Advanced simulations of spectroscopic signatures of charge exchange in laser-produced plasmas

We present an advanced theory of charge-exchange-caused dips (also called X-dips) in spectral lines from laser-produced plasmas. We compare predictions of this advanced theory with our previously published experimental results where, in the process of a laser irradiation of targets made out of aluminum carbide, we observed two X-dips in the L _γ line of Al XIII perturbed by fully stripped carbon. We show that our advanced theory is in excellent agreement with our experimental results. From the practical point of view, our results open up a way to experimentally produce not-yet-available fundamental data on charge exchange between multicharged ions, virtually inaccessible by other experimental methods. From the theoretical viewpoint, the results are important because the X-dips are the only one signature of charge exchange in profiles of spectral lines emitted by plasmas and they are the only one quasimolecular phenomenon that could be observed at relatively “low” densities of laser-produced plasmas. Received 25 March 2002 Published online 19 July 2002     

Velocity selective optical pumping and repumping effects with counter and copropagating laser radiations for D<Subscript>2</Subscript> lines of rubidium

The effects of a strong control or pump laser, counter propagating or copropagating with the probe beam, on the probe absorption spectra of ⁸⁵Rb and ⁸⁷Rb-D₂ transitions have been investigated inside a room temperature Rb vapour cell. In both cases a set of strong velocity selective resonance dips are observed at different velocities. Their movements across the Doppler broadened probe absorption profile have been studied for different lock frequencies of the control laser. These spectra are modified by optical pumping effects due to the presence of another hyperfine component of the ground state. A repumping laser, from the dark hyperfine component of the ground level transfers almost 75% of the atoms from the dark state to the pump probe cycle hence reducing the optical pumping effect. A numerical simulation is done to explain the observed spectra. The effect of a control laser on the Lamb dip spectrum of the probe laser has also been investigated. The control beam is used to improve the strength of a weak hyperfine dip on the Doppler broadened probe spectrum. The strength of the hyperfine dip increases by a factor of 3.2 in presence of the control laser. The observed dips show that pump-probe spectroscopy can be used as velocity selectors of atoms.     

Very high resolution CO laser spectrometer and first sub-Doppler line-shape studies near 60 THz (5 μm)

2 laser standards. Using this technique, we can tune the CO laser frequency with absolute frequency control within the gain profile of each laser transition. The frequency uncertainty is smaller than 15 kHz, corresponding to Δν/ν=2.5×10^-10. Moreover, we obtain a reduction of the CO laser linewidth by a factor of 2 down to 65 kHz, corresponding to a spectral resolution of δν/ν=1×10^-9. With this outstanding accuracy and resolution we studied the shape of saturation dips in rovibrational lines of CO and carbonyl sulfide (OCS) at low pressure (<5 Pa). The self-pressure-broadening rate of CO was found to be γ_c=+83(7) kHz/Pa in this pressure region. This value is about four times higher than values resulting from previous measurements at much higher pressures. To our knowledge the measurements described here are the first line-shape studies with sub-Doppler resolution in the 5 μm spectral region. Received: 4 November 1996     

Spectral dips in ion emission emerging from ultrashort laser-driven plasmas

Deep dips in MeV ion spectra are obtained from water droplet targets irradiated by intense [(0.5-1.2) x 10(19) W/cm(2)] and ultrashort (35 fs) laser pulses. The existence of these dips is ascribed to the generation of a multielectron-temperature plasma, which is confirmed by our experiments. An existing fluid model based on hot-electron components with significantly different temperatures is consistent with the behavior we observe in the ion spectra of the femtosecond laser-driven interaction. The model provides a good simulation of the observed spectral dips and allows us to establish important parameters such as hot- and cold-electron temperatures and the respective electron density ratios. The result may be of interest for spectral tailoring of proton spectra in future applications of laser-generated proton beams.     

