Die Supraleitung von Zinn und Blei unter sehr hohem Druck

The dependence of the critical temperatureT _c upon pressureP is measured in the pressure range up to 160 kbar. The experimental technique developed for very high pressure-low temperature experiments (preceding article) is improved by introducing a double-sample electrical resistance cell. An internal pressure calibration is therefore possible at some well-established room temperature pressure reference points commonly used. Both metals, tetragonal white tin and fcc-lead, show a monotonic decrease ofT _c vs.P with upward curvature. The results recommend the use of Pb as a secondary standard for very high pressure experiments at Helium temperatures. In addition, high pressure polymorphic modifications of Sn and Pb are found to show superconductivity withT _c =(5.30±0.10) ?K for Sn III atP=113 kbar andT _c =(3.55±0.10) ?K for Pb II atP=160 kbar.     

Paramagnetische Relaxation von CeCl3

The paramagnetic relaxation in CeCl₃ was investigated in the temperature interval between 1.07°K and 4.21°K using a mutual inductance bridge at frequencies between 3 Hz and 3200 Hz. The dependence of the complex susceptibility on temperature below theλ point is given by a Debye function. Above this temperature, however, deviations occur. The temperature dependence of the relaxation time forT<T _λ can be described byτ～T ^?n where 1.82≦n≦2.35 for 470 Oe≦H≦3360 Oe. At the highest temperatures Orbach Processes occur over the first excited crystal field component which according to these measurements lies atE _II=k(56±10)°K. In the entire temperature range the relaxation processes are determined by further relaxation mechanisms in addition to the spin lattice relaxation. The nature of these could not, however, be determined.     

Energieverteilung und Wirkungsquerschnitt der Photoprotonen aus N15

The energy spectra of photo protons from highly enriched N¹⁵ were investigated with the bremsstrahlung from the Heidelberg betatron running at six different endpoint energies between 19 and 30.5 MeV. The protons were detected at 90° to theγ-beam by means of a CsJ-spectrometer with pulse shape discrimination. The energy spectra show pronounced maxima atE _p =3.2; 4.6; 9.5 and 13.3 MeV. Proton yields are given as a function of endpoint energy, the yield value atE ₀=30.5 MeV being (7.0±0.8) μb/MeV · ster. Because the first excited state in the daughter nucleus C¹⁴ lies 6.09 MeV above the groundstate, the cross section for groundstate transitions of the process N¹⁵(γ, p)C¹⁴ could be derived from the upper 6 MeV of the single proton spectra. The main contribution to the cross section comes from the region between 18 and 26 MeV excitation energy with maxima at 19.5; 20.4; 22.7 and 24.5 MeV. A “pygmy resonance” occurs at 15.2 MeV with further less pronounced structures at 13.6 and 17.0 MeV. The integrated cross section for groundstate transitions up to 30.5 MeV is (22±3) MeVmb assuming isotropic angular distribution. The ratios of protons from transitions to excited states and from the (γ, n p)-reaction to those of groundstate transitions rise from 0.45 atE ₀=24.5 MeV to 0.70 atE ₀=30.5 MeV.     

Spin-selective low temperature spectroscopy on single molecules with a triplet-triplet optical transition: Application to the NV defect center in diamond

The spin-selective photokinetics of a single matrix-isolated impurity molecule with a triplet-triplet optical transition, T ₀–T ₁, is considered and the manifestations of the photokinetics in the fluorescence excitation spectra and intensity autocorrelation functions g ⁽²⁾(τ) of the molecule undergoing narrow-band optical excitation is studied to resolve the fine structure of the transition. The rates of intersystem crossings (ISCs) T ₁→S→T ₀ to and from a nonradiating singlet state S of the molecule and the rate of population relaxation among the ground (T ₀) state sublevels can be obtained from the spectra and g ⁽²⁾(τ) using the analytical expressions obtained. New experiments on an individual NV defect center in nanocrystals of diamond, where, for the first time, the fine structure of its triplet-triplet ³ A-³ E zero-phonon optical transition (~637 nm) at 1.4 K was resolved, are interpreted. It is concluded that the rate of the ISC transition from the m _S =0 sublevel of the excited ³ E state to the singlet ¹ A state (~1 kHz) is much slower than the rates from the m _S =±1 substates, while the rates of ISC transitions to different m _S substates of the ground ³ A state are close to each other (~1 Hz). As a result, only the optical transition between m _S =0 sublevels in the ³ A-³ E manifold contributes strongly to the fluorescence. The experimentally observed double-exponential decay of the g ⁽²⁾(τ) function is explained by the two pathways available to the center for it to leave the S state: (i) the S→ T ₀(m _S )=0) transition and (ii) the S→T ⁰(m _S =±1) transitions followed by the slow spin-lattice relaxation T ₀(m _S =±1)→T ₀(m _S =0) (rate ~0.1 Hz). The work is important for studies where the NV center is used as a single photon source or for quantum information processing.     

