectively, than those for “Eu₂O₃”, no changes between the two ligand complexes were observed for relative intensities of the conversion lines and their natural widths within the error limits.     

Quantum chemical modelling of “green” luminescence in ABO perovskites

The origin of the intrinsic excitonic (“green”) luminescence in ABO₃ perovskites remains a hot topic over the last quarter of a century. We suggest as a theoretical interpretation for the “green” luminescence in these crystals, the recombination of electron and hole polarons forming a charge transfer vibronic exciton. In order to check quantitatively the proposed model, we performed quantum chemical calculations using the Intermediate Neglect of Differential Overlap (INDO) method combined with the periodic defect model. The luminescence energies calculated for four perovskite crystals are found to be in good agreement with experimental data. Received 19 December 2001 and Received in final form 14 March 2002 Published online 25 June 2002     

Local Wick Polynomials and Time Ordered Products¶of Quantum Fields in Curved Spacetime

In order to have well defined rules for the perturbative calculation of quantities of interest in an interacting quantum field theory in curved spacetime, it is necessary to construct Wick polynomials and their time ordered products for the noninteracting theory. A construction of these quantities has recently been given by Brunetti, Fredenhagen, and K?hler, and by Brunetti and Fredenhagen, but they did not impose any “locality” or “covariance” condition in their constructions. As a consequence, their construction of time ordered products contained ambiguities involving arbitrary functions of spacetime point rather than arbitrary parameters. In this paper, we construct an “extended Wick polynomial algebra”– large enough to contain the Wick polynomials and their time ordered products – by generalizing a construction of Dütsch and Fredenhagen to curved spacetime. We then define the notion of a local, covariant quantum field, and seek a definition of local Wick polynomials and their time ordered products as local, covariant quantum fields. We introduce a new notion of the scaling behavior of a local, covariant quantum field, and impose scaling requirements on our local Wick polynomials and their time ordered products as well as certain additional requirements – such as commutation relations with the free field and appropriate continuity properties under variations of the spacetime metric. For a given polynomial order in powers of the field, we prove that these conditions uniquely determine the local Wick polynomials and their time ordered products up to a finite number of parameters. (These parameters correspond to the usual renormalization ambiguities occurring in Minkowski spacetime together with additional parameters corresponding to the coupling of the field to curvature.) We also prove existence of local Wick polynomials. However, the issue of existence of local time ordered products is deferred to a future investigation. Received: 27 March 2001 / Accepted: 6 June 2001