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1.
Two new 2D Pb2(μ-4,4′-bipy)(μ-2-sb)2 coordination polymers, [Pb2(μ-4,4′-bipy)(μ-2-sb)2(DMF)] n (1) and {[Pb2(μ-4,4′-bipy)(μ-2-sb)2(H2O)2] · H2O} n (2), have been synthesized, characterized and studied by X-ray crystallography. The structural studies show the Pb atoms to have seven- and eight-coordinate holodirected geometries.  相似文献   

2.
IntroductionLinear bidentate N,N′- donor complexes havebeen extensively used in recent years to obtain thepolymeric frameworks with potential applicationprospects in different areas of material sciences,such as electrical conductivity[1] ,magnetism[2 ] ,photomechanical behaviour[3 ] and catalysis[4~ 6] .Among them,4,4′- bipyridine( bpy) has beenproven to be able to form one- dimensional poly-mers[7] ,two- dimensional layers[4] ,and three- di-mensional frameworks exhibiting the interpene-tra…  相似文献   

3.
The title compound {Cu2(pdc)2(4,4′-bipy)(H2O)(3H2O}2 1 (H2pdc = pyridine-2,6- dicarboxylic acid, also known as dipicolinic acid; 4,4′-bipy = 4,4′-bipyridine) has been synthesized by the hydrothermal reaction and its structure was determined by single-crystal X-ray diffraction. The crystal is of triclinic, space group Pī with a = 7.2278(3), b = 10.6259(4), c = 17.7614(6)A, α= 79.5990(10), β = 83.6300(10), γ = 71.8280(10)o, V = 1272.60(8)A3, C48H44Cu4N8O24, Mr = 1371.07, Z = 1, Dc = 1.789 g/cm3, μ = 1.747 mm-1, F(000) = 696, R = 0.0397 and wR = 0.1137 for 3938 observed reflections (I > 2σ(I)). There are two kinds of Cu coordination environments, and each central copper(II) atom is five-coordinated in a distorted square-based pyramidal coordination geo- metry. Four copper(II) atoms are linked by four pdc and two 4,4′-bipy ligands to form an annular rectangle structure. Extensive hydrogen-bonding interactions involving carboxylate O atoms as well as coordinated and free water molecules lead to the formation of a three-dimensional network struc- ture.  相似文献   

4.
A new metal-organic coordination polymer, namely, Zn(HTci)(4,4′-Bipy)0.5 · H2O (I) (H3Tci = tri(2-carboxyethyl)isocyanurate, 4,4′-Bipy = 4,4′-bipyridine), has been synthesized under hydrothermal conditions by the reaction of zinc nitrate, H3Tci, and 4,4′-Bipy with the presence of H2O and characterized by elemental analysis, IR and X-ray single-crystal diffraction. The X-ray diffraction analysis reveals that I crystallizes in the triclinic system, $P\bar 1$ space group. The unit cell parameters for I: a = 5.248(1), b = 12.537(2), c = 14.597(2) Å, α = 91.91(1)°, β = 91.22(2)°, γ = 95.75(1)°, V = 954.8(3) Å3, Z = 2.  相似文献   

5.
Two new supramolecular compounds [M(4,4′-bipy)2 (H2O)4] ·?(4,4′-bipy)2 ·?(3,5-daba)2 ·?8H2O (M=Zn(1) or Mn(2), 4,4′-bipy =?4,4′-bipyridine, 3,5-daba =?3,5-diaminobenzoic acid anion) were synthesized and characterized by elemental analysis and X-ray crystal diffraction. In [M(4,4′-bipy)2(H2O)4]2+, the M(II) is coordinated by two nitrogen atoms from two 4,4′-bipy molecules and four oxygen atoms from four waters to form an octahedral configuration. There exist uncoordinated 4,4′-bipy molecules, 3,5-diaminobenzolate counterions and water guests in the compounds. The 3D structures of the title supramolecular compounds are constructed by rich hydrogen bonds among [M(4,4′-bipy)2(H2O)4]2+, uncoordinated 4,4′-bipy molecules, water molecules and 3,5-daba, containing a diverting hexa-member water ring.  相似文献   

6.
A 2D ZnII(μ-4,4′-bipy) coordination polymer with 1,4-naphthalenedicarboxylate, {[Zn(μ-4,4′-bipy)(1,4-ndc)(H2O)2] · (H2O)} n , has been synthesized, characterized and studied by X-ray crystallography. The structural studies show the Zn atoms have six-coordinate geometry with a distorted octahedral environment. The 2D structure is grown by hydrogen bonds into a hybrid three-dimensional network.  相似文献   

