Justification of standardized level differences in rating of airborne sound insulation between dwellings

It has long been recognized that single-number quantities R′_w, D_nT,w or D_n,w result in different conclusions in objective rating of airborne sound insulation between dwellings. The difference between the values of these single-number quantities (SNQ), however, does not prove which of them describes the sound transmission between rooms most correctly. The main object of this article was to study which SNQ correspond best with transmitted living sound levels in buildings when reverberation time, volume of receiving room and sound insulation are taken into account. Data of 100 field measurements of airborne sound insulation were collected as well as 207 reverberation times of furnished rooms. The transmitted sound levels of living sounds were evaluated on the basis of known living sound spectra and measured level differences D. The results show that the SNQs standardized to reference reverberation time of 0.5 s lead in all cases to best correlation between the SNQs and the sound levels of transmitted living sounds. It was also checked whether the rating by D_nT,w would lead to higher transmitted sound levels of living sounds in larger rooms, but this was not detected. The use of D_nT,w makes rooms of different volumes equal in regard to required sound insulation between them. It is thus justified to replace R′_w with D_nT,w as the SNQ for rating the airborne sound insulation. Widening the frequency range down to 50 Hz or up to 5000 Hz did not give noteworthy improvement in the correlation.     

Development of a 3D finite element acoustic model to predict the sound reduction index of stud based double-leaf walls

Building standards incorporating quantitative acoustical criteria to ensure adequate sound insulation are now being implemented. Engineers are making great efforts to design acoustically efficient double-wall structures. Accordingly, efficient simulation models to predict the acoustic insulation of double-leaf wall structures are needed. This paper presents the development of a numerical tool that can predict the frequency dependent sound reduction index R of stud based double-leaf walls at one-third-octave band frequency range. A fully vibro-acoustic 3D model consisting of two rooms partitioned using a double-leaf wall, considering the structure and acoustic fluid coupling incorporating the existing fluid and structural solvers are presented. The validity of the finite element (FE) model is assessed by comparison with experimental test results carried out in a certified laboratory. Accurate representation of the structural damping matrix to effectively predict the R values are studied. The possibilities of minimising the simulation time using a frequency dependent mesh model was also investigated. The FEA model presented in this work is capable of predicting the weighted sound reduction index R_w along with A-weighted pink noise C and A-weighted urban noise C_tr within an error of 1 dB. The model developed can also be used to analyse the acoustically induced frequency dependent geometrical behaviour of the double-leaf wall components to optimise them for best acoustic performance. The FE modelling procedure reported in this paper can be extended to other building components undergoing fluid–structure interaction (FSI) to evaluate their acoustic insulation.     

Sound reduction in samples of environmentally friendly building materials and their compositions

In order to reduce the negative effect on the environment, environmentally friendly materials are being chosen for the construction of buildings more and more frequently. The building materials that are now used more commonly are clay, straw and reeds. The sound insulation properties of these environmentally friendly materials have not yet been examined thoroughly. This paper presents most commonly used sound reduction indexes R_W that have been measured in the semi-anechoic chamber and determined during the simulation. It has been found that adobe, pressed straw and reeds (oriented parallel to the sound transmission) are suitable for low-frequency sound insulation. The material with the best sound reduction index was adobe. The sound reduction index R_W of a 200 mm thick adobe wall reached up to 43 dB.     

Preparation of non-oriented silicon steel with high magnetic induction using columnar grains

Columnar grains can lead to detrimental surface ridging and an inhomogeneous microstructure, although their {1 0 0}〈0 v w〉 texture is considered desirable due to their good magnetic properties in non-oriented silicon steel. Based on the hereditary tendency of {1 0 0}〈0 v w〉 texture, the effects of lubrication and heating rate on texture and on final magnetic properties were investigated using a cast slab containing 100% columnar grains. Hot rolling with lubrication, normalization at low heating rate, two-stage cold rolling, and final annealing at 1000 °C helped achieve high performance. As a result, a new non-oriented silicon steel with high magnetic induction (B₅₀=1.82 T) and low core loss (P_1.5=2.35 W/kg) was prepared. The possibility of further performance optimization was also discussed.     

Airborne sound insulation and graphical indices

The use of graphical indices is interpreted as an approximate approach to the estimation of sound insulation performance of building elements. Differences of weighted sound pressure levels are considered as quantitative measures for subjective sound insulation. The indices considered are formed by shifting a reference curve until the highest position is found at which certain specifications, or rules, are met. General expressions are mathematically derived for the maximum differences between graphical indices and sound insulation in two cases: a maximum allowable sum rule for unfavourable deviations, and a combination for restriction of the maximum single deviation. The results indicate that the maximum deviation rule limits the variation between sound insulation and indices in a very efficient way. This comparison leads to I_a being preferred to R_w, which are special cases of the study.     

