共查询到20条相似文献,搜索用时 15 毫秒
1.
Ivanova Yu. B. Chizhova N. V. Mamardashvili N. Zh. 《Russian Journal of Organic Chemistry》2019,55(10):1554-1561
Russian Journal of Organic Chemistry - The bromination of [5-(4-nitrophenyl)-10,15,20-triphenylporphyrinato]cobalt(II) and [5,10,15-tris-(4-nitrophenyl)-20-phenylporphyrinato]cobalt(II) with... 相似文献
2.
Unsymmetrical dendrons 1, 2 and 3 were easily prepared accordins to a novel convergent strategy from 3, 4-methylene-dioxybenzaldehyde as starting material. 相似文献
3.
Shastin A. V. Korotchenko V. N. Varseev G. N. Nenaidenko V. G. Balenkova E. S. 《Russian Journal of Organic Chemistry》2003,39(3):403-407
A general procedure for the synthesis of -iodostyrenes is proposed. Aromatic aldehyde and ketone hydrazones are converted into the corresponding -iodostyrenes by treatment with CHI3 in the presence of a catalytic amount of CuCl. 相似文献
4.
2-Benzyl-3-(methylsulfoximino)propionic acid has been prepared from 2-benzyl-3-(methylthio)propionamide by cyclization to a isothiazolinone hydrochloride with N-chlorosuccinimide, followed by peracid oxidation and acidic hydrolysis. 相似文献
5.
A synthesis of β-stannyl esters from ester enolates and iodomethyl (tri-n-butyl) stannane (3) is described. 相似文献
6.
Natural products icaritin and β-anhydroicaritin with P-glycoprotein(P-gp) inhibitory activities were ciently synthesized in nine steps from commercially available phloroglucinol. A modified Algar-Flynn-Oyamada cyclization and relay Claisen-Cope rearrangement were employed in this concise route. Oiir synthesis offers opportunities to synthesize various icariin analogues for biological and pharmacological investigations. 相似文献
7.
Vladimir S. YarmolchukPavel K. Mykhailiuk Igor V. Komarov 《Tetrahedron letters》2011,52(12):1300-1302
A synthetic strategy towards the novel amino acid β-fluoro-β-proline, a fluorinated analogue of β-proline, is elaborated. The synthesis commences from commercially available methyl 2-fluoroacrylate and involves three steps. The overall yield of β-fluoro-β-proline is 57%. 相似文献
8.
β-Ketosulfoxideshaveattractedmanyorganicchemistsbecauseoftheirwideuseinsynthesisofketones,a-ketols,glyoxals,a-ketoacids,glycols,a-hydroxyacidsandsoculGenerally,6-ketosulfoxidescanbepreparedbythereactionofesterwithsulfoxidel',acylchloridewithsulfoxi... 相似文献
9.
V. V. Belakhov A. V. Garabadzhiu I. V. Boikova I. A. Antonova 《Russian Journal of General Chemistry》2017,87(3):456-462
A method of synthesis of β-D-xylopyranoside thiophosphate derivatives was developed. Biological testing revealed a high insecticidal activity in the synthesized compounds. 相似文献
10.
Shipilov D. A. Kurochkina G. I. Levina I. I. Malenkovskaya M. A. Grachev M. K. 《Russian Journal of Organic Chemistry》2017,53(2):290-295
Russian Journal of Organic Chemistry - Reactions of 6-bromo- and 6-iodo-6-deoxy-β-cyclodextrin with organic amines of diverse nature afforded a series of monocationic derivatives with aminium... 相似文献
11.
Jing Xin ZHANG Xiao Chuan TAN Ping XIE Xiao Tian LIANG Institute of Material Medica Chinese Academy of Medical Sciences & Peking Union Medical College Beijing 《中国化学快报》2000,11(11)
Much attention has been paid to carbolines in recent years, owing to the wide range of their biological activity 1. Many papers have reported the synthesis and reactivity of carbolines2,3. Generally there are two ways to synthesize carbolines. One is through the Bischler-Napieralski reaction, and the other through Pictet-Spengler reaction. In the former method, the reaction of carboxylic acids with tryptophan using PPE or POCl3 as the condensing agent give dihydro-?-carbolines, which are c… 相似文献
12.
A method for the synthesis of β-nitramino derivatives ofgem-dinitroalkanes by nitration of the products of condensation of sulfamic acid derivatives with the correspondinggem-dinitroalkanes was proposed. 相似文献
13.
M. I. Kabachnik L. S. Zakharov E. I. Goryunov P. V. Petrovskii T. M. Shcherbina 《Phosphorus, sulfur, and silicon and the related elements》2013,188(3-4)
Abstract The methods of synthesis unsymmetrical polyfluoroalkyl phosphates (II) by catalytic phosphorylation of phenols or polyfluoroalkanols by chlorophosphates (I) were elaborated 相似文献
14.
