Onset of parametric electroconvection in a nematic liquid crystal

The behavior of a nematic liquid crystal (NLC) in an external ac electric field is studied in terms of the weak electrolyte model. Since electroconvection of certain types of NLCs can occur in a constant field in an oscillatory mode, a quasi-periodic response of a nematic to the external action is possible in an ac field, as well as a sharp reduction of the electroconvective stability thresholds at resonance frequencies. Stability maps for NLCs are plotted on the plane of amplitude-frequency parameters of the external field. Phase portraits are constructed for subharmonic and synchronous perturbations. The optical response of a NLC in the ac electric field is studied; the time dependences of the relative intensity of light, which passed through the nematic liquid crystal cell, are obtained.     

Chaotic dynamics in the electroconvection system of a nematic liquid crystal

The transition from a steady domain structure to turbulence in the electroconvection system of a nematic under the action of a constant electric field is studied using the methods of optical and acoustic responses. The chaotic dynamics is investigated both by conventional methods (Fourier signal spectrum) and by methods of nonlinear dynamics. From the quantitative estimates of basic characteristics of the chaotic behavior (namely, the correlation dimension, leading Lyapunov exponent, K-entropy, and embedding dimension), one can conclude that temporal chaos arises in the system, giving rise to a strange attractor, as the control parameter increases at ɛ ≥ ɛ _c ≈ 0.5. The fact that the distribution of laminar domains in the liquid-crystal layer depends on their length under the conditions of developed turbulence indicates that the dynamics of the nematic demonstrates the intermittent behavior.     

Electroconvection in homeotropic nematic liquid crystals

Electroconvection is a classical example of pattern-forming phenomena in liquid crystals, typically observed in nematics with negative dielectric and positive conductivity anisotropies. This article focuses on how electroconvection in the homeotropic geometry differs from that in planar alignment. The influence of an additional magnetic field on the pattern characteristics and on secondary instabilities (the normal roll–abnormal roll transition) is discussed. The homeotropic alignment offers unique possibilities also for studying defect motion. Basic characteristics of some patterns of large wavelength are presented and compared with those of the classical Carr–Helfrich structures. Finally, electroconvection in substances with negative conductivity anisotropy is addressed.     

Inertial mechanism of domain formation in a homeotropic nematic liquid crystal under periodic shear

Formation of a domain structure in a homeotropic liquid crystal layer under the action of a periodic Couette flow is studied. The effect is analyzed using hydrodynamic equations for the nematic liquid crystal. Comparison of the results of calculations with experimental data testifies that, at high frequencies, the formation of domains is governed by inertial effects. It is shown that the inertial mechanism leads to a scaling dependence of the threshold shear amplitude on frequency ω and layer thickness h in the form u _th ～ (ωh ²)^?1.     

Dynamics of fluctuations below a stationary bifurcation to electroconvection in the planar nematic liquid crystal N4

We fitted C(k,tau,epsilon) proportional to exp([-sigma(k,epsilon)tau] to time-correlation functions C(k,tau,epsilon) of structure factors S(k,t,epsilon) of shadowgraph images of fluctuations below a supercritical bifurcation at V(0)=V(c) to electroconvection of a planar nematic liquid crystal in the presence of a voltage V=sqrt[2]V(0)cos((2pift) [k=(p,q) is the wave vector and epsilon identical with V(2)(0)/V(2)(c)-1]. There were stationary oblique (normal) rolls at small (large) f. Fits of a modified Swift-Hohenberg form to sigma(k,epsilon) gave f-dependent critical behavior for the minimum decay rates sigma(0)(epsilon) and the correlation lengths xi(p,q)(epsilon).     

Surface driven transition in a nematic liquid crystal cell

Surface driven reorientation effects in a nematic liquid crystal cell caused by light-induced changes of the anchoring parameters were studied. Theoretical consideration of one-dimensional flat distributions of the director has shown that the director can undergo threshold reorientation between hybrid, homeotropic, and planar alignments as the anchoring energy varies continuously. The threshold reorientation takes place when the reference and light-induced easy axes are perpendicular. In the one-elastic-constant approximation the light-induced transition was found to be of second order as shown by a critical increase of the director thermal fluctuations in the vicinity of the transition point. These effects were experimentally studied in the cells containing 5CB liquid crystal aligned by the photosensitive azo-containing polymer layer. Zh. éksp. Teor. Fiz. 112, 2045–2055 (December 1997) Published in English in the original Russian journal. Reproduced here with stylistic changes by the Translation Editor.     

双轴性向列相液晶的相变理论

假设一双轴性向列相液晶分子简单相互作用模型，利用平均场理论，得到从各向同性相至单轴向列相、单轴向列相至双轴向列相的相变. 结果表明，在一定温度范围内，分子形状的非轴对称性可导致系统双轴向列相的产生. 在核磁共振实验中，导出双轴向列相序参数与谱线分裂频率间的一般关系，并讨论序参数测量性的可能性. 关键词： 向列相液晶 相变     

An azo-isomerization-induced Freedericksz transition of a nematic liquid crystal

We observed an azo-isomerization-induced Freedericksz transition of the 5CB liquid crystal doped with 1% double-azo. In experiment, we found that the Freedericksz transition threshold occurred at optical intensity level of 0.3 mW/mm² for the 12.5 μm-thickness planar alignment doped 5CB, which is four orders of magnitude lower as that for the pure 5CB. Using optical phase retardation, we measured the relations between the Freedericksz transition threshold and the pump beam polarization. The maximum twist angle of liquid crystal molecules under different pump beam intensity is given. The experiment indicated that trans–cis isomerization plays an important role in the decrease of the Freedericksz transition threshold.     

