Plasmon resonance in multilayer graphene nanoribbons

Plasmon resonances in nanopatterned single‐layer graphene nanoribbons (SL‐GNRs), double‐layer graphene nanoribbons (DL‐GNRs) and triple‐layer graphene nanoribbons (TL‐GNRs) are studied experimentally using ‘realistic’ graphene samples. The existence of electrically tunable plasmons in stacked multilayer graphene nanoribbons was first experimentally verified by infrared microscopy. We find that the strength of the plasmonic resonance increases in DL‐GNRs when compared to SL‐GNRs. However, further increase was not observed in TL‐GNRs when compared to DL‐GNRs. We carried out systematic full‐wave simulations using a finite‐element technique to validate and fit experimental results, and extract the carrier‐scattering rate as a fitting parameter. The numerical simulations show remarkable agreement with experiments for an unpatterned SLG sheet, and a qualitative agreement for a patterned graphene sheet. We conclude with our perspective of the key bottlenecks in both experiments and theoretical models.

     

Plasmon resonance microsensor for droplet analysis

Microscale fiber tip sensors based on the plasmon resonance are reported. The fabrication process derived from our previous approach for manufacturing near-field scanning optical microscopy probes has been optimized for sensing applications. A typical tip sensor is a tapered fiber 400 microm in length, coated with a nanoporous thin silver film. The miniaturized geometry of the sensor allows detection in a single droplet of liquid solution (approximately 20 microl). The tip sensor is sensitive for refractive indices between 1.33 and 1.40 with a sensitivity of at least 3 x 10(-4) refractive index unit (RIU)/nm. The Raman scattering enhancement through these microsensors demonstrates the important role played by the localized plasmon resonance. The sensors' linear response covers a large region, interesting for biosensing in aqueous environments such as biomedical applications.     

Dipole and quadrupole surface plasmon resonance contributions in formation of near-field images of a gold nanosphere

Multipolar plasmon optical excitations at spherical gold nanoparticles and their manifestations in the particle images formatted in the particle surface proximity are studied. The multipolar plasmon size characteristic: plasmon resonance frequencies and plasmon damping rates were obtained within rigorous size dependent modelling. The realistic, frequency dependent dielectric function of a metal was used. The distribution of light intensity and of electric field radial component at the flat square scanning plane scattered by a gold sphere of radius 95 nm was acquired. The images resulted from the spatial distribution of the full mean Poynting vector including near-field radial components of the scattered electromagnetic field. Monochromatic images at frequencies close to and equal to the plasmon dipole and quadrupole resonance frequencies are discussed. The changes in images and radial components of the scattered electromagnetic field distribution at the scanning plane moved away from the particle surface from near-field to far-field region are discussed.     

Electrodynamic response of a nanosphere

The electrodynamic response of electron gas on the surface of a nanosphere in a weak magnetic field is studied. The case of the photon polarization vector oriented parallel to the magnetic field (the Faraday geometry) is considered. An analytic expression for the coefficient of electromagnetic-radiation absorption by the nanosphere is derived. It is shown that, at low temperatures, the absorption curve has, in the general case, two resonance peaks. The curve also exhibits breaks.     

Plasmon resonance in Al,deviations from quadratic dispersion observed

The dispersion of the plasmon and its resonance-like penetration into the single particle excitation band has been measured by electron spectroscopy of polycrystalline Al up to wave number $\text{k = 2.1}\text{A}\text{?}{}^{\mathrm{?1}}$. For $\text{k < 0.75}\text{A}\text{?}{}^{\mathrm{?1}}$ there are deviations from the RPA dispersion in the free electron gas due to band effects. Within the experimental accuracy, there is zero dispersion at $\text{k = 1.90}\text{A}\text{?}{}^{\mathrm{?1}}$. This levelling off may be qualitatively explained by electron short range correlations.     