Properties of strained TaS<Subscript>3</Subscript> samples in the state of charge density wave and in the normal state

The uniaxial strain of quasi-one-dimensional conductor whiskers of orthorhombic TaS₃ at a strain higher than ε _c ~ 0.8% leads to a sharp increase in the coherence of the properties of a charge density wave (CDW), which manifests itself in its motion in fields higher than threshold field E _t . During uniaxial elongation, TaS₃ is shown to exhibit the following unusual properties even in weak fields: Peierls transition temperature T _P depends nonmonotonically on ε, one-dimensional fluctuations weaken near T _P , and the coherence length of a charge density increases at T < T _P . Investigations in fields higher than E _t show that the ultracoherent properties of CDW exist in a wide temperature range and are retained when temperature increases up to T _P . These properties of CDW make it possible to observe a sharp increase in E _t near T _P and an almost jumplike increase in E _t at T < 90 K. The increase in E _t at T _P is explained by a decrease in the coherence volume of CDW because of a fluctuational suppression of the Peierls gap.     

Angular correlation measurements in the Be9(d,p, γ)Be10 reaction

Thep-γ angular correlations in the Be⁹(d, p, γ)Be¹⁰ reaction have been measured in the reaction plane atE _d =1.3, 1.5, 1.9, 2.3 and 2.45 MeV for proton anglesθ _p =35°, 80° and 120°. The anisotropy of the angular correlations measured forθ _p =35° is independent of deuteron energy. A systematic shift of the symmetry axis from the recoil direction has been observed. The shift is 20.5° at E_d=2.45 MeV. The anisotropy decreases with increasing proton angle and vanishes atθ _p =120°.     

Angular correlation measurements in the Cr53(p,n γ)Mn53 reaction

Then-γ angular correlation measurements for the Cr⁵³(p, nγ) Mn⁵³ reaction were performed atE _p=2.3, 2.4 and 2.5 MeV. The neutron detector was located in the reaction plane atθ _n=45?, 90? and 120? and perpendicularly to this plane atθ _n=Φ=90?. The experimental results obtained are in good agreement with predictions of the statistical compound-nucleus theory.     

Temperature dependence of the magnetization in the mixed state of superconducting alloys

The theory of Abrikosov of the immediate subcritical region in the mixed state is extended by means of the generalized Ginzburg-Landau theory to temperatures belowT _c and arbitrary mean free pathl of the electrons. The results for the magnetization and the free energy can still be presented in the form derived by Abrikosov apart from the fact thatκ is replaced by a new parameterκ ₂(T). The slope of the curveκ ₂/κ versust=T/T _c att=1 is found to decrease monotonically from ?0.105 to — (1.367-0.136κ ^?2) asl increases from zero to infinity. The results for short mean free paths are consistent with experiment, in particular,κ ₂ is always larger thanκ in the vicinity ofT _c . But the experimental temperature dependence ofκ ₂/κ in pure Nb is much higher than the theoretical one.     

Der Zerfall des Mn52m

Mn^52m(T _1/2=21 m) was produced by irradiating iron-foiles with deuterons ofE _d =9 MeV. Coincidences ofγ-rays with the main 1434 keV-transition had been sought for with the aid of a scintillation fast-slow-coincidence circuit. There was no evidence ofγ-lines which had been found earlier byKatoh et al. atγ-energies 700, 940, 1020, 1150, 1370, 1520 keV. If these transitions exist, their relative intensities are less than 0.7% (700 keV) and 0.3% (all others) per decay of Mn^52m.     