Determination of thermal instabilities thresholds for homeotropic and planar nematic liquid crystal samples

Thermal instabilities have been observed when a nematic liquid crystal sample is submitted to a temperature gradient. The value and the sign of the gradient threshold depend on the initial liquid crystal configuration. We calculate the gradient threshold for planar and homeotropic configurations by solving the exact two-dimensional problem taking into account the boundary conditions.     

Wetting transition of a nematic liquid crystal on a periodic wedge-structured substrate

It is known that the wetting behaviour of a fluid is deeply altered by the presence of rough or structured substrates. We first review some simple considerations about isotropic fluids and rough substrates, and then we generalize Wenzel's law, which assigns an effective contact angle to a droplet on a rough substrate, when the wetting layer has an ordered phase, like a nematic. We estimate the conditions for which the wetting behavior of an ordered fluid can be qualitatively different from that usually found in a simple fluid. To support our general considerations, we use the Landau-de Gennes mean field approach to investigate theoretically and numerically the wetting transition of a nematic phase on a periodic triangular structured substrate.     

Nanostructures in a nematic liquid crystal

The effect of nanoobjects, molecular objects, and α particles introduced into a liquid-crystal matrix that is placed in a dc electric field is studied theoretically and experimentally. The introduced particles form a charged defect, the radius of which is much larger than the particle sizes, in the orientational structure of the liquid crystal. This defect is easily observed under an optical microscope, and its image agrees with calculated data. It is suggested that this effect be used for detection and diagnostics of small objects and for design of ionizing radiation detectors. The phenomena revealed in this work can help in producing new charged-defect-saturated liquid-crystal structures formed by introducing nanoparticles in a medium or by irradiating a medium by ionizing radiation. A nonmechanical principle of transport of nanoparticles and their regular incorporation into the lattice is implemented. The essence of this principle is control of molecular orientations in a liquid crystal by quasi-stationary electric fields.     

Electric Nusselt number characterization of electroconvection in nematic liquid crystals

We develop a characterization method of electroconvection structures in a planar nematic liquid crystal layer by a study of the electric current transport. Because the applied potential difference has a sinusoidal time dependence, we define two electric Nusselt numbers corresponding to the in-phase and out-of-phase components of the current. These Nusselt numbers are predicted theoretically using a weakly nonlinear analysis of the standard model. Our measurements of the electric current confirm that both numbers vary linearly with the distance from onset until the occurence of secondary transitions. A systematic comparison between our theoretical and experimental results, using no adjusted parameters, demonstrates moderate agreement, but discrepancies remain. Electric transport measurements during electroconvection represent a quantitative test of the standard model completely independent from optical probes. Thus, the technique described here can be a useful complement to traditional structural measurements. Received 21 January 2001 and Received in final form 1st February 2002     

Field-induced transition from homeotropic to planar geometry in the SmC* phase of an electroclinic liquid crystal

The optical and electrical behavior was investigated of a symmetric liquid crystal (LC) cell: ITO–silane–LC–silane–ITO. The silane layer induces a perfect homeotropic alignment of the molecules of the studied electroclinic liquid crystal (ELC) material, BDH 764E. A field-induced transition from the perfect homeotropic to planar orientation in the chiral smectic C (SmC*) and smectic A (SmA) phases of the ELC was observed. Optical and dielectric studies were performed for both alignment (geometry) modes. The field-induced transition from the homeotropic to planar orientation was studied vis-à-vis the high negative dielectric anisotropy obtained in the studied material. Such an ELC with large negative dielectric anisotropy and perfect homeotropic alignment may have important implications for modern LC display technology.     

Thermally enhanced optical nonlinearity in nematic liquid crystal close to phase transition temperature

This study investigates the beam profile and the liquid crystal (LC) arrangement affected by an optical field on LC thin films at a temperature close to nematic-isotropic phase transition temperature (T_NI). A combined microscopic and conoscopic technique was used in experiments as a convenient way to analyze the optical nonlinearity that is associated with the molecular configuration of nematic liquid crystal (NLC). An optical field combined with thermal enhancement enhances molecular reorientation and causes additional molecular excitation along the axis of propagation of the beam. The reorientational nonlinearity yields an undulating structure with multi-foci; the length between each pair of foci increases with time, as described.     

Laser-induced nonlinear thermal orientation effects in planar and homeotropic nematic liquid crystals

Nonlinear phenomena induced by laser in nematic liquid crystals are studied experimentally. It is shown that these phenomena are displayed in different forms depending on the initial orientation of liquid-crystal cell and laser polarization. The diffraction nature of the effects is eliminated experimentally and for their explanation the orientation-thermal mechanism is proposed.