Plasmon resonance in sputtered gold films observed in scanning tunneling microscopy

Gold films grown on BaTiO₃ substrates, illuminated by a monochromatic beam in the visible range, were investigated using scanning tunneling microscopy (STM). Irregular variations in the tip displacements versus photon energy are observed at energies of the surface plasmon resonances (2.0 ± 0.1 and 2.7 ± 0.1 eV) of the rough gold film.     

Versatile nanosphere lithography technique combining multiple-exposure nanosphere lens lithography and nanosphere template lithography

A versatile nanosphere composite lithography(NSCL) combining both the advantages of multiple-exposure nanosphere lens lithography(MENSLL) and nanosphere template lithography(NSTL) is demonstrated. By well controlling the development, washing and the drying processes, the nanosphere monolayer can be well retained on the substrate after developing and washing. Thus the NSTL can be performed based on MENSLL to fabricate nanoring, nanocrescent and hierarchical multiple structures. The pattern size and the shape can be systemically tuned by shrinking nanospheres by using dry etching and adjusting the tilted angle. It is a natural nanopattern alignment process and possesses a great potential in the scope of nano-science due to its low cost,simplicity, and versatility for variuos nano-fabrications.     

Polarization Bremsstrahlung radiation on a nanosphere in a dielectric

Within the limits of a new approach based on the Mie scattering theory, polarization bremsstrahlung radiation (PBR), arising during electron scattering on a metallic nanosphere with radius from 10 to 100 nm placed in a dielectric medium is theoretically investigated. The spectral range close to the plasmon resonance is considered, where the contribution of the polarized channel to bremsstrahlung radiation dominates. Spectral, velocity, and angular PBR characteristics are calculated. The sensitivity of the PBR spectrum to the dielectric permittivity of the medium surrounding the nanosphere is demonstrated.     

Plasmon resonance and electric field amplification of crossed gold nanorods

Here we explore the unusual plasmon resonances of crossed gold nanorod structures of varying geometries. Using numerical simulations, we show that the resonances of simple rods are hybridized and blue-shifted in the composite structures and that these structures are surrounded by spatially extended and high intensity electric fields. This attribute suggests several potential uses for these shapes, for example as a nano-antenna for the generation of two-photon fluorescence.     

Plasmon resonance coupling in strongly coupled gold nanotube arrays with structural defects

We theoretically investigate the transmission spectra and the field distributions with different defects in the gold nanotube arrays by using the finite-difference time-domain method.It is found that the optical properties of the nanotube arrays are strongly influenced by different defects.When there are no defects in the central nanotube,the values of peaks located at both sides of the photonic band gap have their maxima.Based on the distributions of electric field component E x and the total energy distribution of the electric and the magnetic field,we show that mainly a dipole field distribution is exhibited for the plasmon mode at the long-wavelength edge of the band gap but higher order modes of the composite are excited at the short-wavelength edge of the band gap.The plasmon resonant modes can also be controlled by introducing defects.     

Electrodynamic response of a nanosphere placed in a magnetic field

Absorption of electromagnetic radiation by 2D electrons at the surface of a quantum sphere placed in a weak magnetic field is studied. It is shown that at low temperatures, the absorption curve exhibits four resonance peaks observed in the Faraday geometry (photon wave vector parallel to the magnetic field) and six peaks in the Voigt geometry (photon wave vector perpendicular to the magnetic field). In the particular case of the Voigt geometry, where the photon polarization vector is parallel to the magnetic field, the absorption curve exhibits only two resonance peaks. The shape, position, and intensity of the peaks are examined. It is shown that at temperatures close to zero, steps of two types appear in the absorption curve. One type of steps is associated with crossing of the μ-?ω level by the electron energy levels, while steps of the other type arise when electron energy levels cross the chemical potential μ.     

Comparison investigation of near- and far-field properties for plasmon resonance of silver nanosphere dimers

Near- and far-field plasmon resonance properties of silver nanospheres dimers are calculated and compared based on the Generalized Multiparticle Mie-solution method. Greater differences between near- and far-field plasmon resonances are found than those of silver single nanoparticle, while the dimer of strongest near-field electric field amplitude and the dimer of highest far-field extinction coefficient almost have the same geometry parameter value under the illumination with fixed wavelength and polarization.     