Annoyance and self-reported sleep disturbances due to structurally radiated noise from railway tunnels

In Norway, the requirement for structure borne noise from tunnels is L_pAFmax = 32 dB inside dwellings. According to the Norwegian Standard 8175 it is expected that up to 20% of the exposed population are disturbed by the noise at this level. However, the scientific basis for this noise limit is poor. The aim of this study was to determine the degree of annoyance and self-reported sleep disturbances as a function of L_pAFmax. In the present study, 521 dwellings exposed to structural sound from railway rock-tunnels were identified. A questionnaire was sent to one randomly selected person above 18 years of age from each dwelling. The results showed that both noise induced annoyance and reported sleep disturbances were significantly related to L_pAFmax. Other factors that increased the annoyance were high pass-by frequency of freight trains per day, and degree of sound insulation of the windows. At L_pAFmax = 32 dB, 20% were slightly or more than slightly annoyed, and 4% were moderately or more than moderately annoyed. According to the pre-existing assumption that up to 20% of the exposed population are disturbed by the noise at this level, the present results give support to the Norwegian noise limit L_pAFmax = 32 dB inside dwellings of structure borne noise from railway tunnels.     

Atom geometry of nanostructured Fe films grown on c(2 × 2)-N/Cu(1 0 0) surface: An investigation by X-ray absorption spectroscopy with multishell analysis

We investigated the growth of Fe nanostructured films on c(2 × 2)-N/Cu(1 0 0) surface with Fe K-edge X-ray absorption fine structure (XAFS) in the near edge and in the extended energy region. The high photon flux of the incident X-rays allowed us to perform multishell analysis of the XAFS oscillations for Fe coverage Θ_Fe < 1 ML. This data analysis yields a detailed investigation of the atom geometry and some insights in the film morphology. At Θ_N < 0.5 ML (N saturation coverage) there is absence of contribution to XAFS from N atoms. First shell analysis of linearly polarized XAFS gives Fe-Fe (or Fe-Cu) bond length values varying between R₁ = 2.526 ± 0.006 Å at the highest Fe coverage (3 ML ) and R₁ = 2.58 ± 0.01 Å at Θ_Fe = 0.5 ML, Θ_N = 0.3 ML, with incidence angle Θ = 35°. These values are different from the case of bcc Fe (R = 2.48 Å), and compatible with fcc Fe (R₁ = 2.52 Å) and fcc Cu (R₁ = 2.55 Å). At the Fe lowest coverage (Θ_Fe = 0.5 ML) the dependence of R₁ on the incidence angle indicates expansion of the outmost layer. Near edge spectra and multishell analysis can be well reproduced by fcc geometry with high degree of static disorder. At N saturation pre-coverage (Θ_N = 0.5 ML) the XAFS analysis has to keep into account the Fe-N bonding. The results suggest two different adsorption sites: one with Fe in a fcc hollow site, surrounded by other metal atoms as nearest neighbours, and one resulting from an exchange with a Cu atom underneath the N layer.     

Wooden windows: Sound insulation evaluation by means of artificial neural networks

Windows are the weakest part of a façade in terms of acoustic performance: the weighted sound insulation index (R_w), measured according to ISO 140-3, is the fundamental parameter to evaluate the façade acoustic insulation.The paper aims at developing an artificial neural network (ANN) model to estimate the R_w value of wooden windows based on a limited number of windows parameters; this is a new approach because acoustic phenomena are non-linear and affected by a plurality of factors and, therefore, usually investigated through experimentation.Data set is taken from experimental campaigns carried out at the Laboratory of Acoustics, University of Perugia. A multilayer feed-forward approach was chosen and the model was implemented in MATLAB. On the basis of the results obtained by means of a preliminary training and test campaign of several ANN architectures, five main parameters were selected as network inputs: window typology, frame and shutters thickness, number of gaskets, R_w of glazing; R_w value of the window is the network output. Different ANN configurations were trained and a root mean-square error less than 3% was obtained, comparable to measurement uncertainty.This approach allows to develop a model which, with input parameters varying within appropriate ranges, can easily estimate the acoustic performance of wooden windows without experimental campaign on prototypes, saving both money and time. If the training data set is large enough, the presented approach could be very useful for design and optimization of acoustic performance of new products.     

