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采用金刚石对顶砧高压装置,在室温下对正辛烷(C8H18)进行了原位高压拉曼光谱研究,实验的最高压力为13GPa。在实验的压力范围内,正辛烷的拉曼峰位随压力的升高均向高频移动,峰强逐渐减弱,峰形变宽。常态为液态的正辛烷在0.8 GPa时,拉曼频移随压力的变化曲线出现了拐点,发生了液-固相变;在6.8 GPa时,伴随着原拉曼峰的消失或劈裂,以及新拉曼峰的出现,此时正辛烷可能发生了固-固相变。该相变压力低于已有的低碳数正烃烷的压致相变结果。正烃烷的压致相变压力点,具有随着结构链长的增加,其相变压力降低的规律。 相似文献
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乙丙共聚物的组成和序列分布的红外光谱测定 总被引:1,自引:0,他引:1
用红外光谱法测定了乙丙共聚物的组成和序列分布.以无规聚丙稀作标样,所得吸光度方程测定乙丙共聚物的组成的平均相对误差在±1.57%。选用无规聚丙稀、2,5-二甲基已烷、鲨烷和正十四碳烷作模型化合物测定乙丙共聚物的序列分布,所建立的吸光度方程组的系数与文献值一致。 相似文献
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圆管内潜热型功能流体对流换热的实验研究 总被引:10,自引:1,他引:9
本文实验研究了由正十四烷和尿素甲醛树脂制成的相变微胶囊和水混合组成的潜热型功能流体流过等热流圆管时的对流换热特性。相变微胶囊的加入可以显著增强流体与壁面间的对流换热,显著降低壁面温度和流体温度;在融化段对流换热系数呈增加分布,流体和壁面温度各自基本稳定在相应的温度值。强化对流换热的效果主要在融化段,并随流体中相变微胶囊浓度的增大而增强,也随R-eynolds数的增大而增强。 相似文献
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玻璃化转变温度(Tg)是聚合物重要的特性参数,压缩CO2环境中聚合物的玻璃化转变温度的测定,更是超临界流体技术在聚合物科学领域中成功应用的前提条件。根据蠕变柔量实验原理,自建一套测定高压环境下玻璃化转变温度的实验装置。利用该装置对聚对苯二甲酸乙二醇酯(PET)、聚苯乙烯(PS)、聚氯乙烯(PVC)以及聚甲基丙烯酸甲酯(PMMA)在大气中及压缩CO2环境中的Tg进行了测定。设定实验的平衡吸附温度为室温,平衡吸附压力范围分别为:PET,0~3.5 MPa;PS,0~11.0 MPa;PVC,0~9.0 MPa;PMMA,0~4.5 MPa。在大气中测定的结果与文献中的结果相吻合,表明所设计的实验方法及实验装置是可靠并有效的,可用于高压环境下聚合物的玻璃化转变温度的测定。从压缩CO2中的聚合物Tg测定结果可以看出,CO2对聚合物具有较明显的溶胀、增塑作用,可显著降低聚合物的Tg。 相似文献
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采用格子Boltzmann方法研究了孔隙尺度下多孔介质内含流固溶解反应的互溶驱替过程,重点研究了被驱替流体与驱替流体黏性差异较大的情况下,溶解反应引起的多孔介质内部结构变化对驱替过程的影响;定量分析了不同达姆科勒数及佩克莱数下多孔介质孔隙率和驱替过程驱替效率随时间的演变.研究结果表明:达姆科勒数较大时,溶解反应的发生会在多孔介质内部生成虫洞,导致一部分被驱替流体不能被波及,驱替流体沿虫洞离开多孔介质,造成驱替效率的减少.在此基础上,随着达姆科勒数的增大,孔隙率变化越大,生成的虫洞越宽,最终驱替效率变大,但仍小于无溶解反应时的驱替效率;随着佩克莱数的增大,指进增长速度越快,孔隙率变化越小,驱替效率越小. 相似文献
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本文构造了一种带权的六点格式,讨论了它的稳定性条件,证明了这种格式的解对微分方程的真解具有单侧逼近的性质;当适当选取权数θ=θ0时,这种格式是一种四阶耗散格式,不仅数值耗散很小,而且满足稳定性条件,不出现非物理振荡;还证明了C.J.Chen的有限分析格式[1]在一定条件下是这种带权格式的一个特殊情形,因此也具有单侧逼近性质;最后给出了几个算例说明上述性质。 相似文献
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本文在详细分析了对流扩散过程物理特性的基础上,按对流扩散过程的物理要求应用特征方法处理对流项、以能充分描述扩散效应的有限分析方法处理扩散项,建立了一种合乎对流扩散物理要求的、无条件L∞稳定的、数值模拟对流扩散物理现象的特征有限分析方法;并就非线性情况证明了特征有限分析方法的收敛性、给出了解的误差估计。最后的数值实验表明它能很好地模拟对流扩散过程,数值粘性小,精度高,稳定性好,并且没有伪振荡现象发生。 相似文献
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基于Level Set方法的双层流体热毛细对流的数值研究 总被引:1,自引:0,他引:1
基于Level Set方法建立了双层流体热毛细对流的数学模型,通过变密度二阶投影法求解控制方程,C-N隐式技术用于扩散项更新,三阶龙格库塔技术用于对流项的更新,采用连续表面张力模型(CSF)模拟Marangoni效应。三维数值模拟了微重力环境下双层流体系统中交界面变形的热毛细对流,结果显示,在Marangoni效应的作用下,交界面在热端凸起,在冷端凹陷;随着Marangoni数增大,双层流体交界面的变形率随之增大,对流强度也随之增大;交界面与壁面的接触条件会影响热毛细对流的流场和温度场。 相似文献
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In this paper a dual-compact scheme, which accommodates a better dispersion relation for the convective terms shown in the transport equation, is proposed to enhance the convective stability of the convection–diffusion equation by virtue of the increased dispersive accuracy. The dispersion-relation-preserving compact scheme has been rigorously developed within the three-stencil point framework through the dispersion and dissipation analyses. To verify the proposed method, several problems that are amenable to the exact and benchmark solutions will be investigated. The results with good rates of convergence are demonstrated for all the investigated problems. 相似文献
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The results of the experiments with solidification in space imply that the effect of gravity conditions should be included into the theoretical and computational models of solidification processes. The paper presents the results of computational simulation of binary-alloy solidification where the gravity acts as the driving force of chemical diffusion. A simplified version of a complex theoretical model constructed by the same authors was implemented on a computer and used to simulate the solidification of a two-dimensional sample of the pseudo-binary mercury-cadmiumtelluride alloy. The computational model was used to study the influence of gravity on the chemical diffusion in the sample. The results of our simulations have shown that the influence of gravity on the diffussion of the solute is a second-order effect only. Therefore, to describe the influence of the gravitational field on solidification processes adequately we would need a more complex model involving convective phenomena in the melt as well. In addition, a series of numerical experiments were performed to consider how the accuracy with which the material parameters had been determined affects the computed temperature and concentration fields. The results imply that the simulation of this kind could be seriously biased by insufficient accuracy in determining the primary material properties. Moreover, the results show that neglecting the thermal diffusion and the temperature and concentration dependence of the material parameters may lead to serious errors. 相似文献
