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Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences. Translated from Zhurnal Strukturnoi Khimii, Vol. 33, No. 3, pp. 141–145, May–June, 1992.  相似文献   

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Institute of Inorganic Chemistry, Siberian Branch, Academy of Sciences of the USSR. Translated from Zhurnal Strukturnoi Khimii, Vol. 30, No. 1, pp. 123–129, January–February, 1989.  相似文献   

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Summary The synthesis, properties and X-ray crystal structure of [Ni(Me3[12]N3)(O2N)(H2O)](ClO4)·2H2O, in which Me3[12]N3 is 2,4,4-trimethyl-1,5,9-triazacyclododec-1-ene, are described. The Ni atom is octahedrally coordinated to three N atoms of the macrocycle, two O atoms of the nitrito group and one H2O molecule. Monomeric units are linked by hydrogen bonds through one of the water of crystallization molecules, forming a chain. Magnetic measurements between 290 and 4 K reveal slight antiferromagnetic behaviour.  相似文献   

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