共查询到20条相似文献,搜索用时 15 毫秒
1.
Benjamin Willy Frank Rominger Thomas J.J. Müller 《Journal of organometallic chemistry》2009,694(6):942-99
A consecutive coupling-cycloaddition sequence of acid chlorides, terminal alkynes, and in situ generated nitrile oxides furnishes ferrocenyl substituted redox active isoxazoles in moderate to good yields. The structure was unambiguously assigned by X-ray structure analyses and the electronic structure was elucidated by computational methods. Redox potentials of all representatives are strongly effected by the electronic nature of the bridging isoxazoloyl moiety. 相似文献
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Solvothermal in situ generation of a Schiff-base ligand (L) in the presence NiCl(2) and trimesic acid (H(3)BTC) in ethanol resulted in clusters, Ni(8)(L)(4)Cl(8).(H(2)O)(0.5), consisting of three different coordination geometries, four paramagnetic and four diamagnetic Ni(II), exhibiting both ferromagnetic and antiferromagnetic exchange interactions. 相似文献
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An efficient one-pot synthesis of 2-substituted quinoxalines from 1,2-diamines and phenacyl bromides is developed using K10-montmorillonite (K10 clay) as a catalyst at 50 °C in acetonitrile medium. This method offers an easy route for the synthesis of substituted quinoxalines in high yields. A plausible mechanism is proposed in which quinoxalines are formed via dehydration–dehydrohalogenation–cyclization sequence. Further, the K10 clay catalyst is recovered by simple filtration and reused six times without any loss in its catalytic activity. 相似文献
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Alexander S. Kiselyov 《Tetrahedron letters》2005,46(10):1663-1665
A series of polysubstituted pyrimidines were synthesized from in situ generated α,β-unsaturated imines and the corresponding amidine or guanidine derivatives in a convenient one-pot procedure. 相似文献
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Isabel C. Henao Castañeda Sonia E. Ulic Carlos O. Della Védova Nils Metzler-NolteJorge L. Jios 《Tetrahedron letters》2011,52(13):1436-1440
We report a simple and suitable method for the preparation of useful 2-trifluoromethylchromones in one step, in high yields and avoiding the use of solvents. We were able to detect the intermediate of this reaction. Furthermore a mechanism for the formation of the 7-methoxy-3-trifluoroacetyl-2-trifluoromethylchromone through the unexpected double trifluoroacetylation of 4-methoxy-2-hydroxyacetophenone followed by dehydration is also proposed. All compounds are fully identified and characterized by spectroscopic techniques. 相似文献
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Yoshitaka Yamakawa Mitsuru Ueda Kazuhiko Takeuchi Michihiko Asai 《Journal of polymer science. Part A, Polymer chemistry》1999,37(18):3638-3645
Dendritic polyamides with polydispersity of 1.1–1.4 have been successfully prepared from trimesic acid, 5-aminoisophthalic acid, and 4-aminophenylpropionic acid as a core molecule, a dendron, and a spacer unit, respectively, with a one-pot procedure. This procedure involves successive activation of end carboxyl groups with the condensing agent diphenyl (2,3-dihydro-2-thioxo-3-benzoxazolyl)phosphonate (DBOP), followed by condensation of active amide with 5-aminoisopthalic acid or 4-aminophenylpropionic acid and, finally, capping of the end carboxyl groups with p-anisidine. The structure of dendritic polyamides was investigated by 1H-NMR spectroscopy, and it was found that the polymers obtained contained approximately 10% defects. Furthermore, the model reaction was studied to demonstrate the feasibility of dendritic polyamides. © 1999 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 37: 3638–3645, 1999 相似文献
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Srinivas Chittaboina 《Tetrahedron letters》2005,46(13):2331-2336
Highly efficient one-pot synthesis of 1,2,3-triazole-linked glycoconjugates was presented involving a Cu(I) catalyzed 1,3-dipolar cycloaddition as the key step. It offers a convenient route to prepare neoglycoconjugates derived from unprotected saccharides or peracetylated saccharides. 相似文献
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A facile one-step synthetic protocol toward multifunctionalized cyclopropanes 4 is developed from substituted chalcones 1 and sulfones 2 in good yields via a [2C+1C] annulation. 相似文献