螺旋形塑料光纤表面等离子体共振折射率传感器

研究了基于波长调制的螺旋形塑料光纤(plastic optical fiber, POF)表面等离子体共振(surface plasmon resonance, SPR)折射率传感器。采用机械热压和扭曲法将塑料光纤制备成螺旋形,在螺旋形POF上通过磁控溅射蒸镀一定厚度(约50 nm)的金属薄膜来激励SPR效应,从而形成螺旋形POF-SPR传感器。通过对螺旋形POF-SPR传感器的结构进行修饰,研究不同结构参数对折射率传感特性的影响。实验结果表明:由厚度为500μm扁平形POF扭制、螺纹数为4的螺旋形POF-SPR传感器具有较好的线性度和折射率传感特性,在折射率为1.335～1.400范围内测得的灵敏度为1 262 nm/RIU。该传感器具有成本较低、制备简单、结构稳定等优点。     

Shake-induced order in nanosphere systems

Self-assembled patterns obtained from a drying nanosphere suspension are investigated by computer simulations and simple experiments. Motivated by the earlier experimental results of Sasaki and Hane and Sch?pe, we confirm that more ordered triangular lattice structures can be obtained whenever a moderate intensity random shaking is applied on the drying system. Computer simulations are realized on an improved version of a recently elaborated Burridge-Knopoff-type model. Experiments are made following the setup of Sasaki and Hane, using ultrasonic radiation as source for controlled shaking.     

Plasmon dispersion in a layered structure

Dispersion of plasmons in a superlattice of finite thickness plasma layers is calculated. Good agreement with dispersion from light scattering experiments is obtained.     

Absorption of electromagnetic radiation by electrons of a nanosphere

The electrodynamic response of an electron gas on the surface of a nanosphere is investigated. An analytical relationship for the absorption of electromagnetic radiation by the nanosphere is derived. It is demonstrated that the absorption curve at low temperatures has two resonance peaks. The shape, position, and intensity of the peaks are examined. The dependence of the absorption on the radiation frequency exhibits kinks associated with the degeneracy of the electron gas. The number and position of the kinks and the absorption jumps at these kinks are analyzed. Consideration is given to the cases of an isolated sphere and a sphere exchanging electrons with a reservoir.     

Plasmon resonance properties of silver-patterned glass substrates fabricated by anodic alumina oxide templates

Ultra-thin anodic aluminum oxide membranes were prepared and served as deposition masks for fabrication of uniformly sized Ag nanodots with different aspect ratios on glass substrates. The surface plasmon resonance (SPR) properties of the supported Ag nanodots were investigated and compared with the predictions of the generalized Maxwell–Garnett theory. By modeling the nanodots as spheroids without adjusting their real geometrical parameters input to the calculation, the resulting theoretical SPR wavelengths are in good agreement with measured extinction peaks. The discrepancy between the theoretical and experimental plasmon resonance peak maxima is within 10 nm for the nanodots with an aspect ratio of less than 1.5. Although this wavelength discrepancy becomes large as the aspect ratio is increased, it is kept at approximately 35 nm for the nanodots with an aspect ratio of 2.44.     

Plasmon dispersion and intersubband resonance at high wavevectors in Si(100) inversion layers

Deviations from the classical two-dimensional plasmon dispersion are observed at high wavevectors q in electron inversion layers on Si(100) MOS-capacitors with periodically structured gate electrodes. For high inversion electron densities (n_s> 6 × 10¹²cm^?2) an unexpected mass enhancement is extracted from the plasmon dispersion. In addition the plasmon linewidth is found to be significantly larger than predicted from transport experiments. On the same samples non-vertical intersubband resonance transitions are observed with radiation incident normal to the interface. They are excited by an electric field component normal to the surface that is induced by the structured gate electrode.