Analysis of BPSK homodyne receivers based on modified balanced optical phase-locked loop in the presence of non-negligible loop propagation delay

Optical homodyne receivers based on modified balanced optical phase-locked loop is analyzed taking into account loop propagation delay. This modified loop contains all the components of a standard BOPLL in conjunction of an additional phase modulator. This modified loop offers a much improved tracking performance and also shows good improvements in the reduction performance over previously reported methods, like, relaxed line-width requirement and improved lock-in range. This study for the first time shows the imperfect-phase-recovery-induced power penalty as a function of laser line-width with the optimum phase deviations in the presence of non-negligible loop propagation delay. It is found that in order to maintain a 10⁻¹⁰ BER system performance with ξ = 1, R = 1 A/W, P_R = −53 dBm, Δυ = 1 MHz, phase modulator sensitivity K_PM = 10 rad/V and 10° phase deviation between the two transmitted bits, the loop delay must be kept below 3 ns. Further, the required line-width with the non-negligible loop delay time is evaluated and found to be (2.1 × 10⁻³)/τ, where τ (s) is the loop delay. This number corresponds to BER = 10⁻¹⁰, imperfect phase recovery power penalty of 1 dB and phase modulator sensitivity K_PM = 20 rad/V.     

Magneto-transport properties of [Co/Bi]n wire structures

The present study examines the artificial control of grain-boundary resistance and its contribution to the magneto-transport properties of [Co(1 nm)/Bi(2.5 nm)]_n (n=10 or 20) line structures on the Si(0 0 1)/SiN_x substrate. Conventional patterning and deposition processes are applied for the fabrication of a device that consists of five-line structures with a line width of 2 μm. A ΔR/R=80% ratio was observed in the five-line structure of [Co(1 nm)/Bi(2.5 nm)]₁₀ multilayers at 10 K. Our measurements indicate that grain-boundary effects can be associated with the large ΔR/R ratio of transverse magnetoresistance.     

Observation of triangle pits in PbSe grown by molecular beam epitaxy

PbSe thin films on BaF₂ (1 1 1) were grown by molecular beam epitaxy with different selenium beam flux. Evolution of PbSe surface morphologies with Se/PbSe beam flux ratio (R_f) has been studied by atomic force microscopy and high-resolution X-ray diffraction. Growth spirals with monolayer steps on PbSe surface are obtained using high beam flux ratio, R_f ≥ 0.6. As R_f decreases to 0.3, nano-scale triangle pits are formed on the surface and the surface of PbSe film changes to 3D islands when R_f = 0. Glide of threading dislocations in 〈1 1 0〉{1 0 0}-glide system and Pb-rich atom agglomerations are the formation mechanism of spiral steps and triangle pits. The nano-scale triangle pits formed on PbSe surface may render potential applications in nano technology.     

Synthesis, structure and magnetic properties of the new double perovskite Ca2CrSbO6

The title double perovskite has been synthesized by solid-state reaction in air. The crystal structure has been studied from powder X-ray diffraction data. Rietveld fits to the pattern show that this compound has a monoclinic symmetry [a=5.4932(3) Å, b=5.4081(3) Å, c=7.6901(5) Å, β=90.0022(1)°, at 300 K] defined in the space group P2₁/n, where the Cr and Sb cations are almost completely ordered in the B-sublattice of the perovskite structure. Magnetic susceptibility and magnetization measurements show that this compound behaves as a Curie-Weiss paramagnet at high temperatures with μ_eff=3.53(1) μ_B and θ_P=8 K, and exhibits a robust ferromagnetic component below the ordering temperature of T_C=13 K, with a saturation magnetization of 2.36 μ_B/f.u. at 5 K. To our knowledge, this is the first example of a ferromagnetic double perovskite containing a non-magnetic element, such as Sb, occupying one half of the B positions of the perovskite structure.     

Structure and properties of (AlCrMnMoNiZrB0.1)Nx coatings prepared by reactive DC sputtering

The microstructure and properties of AlCrMnMoNiZrB_0.1 nitride films prepared by reactive direct current sputtering at various N₂-to-Ar flow ratios (R_N) were investigated. The films had an amorphous structure at low R_N and a face-centered cubic structure at a high R_N. As the R_N increased, the decrease in clusters and defects resulted in a dense columnar structure and low surface roughness. The peak hardness and modulus of the nitride films were 10.3 and 180 GPa, respectively. The enhanced hardness is ascribed to the increased metal-nitrogen bonding, solid solution strengthening of several metallic nitrides, and lattice strain. The nitride films deposited at R_N = 0.2, 0.5, and 0.8 had friction coefficients of 0.16, 0.12 and 0.15, respectively. Wear-out failure occurred within 400 s when R_N = 0 and 1.0. Adhesive wear was the dominant wear mechanism.     