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《Journal of Coordination Chemistry》2012,65(14):1615-1620
The mononuclear complex [Cd(H2NNCHCOO)2(H2O)2] has been prepared from an aqueous solutions of reactants by one-pot synthesis and is characterized by IR, TG-DTA and single-crystal X-ray diffraction studies. The cadmium ion has distorted octahedral coordination (C 2 symmetry) with two trans water molecules and oxygen and nitrogen donors forming two five-membered chelate rings. On heating, the anhydrous complex decomposes in two steps yielding CdO. 相似文献
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Yu. N. Klimochkin A. V. Yudashkin E. O. Zhilkina E. A. Ivleva I. K. Moiseev Ya. F. Oshis 《Russian Journal of Organic Chemistry》2017,53(7):971-976
An efficient one-pot procedure has been developed for the synthesis of cage alcohols with hydroxy groups in the bridgehead positions. The procedure includes initial nitroxylation with nitric acid or a mixture of nitric acid with acetic acid and subsequent hydrolysis in the presence of urea. 相似文献
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Silaichev P. S. Kryuchkova M. A. Maslivets A. N. 《Russian Journal of Organic Chemistry》2009,45(11):1730-1731
Russian Journal of Organic Chemistry - 相似文献
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A new general one-pot method for the synthesis of various metalloporphyrins has been developed from pyrrole and substituted aldehydes using transition metal salts. This method allows higher working concentrations than those previously reported. Along with the reported metalloporphyrins, some new metalloporphyrins were synthesized in good yield. 相似文献
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A regioselective approach for the synthesis of substituted naphthofurans and dibenzofurans has been demonstrated through a ring transformation reaction of suitably functionalized 2H-pyran-2-ones by reaction with 6,7-dihydro-5H-benzofuran-4-one and 7-methoxybenzofuran-3-one, respectively, in high yields. The novelty of the procedure lies in the creation of an aromatic ring transformed by 2H-pyran-2-one involving the -COCH2- moiety of a cyclic ketone. 相似文献
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Helen Y. Luo Vladimir K. Michaelis Sydney Hodges Robert G. Griffin Yuriy Román-Leshkov 《Chemical science》2015,6(11):6320-6324
A new material MIT-1 comprised of delaminated MWW zeolite nanosheets is made in a one-pot synthesis using a rationally designed organic structure-directing agent (OSDA). The OSDA consists of a hydrophilic head segment that resembles the OSDA used to synthesize the zeolite precursor MCM-22(P), a hydrophobic tail segment that resembles the swelling agent used to swell MCM-22(P), and a di-quaternary ammonium linker that connects both segments. MIT-1 features high crystallinity and surface areas exceeding 500 m2 g–1, and can be synthesized over a wide synthesis window that includes Si/Al ratios ranging from 13 to 67. Characterization data reveal high mesoporosity and acid strength with no detectable amorphous silica phases. Compared to MCM-22 and MCM-56, MIT-1 shows a three-fold increase in catalytic activity for the Friedel–Crafts alkylation of benzene with benzyl alcohol. 相似文献
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An efficient one-step synthetic route toward multifunctionalized quaterphenyls 3 or cyclopropanes 4 is developed from substituted chalcones 1 and sulfones 2 in good yields via a regioselective [3C+3C] or [1C+2C] annulation. The reaction features mild conditions, multisubstitution, and functional groups tolerance and is transition metal catalyst-free. The protocol provides a novel alternative to the conventional methodologies for the synthesis of quaterphenyls or cyclopropanes. 相似文献
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Christophe Rochais Rodrigue YougniaThomas Cailly Jana Sopková-de Oliveira SantosSylvain Rault Patrick Dallemagne 《Tetrahedron》2011,67(32):5806-5810
The synthesis of a series of benzo(iso)quinoline and phenanthroline derivatives has been achieved using an efficient one-pot procedure. It proceeds through a Suzuki-Miyaura cross-coupling followed by a Dieckmann-Thorpe ring closure under microwave irradiation and provides easy access to building blocks not readily available through other methods. 相似文献