Supersensitive electronic transition in impurity Nd-Nd nanoclusters in CaF<Subscript>2</Subscript> crystal

A comparison of the theoretical calculations with the results of experiments on high-resolution laser spectroscopy made it possible to reveal the fine structure that arises in the supersensitive ⁴I_9/2? ⁴G_5/2 transition as a result of a strong coherent interaction in the Nd³⁺ ion pair in the CaF₂ crystal and construct the level splitting diagram for the ground and excited states of impurity Nd-Nd nanoclusters.     

Scattering of molecular beams from surfaces

Molecular beam scattering from surfaces offers a unique method for studying elementary gas-solid collisions. Recent technological advances have made it possible to study elastic and inelastic scattering from clean surfaces characterized by LEED and Auger spectroscopy. These experiments have provided information on surface structures, with and without adsorbed gases, on the gas-surface interaction potential, and on inelastic collisions involving phonon annihilation and creation. These recent measurements are reviewed and discussed in terms of the latest theoretical work.     

Pion-Nucleon Scattering Experiments at Low Energies

Pion-nucleon scattering and charge-exchange experiments aim at a determination of the pion-nucleon coupling constant, the sigma term of chiral symmetry breaking in non-perturbative QCD and the possible isospin breaking of strong interactions. A review of the present situation shows that the accuracy of the results is still limited by the existing data base despite 20 years of experimental efforts at meson factories. The present new generation of experiments at PSI and TRIUMF, using novel instrumentation, promises considerable progress.     

The need is compelling to perform an experiment capable of determining the velocity of gravitational interaction

In earlier papers some proposals were made concerning experiments that could lead to the determination of the velocity of the gravitational interaction. This paper points out that this determination can only be achieved by measuring the delayed gravitational field and not by measuring the propagation velocity of gravitational radiation, which remains a controversial problem, both theoretically and experimentally. The possibility is shown of the existence of a gravitational effect not unlike the Poynting-Robertson light effect and the importance is discussed of its determination for space and astronomical research. Some of the proposed mechanisms for explaining the gravitational interaction are reviewed and their nonviability is objectively pointed out. Finally, conclusions are drawn as to the necessity of carrying out experiments to determine the velocity of the gravitational interaction.     

Search for magnetic interaction in In doped AlN using perturbed angular correlation spectroscopy

The possible presence of a large magnetic field due to spin polarization of a Cd nucleus (decay product of ¹¹¹In) at an Al substitutional site in AlN is investigated with perturbed angular correlation (PAC) spectroscopy. The PAC spectra of ¹¹¹In/¹¹¹Cd in AlN show two probe environments: a weak quadrupole interaction (quadrupole interaction constant, $\nu _{\rm Q}^{\,\,\,\rm lattice} = 30$  MHz) due to ¹¹¹In probes at a defect free Al substitutional site and an unknown large interaction ( $\nu _{\rm Q}^{\,\,\,\rm complex} = 300$  MHz) tentatively attributed to a nearest neighbour pair between ¹¹¹In and a nitrogen vacancy (V_N) aligned along the c-axis. Surprisingly, in density functional theory (DFT) calculations, such a large electric field gradient (EFG) could not be reproduced. However, an inclusion of spin polarization in the calculations indicates a strong magnetic field at ~50 % of the ¹¹¹In/¹¹¹Cd site. An attempt to verify the presence of the strong magnetic field and to explain the origin of the strong interaction is made. Orientation measurements show, the large interaction is not characterised by a magnetic interaction and is predominantly due to the EFG. However, in the presence of an external magnetic field, the strong interaction probe environment becomes more uniform and the EFG increases by ~10 %. This definitely hints towards some sort of magnetic interaction at the strong interaction probe site.     

New precision measurements of the strong interaction in kaonic hydrogen

The DEAR experiment performed at the DAΦNE electron-positron collider (Frascati, Italy) studied the strong interaction shift and width of the 1s state in kaonic hydrogen using X-ray spectroscopy. The repulsive character of the kaon-proton interaction at threshold was confirmed and the most precise values of the shift and width were obtained. However, high precision data at the percent level are highly requested to further develop the theories and thus our understanding of the low-energy antikaon-nucleon interaction. Therefore, a new series of precision experiments on kaonic hydrogen and kaonic deuterium are planned at LNF.     

Hot spots and pseudogaps for hole- and electron-doped high-temperature superconductors

Using cluster perturbation theory, it is shown that the spectral weight and pseudogap observed at the Fermi energy in recent angle resolved photoemission spectroscopy of both electron- and hole-doped high-temperature superconductors find their natural explanation within the t-t(')-t(")-U Hubbard model in two dimensions. The value of the interaction U needed to explain the experiments for electron-doped systems at optimal doping is in the weak to intermediate coupling regime where the t-J model is inappropriate. At strong coupling, short-range correlations suffice to create a pseudogap, but at weak-coupling long correlation lengths associated with the antiferromagnetic wave vector are necessary.     