Ultrasound promoted the synthesis of N-propargylic β-enaminones

The synthesis of 14 novel N-propargylic β-enaminones from the reaction of β-alkoxy vinyltrihalomethyl[carboxyethyl] ketones [R³C(O)CHC(R¹)OMe, where R³ = CF₃, CCl₃, CO₂Et and R¹ = Me, Et, Pr, Bu, i-Pent, CH₂CH₂CO₂Me] with propargyl amines [R²NHCH₂CCH, where R² = Pr, PhCH₂] is reported. Yields, solvents and reaction times needed for reaction completion, by microwave irradiation (MW), conventional thermal heating (TH) and under ultrasound irradiation (US) are compared. The best results were obtained under US irradiation in good to excellent yields (70-93%).     

The torsion-rotation spectrum of perchloric acid, HClO4

The rotational spectrum of HClO₄ has been observed in selected regions between 51.7 and 870 GHz. The molecule is a near spherical rotor with a moderately low barrier to internal rotation. The spectrum is characterized by strong μ_a, R-branch groupings with B + C = 5276.78 MHz. Although there are no E torsional states, the R-branches show three distinct groups of lines. There is a relatively tight cluster of symmetric rotor like transitions with K = 3n, a rather regular progression of transitions with K = 3n + 2 to high frequency and a less regular group of transitions with K = 3n + 1 to low frequency. Because the molecule is nearly spherical, the energy as a function of K is dominated by the K dependent solutions of the Mathieu equation. This unusual energy level distribution gives rise to numerous anomalous splittings and shifts due to avoided crossings within the K stacks as well as widely scattered μ_b transitions. The fitting procedure will be described and the effective parameters will be presented. Rotational transitions of excited torsional states at and above the top of the barrier and the v_t = 2-0 far infrared spectrum have been assigned. The dipole moment and the quadrupole coupling constants have been determined. Structural implications will be discussed.     

Sound intensity investigation of the acoustics performances of high insulation ventilating windows integrated with rolling shutter boxes

High sound insulation ventilating windows (HSIVW) were recently proposed for noise control in buildings close to motorways or railways, where noise barriers are not effective or too expensive. These windows are characterized by good insulation performances and at the same time allow airflow through the window itself; such a performance matches summer indoor ventilation and refreshment needs.In the last years at the Acoustics Laboratory of the University of Perugia various prototypes were tested and their acoustic and airflow performances were assessed, also verifying the influence of filtering systems in the aerator.In the present paper a lot of experimental data are presented and in particular the results of a recent campaign, aimed at testing windows samples integrated with insulated rolling shutter boxes are presented. Sound reduction index R and single number sound reduction index R_w are evaluated, considering different exercise conditions; acoustic intensity measurements and analysis have also been performed, in order to verify the parts of the window which need to be optimized.     

Heat capacity of CeIrSi3 under pressure

We measured the heat capacity of CeIrSi₃ (100 mK<T<6 K) under high pressure up to P=1.38 GPa. The measurements have been used a quasiadiabatic method utilizing a CuBe piston-cylinder pressure cell in a dilution refrigerator. At 0 GPa, a sharp anomaly which indicates the antiferromagnetically transition is observed at T_N=5 K. T_N decreases monotonically with increasing pressure up to P=1.38 GPa. The magnetic entropy is released below T_N only 19% of R ln 2 at 0 GPa. And the magnetic entropy decreases with increasing pressure up to 1.38 GPa, 64% compared to that at 0 GPa.     

Physical properties and anisotropies of the RNiGe3 series (R = Y, Ce-Nd, Sm, Gd-Lu)

We have studied RNiGe₃ (R=Y, Ce-Nd, Sm, Gd-Lu) single crystals by measuring crystal structure and stoichiometry, magnetic susceptibility, magnetization, electrical resistivity, magnetoresistance, and specific heat. Clear anisotropies as well as antiferromagnetic ordering in the RNiGe₃ series (R=Ce-Nd, Sm, Gd-Tm) have been observed above 1.8 K from the magnetic susceptibility. A metamagnetic transition in this family (except for R=Sm) was detected at 2 K for applied magnetic fields below 70 kOe. The electrical resistivity of this series follows metallic behavior in the high temperature region. Below the antiferromagnetic ordering temperature a significant anisotropy is exhibited in the resistivity and magnetoresistance for different current directions. The anisotropic magnetic, transport, and thermal properties of RNiGe₃ compounds are discussed in terms of Ni site occupancy as well as a combination of the effect of formation of a magnetic superzone gap and the crystalline electric field.