全频域下窄线宽激光器光谱线宽的分析

窄线宽激光器的线宽表征方式通常采用延时自外差法测量技术。该技术是通过延时光纤差拍产生一个与待测激光线宽相关的洛伦兹频谱,因此该频谱只具有单一的线宽表现形式。为了能够观察到激光器的线宽和频率噪声在其傅里叶频率分布下的完整特性,报道了一种基于β算法计算窄线宽激光器线宽的方法。该方法是结合频率噪声中的白噪声和1/f噪声分别诱导不同激光线型的理论,从而确定激光线宽。首先,对β算法的基本原理进行了详细的分析说明。通过基于维纳-辛钦定理,分析了窄线宽激光器不同频率范围内的频率噪声和激光线宽的依赖关系。阐明了在截止频率趋于0和无穷大的两个范围条件时,激光频谱特性从高斯线型向洛伦兹线型演变。同时推导出使两种线型转换的截止频率表达式,并将其转换为频率噪声函数,该函数定义为β分子线。此时频率噪声分量中高斯线型的总和即为激光线宽计算公式;其次,对窄线宽激光器的频率噪声和激光线型进行数值仿真。将通过OEwaves公司的OE4000互相关零差相位/频率噪声自动测试系统测得的频率噪声谱密度,带入β算法理论公式中。结果显示：1/f噪声导致激光呈现高斯线型,线宽随截止频率的增加而增大。而白噪声将导致洛伦兹线型,线宽不再随截止频率而改变。此外,在低频区域,频率噪声电平远大于其傅里叶频率,噪声调制系数较高,该部分噪声可以决定线宽大小。因此,高斯线型区域对应的频率噪声的积分,即为待测激光器的线宽;在高频区域,频率噪声电平与其傅里叶频率相差较小,频率波动较快,噪声对线宽影响可以忽略。并且频率带宽在截止频率范围内,计算的线宽误差较小。最后,实验上运用β算法对RIO公司的1 550 nm低噪声窄线宽激光器的频率噪声功率谱密度进行积分计算,成功获得了其不同傅里叶频率分布下对应的激光线宽值。其中β分子线将频率噪声中的白噪声和1/f噪声分隔两部分：当频率噪声谱密度大于β分子线时,激光即为高斯线型,线宽随频率积分带宽的增加而减少;而频率噪声谱密度小于β分子线时,激光呈现洛伦兹线型,线宽为定值不再改变。同时为了对β算法进行实验验证,搭建了延迟光纤为50 km、移频频率为60 MHz的延时自外差法测量系统。对注入电流为110 mA的RIO 1 550 nm低噪声窄线宽激光器的线宽进行实验测量,测量结果表明激光线宽为1.8 kHz,与上述β算法中2.8 kHz的频率带宽积分结果一致。充分证明了此算法的准确性。β算法可以对任意类型的窄线宽激光器进行线宽表征,对窄线宽激光器的研究具有重要意义。     

Intracavity spectroscopy with modulated multimode lasers

The output of a cw multimode dye laser with an intracavity narrow-band absorber and its pump power modulated shows spectral condensation on both wings of the absorption line. This indicates phase locking of two groups of laser modes. The dispersion of the absorber modifies the mode spacing of the laser such that mode groups on both sides of the absorption line get into resonance with the modulation. These mode groups feel smaller loss and acquire the total laser power. Spectra of the laser output reveal the total absorption coefficient, the homogeneous broadening of the absorber, and the spectral width of individual laser modes.On leave from Lebedev Physical Institute, Academy of Sciences of the USSR, SU-117924 Moscow, USSR     

A picosecond CuBr laser

A novel method for the pulse shortening of the 578 nm spectral line from a CuBr laser is proposed in this paper. By amplifying a seeded picosecond dye laser through the active medium of a CuBr laser, nearly Fourier-transform-limited picosecond pulses of the CuBr laser have been obtained and the output characteristics are also investigated in detail.     

Multiparametric dependence of hydrogen Stark profiles asymmetry

The Standard Theory for hydrogen spectral lines asymmetry in dense plasmas is developed on the basis of rigorous and consistent approach with respect to simultaneous and complete account of the quadrupole interaction and the quadratic Stark effect. The complex multiparametric scaling and similarity dependence of the conventional asymmetry parameter for each separate Stark component and the H_β line contour as a whole is revealed and studied in detail under the influence of: ionic microfield inhomogeneity and quadratic Stark effect in ionic microfield, electronic collision shifts and impact widths, “trivial” asymmetry sources, the Boltzmann factor and the dipole intensity scaling factor of frequency to the fourth power for the case of emission line. The comparison with the precision experiment on stabilized arc data for H_β line, important for diagnostics, is performed and analyzed from the line center up to the far line wings. An erratum to this article is available at .     

Multiple spectral structure of the 578.2 nm copper laser line

The multiple spectral structure of the 578.2 nm copper laser line of a CuBr laser is investigated. By considering the special hyperfine transitions of the⁶³Cu atom, the discharge disturbance and the competition of transitions, an explanation of the multiple line structure is given     

Comparison of pulse evolutions in low and ultra-large anomalous dispersion mode-locked fiber lasers

We have investigated and compared the pulse evolutions in low and ultra-large anomalous dispersion erbium-doped fiber lasers mode-locked by the nonlinear polarization rotation technique. Two lasers deliver the pulses that exhibit quite distinct characteristics such as pulse duration, spectral width, and spectral sidebands. Experimental observations show that the spectral width decreases from several nanometers to less than one nanometer whereas pulse duration extends about three times by changing the cavity dispersion from −0.03 to −15.50 ps². The solitons in ultra-large anomalous fiber laser show dips in the optical spectrum, which is quite distinct from that of conventional solitons observed in low anomalous regime.     

