CO concentration and temperature measurements in a shock tube for Martian mixtures by coupling OES and TDLAS

CO concentration and gas temperature distribution are diagnosed behind a strong shock wave simulating the Martian atmosphere entry processes by coupling optical emission spectroscopy (OES) and tunable diode laser absorption spectroscopy (TDLAS). The strong shock wave (6.31 ± 0.11 km/s) is established in a shock tube driven by combustion of hydrogen and oxygen. Temperature of the shock-heated gas is inferred through a precise analysis of the high temporal and spatial resolution experimental spectral of CN violet system (B ² Σ ⁺ →X ² Σ ⁺, Δv = 0 sequence) using OES. A CO absorption line near 2,335.778 nm is utilized for detecting the CO concentration using scanned-wavelength direct absorption mode with 50 kHz repetition rate. Combined with temperature results from OES, CO concentration in the thermal equilibrium region is derived. The current experimental results are complementary for determining an accurate rate coefficient of CO₂ dissociation and validation relevant chemical kinetics models in Mars atmosphere entry processes.     

Nonuniqueness of a massive spin-2 theory

The nonunique nature of massive spin-2 fields is explicitly shown in this paper through the construction of all possible field equations, using Dirac formalism for spin-1/2 fields. Out of these four possible theories, we point out two that do not show up scalar representations.     

Selftuned massive spin-2

We calculate the cubic order terms in a covariant theory that gives a nonlinear completion of the Fierz–Pauli massive spin-2 action. The resulting terms have specially tuned coefficients guarantying the absence of a ghost at this order in the decoupling limit. We show in this limit that: (1) The quadratic theory propagates helicity-2, 1, and helicity-0 states of massive spin-2. (2) The cubic terms with six derivatives – which would give ghosts on local backgrounds – cancel out automatically. (3) There is a four-derivative cubic term for the helicity-0 field, that has been known to be ghost-free on any local background. (4) There are four-derivative cubic terms that mix two helicity-0 fields with one helicity-2, or two helicity-1 fields with one helicity-0; none of them give ghosts on local backgrounds. (5) In the absence of external sources, all the cubic mixing terms can be removed by nonlinear redefinitions of the helicity-2 and helicity-1 fields. Notably, the helicity-2 redefinition generates the quartic Galileon term. These findings hint to an underlying nonlinearly realized symmetry, that should be responsible for what appears as the accidental cancellation of the ghost.     

Concentration of CO2 dissociation products in a capillary discharge in a CO2-N2-He mixture

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 51, No. 1, pp. 12–16, July, 1989.     

Diode laser spectroscopy of H2O and CO2 in the 1.877-μm region for the in situ monitoring of the Martian atmosphere

A diode laser spectrometer was used in the laboratory to study H₂O and CO₂ line intensities and self-broadening coefficients around 1.877 μm. The spectral region ranging from 5327 cm^-1 to 5329 cm^-1, which is suitable for the in situ sensing of water vapor and carbon dioxide in the Martian atmosphere, was studied using a distributed feedback GaInSb diode laser from Nanoplus GmbH. We have studied one line from the (011)←(000)band of H₂O and two lines from the (01¹2)_I←(000) band of CO₂. The results of intensity and self-broadening measurements are compared to available databases, ab initio calculations and previous experimental determinations. Finally, we discuss the current development of the tunable diode laser absorption spectrometer instrument, a laser diode sensor devoted to the in situ measurement of H₂O and CO₂ in the Martian atmosphere. PACS 07.57.Ty; 07.87.+v     

CO observations of massive star forming regions at different evolutionary phases

The ¹²CO (J=1-0), ¹³CO (J=1-0) and C¹⁸O (J=1-0) emissions in 9 massive star forming regions, which are believed to be at different stages of massive star formation, were mapped with the 13.7 m millimeter wave telescope at Qinghai Station of Purple Mountain Observatory. Of the observed 9 sources, ¹³CO cores were detected in seven of them, and C¹⁸O cores in five of them. And only two sources associated with C¹⁸O cores and H₂O masers showed the extended structures and strong outflows. This is the first detection of outflow associated with IRAS 22566+5828 in the observing field of S152/S153. The physical parameters of cores and outflows for these sources, derived from Local Thermal Equilibrium (LTE) analysis, are presented. These observing results suggest that the C¹⁸O cores will only appear when the gas density is high enough and the probability to have an outflow is very high when the clumps show the C¹⁸O and H₂O maser simultaneously.     

Optically stimulated luminescence dating properties of Martian sediment analogue materials exposed to a simulated Martian solar spectral environment

Deciphering the geomorphic, climatic, and hydrologic history of Mars will require an extensive geochronology on numerous time scales from both returned samples and in-situ measurements. Optically stimulated luminescence dating (OSL), or optical dating, is an established terrestrial geochronological method that is being developed as a member of a suite of dating tools for Mars. As part of this development process, we have built an optical system simulating the calculated Martian solar spectral irradiance taking into account seasonal variations due to attenuation of dust and the planet's orbital position and used it to catalogue the UV dosimetric response and optical dating behavior of a group of sediment analogues exposed to a simulated Martian spectral environment (SMSE) for the surface of the planet. Our results suggest that optical dating should not be compromised by the interaction of the enhanced UV radiation in the Martian spectrum with K-feldspar, Ca-feldspar, anhydrite, or hydrous Ca and Mg sulfates on Mars. However, Na-feldspar appears to be capable of acquiring and retaining an OSL signal under SMSE conditions, which could present a challenge for optical dating on Mars in sedimentary deposits containing more than a trace quantity of sodic feldspars.