Die Coulomb-Energien leichter Atomkerne

A compilation of the known data on Coulomb energy differences of isobaric doublets and isobaric triplets is given. Plots of the Coulomb energy differences versus¯Z/A ^1/3 with¯Z=(Z ₁+Z ₂)/2 show an analogous shell structure behaviour for the three series with 2¯Z=A?1,A andA+1 (T=1, 1/2 and 1), i.e. discontinuities at the closed shells atA=4, 16 and 40 and the closed subshell atA=32 and oscillations mainly being due to Coulomb proton-proton pairing energy. A positive energy shift of the lowest states withT=1 of all self-conjugate nuclei withA=4n+2 seems to be indicated by the experimental data. A semi-empirical formula is given that describes the data.     

Nonergodic state of relaxation ferroelectric Cd<Subscript>2</Subscript>Nb<Subscript>2</Subscript>O<Subscript>7</Subscript> in a constant electric field

The temperature dependence of the residual polarization of the nonergodic relaxation state (NERS) obtained from the measurements of pyroelectric current during zero-field heating (ZFH) in the temperature interval from 10 to 295 K is investigated for the Cd₂Nb₂O₇ relaxation system in two cases: (1) after sample cooling in a constant electric field E (FC) from T = 295 K to a preset temperature, which is much lower than the “freezing” temperature of the relaxation state (T _f ≈ 182 K), field removal, and subsequent cooling in zero field (ZFC) to T = 10 K and (2) after ZFC from T = 295 K to the same temperature below T _f , application of the same field, and FC to T = 10 K. The behavior of the P _r ^FC (T) and P _r ^ZFC (T) dependences is analyzed. In the field E < 2 kV/cm, the P _r ^ZFC curves as functions of 1/T have a broad low-intensity peak in the region T ≈ T _f , which vanishes in stronger fields, when the P _r ^FC (1/T) curves intersect at T ≈ T _f and have no anomalies. The difference in the behavior of P _r ^ZFC (T) and P _r ^FC (T) indicates the difference in the nature of NERS formed during ZFC and FC of the system upon a transition through T _f . In the ZFC mode, NERS exhibits glasslike behavior; in the FC regime, features of the ferroelectric behavior even in the weak field. Analogous variations of P _r ^ZFC (T) and P _r ^FC (T) in a classical ferroelectric KDP are also given for comparison.     

Role of initial correlation in coarsening of a ferromagnet

We study the dynamics of ordering in ferromagnets via Monte Carlo simulations of theIsing model, employing the Glauber spin-flip mechanism, in space dimensionsd = 2 and3, on square and simplecubic lattices. Results for the persistence probability and the domain growth arediscussed for quenches to various temperatures (T _f ) below the criticalone (T _c ), from differentinitial temperatures T _i ≥T _c . In long timelimit, for T _i >T _c ,the persistence probability exhibits power-law decay with exponents θ ? 0.22 and? 0.18 in d = 2 and 3, respectively. For finite T _i , the early timebehavior is a different power-law whose life-time diverges and exponent decreases asT _i →T _c . The two steps areconnected via power-law as a function of domain length and the crossover to the secondstep occurs when this characteristic length exceeds the equilibrium correlation length atT =T _i . T _i =T _c is expected toprovide a new universality class for which we obtain θ ≡θ _c ? 0.035 ind = 2 and?0.105 in d = 3. The time dependenceof the average domain size ?, however, is observed to be rather insensitive tothe choice of T _i .     

