共查询到19条相似文献,搜索用时 109 毫秒
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锌离子在水相介南Zn/V2O5二次电池中的迁移性能研究 总被引:2,自引:0,他引:2
利用间歇性恒电流测定法和X-Ray衍射法,研究水相介质的Zn/V2O5二次电池中的锌离子在正材料中的迁移性能及其放电机理;讨论锌离子正极材料中发生迁移时的某些动力学参数与放电深度的关系,实验结果表明,该电池的正极放电反应为锌离子在ZnxV2O5中的嵌入过程。 相似文献
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生理条件下稀土及钙、锌离子与L-羟脯氨酸配位作用的研究*高峰**牛春吉孟淑兰倪嘉缵(中国科学院长春应用化学研究所稀土化学和物理开放实验室长春130022)金天柱王瑞瑶王祥云(北京大学稀土材料化学和应用国家重点实验室北京100871)关键词稀土钙锌L-... 相似文献
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钒的氧化物,特别是V6O13与V2O5,由于具有层状结构,可以嵌入一定量的小体积阳离子而保持原有的晶体结构基本不变,因而作为电池的可逆嵌入电极材料,一直受到广泛重视[1-9].从考虑降低电池生产成本、提高电池的安全性和充分利用我国的钒资源角度出发,本课题组研究了锌与一些钒氧化物组成的二次电池,主要是Zn/V6O13有机相二次电池[10]和Zn/V2O5水相二次电池[11,12].研究结果表明,在一定范围内,锌离子能够可逆地嵌入到上述钒氧化物的层状结构中.该类二次电池具有价格低、安全性能好、能量密度大并具有适度的循环寿命和贮存寿命等优点… 相似文献
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电解液添加剂能有效缓解锌金属阳极的不可控枝晶生长和固有副反应,大幅提升锌金属阳极的循环稳定性和可逆性,对水系锌离子电池的发展和商业化应用具有重要意义。本文通过对近期水系锌离子电池电解液添加剂的研究进展进行了系统总结和分析,简要介绍了锌金属阳极目前面临的主要挑战及其相关机理,重点阐述了电解液添加剂对锌金属阳极界面的作用机制,包括改变溶剂化结构、调节沉积方式、构筑界面保护层。此外,还对不同类型电解液添加剂进行了分类讨论,包括离子添加剂、无机添加剂和有机添加剂。最后,我们进一步对电解液添加剂策略在提升水系锌离子电池电化学性能中存在的科学问题和未来的研究方向进行了总结与展望。 相似文献
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A. I. Andrukhiv A. A. Bachaev I. V. Skobeleva 《Russian Journal of Applied Chemistry》2013,86(10):1483-1492
Effect of Tsinkamin-02 additive on characteristics of electrolytically fabricated zinc electrode for backup power sources was studied. Its influence on how a zinc powder is formed, deposition process parameters (current efficiency by zinc, cathodic polarization), and utilization factor of the active substance of the negative electrode in a nickel-zinc power source discharged in a high-intensity mode was determined. The component concentrations of the electrolyte used to deposit the zinc powder were optimized. An explanation was suggested for the mechanism of Tsinkamin-02 action. 相似文献
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Effect of Tsinkamin-02 additive on characteristics of electrolytically fabricated zinc electrode for backup power sources was studied. Its influence on how a zinc powder is formed, deposition process parameters (current efficiency by zinc, cathodic polarization), and utilization factor of the active substance of the negative electrode in a nickel-zinc power source discharged in a high-intensity mode was determined. The component concentrations of the electrolyte used to deposit the zinc powder were optimized. An explanation was suggested for the mechanism of Tsinkamin-02 action. 相似文献
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Nagatani H Tanida H Ozeki T Watanabe I 《Langmuir : the ACS journal of surfaces and colloids》2006,22(1):209-212
The polarized total-reflection X-ray absorption fine structure method was applied to characterize zinc porphyrins at the air-water interface. The X-ray absorption near edge structure exhibited a significant difference depending on the polarization of the X-ray. A shoulder peak of the Zn K-edge corresponding to the 1s-4p(z) transition for a square planar metal complex without axial coordination(s) was observed at 9662 eV, which indicates that the axial coordination sites of zinc porphyrin molecules examined are not fully hydrated at the air-water interface. The molecular orientation of zinc porphyrins was determined by analyzing the polarization dependence of the transition peak intensity. The meso-substituted porphyrin derivative 5,10,15,20-tetraphenylporphyrinatozinc(II) (ZnTPP) orients rather parallel to the solution surface. In contrast to ZnTPP, the zinc(II) protoporphyrin IX (ZnPP) with hydrophilic carboxyl groups at one side of the molecule stands up with respect to the solution surface, and the average tilting angle of the porphyrin plane to the surface was evaluated to be between 57 degrees and 43 degrees. In addition, the axial coordination of ZnPP is modified depending on the surface concentration, in which the axial hydration to the zinc center is effectively inhibited in the compressed surface layer. 相似文献
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Qi Zhang Jingyi Luan Liang Fu Shengan Wu Yougen Tang Xiaobo Ji Haiyan Wang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(44):15988-15994
Rechargeable aqueous zinc‐ion batteries have been considered as a promising candidate for next‐generation batteries. However, the formation of zinc dendrites are the most severe problems limiting their practical applications. To develop stable zinc metal anodes, a synergistic method is presented that combines the Cu‐Zn solid solution interface on a copper mesh skeleton with good zinc affinity and a polyacrylamide electrolyte additive to modify the zinc anode, which can greatly reduce the overpotential of the zinc nucleation and increase the stability of zinc deposition. The as‐prepared zinc anodes show a dendrite‐free plating/stripping behavior over a wide range of current densities. The symmetric cell using this dendrite‐free anode can be cycled for more than 280 h with a very low voltage hysteresis (93.1 mV) at a discharge depth of 80 %. The high capacity retention and low polarization are also realized in Zn/MnO2 full cells. 相似文献
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Dr. Liqi Bai Zihan Hu Cheng Hu Songge Zhang Dr. Yiran Ying Yingge Zhang Lu Li Hanfang Zhang Dr. Nan Li Dr. Shanshan Shi Shuo Liu Dr. Lin Hao Tongyao Liu Prof. Hongwei Huang Prof. Haitao Huang Prof. Yihe Zhang 《Angewandte Chemie (International ed. in English)》2023,62(26):e202301631
High energy density and intrinsic safety are the central pursuits in developing rechargeable Zinc-ion batteries (ZIBs). The capacity and stability of nickel cobalt oxide (NCO) cathode are unsatisfactory because of its semiconductor character. Herein, we propose a built-in electric field (BEF) approach by synergizing cationic vacancies and ferroelectric spontaneous polarization on cathode side to facilitate electron adsorption and suppress zinc dendrite growth on the anode side. Concretely, NCO with cationic vacancies was constructed to expand lattice spacing for enhanced zinc-ion storage. Heterojunction with BEF leads to the Heterojunction//Zn cell exhibiting a capacity of 170.3 mAh g−1 at 400 mA g−1 and delivering a competitive capacity retention of 83.3 % over 3000 cycles at 2 A g−1. We conclude the role of spontaneous polarization in suppressing zinc dendrite growth dynamics, which is conducive to developing high-capacity and high-safety batteries via tailoring defective materials with ferroelectric polarization on the cathode. 相似文献