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超声调制漫射光子自相关的Monte Carlo模拟 总被引:2,自引:2,他引:0
本文首次用Monte Carlo方法研究了超声调制生物介质中漫射光子的时间自相关性质,讨论了超声参量、运动参量和散射参量对自相关函数的影响.正常生物组织和病变生物组织的自相关函数有明显的差别,超声调制自相关函数为光学医学诊断提供一种新参考. 相似文献
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Long-Time Dynamic Response and Stochastic Resonance of Subdiffusive Overdamped Bistable Fractional Fokker--Planck Systems
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To explore the influence of anomalous diffusion on stochastic resonance (SR) more deeply and effectively, the method of moments is extended to subdiffusive overdamped bistable fractional Fokker-Planck systems for calculating the long-time linear dynamic response. It is found that the method of moments attains high accuracy with the truncation order N = 10, and in normal diffusion such obtained spectral amplification factor (SAF) of the first-order harmonic is also confirmed by stochastic simulation. Observing the SAF of the odd-order harmonics we find some interesting results, i.e. for smaller driving frequency the decrease of subdiffusion exponent inhibits the stochastic resonance (S.R), while for larger driving frequency" the decrease of subdiffusion exponent enhances the second SR peak, but the first one vanishes and a double SR is induced in the third-order harmonic at the same time. These observations suggest that the anomalous diffusion has important influence on the bistable dynamics. 相似文献
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Several boundary layer flowswith heat and mass transfer problems do arise from a pebble bed nuclear reactor system. In this study, we examine the combined effects of variable thermal conductivity, thermal diffusion, diffusion thermo, heat source, chemical reaction and fluid rotation on hydromagnetic mixed convective flow with heat and mass transfer over a vertical plate embedded in porous medium. The governing partial differential equations have been transformed into a system of ordinary differential equations by employing the similarity transformation and solved numerically using the Runge–Kutta–Fehlberg method with a shooting technique. Pertinent results obtained are presented graphically and in tabular form with respect to variation in various thermophysical parameters. A comparison of the special case of this study with the previously published work shows excellent agreement. 相似文献
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P. Korpiun R. Osiander H. Schmitt W. Micheler 《Applied Physics A: Materials Science & Processing》1991,52(4):223-233
The temperature oscillation accompanying the photoacoustic effect generates a periodic variation of the vapor pressure of a liquid. The propagation of the oscillating concentration of the vapor in the inert cell gas (air) is described by a mass diffusion wave on which a convective motion of the gas is superposed. The diffusion wave characterized by the diffusion coefficient of the cell gas alone can be measured by the Mirage effect, whereas a microphone detects the total mass flux including the convective flux, which increases with temperature. On approaching the boiling temperature, the convective flow will govern the oscillating transport of mass. The photoacoustic signal is determined directly from the flux of heat and mass at the boundary between liquid and gas using the Gauss' divergence theorem. We have found that the temperature behaviour of the amplitude and phase angle of the photoacoustic signal depends on the length of the gas column in the cell. The contribution of thermal expansion to the photoacoustic signal is considered using the composite piston model. The results of the calculations agree fairly well with the experimental data. 相似文献