Spectral manifestations of <Emphasis Type="Italic">d</Emphasis>-π exchange and charge transfer interactions in Cu(II) porphyrins

New absorption bands due to spin-forbidden transitions from the ground state to excited triplet states are found at 295 K in the near-IR absorption spectra of a number of Cu(II) complexes of octaethylporphyrin (OEP) that differ in the nature, number, and position of their side substituents. The frequency distribution, number, and nature of these transitions are analyzed using computer decomposition of complex contours into Gaussian components and additional data from the phosphorescence and phosphorescence excitation spectra (295-77 K). The d-π exchange integrals, determining the energy splitting ΔE = E(²T₁)–E(⁴T₁) in the compounds under study, are calculated on the basis of the experimental data obtained. It is shown that, in addition to the formally spin-allowed ²S₀ → ²T₁ transition (λ_max = 833 nm), the absorption spectrum of the nonplanar CuOETPP molecule at 295 K exhibits the low-intensity spin-forbidden ²S₀ → ⁴T₁ transition (λ_max = 937 nm). For this compound at 77 K, phosphorescence from the ⁴T₁ state is observed (λ_max = 955 nm), with a quantum yield equal to ?_Ph = 0.0015 and a decay time amounting to τ_Ph = 190 ns. For the CuOEP-Ph(o-NO₂) molecule, which contains the electron-acceptor nitro group, direct absorption from the ground state S₀ to a charge transfer (CT) state (λ_max = 845 nm) is observed at 295 K. The extinction coefficient of this absorption and the energy of the CT state are determined.     

Effect of phase transitions on the exciton absorption spectrum of Rb<Subscript>x</Subscript>K<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Ag<Subscript>4</Subscript>I<Subscript>5</Subscript> superionic conductors

The absorption spectrum of thin films of solid solutions of Rb_xK_1?xAg₄I₅ superionic conductors is investigated in the energy range 3–6 eV at temperatures from 90 to 290 K upon heating and cooling. It is established that the temperature dependences of the spectral position E _m and the half-width Γ of the long-wavelength exciton band are determined by the exciton-phonon interaction and the generation of Frenkel defects at phase transitions to the superionic state. Fluctuations of the composition of solid solutions do not affect the behavior of the dependences E _m (x) and Γ(x) at 90 K, which is indicative of the localization of excitons in the AgI sublattice of these compounds. A difference in the dependences T _c 1(x) and T _c 2(x) (the γ → β and β → α phase transitions, respectively) is revealed: the curve T _c 1(x) has a minimum at x ≈ 0.5, whereas the curve T _c 2(x) shows a weak maximum.     

The RgI<Subscript>2</Subscript> (ion-pair states) van der Waals complexes

This paper is an overview of our recent experimental investigations of the RgI₂ van der Waals complexes, Rg = He, Ar, Kr, performed by means of laser induced fluorescence spectroscopy, optical-optical double resonance and supersonic molecular beam techniques. Spectroscopic parameters of these complexes in the E0 _g ⁺ ion-pair state, such as binding energies and several spectroscopic constants, have been determined. Most likely, the potential energy surfaces of the all RgI₂(E) complexes under study present T-shaped minima. Vibrational and electronic predissociations of the RgI₂(E) complexes were analyzed. Relative contributions of the different electronic predissociation channels and vibrational distributions of the decay products were determined. Possible mechanisms of the complexes decay are suggested and discussed.     

Relationship between <Emphasis Type="Italic">T</Emphasis>-invariance and formation mechanisms for <Emphasis Type="Italic">T</Emphasis>-odd and <Emphasis Type="Italic">T</Emphasis>-even asymmetries in the angular distributions of fission fragments of oriented nuclei

The T-invariance condition was analyzed for the amplitude T _b,a of multiparticle multistep elastic or inelastic a → b nuclear reactions. This condition leads to the equality of the amplitude T _b,a to the amplitude \({\tilde T_{\bar a,\bar b}}\) of \(\bar b \to \bar a\) time-reversed reaction, for which the reaction operator \(\tilde T\) coincides with the inverse-reaction (b → a) operator. It is shown that, in the case where the original, inverse, and time-reversed reactions are governed by a common T-invariant mechanism, the coefficients D of asymmetries appearing in the differential cross sections for these reactions can be represented in the form of a unified scalar (pseudoscalar) function of arguments equal to the momentum and spin vectors of particles of the initial and final channels of the reactions under analysis. It is also shown that the use of the T-invariance condition for the coefficients D of asymmetries in the differential cross section for the original nuclear reaction that are different in P- and T-parity makes it possible to separate mechanisms leading to nonzero coefficients D for a number of the asymmetries under analysis from the remaining mechanisms leading to zero coefficients D of these asymmetries. It is proven that there exist such asymmetries in the differential cross section for the original reaction whose coefficients vanish for all possible T-invariant mechanisms of their appearance, so that, upon proving experimentally the appearance of nonzero coefficients of these asymmetries in the differential cross section for the original reaction, this fact can be used to assess features of T-noninvariant interactions in nuclear systems.     