Hyperfine structure in the atomic spectrum of niobium

We report on hyperfine structure measurements in 21 lines of atomic niobium in the spectral region from 640 nm to 870 nm by means of optogalvanic laser spectroscopy and laser induced fluorescence spectroscopy using a hollow cathode discharge and a tunable single-mode cw ring laser. Hyperfine structure constants A and B of altogether 29 excited energy levels were determined, 18 of them for the first time. Received 18 July 2002 / Received in final form 8 November 2002 Published online 4 February 2003 RID="a" ID="a"e-mail: sk@kalium.physik.tu-berlin.de     

Spectral analysis of a laser beam

The formulas of the dependence of the spectral laser power distribution and its spectral half-width on the physical parameters of its laser active medium are derived. In addition it is found that, if the gain line profile has a Lorentzian or Gaussian distribution, the spectral laser power distribution is of a Lorentzian profile. The spectral halfwidth of the laser beam in both cases are slightly different form each other. For a general gain line profile, the spectral laser power distribution behaves as a differential form like that of the gain line profile.The spectral halfwidth of He/Ne laser beam having powers (0·5 mW, 1·0 mW, 3·0 mW and 50 mW) and that of their longitudinal modes, the laser gain factor and the difference between the population atomic densities of the upper and lower energy levels for the laser line transition are experimentally determined.     

A time-compensated spectral filter for transform-limited tunable picosecond pulse generation from spectro-temporal-selection dye lasers

Diffraction and transform-limited picosecond tunable pulses are generated from Spectro-temporal-Selection (STS) dye lasers by using a new extra-cavity filter. This filter is based on a grazing-incident grating and arranged in the configuration of a folded dispersive delay line. Thus, it provides both high spectral selectivity and controllable temporal compensation for elimination of pulse broadening. Direct production of diffraction- and transform-limited picosecond dye laser (10 µJ, 50 ps) pulses spectrally adjustable between 398 and 702 nm is demonstrated in a compact device, with 8 ns pump pulses from a nanosecond nitrogen laser.     

Early stage expansion and time-resolved spectral emission of laser-induced plasma from polymer

In the nanosecond laser ablation regime, absorption of laser energy by the plasma during its early stage expansion critically influences the properties of the plasma and thus its interaction with ambient air. These influences can significantly alter spectral emission of the plasma. For organic samples especially, recombination of the plasma with the ambient air leads to interfering emissions with respect to emissions due to native species evaporated from the sample. Distinguishing interfering emissions due to ambient air represents a critical issue for the application of laser-induced breakdown spectroscopy (LIBS) to the analysis of organic materials. In this paper, we report observations of early stage expansion and interaction with ambient air of the plasma induced on a typical organic sample (nylon) using time-resolved shadowgraph. We compare, in the nanosecond ablation regime, plasmas induced by infrared (IR) laser pulses (1064 nm) and ultraviolet (UV) laser pulses (266 nm). Nanosecond ablation is compared with femtosecond ablation where the post-ablation interaction is absent. Subsequent to the early stage expansion, we observe for each studied ablation regime, spectral emission from CN, a typical radical for organic and biological samples. Time-resolved LIBS allows identifying emissions from native molecular species and those due to recombination with ambient air through their different time evolution behaviors.     

Prospects of “water-window” X-ray emission from subpicosecond laser plasmas

Soft-X-radiation in the “water-window” region (23.3–43.6 ?) mainly from carbon laser plasmas generated by subpicosecond (700 fs) 0.248-μm laser pulses is studied as a function of angle of incidence and intensity (up to 10¹⁸ W/cm²) for p-polarized laser light. Furthermore, comparison is made between plasmas generated from massive and foil targets. Numerical calculations are performed using a hydrocode coupled to X-ray line and continuum emission calculations including radiation transport. The optimized conditions to achieve maximum water-window X-ray emissivity and, in particular, carbon Lyman-α line emission are investigated. In addition, analytical scalings are presented. These theoretical results are essentially confirmed by previous experiments. It is found that at optimized conditions, picosecond or subpicosecond laser plasma X-ray sources with a power of the order of 1–10 GW in a spectral window of 1 ? could be developed. Received: 6 August 1998 / Final version: 6 August 1999 / Published online: 30 November 1999     

