Electron Paramagnetic Resonance and Electron Spin Echo Studies of Co2+ Coordination by Nicotinamide Adenine Dinucleotide (NAD+) in Water Solution

Co²⁺ binding to the nicotinamide adenine dinucleotide (NAD⁺) molecule in water solution was studied by electron paramagnetic resonance (EPR) and electron spin echo at low temperatures. Cobalt is coordinated by NAD⁺ when the metal is in excess only, but even in such conditions, the Co/NAD⁺ complexes coexist with Co(H₂O)₆ complexes. EPR spin-Hamiltonian parameters of the Co/NAD⁺ complex at 6 K are g _z  = 2.01, g _x  = 2.38, g _y  = 3.06, A _z  = 94 × 10^?4 cm^?1, A _x  = 33 × 10^?4 cm^?1 and A _y  = 71 × 10^?4 cm^?1. They indicate the low-spin Co²⁺ configuration with S = 1/2. Electron spin echo envelope modulation spectroscopy with Fourier transform of the modulated spin echo decay shows a strong coordination by nitrogen atoms and excludes the coordination by phosphate and/or amide groups. Thus, Co²⁺ ion is coordinated in pseudo-tetrahedral geometry by four nitrogen atoms of adenine rings of two NAD⁺ molecules.     

ESR of V3+ in zinc oxide single crystals

Electron spin resonance has been investigated in zinc oxide single crystals containing vanadium. Several groups of ordinary and forbidden transitions can be observed. The experimental results are interpreted with the aid of the spin Hamiltonian, for which the following parameters were determined:g∥=1.945; ⊥=1.937; ¦D¦=750×10^?4 cm^?1, ¦A¦=68 × 10^?4 cm^?1; ¦B ¦=93×10^?4 cm^?1; ¦A?P¦=65×10^?4cm^?1.     

Interaction of slow neutrons with natural Rutenium,Rhodium, Cadmium and Thallium and some of their isotopes

By means of Christiansen filter technique the following bound coherent neutron scattering lengths were obtained:^natRu:b=7.02 ± 0.02 fm¹⁰⁸Cd:b=5.31 ± 0.24 fm¹⁰³Rh:b=5.90 ± 0.04 fm¹¹⁰Cd:b=5.78 ± 0.08 fm^natTl:b=8.773 ± 0.015 fm¹¹¹Cd:b=6.47 ± 0.08 fm²⁰³Tl:b=8.51 ± 0.08 fm¹¹²Cd:b=6.34 ± 0.06 fm²⁰⁵Tl:b=8.87 ± 0.07 fm¹¹⁴Cd:b=7.48 ± 0.05 fm¹¹⁶Cd:b=6.26 ± 0.09 fm In combination with some total cross section measurements with neutrons in the eV-energy range and with the compiled resonance parameters we deduced consistent sets of spin state scattering lengths and potential radii.     

Study of the ρ, ω, ϕ→ηγ→7γ decays with an SND detector on a VEPP-2M collider

The e ⁺ e ^?→ηγ→7γ process was studied in the energy range 2E=600–1060 MeV with an SND detector on a VEPP-2M e ⁺ e ^? collider. The decay branching ratios B(φ→ηγ)=(1.353±0.011±0.052)×10^?2, B(ω→ηγ)=(4.62±0.71±0.18)×10^?4, and B(ρ→ηγ)=(2.73±0.31±0.15)×10^?4 were measured.     

Static quadrupole moments of the first excited states of 200Hg and 202Hg

The static quadrupole moments Q_2⁺ and B(E2; 0⁺ → 2⁺) values of the 2⁺ first excited states of ²⁰⁰Hg and ²⁰²Hg have been determined using the reorientation effect in Coulomb excitation. An annular silicon surface-barrier detector was used to detect backscattered ⁴He, ¹²C and ¹⁶O projectiles. It is found that for ²⁰⁰Hg, Q_2⁺ = +1.07 ± 0.19 e · b(+0.98 ± 0.19 e · b) for destructive (constructive) interference from the 2^+′ state, and B(E2; 0⁺ → 2⁺) = 0.853 ± 0.007 e² · b². For ²⁰²Hg, we find Q_2⁺ = +1.01 ± 0.13 e · b (+0.87 ± 0.13 e · b) and B(E2; 0⁺ → 2⁺) = 0.605 ± 0.005 e² · b². The Q_2⁺ value obtained for ²⁰⁰Hg is in agreement with previous work, but that for ²⁰²Hg is not. The results obtained are compared with the predictions of various nuclear models, and the mass dependence of Q_2⁺ in the region 182 ≦ A ≦ 206 is examined.     