Excitation and ionization of positronium by 50–100 fs laser pulses

The interaction between Ps and a strong laser pulse of short duration is studied. Substantial population is deposited in excited states under few photon excitation. The possible usefulness as a source of excited Ps to spectroscopy and the formation of antihydrogen is discussed. Finally, photoelectron energy spectra are calculated. This revised version was published online in August 2006 with corrections to the Cover Date.     

气相沉积法制备均苯四甲酸二酰亚胺纳米材料及传感应用

以均苯四甲酸二酰亚胺（PMD）为原料,采用真空气相沉积法制得PMD纳米自组装材料,由此建立了测定三硝基甲烷的荧光化学传感新方法。采用真空气相沉积法自组装PMD纳米材料,并用扫描电镜、透射电镜、红外光谱、紫外光谱、差热分析及荧光光谱对材料进行了表征。扫描电镜图像显示,PMD纳米材料呈带状网络结构,长度为30~100 μm;TEM图像表明,PMD纳米带宽度为100~300 nm,其中纳米线直径为120~220 nm。在PMD分子自组装过程中,分子间氢键、π-π等弱相互作用是构筑纳米结构的主要驱动力。一些较低沸点有机分子蒸汽对PMD纳米材料的荧光（λ_ex/λ_em=377 nm/495 nm）有猝灭作用,尤其是PMD纳米材料对三硝基甲烷有灵敏的响应。测定三硝基甲烷的线性范围为2.19×10^-5~1.37×10^-4 mol/L,R²=0.995,检出限为1.02×10^-6 mol/L。     

核物质和夸克物质的对称能（英文）

对称能表征了同位旋非对称强相互作用物质状态方程的同位旋相关部分,它对于理解核物理和天体物理中的许多问题有重要意义。简要总结了关于核物质和夸克物质对称能研究的最新进展。对于核物质对称能,通过对核结构,核反应以及中子星的研究,目前对其亚饱和密度的行为已有比较清楚的认识,同时,对饱和密度附近对称能的约束也取得了很好的研究进展。但如何确定核物质对称能的高密行为仍然是一个挑战。另一方面,在极端高重子数密度条件下,强相互作用物质将以退禁闭的夸克物质状态存在。同位旋非对称夸克物质可能存在于致密星内部,也可能产生于极端相对论重离子碰撞中。对最近关于夸克物质对称能对夸克星性质的影响以及重夸克星的存在对夸克物质对称能的约束的研究工作进行了介绍,结果表明同位旋非对称夸克物质中上夸克和下夸克可能感受到很不一样的相互作用,这对于研究极端相对论重离子碰撞中部分子动力学的同位旋效应有重要启发。The symmetry energy characterizes the isospin dependent part of the equation of state of isospin asymmetric strong interaction matter and it plays a critical role in many issues of nuclear physics and astrophysics. In this talk, we briefly review the current status on the determination of the symmetry energy in nucleon (nuclear) and quark matter. For nuclear matter, while the subsaturation density behaviors of the symmetry energy are relatively well-determined and significant progress has been made on the symmetry energy around saturation density, the determination of the suprasaturation density behaviors of the symmetry energy remains a big challenge. For quark matter, which is expected to appear in dense matter at high baryon densities, we briefly review the recent work about the effects of quark matter symmetry energy on the properties of quark stars and the constraint of possible existence of heavy quark stars on quark matter symmetry energy. The results indicate that the u and d quarks could feel very different interactions in isospin asymmetric quark matter, which may have important implications on the isospin effects of partonic dynamics in relativistic heavy-ion collisions.     

The infra-red and Raman spectra of ice

This paper has reviewed all of the available work on the infra-red and Raman spectroscopy of hexagonal and cubic ice. It has been shown by the studies of Maisch (1956) and Ockman (1957) that it is not possible to obtain a unique solution to the structure problem of ice by measuring its polarized vibration spectrum. However, Maisch's observation of the constancy of the depolarization ratio across each of the bands in the hydrogen stretching region is a strong argument for a disordered structure.

Satisfactory assignments have only been made for the three bands originating in the fundamental modes of the water molecule and for the six strong bands which can be correlated with the overtone and combination modes of the liquid and vapour spectra. An explicit characterization of the low frequency bands in terms of lattice motions must await a solution to the lattice-dynamical problem as well as a careful study of the low frequency, polarized spectra of single crystals.

The solution to the dynamical problem of the ice lattice should make possible a determination of the crystal anharmonicities. This would then enable one to assign the overtone and combination bands.     