7.
近年来,取代在5位上的间苯二甲酸(取代基为:-SO3H,-NH2,-OH,-NO2等)衍生物与过渡金属形成的配位聚合物,由于其具有新奇的结构,而且是潜在的功能材料而备受关注[1 ̄4]。Yaghi等人认为,取代基对配位聚合物的结构和性能具有重要的修饰作用[5]。因此我们在研究5-硝基间苯二甲酸、5-羟基间苯二甲酸与过渡金属形成的配位聚合物结构的同时[6,7],选择了5-氨基间苯二甲酸作为酸性配体,氨基不仅能用其氮原子与金属配位,还能形成氢键,能够提供丰富的配位方式。我们曾经报道了{[Co(4,4′-bipy)(hmbdc)(H2O)2](4,4′-bipy)(DMF)}n的合成与结构[8…  相似文献   

8.
The structures of the mixed-ligand complexes Zn(4,4-Bipy){(n-C3H7)2NCS2}2 (I) and Zn2(4,4-Bipy){(n-C3H7)2NCS2}4 (II) were determined by single crystal X-ray diffractometry (CAD-4 diffractometer, MoK radiation, 2479 and 1616 Fhkl, R = 0.0550 and 0.0523). The crystals are monoclinic with cell parameters a = 16.560(2), b = 11.423(1), c = 15.319(2) , = 94.27(1)°, V = 2889.8(6) 3, Z = 4, space group P21/c (for I) and a = 8.515(1), b = 10.965(1), c = 27.816(3) , = 95.860(1)°, V = 2583.5(5) 3, Z = 2, space group P21/n (for II). The structure of I is composed of discrete mononuclear molecules; the structure of II consists of discrete centrosymmetric binuclear molecules. The coordination polyhedra of the Zn atoms (c.n. 5) are formed by four S atoms of the two cyclic bidentate dithiocarbamate ligands and the N atom of the 4,4-Bipy ligand, which is monodentate in I and bridging bidentate in II. Molecular packings and interactions in the structures are considered.  相似文献   

9.
First representatives of dichloroamino- and chloroaminofurazans, viz., 4,4′-bis(dichloroamino)- and 4,4′-bis(chloroamino)-3,3′-azofurazans, were synthesized by the chlorination of 4,4′-diamino-3,3′-azofurazan with sodium hypochlorite in the CH2Cl2—H2O mixture.  相似文献   

10.
11.
12.
Two metal?Corganic frameworks (MOFs) of M(HBTC)(4,4??-bipy)·3DMF [M?=?Ni (for 1) and Co (for 2); H3BTC?=?1,3,5-benzenetricarboxylic acid (1,3,5-BTC); 4,4??-bipy?=?4,4??-bipyridine; DMF?=?N,N??-dimethylformamide] were synthesized by a one-pot solution reaction and a solvothermal method, respectively, and characterized by powder X-ray diffraction and FT-IR spectra. The low-temperature molar heat capacities of M(HBTC)(4,4??-bipy)·3DMF were measured by temperature-modulated differential scanning calorimetry (TMDSC) for the first time. The thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15?K were derived based on the above molar heat capacity data. Moreover, the thermal stability and the decomposition mechanism of M(HBTC)(4,4??-bipy)·3DMF were investigated by thermogravimetry analysis (TGA). The experimental results through TGA measurement demonstrate that both of the two compounds have a three-stage mass loss in air flow.  相似文献   

13.
用中温水热技术合成了(4,4′-bipyH)3[PW12O40](4,4′-bipy).7 H2O,用元素分析、X射线单晶衍射、IR、UV-vis和TG-DTA对其进行了表征.结果表明,化合物的晶体属单斜晶系,P2(1)/c空间群.标题化合物是由3个质子化的4,4′-bipy分子、一个Keggin结构的钨磷杂多阴离子[PW12O40]3-和一个4,4′-bipy分子及7个结晶水分子所组成.钨磷杂多阴离子与质子化的联吡啶及结晶水分子之间通过氢键作用,连接成无限二维层状结构,形成超分子化合物.  相似文献   

14.
A novel viologen(4,4′-bipyridinium)-based compound FeCl4(4,4′-diethyl-4,4′-bipyH) (1) (bipy = bipyridine), in which 4,4′-diethyl-4,4′-bipyH (MQ +) was generated in situ, is synthesized via the hydrothermal reaction and structurally characterized by single crystal X-ray diffraction. The crystal structure analysis reveals that the title compound features an isolated structure based on 4,4′-diethyl-4,4′-bipyH moieties and an iron atom terminally bound by four chlorine atoms. The 4,4′-diethyl-4,4′-bipyH moieties and (FeCl4)? anions are interconnected by hydrogen bonds to form a 3D supramolecular framework.  相似文献   

15.
4,4-Diiodobenzophenone was obtained by a three-stage synthesis from chloral and iodobenzene. 4,4-Bis(arylethynyl)benzophenones were synthesized by cross-coupling of 4,4-diiodobenzophenone with terminal arylethynes in the presence of a complex Pd catalyst; further oxidation of the products obtained in an iodine/DMSO medium afforded new bis(arylglyoxalyl)benzophenones.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 3, pp. 670–672, March, 1996.  相似文献   