EPR of Cu2+ Impurities in Cytosine Hydrochloride: A Case of Superhyperfine Structure

Electron paramagnetic resonance spectra of Cu²⁺ impurities in cytosine hydrochloride single crystals are observed at liquid nitrogen temperature. Two magnetically equivalent sites for Cu²⁺ have been observed. The parameters of ⁶³Cu obtained with the fitting of spectra to rhombic symmetry spin Hamiltonian are: g _x  = 2.047 ± 0.002, g _y  = 2.187 ± 0.002, g _z  = 2.390 ± 0.002, A _x  = (86 ± 3) × 10^?4 cm^?1, A _y  = (87 ± 3) × 10^?4 cm^?1, and A _z  = (138 ± 3) × 10^?4 cm^?1. The observed bands in optical spectra of the single crystal recorded at room temperature are assigned to various d–d and charge-transfer transitions. Using both EPR and optical data, the nature of bonding of metal ion with different ligands is discussed.     

Effect of the ionic radius on jump frequencies of alkaline earth cations in NaCl crystals

By comparing diffusion coefficientsD of bivalent cations Ba²⁺, Ca²⁺, Sr²⁺ in NaCl crystals it was shown that in the temperature range above 550 °CD (Ba²⁺)>D (Sr²⁺)>D (Ca²⁺) is valid. Temperature dependences of jump frequenciesw ₂ of these cations are described byw ₂ (Ba²⁺)=(2·15±0·55) × 10¹² × exp {?(0·817±0.007)/kT};w ₂ (Sr²⁺)=(2·9±1·1) × 10¹² × exp {?(0·84±0.02)/kT} andw ₂ (Ca²⁺)=(5·5±6·5) × 10¹⁰ × exp {?(0·51±0·07)/kT}. It was demonstrated that in NaCl crystals the activation enthalpy and the preexponential factor of the jump frequencyw ₂ increase with increasing ionic radius and mass of the bivalent alkaline earth cation.     

Measurement of the D0, D+ and Ds+ meson lifetimes at √s = 10.58 GeV

We have measured the lifetimes of the D⁰, D⁺ and D_s⁺ mesons with data from the CLEO detector. We find τ_D⁰ = (5.0 ± 0.7 ± 0.4) × 10⁻¹³s, τ_D⁺ = (11.4 ± 1.6 ± 0.7) × 10⁻¹³s and τ_Ds⁺ = (4.7 ± 2.2 ± 0.5) × 10⁻¹³s, giving lifetime ratios τ_D⁺/τ_D⁰ = 2.3 ± 0.5 and τ_Ds⁺/τ_D⁰ = 0.9 ± 0.5.     

Changes in mean-square nuclear charge radii in Er from optical isotope shifts by laser-atomic-beam spectroscopy

High-resolution laser-atomic-beam spectroscopy has been applied to investigate transitions 4f ¹² 6s ²?4f ¹¹ 5d6s ² and transitions starting from metastable states of the configuration 4f ¹¹ 5d6s ² of Er I. Precise values for the transition isotope shifts and for the hyperfine constants of 10 levels belonging to the configuration 4f ¹¹ 5d6s² and 9 levels belonging to high lying even-parity levels have been determined. From the isotope shift data relative changes of mean-square nuclear charge radiiδ 〈r ²〉 for all the stable Er isotopes have been deduced: ¦168,170¦ 1, ¦166,168¦ 0.984(15), ¦164,166¦ 0.984(15), ¦162,164¦ 1.198(18), ¦166,167¦ 0.3357(50). Absoluteδ 〈r ²〉 values have been obtained by calibrating the optical data with a value from muonic x-ray spectroscopy: ¦168,170¦ 0.121 (10) fm². The odd-even staggering parameter for¹⁶⁷Er has been determined: 0.683(10). Our results are compared with experimental data from electronic x-ray spectroscopy and data from calculations with the extended liquid-drop and the droplet model.     

Iodine as a donor in CdS

Iodine doped single crystals of CdS were grown from the vapor phase. High temperature Hall effect measurements for the crystals equilibrated with Cd and S₂ vapors at temperatures between 700 and 1000°C gave the free electron concentration as a function of p_Cd or p_S2 and temperature. The results can be explained on the basis of a model in which the CdS is saturated with iodine at low p_Cd (=high p_S2) but unsaturated at high p_Cd.The solubility of iodine in CdS is given by c_t=1·73×10²²p_S2^?1/8 exp (?1·045 eV/kT) cm^?3 atm^?1/8=4·62×10¹⁹p_Cd^1/4 exp (?0·195 eV/kT) cm^?3 atm^1/4The formation of pairs (I_SV_Cd)′ from I_S^· and V_Cd″ is governed by the equilibrium constant K_{P(I, V)}=4 exp (≤1·1 eV/kT)If Cd diffusion occurs primarily by free vacancies, the Cd^* tracer self diffusion leads to a vacancy mobility of (1·2±0·5)×10^?5 cm² sec^?1 at 900°C, in agreement with results reported by Woodbury [12], but (7±3) times larger than reported by Kumar and Kroger [10].     

