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G.J. Hills 《Journal of Electroanalytical Chemistry》1976,71(3):353-362
It has been shown by i.r. reflection spectroscopy that a deposit of benzyltrimethyl-ammonium hydroxide is formed at the cathode during the electrochemical, reduction of the benzyltrimethylammonium cation in HMPA; this deposition has been studied in situ by polaromicrotribometry. The deposit is accompanied by the formation of o-methylbenzyldimethylamine. The very hygroscopic benzyltrimethylammonium hydroxide probably complexes residual water at the electrode and thus favours a Sommelet-Hauser rearrangement. 相似文献
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George B. Kauffman 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》1991,103(6):738-739
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Hans-Dieter Jukuhke 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》1993,105(2):318-318
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