Fission lifetimes of Th nuclei measured by crystal blocking

Crystal blocking lifetime measurements have been made for highly excited Th nuclei with neutron number well removed from the stability line. Thin W crystals were bombarded with ³²S ions in the energy range 170-180 MeV and the yield of fission fragments was measured for emission close to a 〈111〉 axis. The fission blocking dips are compared to the appropriately scaled ones for elastic scattering of the ³²S beam ions and no significant difference is seen between the dips. This implies that the fraction of nuclei fissioning with lifetimes longer than 10 as is less than 2%. Fission lifetimes are increased by viscosity in the nuclear mass flow and comparison with a statistical model calculation indicates that the viscosity parameter, η, must be lower than for Th and U nuclei near β-stability. The effect of the N = 126 magic number is discussed. Received: 2 October 2002 / Accepted: 16 January 2003 / Published online: 29 April 2003     

Oscillator strengths of the 4s4p~^{{\mathsf{1,3}}}P1↦ 4snd~^{\mathsf {1,3}}D2 transitions of neutral calcium

A detailed study has been performed for estimating the orbital energies, positions and shifts of the Lyman lines of C⁵⁺, Al¹²⁺ and Ar¹⁷⁺ under strongly coupled plasma with a view to understand such line positions and shifts obtained in laser produced plasma experiments. The effect of strongly coupled plasma has been treated within the Ion Sphere (IS) model. Both non-relativistic and relativistic methods have been used for estimating the spectral properties. Theoretical estimates with IS model of the plasma are in conformity with the results of laser plasma experiments on these highly stripped ions. The experimental data for the systems have also been compared with the theoretical estimates using Debye screening model of the plasma with spatial confinements which gives additional restrictions to the wave functions at finite boundaries.     

Spectral linewidth of inversionless and Raman lasers in V-type three-level systems

A theoretical analysis of the spectral linewidth of V-type inversionless and Raman lasers is presented. First, we examine the effects of the atomic coherence between dressed states and the Autler-Townes splitting on the linewidth. It is demonstrated that near above threshold, the V inversionless laser has a narrower linewidth than that of the two-level laser. Instead of the dressed coherence, it is the Autler-Townes splitting that is responsible for the linewidth reduction though the dressed coherence determines the laser gain. Next, we explore the effects of the generated laser intensity on the linewidth. It is shown that the linewidths of the V inversionless and Raman lasers follow the usual 1/I decrease for smaller laser intensity I, but a slower decrease than 1/I for larger laser intensity. For the V Raman laser, even more surprisingly, with the laser intensity increasing, the linewidth appreciably increases as well. As a result, well above threshold, the V inversionless and Raman lasers may have a larger linewidth than that of the two-level laser. Finally, a comparison is made between the V lasers and the Λ lasers. It is found that the linewidth of the Λ inversionless laser shows a fast 1/I ² decay under optimum conditions. Received 25 October 1999 and Received in final form 10 March 2000     

Optically stabilized tunable diode-laser system for saturation spectroscopy

We present an optically stabilized lead-salt diode-laser system which is the nucleus of a very-high-resolution instrument for sub-Doppler molecular spectroscopy in the mid-infrared. By application of external optical feedback, we have narrowed the diode-laser linewidth by two orders of magnitude, yielding a spectral width of less than 200 kHz. The diode- laser frequency is stabilized and controlled via the external reflector by variable-frequency offset-locking the diode-laser to a CO laser frequency. This substantial improvement in the spectral properties enabled us to perform a Lamb-dip experiment on a carbonyl sulfide (OCS) absorption line near 1985 cm^–1. We were able to detect a saturated dispersion signal at low pressure (5 Pa) with a signal-to-noise ratio of several thousand. The present paper describes the unique features of the optically stabilized tunable diode-laser system and its use as a spectroscopic tool for sub-Doppler applications.     

Power resonances in a Raman gas laser

The observation of a new type of resonance due to double-quantum transitions in the standing-wave field of a Raman gas laser is reported. A resonance dip with a width equal to that of the optically forbidden transition was experimentally detected in the output-vs-timing curve of a Raman Ne laser (λ=1.15 m) upon pumping by radiation of a He−Ne laser at 1.52 m. The theory presented shows that the resonance arises in the third order of perturbation theory when in resonant SRS the line is inhomogeneously broadened. The resonance can be considered as resulting from the overlap of dips in the velocity distribution of the nonlinear polarization induced by the standing laser wave.