ESR study of vanadyl ion in tripotassium citrate

ESR spectra of VO²⁺ doped tripotassium citrate are recorded at room temperature. The observed spectra are fitted to a spin Hamiltonian of orthorhombic symmetry with g_x = 2.001 ± 0.001, g_y = 1.997 ± 0.001, g_z = 1.945 ± 0.001, A_x = (49.0 ± 1) × 10⁻⁴ cm⁻¹, A_y = (66.8 ± 1) × 10⁻⁴ cm⁻¹ and A_z = (168.4 ± 1) × 10⁻⁴ cm⁻¹. The covalency and Fermi contact terms are evaluated and compared with those of other lattices.     

Double beta decay of 96Zr

After 10357 h of running the NEMO-2 tracking detector with an isotopically enriched zirconium source (0.084 mol yr of ⁹⁶Zr), a ββ2ν decay half-life of T_1/2=(2.1^+0.8(stat)_−0.4(stat)±0.2(syst))·10¹⁹ y was measured. Limits with a 90% C.L. on the ⁹⁶Zr half-lives of 1.0·10²¹ y for ββ0ν decay to the ground state, 3.9·10²⁰ y to the 2⁺ excited state and 3.5·10²⁰ y for ββ0νχ⁰ decay with a Majoron (χ⁰) were obtained. The data also provide direct limits at the 90% C.L. for the ⁹⁴Zr half-lives. These limits are 1.1·10¹⁷ y for ββ2ν decay to the ground state, 1.9·10¹⁹ y for ββ0ν decay to the ground state and 2.3·10¹⁸ y for ββ0νχ⁰ decay to ground state.     

ESR study of vanadyl ion in trisodium citrate pentahydrate

ESR study of VO²⁺ doped trisodium citrate pentahydrate is undertaken at room temperature. The observed spectra are correlated with the available crystal structure data and are fitted to a spin Hamiltonian of orthorhombic symmetry with g_x = 1.998 ± 0.001, g_y = 1.992 ± 0.001, g_z = 1.934 ± 0.001, A_x = (70.0 ± 1) × 10^-4cm^-1, A_y = (66.6 ± 1) × 10^-4cm^-1 and A_z = (175.4 ± 1) × 10^-4cm^-1. The covalency and Fermi contact parameters are evaluated and compared with those of VO²⁺ in other lattices.     

Electron paramagnetic resonance of Dy3+ in cubic ZnSe and Tm3+ in hexagonal CdS single crystals

Electron paramagnetic resonance has been observed for Dy³⁺ in ZnSe and Tm³⁺ in CdS. For Dy³⁺ doped ZnSe, an isotropic spectrum was observed having well resolved hyperfine lines due to ¹⁶¹Dy and ¹⁶³Dy. The g value obtained was 6.577 ± 0.002 and ¹⁶¹A was 191 ± 1 × 10⁴ cm^?1 and ¹⁶³A was 265 ± 3 × 10^?4 cm^?1. The agreement of the observed g value to g(τ₆) = 6.667 and the point-charge calculations suggest that Dy³⁺ occupies an interstitial (II) site with no local charge compensation. For Tm³⁺ doped in hexagonal CdS, an axial spectrum consistent with g_⊥ = 0, g_∥ = 10.722 ± 0.007, D = 2.57 GHz (crystal field splitting) and ¹⁶⁹A = 1207 ± 5 × 10^?4cm^?1. The large g_∥ value indicates that the Tm ion exits in the trivalent state. This is in reasonable agreement with previous reports of the non-Kramer's state of Tm³⁺.     

Hadronic vacuum polarization effects in Bhabha and Moller scattering

Effects of hadronic vacuum polarization in the reactions e⁺e^? → e⁺e^? and e^±e^± → e^±e^± are discussed. The cross sections with spin polarization are given. Measurements of these effects could directly determine in the hadronic vacuum polarization at spacelike momentum transfers and could improve tests of quantum electrodynamics.     

Dilepton and trilepton production by antineutrinos and neutrinos in neon

A sample of over 25,000 fully measured neutrino and antineutrino charged current interactions in BEBC includes 192 dilepton candidates. The prompt signal after subtraction of background is 41 ±7µ⁺ e ^-, 35±7µ⁺µ^- events from \(\bar v\) interactions, and 32±7µ^-µ⁺ events from ν interactions. There are 2 trileptons, µ^-µ^- e ⁺ and µ^-µ^-µ⁺. Results are compared with other experimental data and with the standard model. Limits to prompt like sign µ⁺ e ⁺, µ⁺µ⁺ and µ^-µ^- signals are given and compared with other experiments and with theoretical calculations.     