Heat capacity of the Pb<Subscript>5</Subscript>(Ge<Subscript>1−<Emphasis Type="Italic">x</Emphasis></Subscript>Si<Subscript>x</Subscript>)<Subscript>3</Subscript>O<Subscript>11</Subscript> ferroelectric system

The temperature dependences of the molar heat capacity at constant pressure, C_p, of Pb₅(Ge_1?xSi_x)₃O₁₁ crystals with x=0, 0.39, and 0.45 in the range 5–300 K, as well as of their permittivity, dielectric losses, and the pyroelectric effect, have been measured. Experimental data on the temperature behavior of the heat capacity are presented in the form of a sum of two Debye and one Einstein terms, C_p(T)=0.405C_D1(Θ_D1=160 K, T)+0.53C_D2(Θ_D2=750 K, T)+0.046C_E(Θ_E=47 K, T). Besides a peak in the region of the ferroelectric Curie point T_c=450 K for crystals with x=0, the temperature dependences of the heat capacity did not reveal any other pronounced anomalies.     

Temperature dependence of the surface upper critical field of superconducting alloys

The temperature dependence of the surface upper critical field,H _c3, nearT _c is calculated for arbitrary values of the mean free pathl by taking into account the fourthorder term of the generalized Ginzburg-Landau theory. For finitel the boundary condition is modified such that the normal derivative of the energy gap at the surface becomes positive. The slope of the curveH _c3/H _c2 versust=T/T _c att=1 is found to decrease monotoneously from zero to ?1.040 as one goes from the “dirty” to the “clean” limit.     

Antiferromagnetic Resonance in GdB<Subscript>6</Subscript>

The electron spin resonance has been measured for the first time both in the paramagnetic phase of the metallic GdB₆ antiferromagnet (T_N = 15.5K) and in the antiferromagnetic state (T < T_N). In the paramagnetic phase below T* ~ 70 K, the material is found to exhibit a pronounced increase in the resonance linewidth and a shift in the g-factor, which is proportional to the linewidth Δg(T) ~ ΔH(T). Such behavior is not characteristic of antiferromagnetic metals and seems to be due to the effects related to displacements of Gd³⁺ ions from the centrosymmetric positions in the boron cage. The transition to the antiferromagnetic phase is accompanied by an abrupt change in the position of resonance (from μ₀H₀ ≈ 1.9 T to μ₀H₀ ≈ 3.9 T at ν = 60 GHz), after which a smooth evolution of the spectrum occurs, resulting eventually in the formation of the spectrum consisting of four resonance lines. The magnetic field dependence of the frequency of the resonant modes ω₀(H₀) obtained in the range of 28–69 GHz is well interpreted within the model of ESR in an antiferromagnet with the easy anisotropy axis ω/γ = (H ₀ ² +2H_AH_E)^1/2, where H_E is the exchange field and H_A is the anisotropy field. This provides an estimate for the anisotropy field, H_A ≈ 800 Oe. This value can result from the dipole?dipole interaction related to the mutual displacement of Gd³⁺ ions, which occurs at the antiferromagnetic transition.     

The anisotropic conductivity of two-dimensional electrons on a half-filled high Landau evel

We study the conductivity of two-dimensional interacting electrons on the half-filled Nth Landau level with N?1 in the presence of quenched disorder. The existence of the unidirectional charge-density wave state at temperature T<T _c , where T _c is the transition temperature, leads to the anisotropic conductivity tensor. We find that the leading anisotropic corrections are proportional to (T _c ?T)/T _c just below the transition, in accordance with the experimental findings. Above T _c , the correlations corresponding to the unidirectional charge-density wave state below T _c result in corrections to the conductivity proportional to \(\sqrt {{{T_c } \mathord{\left/ {\vphantom {{T_c } {T - T_c }}} \right. \kern-\nulldelimiterspace} {T - T_c }}} \).