Definitive experimental evidence for two-band superconductivity in MgB2

The superconducting-gap of MgB2 has been studied by high-resolution angle-resolved photoemission spectroscopy. The results show that superconducting gaps with values of 5.5 and 2.2 meV open on the sigma band and the pi band, respectively, but both the gaps close at the bulk transition temperature, providing a definitive experimental evidence for the two-band superconductivity with strong interband pairing interaction in MgB2. The experiments validate the role of k-dependent electron-phonon coupling as the origin of multiple-gap superconductivity as well as the high transition temperature of MgB2.     

On the potential of human sinus cavity diagnostics using diode laser gas spectroscopy

A method for studying human sinus cavities and inflammation status is described. Diode laser spectroscopy of molecular oxygen gas in the cavity is performed at 760 nm through the strongly scattering facial tissue in a backscattering geometry. Model experiments on tissue-like scattering plastics were made to elucidate the possible penetration depths and the expected signal levels. Measurements on the frontal sinuses of a healthy volunteer verify the viability of the technique. The potential for dynamic gas measurements of the possible occlusion of the channels connecting the sinuses with the nasopharyngeal cavity are discussed, and demonstrated in model experiments using a gas with a composition different from that of the ambient air. Extensions to other biomedical diagnostics arenas are discussed. The results obtained suggest that a complementary method for real-time and non-intrusive medical diagnostics using compact instrumentation could be developed.     

An RF quadrupole–time-of-flight system for isobar-separation and multiplexed low-energy Rare-Isotope Beam experiments

A novel system consisting of RF quadrupole and time-of-flight sections is proposed, in which ions can be cooled, bunched, mass separated with a resolution sufficient to differentiate between isobars, and guided to different experimental setups, e.g. for precision mass measurements or mass-resolved decay spectroscopy. It enables multiplexed operation of several connected experiments and interleaved measurements using different nuclides in one connected experiment. Such a system could be employed advantageously at in-flight facilities, at which experiments with stopped exotic nuclei are made possible using gas-filled stopping cells, such as SHIPTRAP at GSI, or potentially at ISOL facilities. First results for individual stages of the system are presented.     

Imaging of laser-polarized solid xenon

The enhanced spin polarization produced by optical pumping of gaseous rubidium/xenon samples has made possible a number of recent experiments in nuclear magnetic resonance (NMR) spectroscopy and magnetic resonance imaging (MRI). Here we report MRI of laser-polarized xenon in the solid phase at low temperature. Due to the high xenon density in the solid phase and the enhanced spin polarization, it is possible to achieve high intensity and spatial resolution of the image. Signals were observed from xenon films solidified onto the glass container walls and not from an enclosed chili pepper.     

Mössbauer effect in small particles

Mössbauer spectroscopy is very sensitive to the special magnetic properties of ultrafine particles. Studies of particles in the superparamagnetic state allow determination of the particle size and the magnetic anisotropy energy constant A strong magnetic interaction between the particles may result in ordering of the magnetic moments of particles which would be superparamagnetic if they were non-interacting. This so-called superferromagnetic state can also be characterized by Mössbauer spectroscopy measurements. Furthermore, because a large fraction of the atoms in very small particles are in the surface layer, Mössbauer spectroscopy can be applied for studies of surface magnetism in small particles.     

火焰发射光谱测定微量钡的方法研究

本文在原子吸收光谱仪的发射方式上，选择钡５５３．５ｎｍ发射线，以空气乙炔火焰为发射光源，进行了火争发射法测钡的方法研究。全面讨论了测试条件和干扰试验，并与ＩＣＰ－ＡＥＳ、笑气乙炔ＡＡＳ，以及空气乙炔ＡＡＳ进行了比较，还讨论了乙醇的增感作用，并对出口材料中的可溶性钡进行了测定比较，得到满意结果。     

Excited level lifetime measurements following very low energy nuclear recoils

Using high resolution gamma spectroscopy it is possible to observe Doppler broadening of gamma transitions from excited states which have themselves been populated after emission of gamma photons or other low energy nuclear radiation. This allows the determination of the lifetimes of these intermediate states, providing the time dependence of the recoil velocities is known. Conversely, if the lifetime is well known, this technique may be used to study the recoil process itself (and hence the atomic interaction) at energies of only a few times the lattice binding energy.     

Laser Stark and diode laser spectroscopy of the 10-μm bands of CH2NH: Determination of the dipole moment orientation

The complexities apparent in the laser Stark spectra obtained from the 10-μm band system of CH₂NH are shown to be due to the interplay of the a and b components of the Coriolis and Stark effect coupling. As a result it has been possible to determine the relative orientations of the a and b components of the permanent electric dipole moment. This is analogous to the determination of the relative signs of the dipole moment derivatives from the analysis of the intensity perturbations produced by Coriolis interaction.A detailed comparison has also been made of the uses of laser Stark, diode laser, and Fourier transform spectroscopy for studying heavily perturbed molecular spectra.