16.
The combination of both 4,4′-bipyridine(4,4′-bipy) and dihydrogen phosphate anion ligands with copper(Ⅱ) results in the formation of a novel layered compound Cu(4,4′-bipy)2(H2PO4)2(H2O)2. The crystal structure comprises discrete neutral Cu(4,4′-bipy)2(H2PO4)2(H2O)2 units. The copper atom, located on the crystallographic twofold axis, is coordinated with two nitrogen atoms of terminal 4,4′-bipy ligands and two water molecules at the equatorial positions, and two dihydrogen phosphate oxygen atoms at the axial positions, forming an elongated octahedron. The complex is a two-dimensional distorted rhomboidal network possessing two kinds of rhomboids with dimensions of ca. 1.6792 nm×0.3203 nm and 1.2778 nm×0.3198 nm, respectively. The two-dimensional networks are stacked parallelly on each other along c-axis to give an extended three-dimensional channel network with an interlayer distance of ca. 0.5030 nm. Crystal data: triclinic, space group P-1, a=1.0253(2) nm, b=1.4501(3) nm, c=0.79715(16) nm, α=97.91(3)°, β=90.99(3)°, γ=85.54(3)°, V=1.1703(4) nm3, Z=2, R=0.0892, wR=0.2451.  相似文献   

17.
18.
A new 2D coordination polymer, [Cd2(pzdc)2(4,4′-bpy)(H2O)2] n (1) (pzdc = pyrazine-2,3-dicarboxylic acid, 4,4′-bpy = 4,4′-bipyridine), has been hydrothermally synthesized and characterized by elemental analyses, IR spectra and single crystal X-ray diffraction. X-ray diffraction analysis reveals that 1 features an interesting 2D stair-like layer with linear [Cd2(pzdc)2(H2O)2] n ribbons linked by 4,4′-bpy bridges. Furthermore, these layers are packed in an ABAB arrangement to give a 3D supramolecular network via hydrogen bonding and π–π packing interactions. Compound 1 displays strong fluorescent emission in the solid state at room temperature.  相似文献   

19.
Treatment of [MI2(CO)3(NCMe)2] with two equivalents of 4,4-bipyridine (4,4-bipy) in CH2Cl2 at room temperature gave the MeCN displaced products, [MI2(CO)3(4,4-bipy-N)2] (1) and (2). Equimolar amounts of [MI2(CO)3(NCMe)2] and L (L = PPh3, AsPh3 or SbPh3) react to give [MI2(CO)3(NCMe)L], which when reacted in situ with 4,4-bipy yield the new complexes, [MI2(CO)3(4,4-bipy-N)L] (3)(8). Reaction of equimolar quantities of [WI2(CO)(NCMe)( 2-RC2R)2] (R = Me or Ph) and 4,4-bipy gave the new bis(alkyne) complexes, [WI2(CO)(4,4-bipy-N)( 2-RC2R)2] (9) and (10). Treatment of [MI2(CO)3(NCMe)2] with two equivalents of (9) or (10) in CH2Cl2 at room temperature affords the bimetallic complexes, [MI2(CO)3{WI2(CO)(4,4-bipy-N,N)( 2-RC2R)2}2] (11)(14). Equimolar quantities of [MI2(CO)3(NCMe)(PPh3)] (prepared in situ) and (9) or (10), react to give the 4,4-bipy-bridged complexes, [MI2(CO)3{WI2(CO)(4,4-bipy-N,N)( 2-RC2R)2}(PPh3)] (15)(18). All the new complexes, (1)(18) were characterised by elemental analysis (C, H and N), i.r. and 1H-n.m.r. spectroscopy.  相似文献   

20.
A fluorinated tetraphenylbenzidine derivative, N,N′-diphenyl-N,N′-bis(2-fluorophenyl)-1,1′-biphenyl-4,4′-diamine (C36H26F2N2, Mr = 524.59) was synthesized via the palladiumcatalyzed Buchwald-Hartwig reaction of N,N′-diphenyl-1,1′-biphenyl-4,4′-diamine with 2-fluoroiodobenzene (yield: 75%) and structurally characterized. It crystallizes in monoclinic, space group P21/n with a = 9.820(7), b = 14.305(11), c = 10.233(8) , β = 108.973(9)o, V = 1359.3(18) 3, Z = 2, Dc = 1.282 g/cm3, μ(MoKα) = 0.084 mm-1, F(000) = 548, S = 1.018, the final R = 0.0439 and wR = 0.0928. It presents a linear centrosymmetric framework constituted by a linkage of biphenyl as a bridge and two fluorinated diphenylamine moieties. The UV-Vis absorption and fluorescence spectra of the title compound were also investigated. This compound emits intense blue fluorescence with a peak wavelength of 406 nm in film.  相似文献   

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