Jian Feng GE Li Fen ZHANG Zong Xuan SHEN Ya Wen ZHANG* Department of Chemistry Chemical Engineering Suzhou University Suzhou Department of Material Engineering Suzhou University Suzhou 《中国化学快报》2001,(7)
Mercaptoalcohols are a rare class of natural products. Some optically active mercaptoalcohols have been used as catalysts in asymmetric reduction of prochiral Ketone1,2. In this letter, we report the synthesis of a new optically active (-mercaptoalcohols, (R)-1,1-diphenyl-2-mercapto-3-methyl-1-butanol 7, from L- valine.Our first attempt is showed in Scheme 1. According to literature's method L-valine was converted to (S)-2-Hydroxy-3-methylbutanoic acid 21,2. 2 was treated with MeOH/SOCl2… 相似文献
15.
New bimolecular sulfur-containing -phenylethylamines and N-benzyltetrahydroisoquinolines have been synthesized from formyl derivatives of diaryl sulfides. The possibility of using metals as catalysts for obtaining diaryl sulfides in the reaction of ortho-substituted benzaldehydes with SCl2 has been shown for the first time.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, fax (3712) 89 14 75. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 731–735, September–October, 1995. Original article submitted November 11, 1994. 相似文献
16.
An efficient synthesis of high generation conjugated polyphenylene dendrimer-based β-diketones was investi- gated using simple synthetic methods. The new dendrimer-based β-diketones were characterized by NMR, MS and elemental analysis. The UV-Vis and fluorescence spectra of these β-diketones in different solvents were investigated The photoluminescent (PL) quantum yield and TG and DSC curves were also investigated. A new intermediate, 1-bromo-3,5-diiodobenzene, was developed to synthesize high generation dendrimers with good yields. 相似文献
17.
Marianne Lenes Rosenberg 《Tetrahedron letters》2009,50(47):6506-6508
Pd(OAc)2-catalyzed decomposition of ethyl 2-diazo-4-(4-indolyl)-3-oxobutanoate leads to a tricyclic tetrahydrobenzindole compound formed by a formal C-H insertion reaction. This tricyclic indole rearranges to a novel and thermodynamically more stable naphthalene derivative. Treatment of N-tosyl-protected ethyl 2-diazo-4-(4-indolyl)-3-oxobutanoate with a base induces facile pyrazole formation. 相似文献
18.
A Facile Synthesis of β-Cyclodextrin Monoaldehyde 总被引:3,自引:0,他引:3
Cyclodextrinsandtheirderivativeshaveplayedimportantrolesinsuchdiversefieldsaschiralseperation,artificalenZymes,asymmetricsynthesisanddrugdelivery'.ThecyclodextrinmonoaldehydeisanewlydevelopedintermediatetosynthesizenovelderivativesthroughreductiveaminationinthepresenseofsodiumcyanoborohydrideThereportedsynthesisofcyclodextrinmonoaldehydeinvolvedtheoxidationofp-CDmonotosylatebyDMSOinthepresenceofcollidineordiisopropylethylamine",ordirectoxidationofP-CDwithDess-Martinperiodinane(DMP)'.Thel… 相似文献
19.
Several new monocyclic β-lactam monomers bearing the NO2 group 2a–g were synthesized via a [2 + 2] ketene–imine cycloaddition reaction (Staudinger reaction). Calculation of coupling constant of H-3 and H-4, and the X-ray crystallography of β-lactam 2e confirmed the cis stereochemistry of these β-lactams. Then aminophenyl β-lactams were synthesized by the reduction of NO2 to NH2 group in the presence of Raney Ni and hydrazine hydrate. Treatment of these aminophenyl β-lactams with acryloyl chloride and sodium bicarbonate (NaHCO3), afforded the monomers bearing the NHCOCH=CH2 group. These acrylated β-lactam monomers were dissolved in a warm mixture of butyl acrylate and styrene and then were converted to the corresponding polyacrylate nano β-lactams by emulsion polymerization in water. A unique feature of this methodology is the ability to incorporate water-insoluble compounds directly into the nanoparticle framework. Structures of the synthesized compounds were confirmed by physical and spectral analyses. Dynamic light scattering analysis and transmission electron microscopy of the final emulsions show that the nanoparticles were about 50–70 nm in diameter. 相似文献
20.
Rajendran Suresh 《合成通讯》2013,43(14):1696-1703
A simple and efficient protocol for the construction of medicinally important substituted isoquinolines through intramolecular cyclization of β-hydroxyarylethanamides using acetic anhydride and phosphorous pentoxide in dioxane has been described. The chemo- and regioselectivities due to the influence of different catalysts were investigated and optimized for good to excellent yields. All the synthesized compounds have been characterized by NMR and mass spectral analyses. 相似文献