Spin-orbit effects in the ground X2Π state and two low-lying excited valence states B2Π and L′2Φ for NO

The potential energy curves and spectroscopic constants B _e , ω _e , ω _e χ _e , α _e , D _e of the six Ω states (X ²Π_1/2, ? 3/2, B ²Π_1/2, ? 3/2 and L ^′2Φ_{5/2,   7/2}) of the NO radical molecule were calculated using spin-orbit multi-configuration quasi-degenerate perturbation theory (SO-MCQDPT). The spin-orbit coupling effect was considered via the state interaction approach with the full Breit-Pauli Hamiltonian. The spin-orbit splitting energy between the X ²Π_1/2 and X ²Π_3/2 states of the NO radical is 129.61 cm^-1, which agrees reasonably well with the experimental value of 123.13 cm^-1. For the B ²Π_{1/2,   3/2} states, the spin-orbit coupling (SOC) splitting energy is 35.99 cm^-1, the corresponding experimental value is 31.7 cm^-1. The SOC splitting value of the L ^′2Φ_{5/2,   7/2} states was calculated to be 103.2 cm^-1. The spectroscopic constants R _e , ω _e , ω _e χ _e , B _e , α _e , D _e are in reasonable agreement with available experimental and theoretical data for the six Ω states.     

Measurement of particle and antiparticle elastic scattering on protons between 6 and 14 GeV

Differential cross sections in the t-range between 0.02 and 1.5 GeV² have been measured for the elastic scattering of particles and antiparticles on protons at 6.4, 10.4 and 14 GeV for K^±p and 10.4 GeV for π^±p and p^±p. Large statistics have been achieved and systematic uncertainties have been minimized. The relative systematic uncertainty between particle and antiparticle data is less than 0.5%. Accurate measurements of the position of the first crossover between particle and antiparticle differential cross sections have been performed. As the energy increases from 6.4 to 14 GeV the K^±p crossover moves to smaller values by 0.010 GeV² with a statistical error of 0.006 GeV² and a systematic uncertainty of 0.005 GeV². The crossover positions at 10.4 GeV for π^±, K^± and p^± scale approximately with the interaction radii.     

Mössbauer study of new vanadate glass with large charge-discharge capacity

Charge-discharge capacity and cyclicity of lithium ion battery (LIB) was evaluated in which 15Li₂O·10Fe₂O₃·xSnO₂·5P₂O₅·(70–x)V₂O₅ glass (x?=?0 and 20 in mol%, abbreviated as xLFSPV) was used as a cathode. A local structure of xLFSPV glass before and after charging was investigated by ⁵⁷Fe- and ¹¹⁹Sn-Mössbauer spectroscopies. ⁵⁷Fe-Mössbauer spectrum of xLFSPV glass with ‘x’ of 20 was composed of a doublet with isomer shift (δ) of 0.35_±0.02 mm s^???1 and quadrupole splitting (Δ) of 0.88_±0.03 mm s^???1 due to distorted Fe^IIIO₄ tetrahedra. ¹¹⁹Sn-Mössbauer spectrum of this glass consisted of a doublet with δ of 0.08_±0.01 and Δ of 0.52_±0.01 mms^???1 due to distorted Sn^VIO₆ octahedra. After discharging the battery from 4.5 to 1.0 V, larger δ of 0.40_±0.03 mm s^???1 and Δ of 0.94_±0.04 mm s^???1 were obtained, indicating that both iconicity of Fe-O bonds and local distortion of Fe^IIIO₄ tetrahedra were increased. On the contrary, identical δ of 0.09_±0.01 mm s^???1 and Δ of 0.50_±0.01 mm s^???1 were observed in the ¹¹⁹Sn-Mössbauer spectrum of 20LFSPV glass after the discharge, indicating that chemical environment of Sn^IVO₆ octahedra was not affected after the discharge. Charge-discharge curve of LIB containing 20LFSPV glass as a cathode active material recorded under the current density of 8.3 mA g^???1 (0.011 mA cm^???2) between 1.0 and 4.5 V showed a large initial charge capacity of 431.1 mAh g^???1 and discharge capacity of 382.3 mAh g^???1, respectively. These results indicate that 20LFSPV glass could be a new cathode active material for LIB.     

Cluster Model Analysis of Pion Elastic and Inelastic Scattering from 12C

Angular distributions of differential cross sections for the ¹²C(π ^±, π ^±)¹²C and ¹²C(π ^±, π ^±)¹²C^* reactions at pion kinetic energy ranging from 50 to 260 MeV have been analyzed with the 3α-particle model of ¹²C. The model provides good fits to a wide range of data. Differential cross sections for inelastic transitions to the (2^?+?; 4.44 MeV) and (3^???; 9.64 MeV) states in ¹²C are computed and the deformation lengths δ ₂ and δ ₃ are extracted. It is found that the extracted deformation lengths are sensitive to the nuclear model used and similar to the corresponding values found with other probes and nuclear models.